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    • 4. 发明授权
    • Pyrazole derivative and herbicide containing it
    • 吡唑衍生物和含有它的除草剂
    • US4948887A
    • 1990-08-14
    • US168139
    • 1988-03-14
    • Masatoshi BabaTakuya KakutaNorio TanakaEiichi OyaTakashi IkaiTsutomu NawamakiShigeomi Watanabe
    • Masatoshi BabaTakuya KakutaNorio TanakaEiichi OyaTakashi IkaiTsutomu NawamakiShigeomi Watanabe
    • C07D231/20A01N43/56A01P13/00C07C65/21C07C317/46C07C317/48C07C323/62C07C323/63C07D231/22C07D231/24C07D231/30C07D231/36C07D405/12C07D409/12C07F7/18C07F9/6503
    • C07D231/22A01N43/56C07D231/24
    • A pyrazole derivative having the formula: ##STR1## wherein A is alkyl, alkenyl or alkynyl; B is hydrogen, alkyl, halogen, haloalkyl, alkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl or alkoxycarbonyl; X is alkyl, alkoxy, halogen, nitro, cyano, haloalkyl, alkoxyalkyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl substituted by hydrogen or alkyl, haloalkoxy, alkylthio or alkylthioalkyl; Y is --COOR1 (wherein R1 is hydrogen, alkyl, etc.), --COO--L--OR1 (wherein L is alkylene which may be substituted), --COO--L--R2 (wherein R2 is phenyl group which may be substituted), --COO--M (wherein M is 3 to 6-membered alicyclic residue containing not more than 2 sulfur or oxygen atoms), --COO--L--M, --COO--L--O--L--R2, --COO--L--S(O).sub.n --CON (R3) (R4) (wherein each of R3 and R4 is hydrogen, alkyl, etc.), a --CON--(CH.sub.2).sub.n, ##STR2## wherein R5 is alkyl), ##STR3## --CONHSO.sub.2 CH.sub.3, --CONHSO.sub.2 CF.sub.3, --COO--L--N(R3) (R4), --COO--L--CO--R1, --COO--L--CO--O--R1, --COO--L--CN, --Coo--L--NO.sub.2 --COOSi (R5).sub.3, --COO--N.dbd.(R6) (R7) (wherein each of R6 and R7 is alkyl), --COO--N.dbd.C--(CH.sub.2).sub.n, --COO--L--O--SO.sub.2 --R1, --Coo--L--O--CO--R1, --COO--L--O--L--O--R1, --COO--L--Si (R5).sub.3, --C(O)S--R1, --C(S)O--R1, --C(S)S--R1, --L--O--R1, --L--O--L--O--R8 (wherein R8 is hydrogen or alkyl), --L--O--M, --L--O--L--M, --L--NR8R9 (wherein R9 is alkyl group), --L--O--CH.sub.2 Ph, --L--O--L--COOR9, --L--CN, --L--S(O).sub.n --R1, --L--S--L--O--R9, --L--O--COR9, --L--O--SO.sub.2 R9, --L--COOR8, --C.dbd.CHOR8 or --L--O--L--CN; Z is halogen, nitro, alkoxy, trifluoromethyl, cyano or --S(O).sub.n R10 (wherein R10 is alkyl or haloalkyl); V is a hydrogen atom, a halogen atom, an alkyl group having from 1 to 4 carbon atoms or an alkoxy group having from 1 to 4 carbon atoms; W is a hydrogen atom, a halogen atom, an alkyl group having from 1 to 4 carbon atoms, a haloalkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxyalkyl group having from 2 to 6 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, a haloalkoxy group having from 1 to 3 carbon atoms, a nitro group, a cyano group or a --S(O).sub.n --R group (wherein n is as defined above and R is an alkyl group having from 1 to 4 carbon atoms); Q is hydrogen, alkyl, alkenyl, alkynyl, cyanomethyl, --C(O)--R11 (wherein R11 is phenyl group which may be substituterd, alkyl, alkoxy or hydroxyl), --S(O).sub.2 R11, --P(O) (OR11).sub.2 --L--C(O)--R11, --L--C(O)--N (R12) (R13) (wherein each of R12 and R13 is hydrogen or alkyl), --L--R14 (wherein R14 is phenyl which may be substituted, alkyl, alkoxy or hydroxy), --L--N(R12) (R13), a --L--OR15 (wherein R15 is hydrogen, alkyl or alkenyl), --L--OC(O)R16 (wherein R16 is alkyl or alkoxy), --L--S(O).sub.n R15, --L--SC(O)R12, ##STR4## wherein each of L1 and L2 is methylene, oxygen is sulfur and R16 is hydrogen or alkyl), and a salt thereof, useful as a herbicide.
    • 9. 发明授权
    • Pyrazole derivatives and herbicides containing them
    • 吡唑衍生物和含有它们的除草剂
    • US4986845A
    • 1991-01-22
    • US369523
    • 1989-06-21
    • Eiichi OyaJunichi WatanabeYasuo KondoTakuya KakutaKoichi SuzukiTsutomu NawamakiShigeomi Watanabe
    • Eiichi OyaJunichi WatanabeYasuo KondoTakuya KakutaKoichi SuzukiTsutomu NawamakiShigeomi Watanabe
    • A01N43/56A01P13/00C07C63/68C07C205/37C07C317/46C07D231/20C07D231/22C07D231/24C07D405/12C07D409/12C07F9/12C07F9/6503
    • C07D405/12A01N43/56C07C205/37C07C317/46C07D231/22C07D231/24C07D409/12C07F9/12C07F9/65033
    • A pyrazole derivative of the formula I ##STR1## wherein A is C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl or C.sub.2 -C.sub.4 alkynyl; B is hydrogen, C.sub.1 -C.sub.3 alkyl, halogen, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.2 -C.sub.4 alkylthioalkyl or C.sub.2 -C.sub.4 alkoxycarbonyl; X is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, halogen, nitro, cyano, etc.; Y is --OR.sup.1 (wherein R.sup.1 is C.sub.3 -C.sub.8 cycloalkyl, etc), --O--L--O--R.sup.1 (wherein L is C.sub.1 -C.sub.6 alkylene which may be substituted by C.sub.1 -C.sub.3 alkyl), --O--L--OH, --O--L--O--L--O--R.sup.2 (wherein R.sup.2 is hydrogen, C.sub.1 -C.sub.6 alkyl group, etc.), --O--L--R.sup.3 (wherein R.sup.3 is phenyl which may be substituted by C.sub.1 -C.sub.3 alkyl, etc.), --O--M (wherein M is a 3- to 6-membered alicyclic group), --O--L--M, --O--L--NR.sup.4 R.sup.5 (wherein each of R.sup.4 and R.sup.5 is hydrogen or C.sub.1 -C.sub.6 alkyl, or R.sup.4 and R.sup.5 form a ring together with the adjacent nitrogen atom), --O--L--COOR.sup.4, --O--CH.dbd.CH--COOR.sup.4, --O--L--CN, --O--L--C(O)--R.sup.2, --O--L--S(O).sub.n --R.sup.4 (wherein n is an integer of from 0 to 2), --O--COOR.sup.4, --O--CONR.sup.4 R.sup.5, --OP(O)(OR.sup.4).sub.2, --S(O).sub.n R.sup.1, or --S(O).sub.n --L--O--R.sup.1 ; Z is halogen, nitro, C.sub.1 -C.sub.3 alkoxy, etc.; V is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; W is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, etc.; Q is hydrogen, C.sub.1 -C.sub.6 alkyl which may be substituted by halogen, . . . --C(O)--R.sup.7 (wherein R.sup.7 is phenyl which may be substituted), --S(O).sub.2 R.sup.7, --P(O)(OR.sup.7).sub.2, --L--C(O)--R.sup.7, --L--C(O)--N(R.sup.8)(R.sup.9) (wherein each of R.sup.8 and R.sup.9 is hydrogenor C.sub.1 -C.sub.6 alkyl), --L--R.sup.10 (wherein R.sup.10 is phenyl group may be substituted, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.7 alkoxy, or hydroxyl), --L--N(R.sup.8)(R.sup.9), --L--OR.sup.11 (wherein R.sup.11 is hydrogen, C.sub.1 -C.sub.6 alkyl, or C.sub.1 -C.sub.6 alkenyl), --L--OC(O)R.sup.12 (wherein R.sup.12 is C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy), --L--S(O).sub.n R.sup.11, --L--SC(O)R.sup.8, ##STR2## (wherein each of L1 and L2 is methylene, oxygen or sulfur, R.sup.12 is hydrogen or C.sub.1 -C.sub.3 alkyl, and m is 2 or 3); and a salt thereof.
    • 10. 再颁专利
    • Pyrazole derivatives and herbicides containing them
    • USRE34779E
    • 1994-11-08
    • US946900
    • 1992-09-18
    • Eiichi OyaJunichi WatanabeYasuo KondoTakuya KakutaKoichi SuzukiTsutomu NawamakiShigeomi Watanabe
    • Eiichi OyaJunichi WatanabeYasuo KondoTakuya KakutaKoichi SuzukiTsutomu NawamakiShigeomi Watanabe
    • A01N43/56A01P13/00C07C63/68C07C205/37C07C317/46C07D231/20C07D231/22C07D231/24C07D405/12C07D409/12C07F9/12C07F9/6503C07D401/12C07D413/12
    • C07D405/12A01N43/56C07C205/37C07C317/46C07D231/22C07D231/24C07D409/12C07F9/12C07F9/65033
    • A pyrazole derivative of the formula I ##STR1## wherein A is C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.4 alkenyl or C.sub.2 -C.sub.4 alkynyl; B is hydrogen, C.sub.1 -C.sub.3 alkyl, halogen, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.2 -C.sub.4 alkylthioalkyl or C.sub.2 -C.sub.4 alkoxycarbonyl; X is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, halogen, nitro, cyano, etc.; Y is --OR.sup.1 (wherein R.sup.1 is C.sub.3 -C.sub.8 cycloalkyl, etc), --O--L--O--R.sup.1 (wherein L is C.sub.1 -C.sub.6 alkylene which may be substituted by C.sub.1 -C.sub.3 alkyl), --O--L--OH, --O--L--O--L--O--R.sup.2 (wherein R.sup.2 is hydrogen, C.sub.1 -C.sub.6 alkyl group, etc.), --O--L--R.sup.3 (wherein R.sup.3 is phenyl which may be substituted by C.sub.1 -C.sub.3 alkyl, etc.), --O--M (wherein M is a 3- to 6-membered alicyclic group), --O--L--M, --O--L--NR.sup.4 R.sup.5 (wherein each of R.sup.4 and R.sup.5 is hydrogen or C.sub.1 -C.sub.6 alkyl, or R.sup.4 and R.sup.5 form a ring together with the adjacent nitrogen atom), --O--L--COOR.sup.4, --O--CH.dbd.CH--COOR.sup.4, --O--L--CN, --O--L--C(O)--R.sup.2, --O--L--S(O).sub.n --R.sup.4 (wherein n is an integer of from 0 to 2), --O--COOR.sup.4, --O--CONR.sup.4 R.sup.5, --OP(O)(OR.sup.4).sub.2, --S(O).sub.n R.sup.1, or --S(O).sub.n --L--O--R.sup.1 ; Z is halogen, nitro, C.sub.1 -C.sub.3 alkoxy, etc.; V is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; W is hydrogen, halogen, C.sub.1 -C.sub.4 alkyl, etc.; Q is hydrogen, C.sub.1 -C.sub.6 alkyl which may be substituted by halogen, . . . --C(O)--R.sup.7 (wherein R.sup.7 is phenyl which may be substituted), --S(O).sub.2 R.sup.7, --P(O)(OR.sup.7).sub.2, --L--C(O)--R.sup.7, --L--C(O)--N(R.sup.8)(R.sup.9) (wherein each of R.sup.8 and R.sup.9 is hydrogenor C.sub.1 -C.sub.6 alkyl), --L--R.sup.10 (wherein R.sup.10 is phenyl group may be substituted, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.7 alkoxy, or hydroxyl), --L--N(R.sup.8)(R.sup.9), --L--OR.sup.11 (wherein R.sup.11 is hydrogen, C.sub.1 -C.sub.6 alkyl, or C.sub.1 -C.sub.6 alkenyl), --L--OC(O)R.sup.12 (wherein R.sup.12 is C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy), --L--S(O).sub.n R.sup.11, --L--SC(O)R.sup.8, ##STR2## (wherein each of L1 and L2 is methylene, oxygen or sulfur, R.sup.12 is hydrogen or C.sub.1 -C.sub.3 alkyl, and m is 2 or 3); and a salt thereof.