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    • 8. 发明授权
    • Process for forming copper interconnect structure
    • 形成铜互连结构的工艺
    • US5391517A
    • 1995-02-21
    • US120097
    • 1993-09-13
    • Avgerinos V. GelatosRobert W. Fiordalice
    • Avgerinos V. GelatosRobert W. Fiordalice
    • H01L21/3205H01L21/768H01L23/522H01L23/532H01L21/44
    • H01L23/5226H01L21/32051H01L21/76838H01L23/53238H01L2924/0002
    • A copper metallization structure and process for the formation of electrical interconnections fabricated with pure copper metal is provided. The metallization structure includes an interface layer (22) intermediate to a dielectric layer (12), and a copper interconnect (30). The interface layer (22) functions to adhere the copper interconnect (30) to a device substrate (10) and to prevent the diffusion of copper into underlying dielectric layers. The interconnect layer (22) is fabricated by depositing a first titanium layer (16) followed by the sequential deposition of a titanium nitride layer (18), and a second titanium layer (20). A copper layer (24) is deposited to overlie the second titanium layer (20) and an annealing step is carried out to form a copper-titanium intermetallic layer (26). The titanium nitride layer (18) functions as a diffusion barrier preventing the diffusion of copper into the underlying dielectric layer (12), and the copper titanium intermetallic layer (26) provides an adhesive material, which adheres the copper layer (24) to the device substrate ( 10). Following the formation of the intermetallic layer (26), the device surface is planarized to form a planar surface (28), and to form an inlaid copper interconnect (30).
    • 提供了一种用于形成用纯铜金属制造的电互连的铜金属化结构和工艺。 金属化结构包括介于介电层(12)中间的界面层(22)和铜互连(30)。 界面层(22)用于将铜互连(30)粘附到器件衬底(10)并防止铜扩散到下面的介电层中。 通过沉积第一钛层(16)然后顺序沉积氮化钛层(18)和第二钛层(20)来制造互连层(22)。 沉积铜层(24)以覆盖第二钛层(20),并执行退火步骤以形成铜 - 钛金属间层(26)。 氮化钛层(18)作为阻止铜扩散到下面的电介质层(12)中的扩散阻挡层而起作用,铜钛金属间化合物层(26)提供将铜层(24)粘合到 器件衬底(10)。 在形成金属间层(26)之后,将器件表面平坦化以形成平坦表面(28),并形成镶嵌铜互连(30)。