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1. 发明授权

US07214470B2 Fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and fluorine-containing polymer prepared by polymerization of same 有权
标题翻译：具有羟基或氟代烷基羰基的含氟乙烯性单体和通过聚合制备的含氟聚合物
公开(公告)号：US07214470B2
公开(公告)日：2007-05-08
申请号：US10644953
申请日：2003-08-21
申请人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
发明人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
IPC分类号： G03F7/038
CPC分类号： G03F7/091 , C07C33/423 , C07C43/178 , C07C45/45 , C07C49/227 , C07C49/255 , C08F16/04 , C08F16/34 , C08F216/04 , G03F7/0046 , G03F7/0382 , G03F7/0392
摘要： There are provided a fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and represented by the formula (1): and the formula (14): respectively, wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, Cl or CF3; Rf1 and Rf2 are the same or different and each is a perfluoroalkyl group having 1 to 20 carbon atoms; Rf3 is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having ether bond which has 1 to 100 carbon atoms and the sum of carbon atom and oxygen atom of two or more; a is 0 or 1, a fluorine-containing polymer having a structural unit of the above-mentioned monomer and a composition for a photoresist. The monomer has good polymerizability, particularly radical polymerizability, and the polymer obtained by polymerizing the monomer has excellent optical characteristics and is useful as a base polymer for an antireflection film and for a composition for a resist.
摘要翻译：提供具有羟基或氟代烷基羰基并由式（1）表示的含氟乙烯性单体：和式（14）：其中X 1和X 2 相同或不同，分别为H或F; X 3是H，F，Cl或CF 3; Rf 1和Rf 2相同或不同，各自为具有1至20个碳原子的全氟烷基; Rf 3是具有1〜40个碳原子的含氟亚烷基或具有1〜100个碳原子的醚键的含氟亚烷基，碳原子和氧原子之和为2 或者更多; a为0或1，具有上述单体的结构单元的含氟聚合物和光致抗蚀剂的组合物。单体具有良好的聚合性，特别是自由基聚合性，通过聚合单体获得的聚合物具有优异的光学特性，可用作抗反射膜和抗蚀剂组合物的基础聚合物。

2. 发明申请

US20070172763A1 Fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and fluorine-containing polymer prepared by polymerization of same 审中-公开
公开(公告)号：US20070172763A1
公开(公告)日：2007-07-26
申请号：US11727908
申请日：2007-03-29
申请人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
发明人： Takayuki Araki , Yuzo Komatsu , Meiten Koh
IPC分类号： G03C1/00 , C08F12/20 , C07C43/17
CPC分类号： G03F7/091 , C07C33/423 , C07C43/178 , C07C45/45 , C07C49/227 , C07C49/255 , C08F16/04 , C08F16/34 , C08F216/04 , G03F7/0046 , G03F7/0382 , G03F7/0392
摘要： There are provided a fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and represented by the formula (1): and the formula (14): respectively, wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, Cl or CF3; Rf1 and Rf2 are the same or different and each is a perfluoroalkyl group having 1 to 20 carbon atoms; Rf3 is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having ether bond which has 1 to 100 carbon atoms and the sum of carbon atom and oxygen atom of two or more; a is 0 or 1, a fluorine-containing polymer having a structural unit of the above-mentioned monomer and a composition for a photoresist. The monomer has good polymerizability, particularly radical polymerizability, and the polymer obtained by polymerizing the monomer has excellent optical characteristics and is useful as a base polymer for an antireflection film and for a composition for a resist.

3. 发明授权

US07682753B2 Solid electrolyte comprising fluorine-containing polymer having fluorine-containing ether chains 有权
标题翻译：含有含氟醚链的含氟聚合物的固体电解质
公开(公告)号：US07682753B2
公开(公告)日：2010-03-23
申请号：US11096056
申请日：2005-04-01
申请人： Meiten Koh , Takayuki Araki
发明人： Meiten Koh , Takayuki Araki
IPC分类号： H01M10/40
CPC分类号： G02F1/1508 , H01B1/122 , H01G9/025 , H01G9/028 , H01G9/038 , H01G11/56 , H01M8/0289 , H01M8/1025 , H01M8/1039 , H01M8/1044 , H01M8/1048 , H01M8/1072 , Y02E60/13 , Y02P70/56
摘要： There is provided a fluorine-containing polymer solid electrolyte which has an excellent ion-conducting property, is high in oxidation resistance, is stable electrochemically and thermally, has sufficient strength and is applicable to various electrochemical devices. The electrolyte comprises (A) a non-crystalline fluorine-containing polymer having, in a trunk chain and/or side chain of the polymer molecule, a structural unit D having five or more chained units derived from a fluorine-containing ether, (B) an electrolytic compound and (C) a solvent, and has an ionic conductivity of from 10−10 to 101 S/cm measured at 25° C. by an alternating current complex impedance method. The electrolyte is useful for various electrochemical devices.
摘要翻译：提供了具有优异的离子传导性，耐氧化性高，电化学和热稳定性好的含氟聚合物固体电解质，具有足够的强度并适用于各种电化学装置。电解质包含（A）在聚合物分子的主链和/或侧链中具有5个以上来自含氟醚的链状单元的结构单元D（B）的非结晶性含氟聚合物）电解化合物和（C）溶剂，并且通过交流复阻抗法在25℃下测得的离子电导率为10-10至101S / cm。电解质可用于各种电化学装置。

4. 发明申请

US20070179263A1 Functional material comprising fluorine-containing compound 审中-公开
公开(公告)号：US20070179263A1
公开(公告)日：2007-08-02
申请号：US10591860
申请日：2005-03-03
申请人： Meiten Koh , Mamoru Miyata , Takayuki Araki
发明人： Meiten Koh , Mamoru Miyata , Takayuki Araki
IPC分类号： C08F214/18 , C07C215/28
CPC分类号： H01M14/005 , C07C235/16 , C07D239/42 , C07D249/14 , C07D251/18 , C07D251/22 , C07D251/24 , C08F214/18 , C08F216/1408 , C10N2220/04
摘要： There is provided an ionic liquid type functional material which is useful for a lubricant, acid-removing agent, various ionic liquid materials, electrolyte for solar cell and actuator material. The ionic liquid type functional material contains an aromatic compound which has a fluorine-containing ether chain and is represented by the formula (1): [Ra-DmRy (1)wherein -D- is a fluoroether unit represented by the formula (1-1): O—Rn or R—On (1-1) in which R is at least one selected from divalent fluorine-containing alkylene groups having 1 to 5 carbon atoms in which at least one of hydrogen atoms is replaced by fluorine atom; n is an integer of from 1 to 20; when m is not less than 2, two or more of D may be the same or different; Ra is a monovalent organic group which has 1 to 20 carbon atoms and does not contain D; when m is not less than 2, two or more of Ra may be the same or different; m is an integer of from 1 to 4; Ry is a mono-, di-, tri- or tetra-valent organic group having 2 to 30 carbon atoms which has at least one selected from a basic functional group Y1 and/or a salt Y2 of the basic functional group and contains an aromatic ring structure, provided that a unit of —O—O— is not contained in the formulae (1) and (1-1).

5. 发明申请

US20050170255A1 Solid electrolyte comprising fluorine-containing polymer having fluorine-containing ether chains 有权
标题翻译：含有含氟醚链的含氟聚合物的固体电解质
公开(公告)号：US20050170255A1
公开(公告)日：2005-08-04
申请号：US11096056
申请日：2005-04-01
申请人： Meiten Koh , Takayuki Araki
发明人： Meiten Koh , Takayuki Araki
IPC分类号： C08F216/14 , G01N27/26 , G02F1/15 , H01B1/06 , H01B1/12 , H01G9/025 , H01G9/028 , H01G9/032 , H01G9/035 , H01G11/14 , H01G11/54 , H01G11/56 , H01G11/84 , H01M8/02 , H01M8/10 , H01M10/05 , H01M10/0565 , H01M10/40
CPC分类号： G02F1/1508 , H01B1/122 , H01G9/025 , H01G9/028 , H01G9/038 , H01G11/56 , H01M8/0289 , H01M8/1025 , H01M8/1039 , H01M8/1044 , H01M8/1048 , H01M8/1072 , Y02E60/13 , Y02P70/56
摘要： There is provided a fluorine-containing polymer solid electrolyte which has an excellent ion-conducting property, is high in oxidation resistance, is stable electrochemically and thermally, has sufficient strength and is applicable to various electrochemical devices. The electrolyte comprises (A) a non-crystalline fluorine-containing polymer having, in a trunk chain and/or side chain of the polymer molecule, a structural unit D having five or more chained units derived from a fluorine-containing ether, (B) an electrolytic compound and (C) a solvent, and has an ionic conductivity of from 10−10 to 101 S/cm measured at 25° C. by an alternating current complex impedance method. The electrolyte is useful for various electrochemical devices.
摘要翻译：提供了具有优异的离子传导性，耐氧化性高，电化学和热稳定性好的含氟聚合物固体电解质，具有足够的强度并适用于各种电化学装置。电解质包含（A）在聚合物分子的主链和/或侧链中具有5个以上来自含氟醚的链状单元的结构单元D（B）的非结晶性含氟聚合物）电解化合物和（C）溶剂，并且在25℃下通过交替地测量的离子电导率为10 -10 -10 10 S / cm 当前复阻抗法。电解质可用于各种电化学装置。

6. 发明申请

US20090291369A1 SOLID ELECTROLYTE COMPRISING FLUORINE-CONTAINING POLYMER HAVING FLUORINE-CONTAINING ETHER CHAINS 有权
标题翻译：包含含荧氟醚的含氟聚合物的固体电解质
公开(公告)号：US20090291369A1
公开(公告)日：2009-11-26
申请号：US12471860
申请日：2009-05-26
申请人： Takayuki Araki , Meiten Koh
发明人： Takayuki Araki , Meiten Koh
IPC分类号： H01M6/18 , H01G9/028
CPC分类号： H01G9/028 , H01B1/122 , H01G9/038 , H01G11/56 , H01M8/0289 , H01M8/1023 , H01M8/1039 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要： There is provided a fluorine-containing polymer solid electrolyte which has an excellent ion-conducting property, is high in oxidation resistance, is stable electrochemically and thermally, has sufficient strength and is applicable to various electrochemical devices. The electrolyte comprises (I) a non-crystalline fluorine-containing polymer which has a polar nonionic functional group and has, in a side chain of the polymer molecule, a structural unit D having 1 to 4 units derived from a fluorine-containing ether in the form of continuous chain, (II) an electrolytic compound and as case demands, (III) a solvent. The electrolyte has an ionic conductivity of from 10−10 to 101 S/cm measured at 25° C. by an alternating current complex impedance method, and is useful for various electrochemical devices.
摘要翻译：提供了具有优异的离子传导性，耐氧化性高，电化学和热稳定性好的含氟聚合物固体电解质，具有足够的强度并适用于各种电化学装置。电解质包含（I）具有极性非离子官能团的非结晶性含氟聚合物，在聚合物分子的侧链中，具有1〜4个由含氟醚衍生的单元的结构单元D 连续链的形式，（II）电解化合物，如果需要，（III）溶剂。电解质在25℃下通过交流复阻抗法测得的10-10至101S / cm的离子电导率，并且可用于各种电化学装置。

7. 发明申请

US20050287471A1 Novel fluorine-containing polymer having acid-reactive group and chemically amplifying type photoresist composition prepared from same 审中-公开
标题翻译：具有酸反应性基团的新型含氟聚合物和由其制备的化学放大型光致抗蚀剂组合物
公开(公告)号：US20050287471A1
公开(公告)日：2005-12-29
申请号：US11033954
申请日：2005-01-13
申请人： Takayuki Araki , Meiten Koh , Yoshito Tanaka , Takuji Ishikawa , Hirokazu Aoyama , Tetsuo Shimizu
发明人： Takayuki Araki , Meiten Koh , Yoshito Tanaka , Takuji Ishikawa , Hirokazu Aoyama , Tetsuo Shimizu
IPC分类号： G03F7/004 , G03F7/038 , G03F7/039 , G03F7/075 , G03C1/76
CPC分类号： G03F7/039 , G03F7/0045 , G03F7/0046 , G03F7/0382 , G03F7/0392 , G03F7/0395 , G03F7/0397 , G03F7/0758 , Y10S430/106 , Y10S430/108
摘要： There is provided a novel fluorine-containing polymer having an acid-reactive group which has a high transparency against energy rays (radioactive rays) in a vacuum ultraviolet region (157 nm), and further there are provided a material for fluorine-containing base polymer prepared from the polymer and suitable for a photoresist and a chemically amplifying type resist composition obtained therefrom. The polymer has a number average molecular weight of from 1,000 to 1,000,000 and represented by the formula: -(M1)-(M2)-(A)-, wherein M1 is a structural unit having an acid-labile or acid-degradable functional group, M2 is a structural unit of fluorine-containing acryl ester, A is a structural unit derived from other copolymerizable monomer, the percent by mole ratio M1/M2 is 1 to 99/99 to 1 and the polymer comprises from 1 to 99% by mole of the structural unit M1, from 1 to 99% by mole of the structural unit M2 and from 0 to 98% by mole of the structural unit A1. The material for fluorine-containing base polymer comprises a fluorine-containing polymer having an acid-reactive group such as the above-mentioned polymer and is suitable for a photoresist, and the chemically amplifying type resist composition is obtained from those polymer and material.
摘要翻译：提供了一种具有酸反应性基团的新型含氟聚合物，其具有对真空紫外区域（157nm）中的能量射线（放射线）的高透明性，并且还提供了含氟基础聚合物由聚合物制备并适用于由其获得的光致抗蚀剂和化学放大型抗蚀剂组合物。聚合物的数均分子量为1,000〜1,000,000，由下式表示： - （M1） - （M2） - （A） - ，其中M1是具有酸不稳定性或酸可降解官能团的结构单元 M2是含氟丙烯酸酯的结构单元，A是来自其它可共聚单体的结构单元，M1 / M2的摩尔比为1〜99/99〜1，聚合物的含量为1〜99％结构单元M1的摩尔数，结构单元M2的1〜99摩尔％和结构单元A1的0〜98摩尔％。含氟基础聚合物的材料包括具有酸反应性基团的含氟聚合物如上述聚合物，并且适用于光致抗蚀剂，化学放大型抗蚀剂组合物由那些聚合物和材料获得。

8. 发明申请

US20050191578A1 Process for preparing fluorine-containing polymer and photoresist composition 审中-公开
标题翻译：制备含氟聚合物和光致抗蚀剂组合物的方法
公开(公告)号：US20050191578A1
公开(公告)日：2005-09-01
申请号：US11104554
申请日：2005-04-13
申请人： Takayuki Araki , Takuji Ishikawa , Meiten Koh , Minoru Toriumi
发明人： Takayuki Araki , Takuji Ishikawa , Meiten Koh , Minoru Toriumi
IPC分类号： C08F4/34 , C08F8/00 , C08F214/18 , G03C1/492 , G03F7/004 , G03F7/039
CPC分类号： C08F214/18 , C08F8/00 , C08F2800/20 , G03C1/492 , G03F7/0046 , G03F7/0392 , C08F214/26
摘要： There is provided a process for preparing a fluorine-containing polymer for resist which is excellent in transparency in a vacuum ultraviolet region, comprises a structural unit derived from a fluorine-containing ethylenic monomer and/or a structural unit derived from a monomer which can provide an aliphatic ring structure in the polymer trunk chain and may have a fluorine atom, and has an acid-reactive group Y1 reacting with an acid or a group Y2 which can be converted to the acid-reactive group Y1, in which the fluorine-containing ethylenic monomer and/or the monomer which can provide an aliphatic ring structure in the polymer trunk chain are subjected to radical polymerization by using an organic peroxide represented by the formula (1): wherein R50 and R51 are the same or different and each is a hydrocarbon group having 1 to 30 carbon atoms which may have ether bond (an atom at an end of bond is not oxygen atom); p1 and p2 are the same or different and each is 0 or 1; p3 is 1 or 2, and also there is provided a photoresist composition comprising the obtained polymer. The fluorine-containing polymer is excellent in transparency in a vacuum ultraviolet region, and can form an ultra fine pattern as a polymer for a photoresist, particularly for a F2 resist.
摘要翻译：提供了一种制备真空紫外线区域的透明度优异的抗蚀剂用含氟聚合物的方法，包括衍生自含氟乙烯性单体的结构单元和/或衍生自单体的结构单元，其可以提供聚合物主链中的脂族环结构，并且可以具有氟原子，并且具有与酸或Y 2的基团反应的酸反应性基团Y 1，其可以是转化为酸反应性基团Y 1，其中可以在聚合物主链中提供脂族环结构的含氟乙烯性单体和/或单体通过使用由式（1）表示的有机过氧化物：其中R 50和R 51相同或不同，并且各自为具有1至30个碳原子的烃基，其可以具有醚键（键的末端的原子不是氧原子）; p1和p2相同或不同，分别为0或1; p3为1或2，并且还提供包含所得聚合物的光致抗蚀剂组合物。含氟聚合物在真空紫外区域的透明度优异，并且可以形成作为光致抗蚀剂的聚合物的超细图案，特别是用于F2抗蚀剂。

9. 发明申请

US20060204893A1 Novel fluorine-containing polymer, resist composition prepared from same and novel fluorine-containing monomer 审中-公开
公开(公告)号：US20060204893A1
公开(公告)日：2006-09-14
申请号：US11434917
申请日：2006-05-17
申请人： Takayuki Araki , Takuji Ishikawa , Meiten Koh
发明人： Takayuki Araki , Takuji Ishikawa , Meiten Koh
IPC分类号： G03C1/76
CPC分类号： C07C25/13 , C07C25/18 , C07C25/22 , C07C31/38 , C07C33/423 , C07C33/44 , C07C35/52 , C07C43/313 , C07C45/63 , C07C49/167 , C07C2601/08 , C07C2602/42 , C07F9/5407 , C07F9/5435 , C07F9/5442 , C07F9/5449 , C07F9/5456 , C07F9/59 , C08F8/00 , C08F214/18 , C08F214/186 , C08F2800/10 , C08F2800/20 , G03F7/0045 , G03F7/0046 , G03F7/0382 , G03F7/0392 , G03F7/0395 , Y02P20/55 , Y10S430/106 , Y10S430/108 , C08F214/265 , C08F232/04 , C08F234/00 , C08F220/22
摘要： There is provided a fluorine-containing copolymer having an aliphatic monocyclic structure in the polymer trunk chain which has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (Ma): -(M1)-(M2a)-(N)- (Ma) in which the structural unit M1 is a structural unit derived from an ethylenic monomer having 2 or 3 carbon atoms and at least one fluorine atom, the structural unit M2a is at least one structural unit which introduces an aliphatic monocyclic structure in the polymer trunk chain and is represented by the formula (a): wherein R1 is at least one hydrocarbon group selected from the group consisting of a divalent hydrocarbon group having 1 to 8 carbon atoms and constituting a ring which may be further substituted with a hydrocarbon group or a fluorine-containing alkyl group and a divalent hydrocarbon group having ether bond which has the sum of carbon atoms and oxygen atoms of 2 to 8, constitutes a ring and may be further substituted with a hydrocarbon group or a fluorine-containing alkyl group; R2 is an alkylene group which has 1 to 3 carbon atoms and constitutes a ring; R3 and R4 are the same or different and each is a divalent alkylene group which has 1 or 2 carbon atoms and constitutes a ring; n1, n2 and n3 are the same or different and each is 0 or 1, the structural unit N is a structural unit derived from a monomer copolymerizable with the monomers to introduce the structural units M1 and M2a, and the structural units M1, M2a and N are contained in amounts of from 1 to 99% by mole, from 1 to 99% by mole and from 0 to 98% by mole, respectively. The fluorine-containing polymer possesses excellent dry etching resistance and transparency in a vacuum ultraviolet region.

10. 发明授权

US08034490B2 Solid electrolyte comprising fluorine-containing polymer having fluorine-containing ether chains 有权
标题翻译：含有含氟醚链的含氟聚合物的固体电解质
公开(公告)号：US08034490B2
公开(公告)日：2011-10-11
申请号：US12471860
申请日：2009-05-26
申请人： Takayuki Araki , Meiten Koh
发明人： Takayuki Araki , Meiten Koh
IPC分类号： H01M10/40
CPC分类号： H01G9/028 , H01B1/122 , H01G9/038 , H01G11/56 , H01M8/0289 , H01M8/1023 , H01M8/1039 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要： There is provided a fluorine-containing polymer solid electrolyte which has an excellent ion-conducting property, is high in oxidation resistance, is stable electrochemically and thermally, has sufficient strength and is applicable to various electrochemical devices. The electrolyte comprises (I) a non-crystalline fluorine-containing polymer which has a polar nonionic functional group and has, in a side chain of the polymer molecule, a structural unit D having 1 to 4 units derived from a fluorine-containing ether in the form of continuous chain, (II) an electrolytic compound and as case demands, (III) a solvent. The electrolyte has an ionic conductivity of from 10—10 to 101 S/cm measured at 25° C. by an alternating current complex impedance method, and is useful for various electrochemical devices.
摘要翻译：提供了具有优异的离子传导性，耐氧化性高，电化学和热稳定性好的含氟聚合物固体电解质，具有足够的强度并适用于各种电化学装置。电解质包含（I）具有极性非离子官能团的非结晶性含氟聚合物，在聚合物分子的侧链中，具有1〜4个由含氟醚衍生的单元的结构单元D 连续链的形式，（II）电解化合物，如果需要，（III）溶剂。电解质在25℃下通过交流复阻抗法测得的10-10至101S / cm的离子电导率，并且可用于各种电化学装置。

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