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1. 发明授权

US06380353B1 Method for reducing the C1-C2-aldehyde content formed from compounds with -CH2-CHR-O-or-CH(OH)-groups 失效
标题翻译：降低由-CH 2 -CHR-O-或-CH 2 -CH（OH） - 基组成的化合物形成的C1-C2-醛含量的方法
公开(公告)号：US06380353B1
公开(公告)日：2002-04-30
申请号：US09623510
申请日：2000-09-29
申请人： Robert Rupaner , Martin Scholtissek , Karl-Heinz Schumacher , Maximilian Angel
发明人： Robert Rupaner , Martin Scholtissek , Karl-Heinz Schumacher , Maximilian Angel
IPC分类号： C08F656
CPC分类号： C08F6/006 , C07B63/04 , C07C29/94 , C07C31/202 , C07C31/18
摘要： Organic compounds containing —CH2—CHR—O— and/or —CH2—CH(OH)— groupings (R=H, C1-C4-alkyl) produce, under the action of free radicals, small amounts of C1-C2-aldehydes, the content of which can be reduced to
摘要翻译：含有-CH2-CHR-O-和/或-CH2-CH（OH） - 基团（R = H，C1-C4-烷基）的有机化合物在自由基的作用下产生少量的C1-C2-醛，通过加入可与醛基反应的化合物，根据新方法，其含量可以降至<1ppm。包含所述组的材料包括聚合物化学中使用的许多乳化剂和保护胶体，例如聚乙二醇，聚乙烯醇或长链醇，酚或胺的乙氧基化产物。该方法对于在这种乳化剂或保护胶体的存在下通过单体的自由基聚合制备的聚合物分散体的处理特别重要，并且允许制备无醛聚合物分散体及其用于卫生和卫生文章。

2. 发明授权

US06458230B1 Preparation of recyclable fiber composites 失效
标题翻译：可回收纤维复合材料的制备
公开(公告)号：US06458230B1
公开(公告)日：2002-10-01
申请号：US08711883
申请日：1996-09-12
申请人： Robert Rupaner , Karl-Heinz Schumacher , Werner Kirchner , Bradley Ronald Morrison , Roland Offner , Hermann Seyffer
发明人： Robert Rupaner , Karl-Heinz Schumacher , Werner Kirchner , Bradley Ronald Morrison , Roland Offner , Hermann Seyffer
IPC分类号： B32B3100
CPC分类号： D04H1/587 , C08F220/18 , D04H1/4209 , D04H1/4218 , D04H1/4242 , D04H1/425 , D04H1/4258 , D04H1/43 , D04H1/4334 , D04H1/435 , D04H1/64 , D04H1/645 , D06M15/227 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/29 , D06M15/31 , D06M15/327 , D06M15/333 , D06M15/347 , D06M15/3566
摘要： A process for preparing recyclable fiber composites, comprising bonding fibers with a polymeric bonding agent applied as an aqueous polymer dispersion to said fibers, the polymeric bonding agent comprising at least one addition polymer which, in the state of an aqueous dispersion, has a film forming capability at the temperature at which the addition polymer is combined with said fibers, and said aqueous polymer dispersion, when subjected to a change in pH, is converted into an aqueous solution of the addition polymer. The aqueous addition polymer of the addition polymer dispersion can contain protic acid groups, and the state of the dispersion can be converted to an aqueous addition polymer solution by raising the pH of the aqueous medium. Alternatively, the addition polymer may contain basic groups, in particular, amino groups, and its state as a dispersion can be converted into an aqueous addition polymer resolution by lowering the pH of the aqueous medium.
摘要翻译：一种制备可回收纤维复合材料的方法，包括将纤维与作为水性聚合物分散体施加到所述纤维上的聚合物粘合剂粘合，所述聚合粘合剂包含至少一种在水分散体状态下具有成膜性的加成聚合物在加成聚合物与所述纤维组合的温度下的能力，以及当经历pH变化时所述聚合物水分散体转化为加成聚合物的水溶液。加成聚合物分散体的水性加成聚合物可以含有质子酸基团，并且通过提高水性介质的pH可以将分散体的状态转化为含水的加成聚合物溶液。或者，加成聚合物可以含有碱性基团，特别是氨基，并且作为分散体的状态可以通过降低水性介质的pH而转化为水性加聚物分辨率。

3. 发明授权

US5753746A Formaldehyde-free aqueous synthetic resin dispersions 失效
标题翻译：无甲醛水溶性合成树脂分散体
公开(公告)号：US5753746A
公开(公告)日：1998-05-19
申请号：US806758
申请日：1997-03-03
申请人： Robert Rupaner , Karl-Heinz Schumacher , Manfred Weber
发明人： Robert Rupaner , Karl-Heinz Schumacher , Manfred Weber
IPC分类号： C08L25/08 , C08F2/22 , C08F6/00 , C08F212/00 , C08F212/08 , C08F220/12 , C08F220/58 , C08F246/00 , C08L25/00 , C08L31/02 , C08L31/04 , C08L33/04 , C08L33/08 , C08L33/18 , D04H1/4258 , D04H1/435 , D04H1/587 , D04H1/64 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/31 , D06M15/333 , B32B27/00
CPC分类号： D04H1/587 , C08F220/12 , C08F220/58 , C08F246/00 , C08F6/006 , D04H1/4258 , D04H1/435 , D04H1/64 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/31 , D06M15/333 , Y10T442/2738
摘要： Formaldehyde-free aqueous synthetic resin dispersions are obtainable by single-stage emulsion polymerization of monomer mixtures containing (A) from 50 to 99% by weight of at least one monomer selected from the group consisting of the acrylic and methacrylic esters of C.sub.1 -C.sub.14 -alkanols, the vinyl esters of monocarboxylic acids having up to 5 carbon atoms, and styrene (monomer A), (B) from 0.5 to 40% by weight of at least one of the monomers acrylonitrile and methacrylonitrile (monomer B), (C) from 0.5 to 10% by weight of at least one monomer of the general formula I ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 and R.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 -alkyl (monomer C), (D) from 0 to 5% by weight of at least one monomer selected from the group consisting of the 3 carbon to 5 carbon .alpha.,.beta.-unsaturated mono- and dicarboxylic acids and their amides and anhydrides (monomer D), and (E) from 0 to 3% by weight of at least one further bifunctional monomer (monomer E).
摘要翻译：不含甲醛的水性合成树脂分散体可通过单体乳液聚合获得，该单体混合物含有（A）50-99重量％的至少一种选自下组的单体：C1-C14- 链烷醇，具有至多5个碳原子的单羧酸的乙烯基酯和苯乙烯（单体A），（B）0.5至40重量％的至少一种单体丙烯腈和甲基丙烯腈（单体B），（C） 0.5至10重量％的至少一种通式I的单体，其中R 1是氢或甲基，R 2和R 3各自独立地是氢或C 1 -C 4 - 烷基（单体C），（ D）0至5重量％的至少一种选自3碳至5碳α，β-不饱和一羧酸和二羧酸及其酰胺和酸酐（单体D）的单体，和（E） 0至3重量％的至少一种另外的双官能单体（单体E）。

4. 发明授权

US5356968A Coating agents 失效
标题翻译：涂层剂
公开(公告)号：US5356968A
公开(公告)日：1994-10-18
申请号：US3436
申请日：1993-01-12
申请人： Robert Rupaner , Michael W. Mueller , Maximilian Angel , Klaus Boehlke
发明人： Robert Rupaner , Michael W. Mueller , Maximilian Angel , Klaus Boehlke
IPC分类号： C08F2/26 , C08F2/30 , C08F20/10 , C08F20/52 , C08F212/00 , C08F212/08 , C08F218/02 , C08F218/04 , C08F220/04 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/42 , C08F220/44 , C08F220/56 , C08F222/02 , C08F246/00 , C09D125/00 , C09D125/02 , C09D125/08 , C09D131/02 , C09D133/02 , C09D133/04 , C09D133/08 , C09D133/26 , C09D157/04 , C09G1/16 , C08K5/41
CPC分类号： C09G1/16 , C08F2/26 , C08F220/12 , C09D125/02 , C09D133/04
摘要： A coating agent comprises an emulsion polymer obtained by free radical emulsion polymerization of a monomer mixture ofA) from 15 to 60% by weight of an acrylic or methacrylic ester having a primary or secondary C.sub.1 -C.sub.18 -alkyl group, as alcohol radical,B) from 15 to 50% by weight of an acrylic or methacrylic ester having tertiary C.sub.4 -C.sub.8 -alkyl group or a C.sub.6 -C.sub.12 -radical that is an alicyclic or aromatic group as alcohol group a methacrylic ester having a primary or secondary C.sub.2 -C.sub.4 -alkyl group as alcohol radical, acrylo- or methacrylonitrile, acryl- or meth-acrylamide, a vinyl ester of a C.sub.1 -C.sub.8 - carboxylic acid,C) from 10 to 50% by weight of one or more C.sub.8 -C.sub.12 - aromatic vinyl compounds,D) from 8 to 20% by weight of an olefinically unsaturated C.sub.3 -C.sub.5 -mono- or C.sub.4 -C.sub.8 -dicarboxylic acid or anhydride, andE) from 0 to 5% by weight of further copolymerizable monomers having functional groups in the presence of from 0.1 to 10% by weight, based on the monomer mixture of A to E, of an emulsifier mixture of(a) one or more anionic emulsified of formula I where ##STR1## M is an alkali metal or ammonium and X and Y are identical or different and each is O--(C.sub.n H.sub.2n O).sub.m --R, OM or NHR, wherein at least one of the radicals X and Y is O--(C.sub.n H.sub.2n O).sub.m --R or NHR, and(b) from 0.1 to 10 parts by weight per part by weight of (a) of at least one further different anionic emulsifier.
摘要翻译：涂层剂包括通过自由基乳液聚合获得的乳液聚合物，A单体混合物为15至60重量％的具有伯或仲C 1 -C 18烷基的丙烯酸或甲基丙烯酸酯，作为醇基，B ）15至50重量％的具有叔C4-C8烷基的丙烯酸或甲基丙烯酸酯或作为醇基的脂环族或芳族基团的C 6 -C 12基团具有伯或仲C 2 -C 4的甲基丙烯酸酯 - 烷基作为醇基，丙烯酰基或甲基丙烯腈，丙烯酰基或甲基丙烯酰胺，C1-C8-羧酸的乙烯基酯，C）10至50重量％的一种或多种C 8 -C 12 - 芳族乙烯基化合物，D）8至20重量％的烯属不饱和C 3 -C 5 - 单 - 或C 4 -C 8 - 二羧酸或酸酐，和E）0至5重量％的其它可共聚单体，其具有官能团基于A至E的单体混合物，乳化剂mixtu的存在为0.1至10重量％（a）一种或多种式I的乳化的式I，其中IM是碱金属或铵，X和Y是相同或不同的，并且各自是O-（C n H 2n O）m R，OM或NHR，其中至少一个的基团X和Y是O-（C n H 2n O）m R或NHR，和（b）0.1至10重量份每重量份的（a）至少一种其它不同的阴离子乳化剂。

5. 发明授权

US08420751B2 Method for producing a polymer 有权
标题翻译：聚合物的制造方法
公开(公告)号：US08420751B2
公开(公告)日：2013-04-16
申请号：US13442221
申请日：2012-04-09
申请人： Ilshat Gubaydullin , Karl-Heinz Wassmer , Robert Rupaner , Jochen Kessler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Huemmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
发明人： Ilshat Gubaydullin , Karl-Heinz Wassmer , Robert Rupaner , Jochen Kessler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Huemmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
IPC分类号： C08F2/00 , C08F4/00 , C08F4/28 , B01J10/00
CPC分类号： B01J19/0006 , B01J19/18 , B01J2219/00166 , B01J2219/00184 , C08F2/00 , C08F2/24 , C08F2400/02
摘要： Provided is a method for performing a polymerization process in a stirred reactor, wherein a critical time window is determined by means of a monitor of at least one polymerization process parameter and an associated process window, and when a critical time window is present, an adaptation of process conditions is made in order to configure the polymerization process to conform to the process window.
摘要翻译：提供了一种在搅拌反应器中进行聚合过程的方法，其中通过至少一个聚合过程参数和相关工艺窗口的监测来确定临界时间窗，并且当存在临界时间窗时，适应的工艺条件是为了配置聚合过程以符合工艺窗口。

6. 发明授权

US06462138B1 Method for reducing residual monomers in liquid systems by adding an oxidation-reduction initiator system 有权
标题翻译：通过添加氧化还原引发剂体系来减少液体体系中残留单体的方法
公开(公告)号：US06462138B1
公开(公告)日：2002-10-08
申请号：US09508089
申请日：2000-03-15
申请人： Robert Rupaner , Sven Lawrenz , Johannes Dobbelaar , Gerhard Bauer , Franz-Josef Mueseler , Werner Kirchner , Bradley Ronald Morrison , Jürgen Nahstoll , Martin Meister , Reinhard Bächer , Wolfgang Hübinger , Gerhard Schumacher
发明人： Robert Rupaner , Sven Lawrenz , Johannes Dobbelaar , Gerhard Bauer , Franz-Josef Mueseler , Werner Kirchner , Bradley Ronald Morrison , Jürgen Nahstoll , Martin Meister , Reinhard Bächer , Wolfgang Hübinger , Gerhard Schumacher
IPC分类号： C08F600
CPC分类号： C08F6/003 , C08F6/006 , Y10S526/919
摘要： A process is described for reducing the residual monomer content in a liquid solution, mixture, melt, suspension or dispersion of a polymer by postpolymerization with addition of a redox initiator system at a reaction temperature appropriate to it and with an extremely short mixing time of the liquid system in the production reactor by metering—gradually, in portions or continuously—at least one of the redox initiator components required to initiate polymerization of the residual monomers over a period (metering time) which is from about 10 to 250 times the mixing time of the liquid system in said reactor.
摘要翻译：描述了一种方法，用于通过在适合于它的反应温度下加入氧化还原引发剂体系并以极短的混合时间减少聚合物的液体溶液，混合物，熔体，悬浮液或分散体中的残余单体含量，液体系统在生产反应器中逐渐，部分或连续地至少一种氧化还原引发剂组分在一段时间（计量时间）内引发聚合残留单体所需的量，其为混合时间的约10至250倍的液体系统。

7. 发明授权

US06428199B1 Chemical reactor with stirrer and incoming and outgoing lines on the reactor floor 失效
标题翻译：具有搅拌器的化学反应器和反应器底板上的输入和输出管线
公开(公告)号：US06428199B1
公开(公告)日：2002-08-06
申请号：US09037798
申请日：1998-03-10
申请人： Robert Rupaner , Sven Lawrenz , Gerhard Bauer
发明人： Robert Rupaner , Sven Lawrenz , Gerhard Bauer
IPC分类号： B01F716
CPC分类号： B01J19/0066 , B01F7/162 , B01F2015/00597 , B01J19/0053 , B01J19/0073 , B01J19/18 , B01J19/20 , B01J2219/00094 , C08F6/006 , Y02P20/149
摘要： A reactor for chemical reactions, especially polymerization reactions, and in particular a reactor for emulsion, suspension, solution, bulk and/or precipitation polymerizations, which has a stirring mechanism, incoming and outgoing lines and a removable lid, and where both the stirring mechanism and incoming and outgoing lines are installed on the reactor floor. The novel reactor is quick and easy to open and clean and permits simple and rapid changeover of the installed stirring elements.
摘要翻译：用于化学反应的反应器，特别是聚合反应的反应器，特别是用于乳液，悬浮液，溶液，本体和/或沉淀聚合的反应器，其具有搅拌机构，输入和输出管线和可移除的盖子，并且其中搅拌机构输入和输出线路安装在电抗器底板上。新型反应器快速且易于打开和清洁，并允许安装的搅拌元件的简单和快速的切换。

8. 发明授权

US08188197B2 Method for producing a polymer 有权
标题翻译：聚合物的制造方法
公开(公告)号：US08188197B2
公开(公告)日：2012-05-29
申请号：US12742552
申请日：2008-09-08
申请人： Ilshat Gubaydullin , Karl-Heinz Wassmer , Robert Rupaner , Jochen Kessler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Huemmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
发明人： Ilshat Gubaydullin , Karl-Heinz Wassmer , Robert Rupaner , Jochen Kessler , Guillermo Arens , Gerald Wildburg , Christian Magin , Wolfgang Huemmer , Lambertus Manders , Rudolf Schuhmacher , Oliver Birkert
IPC分类号： C08F2/00 , C08F4/00 , C08F4/28 , B01J10/00
CPC分类号： B01J19/0006 , B01J19/18 , B01J2219/00166 , B01J2219/00184 , C08F2/00 , C08F2/24 , C08F2400/02
摘要： The present invention relates to a method for performing a polymerization process in a stirred reactor, wherein a critical time window is determined by means of a monitor of at least one polymerization process parameter and an associated process window, and when a critical time window is present, an adaptation of process conditions is made in order to configure the polymerization process to conform to the process window.
摘要翻译：本发明涉及一种在搅拌反应器中进行聚合过程的方法，其中通过至少一个聚合过程参数和相关工艺窗口的监测来确定临界时间窗，并且当存在临界时间窗时为了配置聚合过程以符合工艺窗口，进行工艺条件的适应。

9. 发明授权

US6146746A Formaldehyde-free coating composition for shaped articles 有权
标题翻译：用于成型制品的无甲醛涂料组合物
公开(公告)号：US6146746A
公开(公告)日：2000-11-14
申请号：US101797
申请日：1998-08-19
申请人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
发明人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
IPC分类号： B05D7/24 , B05D1/00 , C08F8/30 , C08J7/04 , C08K5/17 , C08L23/26 , C08L35/00 , C08L57/00 , C08L57/10 , C09D135/00 , B05D3/02 , E04B1/82 , E04B1/84
CPC分类号： C08K5/17
摘要： The use of a formaldehyde-free aqueous binder comprisingA) a polymer obtained by free-radical polymerization comprising 5-100% by weight of an ethylenically unsaturated acid anhydride or of an ethylenically unsaturated dicarboxylic acid whose carboxyl groups may form an anhydride group, andB) an alkanolamine having at least two hydroxyl groupsas a coating composition for shaped articles.
摘要翻译： PCT No.PCT / EP97 / 00773 Sec。 371日期1998年8月19日 102（e）1998年8月19日PCT PCT 1997年2月19日PCT公布。公开号WO97 / 31060 PCT 日期1997年8月28日使用不含甲醛的水性粘合剂，其包含A）通过自由基聚合获得的聚合物，其包含5-100重量％的烯键式不饱和酸酐或其羧基可形成的烯属不饱和二羧酸酸酐基，B）具有至少两个羟基的链烷醇胺作为成型制品的涂料组合物。

10. 发明授权

US6099773A Formaldehyde-free binder for mouldings 有权
标题翻译：用于模塑的无甲醛粘合剂
公开(公告)号：US6099773A
公开(公告)日：2000-08-08
申请号：US101805
申请日：1998-08-21
申请人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
发明人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
IPC分类号： B05D1/00 , B27N1/02 , B27N3/00 , C08F8/30 , C08K5/17 , C08L33/02 , C08L35/00 , C08L57/00 , C08L97/02 , B32B21/02
CPC分类号： C08K5/17 , B27N3/00 , C08L35/00 , C08L97/00 , Y10T428/249925
摘要： A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50.degree. C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130.degree. C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.
摘要翻译： PCT No.PCT / EP97 / 00768 Sec。 371日期1998年8月21日 102（e）1998年8月21日PCT PCT 1997年2月19日PCT公布。公开号WO97 / 31059 日本1997年8月28日一种通过混合不含甲醛的水性粘合剂形成成形制品的方法，其包括A）含有5至100重量％衍生自烯属不饱和酸酐或烯属不饱和酸酐的单元的自由基聚合的聚合物羧酸可以形成酸酐基的二羧酸，以及B）具有至少两个羟基的链烷醇胺与纤维或碎片形成成型制品，其中所述粘合剂具有在72℃下在72℃下干燥的性质，厚度为0.3〜1mm的薄膜，然后在130℃下在空气中固化15分钟后，凝胶含量在50％（重量）以上，其中粘合剂的含量小于0.1％（重量），基于A ）+ B），含有纤维或芯片的含磷反应促进剂。

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