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1. 发明授权

US4948887A Pyrazole derivative and herbicide containing it 失效
标题翻译：吡唑衍生物和含有它的除草剂
公开(公告)号：US4948887A
公开(公告)日：1990-08-14
申请号：US168139
申请日：1988-03-14
申请人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe
发明人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe
IPC分类号： C07D231/20 , A01N43/56 , A01P13/00 , C07C65/21 , C07C317/46 , C07C317/48 , C07C323/62 , C07C323/63 , C07D231/22 , C07D231/24 , C07D231/30 , C07D231/36 , C07D405/12 , C07D409/12 , C07F7/18 , C07F9/6503
CPC分类号： C07D231/22 , A01N43/56 , C07D231/24
摘要： A pyrazole derivative having the formula: ##STR1## wherein A is alkyl, alkenyl or alkynyl; B is hydrogen, alkyl, halogen, haloalkyl, alkoxy, alkylthio, alkoxyalkyl, alkylthioalkyl or alkoxycarbonyl; X is alkyl, alkoxy, halogen, nitro, cyano, haloalkyl, alkoxyalkyl, alkylcarbonyl, alkoxycarbonyl, aminocarbonyl substituted by hydrogen or alkyl, haloalkoxy, alkylthio or alkylthioalkyl; Y is --COOR1 (wherein R1 is hydrogen, alkyl, etc.), --COO--L--OR1 (wherein L is alkylene which may be substituted), --COO--L--R2 (wherein R2 is phenyl group which may be substituted), --COO--M (wherein M is 3 to 6-membered alicyclic residue containing not more than 2 sulfur or oxygen atoms), --COO--L--M, --COO--L--O--L--R2, --COO--L--S(O).sub.n --CON (R3) (R4) (wherein each of R3 and R4 is hydrogen, alkyl, etc.), a --CON--(CH.sub.2).sub.n, ##STR2## wherein R5 is alkyl), ##STR3## --CONHSO.sub.2 CH.sub.3, --CONHSO.sub.2 CF.sub.3, --COO--L--N(R3) (R4), --COO--L--CO--R1, --COO--L--CO--O--R1, --COO--L--CN, --Coo--L--NO.sub.2 --COOSi (R5).sub.3, --COO--N.dbd.(R6) (R7) (wherein each of R6 and R7 is alkyl), --COO--N.dbd.C--(CH.sub.2).sub.n, --COO--L--O--SO.sub.2 --R1, --Coo--L--O--CO--R1, --COO--L--O--L--O--R1, --COO--L--Si (R5).sub.3, --C(O)S--R1, --C(S)O--R1, --C(S)S--R1, --L--O--R1, --L--O--L--O--R8 (wherein R8 is hydrogen or alkyl), --L--O--M, --L--O--L--M, --L--NR8R9 (wherein R9 is alkyl group), --L--O--CH.sub.2 Ph, --L--O--L--COOR9, --L--CN, --L--S(O).sub.n --R1, --L--S--L--O--R9, --L--O--COR9, --L--O--SO.sub.2 R9, --L--COOR8, --C.dbd.CHOR8 or --L--O--L--CN; Z is halogen, nitro, alkoxy, trifluoromethyl, cyano or --S(O).sub.n R10 (wherein R10 is alkyl or haloalkyl); V is a hydrogen atom, a halogen atom, an alkyl group having from 1 to 4 carbon atoms or an alkoxy group having from 1 to 4 carbon atoms; W is a hydrogen atom, a halogen atom, an alkyl group having from 1 to 4 carbon atoms, a haloalkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxyalkyl group having from 2 to 6 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, a haloalkoxy group having from 1 to 3 carbon atoms, a nitro group, a cyano group or a --S(O).sub.n --R group (wherein n is as defined above and R is an alkyl group having from 1 to 4 carbon atoms); Q is hydrogen, alkyl, alkenyl, alkynyl, cyanomethyl, --C(O)--R11 (wherein R11 is phenyl group which may be substituterd, alkyl, alkoxy or hydroxyl), --S(O).sub.2 R11, --P(O) (OR11).sub.2 --L--C(O)--R11, --L--C(O)--N (R12) (R13) (wherein each of R12 and R13 is hydrogen or alkyl), --L--R14 (wherein R14 is phenyl which may be substituted, alkyl, alkoxy or hydroxy), --L--N(R12) (R13), a --L--OR15 (wherein R15 is hydrogen, alkyl or alkenyl), --L--OC(O)R16 (wherein R16 is alkyl or alkoxy), --L--S(O).sub.n R15, --L--SC(O)R12, ##STR4## wherein each of L1 and L2 is methylene, oxygen is sulfur and R16 is hydrogen or alkyl), and a salt thereof, useful as a herbicide.

2. 发明授权

US5094685A Substituted benzoyl derivatives and selective herbicides 失效
标题翻译：取代苯甲酰衍生物和选择性除草剂
公开(公告)号：US5094685A
公开(公告)日：1992-03-10
申请号：US538089
申请日：1990-06-13
申请人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe , Koichi Suzuki
发明人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe , Koichi Suzuki
IPC分类号： C07C69/003 , A01N31/04 , A01N35/02 , A01N35/06 , A01N37/34 , A01N37/36 , A01N37/40 , A01N41/02 , A01N41/10 , C07C45/00 , C07C49/747 , C07C49/753 , C07C49/83 , C07C49/84 , C07C65/36 , C07C65/40 , C07C67/00 , C07C69/76 , C07C201/00 , C07C205/45 , C07C205/46 , C07C205/61 , C07C209/00 , C07C211/27 , C07C225/16 , C07C255/56 , C07C255/57 , C07C317/44 , C07C323/22 , C07C323/56 , C07C323/62
CPC分类号： C07C49/83 , A01N35/06 , A01N37/40 , A01N41/10 , C07C205/45 , C07C205/61 , C07C225/16 , C07C255/56 , C07C255/57 , C07C317/44 , C07C323/62 , C07C49/84 , C07C65/36 , C07C2101/14
摘要： A substituted benzoyl derivative having the formula: ##STR1## wherein X.sub.1 is C.sub.1 -C.sub.4 alkyl, C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, cyano, nitro or halogen; X.sub.2 is --L--OR.sub.1 (wherein L is C.sub.1 -C.sub.4 alkylene or C.sub.1 -C.sub.4 alkylidene, and R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkenyl or C.sub.1 -C.sub.4 alkynyl), --L--O--L--OR.sub.1 (wherein L and R.sub.1 are as defined above), --L--S(O).sub.n --R.sub.2 (wherein L is as defined above, R.sub.2 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkenyl or C.sub.1 -C.sub.4 alkynyl, and n is an integer of 0, 1 or 2), --L--O--COR.sub.2 (wherein L and R.sub.2 are as defined above), --L--NR.sub.1 R.sub.3 (wherein L and R.sub.1 are as defined above, and R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl), --COOR.sub.1 (wherein R.sub.1 is as defined above) or --COO--L--O--R.sub.1 (wherein L and R.sub.1 are as defined above), provided that when X.sub.1 is C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 haloalkyl, X.sub.2 is not --COOR.sub.1 ; X.sub.3 is trifluoromethyl, C.sub.1 -C.sub.3 alkoxy, halogen, cyano, nitro or --S(O).sub.n R.sub.4 (wherein n is as defined above, and R.sub.4 is C.sub.1 C.sub.3 alkyl); X.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen; X.sub.5 is hydrogen or fluorine; and each of Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4 and Y.sub.5 is hydrogen or C.sub.1 -C.sub.4 alkyl; or a salt thereof.

3. 发明授权

US4885022A Herbicidal pyrazole derivatives 失效
标题翻译：除草吡唑衍生物
公开(公告)号：US4885022A
公开(公告)日：1989-12-05
申请号：US122366
申请日：1987-11-18
申请人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe
发明人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe
IPC分类号： A01N43/56 , C07D231/22 , C07D231/24
CPC分类号： C07D231/24 , A01N43/56 , C07D231/22
摘要： A pyrazole derivative having the formula: ##STR1## where A, B, X, Y, Z and Q are described below.
摘要翻译：下文描述具有下式的吡唑衍生物：其中A，B，X，Y，Z和Q如下所述。

4. 发明授权

US4954165A Substituted benzoyl derivatives and selective herbicides 失效
标题翻译：取代的苯甲酰基衍生物和选择性除草剂
公开(公告)号：US4954165A
公开(公告)日：1990-09-04
申请号：US259587
申请日：1988-10-18
申请人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe , Koichi Suzuki
发明人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe , Koichi Suzuki
IPC分类号： C07C69/003 , A01N31/04 , A01N35/02 , A01N35/06 , A01N37/34 , A01N37/36 , A01N37/40 , A01N41/02 , A01N41/10 , C07C45/00 , C07C49/747 , C07C49/753 , C07C49/83 , C07C49/84 , C07C65/36 , C07C65/40 , C07C67/00 , C07C69/76 , C07C201/00 , C07C205/45 , C07C205/46 , C07C205/61 , C07C209/00 , C07C211/27 , C07C225/16 , C07C255/56 , C07C255/57 , C07C317/44 , C07C323/22 , C07C323/56 , C07C323/62
CPC分类号： C07C49/83 , A01N35/06 , A01N37/40 , A01N41/10 , C07C205/45 , C07C205/61 , C07C225/16 , C07C255/56 , C07C255/57 , C07C317/44 , C07C323/62 , C07C49/84 , C07C65/36 , C07C2101/14
摘要： An herbicidally effective benzoyl derivative having the formula: ##STR1## wherein X.sub.1 is C.sub.1 -C.sub.4 alkoxy or halogen;X.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen;X.sub.5 is hydrogen or fluorine;Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4 and Y.sub.5 are independently hydrogen or C.sub.1 -C.sub.4 alkyl;R.sub.1 is C.sub.1 -C.sub.4 alkyl;R.sub.4 is C.sub.1 -C.sub.3 alkyl;n is an integer of 0, 1 or 2 is discosed.In addition, the herbicidally effective benzoyl derivative having the formula: ##STR2## wherein: X.sub.1 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy halogen;X.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen;X.sub.5 is hydrogen or fluorine;Y.sub.1, Y.sub.2, Y.sub.3, Y.sub.4 and Y.sub.5 are independently hydrogen or C.sub.1 -C.sub.4 alkyl;R.sub.1 is C.sub.1 -C.sub.4 alkyl;R.sub.4 is C.sub.1 -C.sub.3 alkyl;n is an integer of 0, 1 or 2;L is C.sub.1 -C.sub.4 alkylene is disclosed.
摘要翻译：具有下式的除草有效的苯甲酰基衍生物：其中X 1是C 1 -C 4烷氧基或卤素; X4是氢，C1-C4烷基，C1-C4烷氧基或卤素; X5是氢或氟; Y1，Y2，Y3，Y4和Y5独立地为氢或C1-C4烷基; R1是C1-C4烷基; R4是C1-C3烷基; n是0的整数，1或2被舍弃。此外，具有下式的除草有效的苯甲酰基衍生物：其中：X 1是C 1 -C 4烷基，C 1 -C 4烷氧基卤素; X4是氢，C1-C4烷基，C1-C4烷氧基或卤素; X5是氢或氟; Y1，Y2，Y3，Y4和Y5独立地为氢或C1-C4烷基; R1是C1-C4烷基; R4是C1-C3烷基; n是0,1或2的整数; L是C1-C4亚烷基。

5. 发明授权

US5175299A Benzoic acid derivatives useful as intermediates for the preparation of herbicidal 4-benzoylpyrazoles 失效
标题翻译：苯甲酸衍生物可用作制备除草4-苯甲酰基吡唑的中间体
公开(公告)号：US5175299A
公开(公告)日：1992-12-29
申请号：US785241
申请日：1991-11-01
申请人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe
发明人： Masatoshi Baba , Takuya Kakuta , Norio Tanaka , Eiichi Oya , Takashi Ikai , Tsutomu Nawamaki , Shigeomi Watanabe
IPC分类号： A01N43/56 , C07D231/22 , C07D231/24
CPC分类号： C07D231/22 , A01N43/56 , C07D231/24
摘要： A pyrazole derivative having the formula ##STR1## is disclosed; the groups A, B, Q, V, W, X, Y, and Z are defined in the description.
摘要翻译：公开了具有式（I）的吡唑衍生物：组A，B，Q，V，W，X，Y和Z在说明书中定义。

6. 发明授权

US4557753A Herbicidal 4-benzoyl-1-methyl-5-phenylalkoxy pyrazoles 失效
标题翻译：除草4-苯甲酰基-1-甲基-5-苯基烷氧基吡唑
公开(公告)号：US4557753A
公开(公告)日：1985-12-10
申请号：US485832
申请日：1983-04-18
申请人： Norio Tanaka , Masakazu Taniguchi , Masatoshi Baba , Takashi Ikai , Tsutomu Nawamaki , Masaji Matsunaga
发明人： Norio Tanaka , Masakazu Taniguchi , Masatoshi Baba , Takashi Ikai , Tsutomu Nawamaki , Masaji Matsunaga
IPC分类号： A01N43/56 , C07D231/16 , C07D231/20 , C07D405/12
CPC分类号： C07D405/12 , A01N43/56 , C07D231/16 , C07D231/20
摘要： Pyrazole derivatives, preparations thereof, selective herbicidal compositions containing said derivatives and the use of said derivatives are provided. The pyrazole derivatives having selective herbicidal activity are represented by the formula I: ##STR1## wherein, A denotes a straight or branched lower alkylene or lower alkylidene group; X denotes a halogen atom, nitro group, a lower alkyl group, a lower haloalkyl group, a lower alkoxy group, a lower haloalkoxy group, a lower alkenyl group, phenyl group, cyano group, phenoxy group, a lower alkoxycarbonyl group, an aliphatic or aromatic acyl group, methanesulfonyloxy group or group ##STR2## and n is 0 or an integer of 1 to 5, said Xs being the same or different when n is an integer of 2 to 5; and Y denotes a halogen atom, a lower alkyl group, nitro group, phenyl group, a lower alkoxy group or trifluoromethyl group and m is in integer of 1 to 3, said Ys being the same or different when m is 2 or 3.
摘要翻译：提供吡唑衍生物，其制剂，含有所述衍生物的选择性除草组合物和所述衍生物的用途。具有选择性除草活性的吡唑衍生物由式I表示：其中，A表示直链或支链的低级亚烷基或低级亚烷基; X表示卤素原子，硝基，低级烷基，低级卤代烷基，低级烷氧基，低级卤代烷氧基，低级烯基，苯基，氰基，苯氧基，低级烷氧基羰基，脂肪族或芳香族酰基，甲磺酰氧基或基团，n为0或1〜5的整数，所述X为2〜5的整数时相同或不同; Y表示卤原子，低级烷基，硝基，苯基，低级烷氧基或三氟甲基，m表示1〜3的整数，当m为2或3时，所述Y相同或不同。

7. 再颁专利

USRE34408E Process for producing 4-benzoyl-5-hydroxypyrazoles 失效
标题翻译： 4-苯甲酰基-5-羟基吡唑的制备方法
公开(公告)号：USRE34408E
公开(公告)日：1993-10-12
申请号：US885990
申请日：1992-05-20
申请人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
发明人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
IPC分类号： C07C315/02 , C07C315/04 , C07C317/44 , C07C319/14 , C07D231/32 , C07D231/20
CPC分类号： C07D231/32
摘要： A process for producing a 4-benzoyl-5-hydroxylpyrazole of the formula III: ##STR1## which comprises reacting carbon monoxide and a 5-hydroxypyrazole of the formula II: ##STR2## to a substituted benzene of the formula I: ##STR3## wherein X is a bromine atom, an iodine atom or a diazonium tetrafluoroboron salt group, in the presence of a base and a catalyst of Group VIII of the Periodic Table.

8. 再颁专利

USRE34423E Substituted benzenes useful as intermediates 失效
标题翻译：取代的苯可用作中间体
公开(公告)号：USRE34423E
公开(公告)日：1993-10-26
申请号：US885989
申请日：1992-05-20
申请人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
发明人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
IPC分类号： C07C317/22 , C07C317/44 , C07C323/09 , C07C323/19 , C07C323/20 , C07C323/62 , C07D231/22 , C07D231/24
CPC分类号： C07C317/22 , C07C317/44 , C07C323/09 , C07C323/19 , C07C323/20 , C07C323/62 , C07D231/22 , C07D231/24
摘要： A process for producing a 4-benzoyl-5-hydroxylpyrazole of the formula III: ##STR1## which comprises reacting carbon monoxide and a 5-hydroxypyrazole of the formula II: ##STR2## with a substituted benzene of the formula I: ##STR3## in the presence of a base and a catalyst of Group VIII of the Periodic Table.

9. 发明授权

US4942246A Process for producing 4-benzoyl-5-hydroxypyrazoles 失效
标题翻译： 4-苯甲酰基-5-羟基吡唑的制备方法
公开(公告)号：US4942246A
公开(公告)日：1990-07-17
申请号：US360468
申请日：1989-06-02
申请人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
发明人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
IPC分类号： C07D231/20 , A01N43/56 , B01J27/128 , B01J31/28 , C07B61/00 , C07C17/12 , C07C25/13 , C07C43/174 , C07C63/70 , C07C205/12 , C07C205/19 , C07C205/34 , C07C245/20 , C07C255/50 , C07C255/53 , C07C255/54 , C07C317/14 , C07C317/22 , C07C317/32 , C07C317/44 , C07C317/46 , C07C323/09 , C07C323/20 , C07C323/36 , C07C323/48 , C07C323/62 , C07C323/63 , C07C331/12 , C07D231/22
CPC分类号： C07D231/22 , C07C17/12 , C07C201/12 , C07C255/50 , C07C315/02 , C07C315/04 , C07C317/14 , C07C317/22 , C07C317/44 , C07C319/14 , C07C319/20 , C07C323/09 , C07C323/20 , C07C323/36 , C07C323/62 , C07C323/63 , C07C331/12
摘要： A process for producing a 4-benzoyl-5-hydroxylpyrazole of the formula III: ##STR1## which comprises reacting carbon monoxide and a 5-hydroxypyrazole of the formula II: ##STR2## to a substituted benzene of the formula I: ##STR3## wherein X is a bromine atom, an iodine atom or a diazonium tetrafluoroboron salt group, in the presence of a base and a catalyst of Group VIII of the Periodic Table.

10. 发明授权

US5087724A Substituted benzenes useful as intermediates 失效
标题翻译：取代的苯可用作中间体
公开(公告)号：US5087724A
公开(公告)日：1992-02-11
申请号：US519727
申请日：1990-05-07
申请人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
发明人： Norio Tanaka , Takuya Kakuta , Eiichi Oya , Masatoshi Baba
IPC分类号： C07D231/20 , A01N43/56 , B01J27/128 , B01J31/28 , C07B61/00 , C07C25/13 , C07C43/174 , C07C63/70 , C07C245/20 , C07C255/50 , C07C255/53 , C07C255/54 , C07C317/14 , C07C317/22 , C07C317/32 , C07C317/44 , C07C317/46 , C07C323/09 , C07C323/19 , C07C323/20 , C07C323/48 , C07C323/62 , C07D231/22
CPC分类号： C07C323/19 , C07C317/14 , C07C317/22 , C07C317/44 , C07C323/09 , C07C323/20 , C07C323/62 , C07D231/22
摘要： A process for producing a 4-benzoyl-5-hydroxylpyrazole of the formula III: ##STR1## which comprises reacting carbon monoxide and a 5-hydroxypyrazole of the formula II: ##STR2## with a substituted benzene of the formula I: ##STR3## in the presence of a base and a catalyst of Group VIII of the Periodic Table.
摘要翻译：制备式III的4-苯甲酰基-5-羟基吡唑的方法：（III），其包括使一氧化碳与式II的5-羟基吡唑：（II）与取代的苯的式I化合物（Ⅰ）在碱的存在下和元素周期表第VIII族的催化剂存在下进行。

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