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1. 发明授权

US4105839A Method for polymerizing ethylenically unsaturated monomers in order to eliminate polymer deposition 失效
标题翻译：聚合烯属不饱和单体以消除聚合物沉积的方法
公开(公告)号：US4105839A
公开(公告)日：1978-08-08
申请号：US713894
申请日：1976-08-12
申请人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu , Kenji Fushimi
发明人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu , Kenji Fushimi
IPC分类号： C08F236/10 , C08F2/00 , C08F2/18 , C08F2/44 , C08F214/08 , C08F216/06 , C08F2/16
CPC分类号： C08F2/004
摘要： In the polymerization of at least one ethylenically unsaturated monomer other than vinyl chloride, deposition of polymer scale on the inner walls of a polymerization reactor and other surfaces coming into contact with the monomer is effectively prevented (regardless of the type of polymerization used, so long as it takes place in a heterogeneous phase) by coating the surfaces of the reactor with at least one compound selected from organic electron donor compounds and organic electron-acceptor compounds prior to polymerization; the compound or compounds having been or being brought into contact with an oxidizing agent, a reducing agent, an acid or a base, or having been or being irradiated with ultraviolet light.
摘要翻译：在除了氯乙烯之外的至少一种烯键式不饱和单体的聚合中，聚合物垢在聚合反应器的内壁和与单体接触的其它表面上的沉积被有效地防止（不管使用的聚合物类型如何长因为它发生在非均相中）通过在聚合之前用至少一种选自有机电子给体化合物和有机电子受体化合物的化合物涂覆反应器的表面; 已经或已经与氧化剂，还原剂，酸或碱接触的化合物或化合物，或已被或被紫外线照射的化合物或化合物。

2. 发明授权

US4528336A Method for preventing polymer scale deposition in polymerization of ethylenically unsaturated monomers 失效
标题翻译：防止烯属不饱和单体聚合中聚合物垢沉积的方法
公开(公告)号：US4528336A
公开(公告)日：1985-07-09
申请号：US361040
申请日：1982-03-23
申请人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu , Ichiro Kaneko
发明人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu , Ichiro Kaneko
IPC分类号： C08F2/00 , C08F2/12 , C08F2/20 , C08F14/06
CPC分类号： C08F2/004
摘要： The invention provides a very efficient method with highly durable effect for preventing polymer scale deposition on the reactor walls and other surfaces coming into contact with the monomer during polymerization of an ethylenically unsaturated polymerizable monomer in an aqueous medium such as in the suspension polymerization of vinyl chloride. The method comprises coating the reactor walls, prior to polymerization, with a novel coating material which is a condensation product obtained by the condensation reaction of an aromatic amine compound such as aniline and an aromatic nitro compound such as nitrobenzene in the presence of a mineral acid and a specified condensation catalyst. It is sometimes preferable that the condensation product is basified or treated with an alkali or ammonium compound to be imparted with a modified solubility behavior.
摘要翻译：本发明提供了一种非常有效的方法，其具有高度耐久的效果，用于防止聚合物垢沉积在反应器壁和其它与单体接触的表面中，所述表面在烯属不饱和可聚合单体在水性介质中聚合期间，例如在氯乙烯的悬浮聚合中。该方法包括在聚合之前用反应器壁涂覆新的涂料，该涂料是通过在无机酸存在下芳族胺化合物如苯胺和芳族硝基化合物如硝基苯的缩合反应获得的缩合产物和指定的缩合催化剂。有时优选将缩合产物碱化或用碱或铵化合物处理以赋予改性的溶解行为。

3. 发明授权

US4757124A Process for production of vinyl chloride polymer 失效
标题翻译：生产氯乙烯聚合物的方法
公开(公告)号：US4757124A
公开(公告)日：1988-07-12
申请号：US76996
申请日：1987-07-21
申请人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu , Ichiro Kaneko
发明人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu , Ichiro Kaneko
IPC分类号： C08F14/06 , C08F2/00 , C08F2/18 , C08F4/06 , C08F2/22 , C08F2/44
CPC分类号： C08F2/004
摘要： This process is a process for production of a vinyl chloride polymer by suspension polymerization or emulsion polymerization of vinyl chloride monomer or a mixture of vinyl chloride monomer with a vinyl monomer copolymerizable with said vinyl chloride monomer in an aqueous medium, characterized in that the polymerization is carried out in a polymerizer, the inner wall surface and portions of the auxiliary equipment thereof which may come into contact with the monomer during polymerization being previously coated with a scaling preventive comprising at least one selected from dyes, pigments and aromatic or heterocyclic compounds having at least 5 conjugated .pi. bonds, while controlling the chloride ion concentration in the reaction mixture to not higher than 100 ppm. According to said process, scaling onto the inner wall surface of a polymerizer, etc. during polymerization can be prevented effectively and surely.
摘要翻译：该方法是通过氯乙烯单体或氯乙烯单体与可与所述氯乙烯单体在水性介质中共聚的乙烯基单体的混合物的悬浮聚合或乳液聚合制备氯乙烯聚合物的方法，其特征在于聚合是在聚合反应器中进行的内壁表面及其辅助设备的部分可在聚合期间与单体接触，预先涂覆防垢剂，其包含选自染料，颜料和芳族或杂环化合物中的至少一种，其具有最少5个共轭π键，同时将反应混合物中的氯离子浓度控制在不高于100ppm。根据所述方法，能够有效且可靠地防止在聚合反应期间缩聚到聚合反应器内壁表面等。

4. 发明授权

US3945958A Method for suspension-polymerizing vinyl chloride 失效
标题翻译：悬浮聚合氯乙烯的方法
公开(公告)号：US3945958A
公开(公告)日：1976-03-23
申请号：US475052
申请日：1974-05-31
申请人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu
发明人： Shunichi Koyanagi , Hajime Kitamura , Toshihide Shimizu
IPC分类号： C08F14/06 , C08F2/20
CPC分类号： C08F14/06
摘要： When vinyl chloride or a mixture of monomers containing vinyl chloride as its main component is subjected to suspension-polymerization, in the presence of a polymerization initiator, employing as a suspending agent an aqueous medium consisting of two kinds of water-soluble cellulose ethers, the 2% aqueous solution of one of which has a viscosity of at most 100 cps at 20.degree.C, and that of the other has a viscosity of at least 400 cps at 20.degree.C, the product obtained will be a porous polymer superior not only in uniformity of particle size, and absorptivity of plasticizers and liquid heat-stabilizers but also in processability.
摘要翻译：当氯乙烯或含有氯乙烯作为其主要成分的单体的混合物进行悬浮聚合时，在聚合引发剂的存在下，使用由两种水溶性纤维素醚组成的水性介质作为悬浮剂，其中之一的2％水溶液在20℃下的粘度至多为100cps，另一种的水溶液在20℃时的粘度至少为400cps，所得产品将不仅优于多孔聚合物颗粒尺寸的均匀性和增塑剂和液体热稳定剂的吸收性，而且在加工性方面。

5. 发明授权

US4232141A Method for the preparation of vinyl chloride polymers 失效
标题翻译：氯乙烯聚合物的制备方法
公开(公告)号：US4232141A
公开(公告)日：1980-11-04
申请号：US925704
申请日：1978-07-18
申请人： Shunichi Koyanagi , Hajime Kitamura , Kazuhiko Kurimoto
发明人： Shunichi Koyanagi , Hajime Kitamura , Kazuhiko Kurimoto
IPC分类号： C08F14/00 , C08F2/00 , C08F2/16 , C08F2/18 , C08F2/20 , C08F2/22 , C08F4/00 , C08F14/06
CPC分类号： C08F14/06 , Y10S526/908
摘要： An improved method for the polymerization of vinyl chloride or a monomer mixture mainly composed of vinyl chloride in an aqueous polymerization medium is proposed in which a water-insoluble polymerization initiator, being solid at room temperature as dispersed in the aqueous medium and having a particle size distribution of 50 .mu.m or finer, is added to the polymerization mixture which is maintained at a temperature where the half-life period of the initiator is 120 minutes or longer or, alternatively, over a duration equal to or shorter than one-tenth of the half-life period of the initiator at the temperature of the polymerization mixture. By this method the polymerization can be homogeneously proceeded to produce vinyl chloride polymers having a uniform particle size distribution, excellent heat stability and much less fish-eyes when fabricated into sheets.
摘要翻译：提出了一种在水性聚合介质中聚合氯乙烯或主要由氯乙烯组成的单体混合物的改进方法，其中水不溶性聚合引发剂在室温下分散在水性介质中为固体，具有粒径将分布为50μm或更细的聚合混合物加入到保持在引发剂的半衰期为120分钟或更长的温度下的聚合混合物中，或者在等于或短于引发剂的十分之一的时间内，引发剂在聚合混合物温度下的半衰期。通过该方法，可以均匀地进行聚合以制备具有均匀粒度分布，优异的热稳定性和制造成片材的鱼眼少得多的氯乙烯聚合物。

6. 发明授权

US4272622A Method for preventing polymer scale deposition in the polymerization of an ethylenically unsaturated monomer in an aqueous medium 失效
标题翻译：防止水性介质中烯属不饱和单体聚合中的聚合物垢沉积的方法
公开(公告)号：US4272622A
公开(公告)日：1981-06-09
申请号：US149414
申请日：1980-05-13
申请人： Hajime Kitamura , Toshihide Shimizu , Ichiro Kaneko
发明人： Hajime Kitamura , Toshihide Shimizu , Ichiro Kaneko
IPC分类号： C08F2/00 , C08F2/18 , C08F2/44 , C08F2/20 , C08F2/22 , C08F2/24
CPC分类号： C08F2/004
摘要： The invention provides a novel method for preventing polymer scale deposition on the reactor walls in the polymerization of vinyl chloride, vinylidene chloride, styrene and other ethylenically unsaturated monomers in an aqueous medium. The inventive method comprises coating the reactor walls, piror to polymerization, with an aqueous coating solution containing a water-soluble ionic polymer and a water-soluble ionic dye having counteractive polarity to the polarity of the water-soluble ionic polymer compound. In other words, a water-soluble anionic dye is used as combined with a water-soluble cationic polymer and a water-soluble cationic dye is used as combined with a water-soluble anionic polymer compound. The scale preventing effect obtained with the combined use of the above two components can be further increased when the aqueous coating solution is admixed with a monovalent alcohol having from 3 to 6 carbon atoms in a molecule owing to the improved spreading of the aqueous solution on the metal surface of the reactor walls. The effect of the method is so remarkable and reliable that polymerization of styrene and other monomers can be performed in a stainless steel polymerization reactor, said polymerization being hitherto conducted in a glass-lined reactor due to the lack of an efficient method for preventing polymer scale deposition on the stainless steel surfaces.
摘要翻译：本发明提供了一种用于在水性介质中聚合氯乙烯，偏二氯乙烯，苯乙烯和其它烯键式不饱和单体的聚合物垢沉积在反应器壁上的新方法。本发明的方法包括用含有水溶性离子聚合物的水性涂料溶液和反应器壁，吡喃聚合反应，并且与水溶性离子聚合物化合物的极性具有相反极性的水溶性离子染料。换句话说，使用水溶性阴离子染料与水溶性阳离子聚合物组合，并且使用水溶性阳离子染料与水溶性阴离子聚合物化合物组合。当水性涂料溶液与分子中具有3至6个碳原子的一价醇混合时，可以进一步提高通过组合使用上述两种组分获得的防垢效果，这是由于水溶液在反应器壁的金属表面。该方法的效果是非常显着和可靠的，苯乙烯和其它单体的聚合可以在不锈钢聚合反应器中进行，所述聚合迄今为止在玻璃衬里的反应器中进行，因为缺乏有效的防止聚合物垢的方法沉积在不锈钢表面上。

7. 发明授权

US4105838A Method for the polymerization of vinyl chloride 失效
标题翻译：氯乙烯聚合方法
公开(公告)号：US4105838A
公开(公告)日：1978-08-08
申请号：US626328
申请日：1975-10-28
申请人： Hajime Kitamura , Toshihide Shimizu
发明人： Hajime Kitamura , Toshihide Shimizu
IPC分类号： C08F14/00 , C08F2/00 , C08F14/06
CPC分类号： C08F2/004
摘要： Vinyl chloride monomer or a monomeric mixture composed mainly of vinyl chloride is polymerized in a polymerization vessel having its inner walls and the surfaces of an agitator and other equipment attached thereto coming into contact with the monomer or monomers coated with a metal complex of a polar organic compound and/or an organic dye. This method of polymerization serves to greatly reduce the deposition of polymer scale on those surfaces and produce high quality polymer.
摘要翻译：氯乙烯单体或主要由氯乙烯组成的单体混合物在聚合容器中聚合，其聚合容器的内壁和搅拌器的表面以及附着于其上的其它设备与涂覆有极性有机物金属络合物的单体或单体接触化合物和/或有机染料。这种聚合方法大大减少了聚合物垢在这些表面上的沉积并产生高质量的聚合物。

8. 发明授权

US07551748B2 Earphone 失效
标题翻译：耳机
公开(公告)号：US07551748B2
公开(公告)日：2009-06-23
申请号：US11084045
申请日：2005-03-21
申请人： Shotaro Kamo , Eiji Matsuyama , Hajime Kitamura , Isao Fushimi , Masayoshi Sugiyama
发明人： Shotaro Kamo , Eiji Matsuyama , Hajime Kitamura , Isao Fushimi , Masayoshi Sugiyama
IPC分类号： H04R25/00
CPC分类号： H04R1/1016 , H04R1/1033
摘要： The receiver unit includes a receiver body, a housing containing this receiver body, a cord connected to the receiver body, and a cord protector for protecting the cord. The cord protector is a plate-like member having a substantially rectangular shape, and includes an engaging portion and a semicircular portion. The cord protector is formed of soft material such as urethane rubber having Shore hardness of about A90, and its wall thickness is set to be 0.3 to 0.6 mm (0.5 mm, for example).
摘要翻译：接收器单元包括接收器主体，容纳该接收器主体的壳体，连接到接收器主体的绳索以及用于保护绳索的帘线保护器。帘线保护器是具有大致矩形形状的板状构件，并且包括接合部和半圆形部。帘线保护器由软质材料形成，例如肖氏硬度为约A90的聚氨酯橡胶，其壁厚设定为0.3〜0.6mm（例如0.5mm）。

9. 发明授权

US06763120B2 Speaker 失效
标题翻译：扬声器
公开(公告)号：US06763120B2
公开(公告)日：2004-07-13
申请号：US10100988
申请日：2002-03-20
申请人： Shigeru Sugiyama , Hajime Kitamura , Yoshio Imahori
发明人： Shigeru Sugiyama , Hajime Kitamura , Yoshio Imahori
IPC分类号： H04R2500
CPC分类号： H04R1/06 , H04R9/06
摘要： A low cost dynamic speaker (10) prevents damage of the diaphragm (16) when the speaker (10) is mounted on a printed circuit board (2). An insulating ring (22) is attached to the front surface of the diaphragm (16) at the periphery. The insulating ring (22) has a pair of terminal pins (24) supported thereon for continuity of the lead wire (18a) with the conductor (4) of the printed circuit board (2). The conducting portion (24b) of each of the terminal pins (24) is protruded forward beyond the annular flat surface (22a) of the insulating ring (22).
摘要翻译：当扬声器（10）安装在印刷电路板（2）上时，低成本动态扬声器（10）防止隔膜（16）的损坏。绝缘环（22）在外围附着到隔膜（16）的前表面。绝缘环（22）具有一对支撑在其上的端子销（24），用于使引线（18a）与印刷电路板（2）的导体（4）导通。每个端子销（24）的导电部分（24b）向前突出超过绝缘环（22）的环形平坦表面（22a）。

10. 发明授权

US5435171A Apparatus for automatically preparing solution of powdery product as specimen for use in viscosity measurement 失效
标题翻译：用于自动制备粉状产品溶液作为粘度测量用样品的装置
公开(公告)号：US5435171A
公开(公告)日：1995-07-25
申请号：US171734
申请日：1993-12-22
申请人： Takashi Chino , Yuji Nogami , Hajime Yashiro , Keisuke Kato , Hajime Kitamura , Masaru Takeuchi , Hideo Yoshikoshi , Mikio Kitai
发明人： Takashi Chino , Yuji Nogami , Hajime Yashiro , Keisuke Kato , Hajime Kitamura , Masaru Takeuchi , Hideo Yoshikoshi , Mikio Kitai
IPC分类号： G01N1/36 , G01N1/28 , G01N1/38 , G01N11/00 , G01N33/00 , G01N33/44 , G01N35/00 , B01J4/02
CPC分类号： G01N1/38 , G01N35/0099 , G01N11/00 , G01N2033/0091 , G01N2035/00188 , G01N2035/00217 , G01N2035/00287 , G01N2035/00415 , G01N2035/00524 , G01N2035/00534 , G01N33/442 , Y10T436/10 , Y10T436/109163
摘要： An apparatus for supplying a solution of a powdery product as a specimen of viscosity measurement. The apparatus includes electronic discharge-weighing device (4) for determining the amount of the powdery sample in sample container (2), introduced into hopper (6) and discharged therefrom by vibration-generating drive (5); dissolution container (12) for receiving and dissolving the powdery sample from hopper (6); electronic balance (13)for weighing the powdery sample in container (12); supply source (14) for solvent into container (12); device (36) for heating and stirring the powdery sample and the solvent in container (12), and a control circuit for controlling the apparatus.
摘要翻译：供给作为粘度测定试样的粉末状溶液的装置。该装置包括电子放电称重装置（4），用于确定样品容器（2）中的粉末样品的量，被引入料斗（6）并通过振动产生驱动器（5）从其中排出; 溶解容器（12），用于从料斗（6）接收和溶解粉末样品; 用于称量容器（12）中的粉末样品的电子天平（13）; 用于溶剂的供应源（14）进入容器（12）; 用于加热和搅拌容器（12）中的粉末样品和溶剂的装置（36），以及用于控制装置的控制电路。

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