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    • 5. 发明授权
    • Method of plasma etching thin films of difficult to dry etch materials
    • 等离子体蚀刻难以干蚀刻材料的薄膜的方法
    • US06548414B2
    • 2003-04-15
    • US09396178
    • 1999-09-14
    • Satish D. AthavaleMartin Gutsche
    • Satish D. AthavaleMartin Gutsche
    • H01L21302
    • H01L28/60C23F4/00H01L21/32136
    • A method for etching material which does not readily form volatile compounds in a plasma includes providing a plasma etch chamber including a wafer electrode at an initial temperature. The wafer electrode supports a wafer, and the wafer includes a layer of the material which does not readily form volatile compounds in plasma. The wafer is bombarded with charged particles from a plasma generated in the plasma etch chamber to impart thermal energy to the wafer. A reactive gas flow is provided to react with etch products of the material. Bias power is applied to the wafer electrode to impart bombardment energy to the charged particles incident on the wafer from the plasma such that a predetermined temperature is generated on a surface of the wafer wherein the wafer electrode is maintained at about the initial temperature.
    • 在等离子体中不容易形成挥发性化合物的蚀刻材料的方法包括在初始温度下提供包括晶片电极的等离子体蚀刻室。 晶片电极支撑晶片,并且晶片包括不容易在等离子体中形成挥发性化合物的材料层。 晶圆被等离子体蚀刻室中产生的等离子体的带电粒子轰击,以向晶片赋予热能。 提供反应气流以与材料的蚀刻产物反应。 偏转功率被施加到晶片电极,以从等离子体向入射到晶片上的带电粒子提供轰击能量,从而在晶片的表面上产生预定的温度,其中晶片电极保持在初始温度附近。
    • 9. 发明授权
    • Method for removal of hard mask used to define noble metal electrode
    • 去除用于定义贵金属电极的硬掩模的方法
    • US06420272B1
    • 2002-07-16
    • US09460700
    • 1999-12-14
    • Hua ShenDavid Edward KoteckiSatish D. AthavaleJenny LianGerhard KunkelNimal Chaudhary
    • Hua ShenDavid Edward KoteckiSatish D. AthavaleJenny LianGerhard KunkelNimal Chaudhary
    • H01L2100
    • H01L28/60H01L21/02071H01L21/31116H01L21/32139H01L28/55
    • In semiconductor dynamic random access memory circuits using stacked capacitor storage elements formed using high permittivity dielectric material, it is typical to form the stacked capacitors using noble metal electrodes. Typically, the etching process for the noble metal electrodes requires the use of a hard mask patterning material such as silicon oxide. Removal of this hard mask frequently results in damage to the dielectric surface surrounding the patterned noble metal electrode. A method of removing the hard mask material without damaging the surrounding surface includes the steps of: depositing a soft mask photoresist material over the composite surface, including the hard masked covered noble metal electrode and the dielectric surface, in a manner such that the soft mask material is thinner over the region of the noble metal electrode; removing the portion of the soft mask material over the noble metal electrode leaving the soft mask material over the dielectric surface; etching the hard mask material with the soft mask material protecting the dielectric surface; and removing the remaining portion of the soft mask material.
    • 在使用高介电常数电介质材料形成的叠层电容器存储元件的半导体动态随机存取存储器电路中,典型的是使用贵金属电极形成叠层电容器。 通常,贵金属电极的蚀刻工艺需要使用诸如氧化硅的硬掩模图形材料。 去除这种硬掩模常常导致图案化的贵金属电极周围的电介质表面的损坏。 在不损坏周围表面的情况下去除硬掩模材料的方法包括以下步骤:在复合表面上沉积软掩模光致抗蚀剂材料,包括硬掩蔽的贵金属电极和电介质表面,使得软掩模 材料在贵金属电极的区域上较薄; 在所述贵金属电极上除去所述软掩模材料的所述部分,从而将所述软掩模材料留在所述电介质表面上; 用保护电介质表面的软掩模材料蚀刻硬掩模材料; 以及去除所述软掩模材料的剩余部分。