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    • 1. 发明授权
    • Capacitive chemical sensor
    • 电容化学传感器
    • US08736000B1
    • 2014-05-27
    • US11583442
    • 2006-10-19
    • Ronald P. ManginellMatthew W. MoormanDavid R. Wheeler
    • Ronald P. ManginellMatthew W. MoormanDavid R. Wheeler
    • H01L29/78
    • G01N27/221
    • A microfabricated capacitive chemical sensor can be used as an autonomous chemical sensor or as an analyte-sensitive chemical preconcentrator in a larger microanalytical system. The capacitive chemical sensor detects changes in sensing film dielectric properties, such as the dielectric constant, conductivity, or dimensionality. These changes result from the interaction of a target analyte with the sensing film. This capability provides a low-power, self-heating chemical sensor suitable for remote and unattended sensing applications. The capacitive chemical sensor also enables a smart, analyte-sensitive chemical preconcentrator. After sorption of the sample by the sensing film, the film can be rapidly heated to release the sample for further analysis. Therefore, the capacitive chemical sensor can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.
    • 微型电容化学传感器可用作较大的微量分析系统中的自主化学传感器或分析物敏感的化学预浓缩器。 电容化学传感器检测传感膜介电性能的变化,例如介电常数,电导率或维度。 这些变化是由目标分析物与传感膜的相互作用所致。 该功能提供了一种适用于远程和无人值守感应应用的低功率自加热化学传感器。 电容化学传感器还可以实现智能的分析物敏感化学预浓缩器。 在通过感测膜吸附样品后,可以快速加热膜以释放样品用于进一步分析。 因此,电容化学传感器可以在释放之前优化采样时间,以便通过微量分析系统快速准确地分析分析物。
    • 2. 发明授权
    • Tortuous path chemical preconcentrator
    • 曲折路径化学预浓缩器
    • US07799280B1
    • 2010-09-21
    • US11355480
    • 2006-02-16
    • Ronald P. ManginellPatrick R. LewisDouglas R. AdkinsDavid R. WheelerRobert J. Simonson
    • Ronald P. ManginellPatrick R. LewisDouglas R. AdkinsDavid R. WheelerRobert J. Simonson
    • B01L99/00
    • B01L3/502753B01L2200/0668B01L2300/0883B01L2300/16B01L2400/086G01N1/405Y10T436/2575
    • A non-planar, tortuous path chemical preconcentrator has a high internal surface area having a heatable sorptive coating that can be used to selectively collect and concentrate one or more chemical species of interest from a fluid stream that can be rapidly released as a concentrated plug into an analytical or microanalytical chain for separation and detection. The non-planar chemical preconcentrator comprises a sorptive support structure having a tortuous flow path. The tortuosity provides repeated twists, turns, and bends to the flow, thereby increasing the interfacial contact between sample fluid stream and the sorptive material. The tortuous path also provides more opportunities for desorption and readsorption of volatile species. Further, the thermal efficiency of the tortuous path chemical preconcentrator is comparable or superior to the prior non-planar chemical preconcentrator. Finally, the tortuosity can be varied in different directions to optimize flow rates during the adsorption and desorption phases of operation of the preconcentrator.
    • 非平面曲折路径化学预浓缩器具有高内表面积,其具有可加热吸附涂层,其可用于选择性地收集和浓缩一种或多种感兴趣的化学物质,所述流体物流可作为集中塞快速释放 用于分离和检测的分析或微量分析链。 非平面化学预浓缩器包括具有曲折流动路径的吸附支撑结构。 弯曲度为流动提供了反复的扭转,弯曲和弯曲,从而增加了样品流体流与吸附材料之间的界面接触。 曲折的路径还为挥发物种的解吸和吸收提供了更多的机会。 此外,曲折路径化学预浓缩器的热效率相当于或优于现有的非平面化学预浓缩器。 最后,曲折度可以在不同的方向上变化,以优化预浓缩器的吸附和解吸阶段的流速。
    • 4. 发明授权
    • Weak-link capacitor
    • 弱连接电容
    • US07955945B1
    • 2011-06-07
    • US12892055
    • 2010-09-28
    • Shawn M. DirkRoss S. JohnsonDavid R. WheelerGregory R. Bogart
    • Shawn M. DirkRoss S. JohnsonDavid R. WheelerGregory R. Bogart
    • H01L21/20
    • H01G4/18H01G4/232H01G4/306
    • A process for making a dielectric material where a precursor polymer selected from poly(phenylene vinylene) polyacetylene, poly(p-phenylene), poly(thienylene vinylene), poly(1,4-naphthylene vinylene), and poly(p-pyridine vinylene) is energized said by exposure by radiation or increase in temperature to a level sufficient to eliminate said leaving groups contained within the precursor polymer, thereby transforming the dielectric material into a conductive polymer. The leaving group in the precursor polymer can be a chloride, a bromide, an iodide, a fluoride, an ester, an xanthate, a nitrile, an amine, a nitro group, a carbonate, a dithiocarbamate, a sulfonium group, an oxonium group, an iodonium group, a pyridinium group, an ammonium group, a borate group, a borane group, a sulphinyl group, or a sulfonyl group.
    • 一种制备介电材料的方法,其中前体聚合物选自聚(亚苯基亚乙烯基)聚乙炔,聚(对亚苯基),聚(亚苯基亚乙烯基),聚(1,4-亚萘基亚乙烯基)和聚(对 - 吡啶亚乙烯基) )通过辐射曝光或者将温度升高到足以消除前体聚合物中包含的所述离去基团的水平,从而将电介质材料转化为导电聚合物而被激发。 前体聚合物中的离去基团可以是氯化物,溴化物,碘化物,氟化物,酯,黄原酸酯,腈,胺,硝基,碳酸酯,二硫代氨基甲酸酯,锍基,氧鎓基 ,碘鎓基,吡啶鎓基,铵基,硼酸酯基,硼烷基,亚磺酰基或磺酰基。
    • 6. 发明授权
    • Weak-link capacitor
    • 弱连接电容
    • US08426321B1
    • 2013-04-23
    • US13099143
    • 2011-05-02
    • Shawn M. DirkRoss S. JohnsonDavid R. WheelerGregory R. Bogart
    • Shawn M. DirkRoss S. JohnsonDavid R. WheelerGregory R. Bogart
    • H01L21/31H01L21/469
    • H01G4/18H01G4/232H01G4/306
    • A process for making a dielectric material where a precursor polymer selected from poly(phenylene vinylene)polyacetylene, poly(p-phenylene), poly(thienylene vinylene), poly(1,4-naphthylene vinylene), and poly(p-pyridine vinylene) is energized said by exposure by radiation or increase in temperature to a level sufficient to eliminate said leaving groups contained within the precursor polymer, thereby transforming the dielectric material into a conductive polymer. The leaving group in the precursor polymer can be a chloride, a bromide, an iodide, a fluoride, an ester, an xanthate, a nitrile, an amine, a nitro group, a carbonate, a dithiocarbamate, a sulfonium group, an oxonium group, an iodonium group, a pyridinium group, an ammonium group, a borate group, a borane group, a sulphinyl group, or a sulfonyl group.
    • 一种制备介电材料的方法,其中前体聚合物选自聚(亚苯基亚乙烯基)聚乙炔,聚(对亚苯基),聚(亚苯基亚乙烯基),聚(1,4-亚萘基亚乙烯基)和聚(对 - 吡啶亚乙烯基) )通过辐射曝光或者将温度升高到足以消除前体聚合物中包含的所述离去基团的水平,从而将电介质材料转化为导电聚合物而被激发。 前体聚合物中的离去基团可以是氯化物,溴化物,碘化物,氟化物,酯,黄原酸酯,腈,胺,硝基,碳酸酯,二硫代氨基甲酸酯,锍基,氧鎓基 ,碘鎓基,吡啶鎓基,铵基,硼酸酯基,硼烷基,亚磺酰基或磺酰基。
    • 8. 发明授权
    • Method of making thermally removable polyurethanes
    • 制造热可去除的聚氨酯的方法
    • US06403753B1
    • 2002-06-11
    • US09863173
    • 2001-05-22
    • Douglas A. LoyDavid R. WheelerJames R. McElhanonRandall S. Saunders
    • Douglas A. LoyDavid R. WheelerJames R. McElhanonRandall S. Saunders
    • C08G1862
    • C08G18/6765
    • A method of making a thermally-removable polyurethane material by heating a mixture of a maleimide compound and a furan compound, and introducing alcohol and isocyanate functional groups, where the alcohol group and the isocyanate group reacts to form the urethane linkages and the furan compound and the maleimide compound react to form the thermally weak Diels-Alder adducts that are incorporated into the backbone of the urethane linkages during the formation of the polyurethane material at temperatures from above room temperature to less than approximately 90° C. The polyurethane material can be easily removed within approximately an hour by heating to temperatures greater than approximately 90° C. in a polar solvent. The polyurethane material can be used in protecting electronic components that may require subsequent removal of the solid material for component repair, modification or quality control.
    • 通过加热马来酰亚胺化合物和呋喃化合物的混合物并引入醇和异氰酸酯官能团来制备热可去除的聚氨酯材料的方法,其中醇基和异氰酸酯基团反应形成氨基甲酸酯键和呋喃化合物, 马来酰亚胺化合物在高于室温至小于约90℃的温度下,在形成聚氨酯材料期间反应形成加入了弱的Diels-Alder加合物,其加入聚氨酯键的主链中。聚氨酯材料可以容易地 在大约1小时内通过在极性溶剂中加热至大于约90℃的温度来除去。 聚氨酯材料可用于保护可能需要随后去除固体材料的电子部件,用于部件修理,修改或质量控制。