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1. 发明授权

US06462138B1 Method for reducing residual monomers in liquid systems by adding an oxidation-reduction initiator system 有权
标题翻译：通过添加氧化还原引发剂体系来减少液体体系中残留单体的方法
公开(公告)号：US06462138B1
公开(公告)日：2002-10-08
申请号：US09508089
申请日：2000-03-15
申请人： Robert Rupaner , Sven Lawrenz , Johannes Dobbelaar , Gerhard Bauer , Franz-Josef Mueseler , Werner Kirchner , Bradley Ronald Morrison , Jürgen Nahstoll , Martin Meister , Reinhard Bächer , Wolfgang Hübinger , Gerhard Schumacher
发明人： Robert Rupaner , Sven Lawrenz , Johannes Dobbelaar , Gerhard Bauer , Franz-Josef Mueseler , Werner Kirchner , Bradley Ronald Morrison , Jürgen Nahstoll , Martin Meister , Reinhard Bächer , Wolfgang Hübinger , Gerhard Schumacher
IPC分类号： C08F600
CPC分类号： C08F6/003 , C08F6/006 , Y10S526/919
摘要： A process is described for reducing the residual monomer content in a liquid solution, mixture, melt, suspension or dispersion of a polymer by postpolymerization with addition of a redox initiator system at a reaction temperature appropriate to it and with an extremely short mixing time of the liquid system in the production reactor by metering—gradually, in portions or continuously—at least one of the redox initiator components required to initiate polymerization of the residual monomers over a period (metering time) which is from about 10 to 250 times the mixing time of the liquid system in said reactor.
摘要翻译：描述了一种方法，用于通过在适合于它的反应温度下加入氧化还原引发剂体系并以极短的混合时间减少聚合物的液体溶液，混合物，熔体，悬浮液或分散体中的残余单体含量，液体系统在生产反应器中逐渐，部分或连续地至少一种氧化还原引发剂组分在一段时间（计量时间）内引发聚合残留单体所需的量，其为混合时间的约10至250倍的液体系统。

2. 发明授权

US06458230B1 Preparation of recyclable fiber composites 失效
标题翻译：可回收纤维复合材料的制备
公开(公告)号：US06458230B1
公开(公告)日：2002-10-01
申请号：US08711883
申请日：1996-09-12
申请人： Robert Rupaner , Karl-Heinz Schumacher , Werner Kirchner , Bradley Ronald Morrison , Roland Offner , Hermann Seyffer
发明人： Robert Rupaner , Karl-Heinz Schumacher , Werner Kirchner , Bradley Ronald Morrison , Roland Offner , Hermann Seyffer
IPC分类号： B32B3100
CPC分类号： D04H1/587 , C08F220/18 , D04H1/4209 , D04H1/4218 , D04H1/4242 , D04H1/425 , D04H1/4258 , D04H1/43 , D04H1/4334 , D04H1/435 , D04H1/64 , D04H1/645 , D06M15/227 , D06M15/233 , D06M15/263 , D06M15/285 , D06M15/29 , D06M15/31 , D06M15/327 , D06M15/333 , D06M15/347 , D06M15/3566
摘要： A process for preparing recyclable fiber composites, comprising bonding fibers with a polymeric bonding agent applied as an aqueous polymer dispersion to said fibers, the polymeric bonding agent comprising at least one addition polymer which, in the state of an aqueous dispersion, has a film forming capability at the temperature at which the addition polymer is combined with said fibers, and said aqueous polymer dispersion, when subjected to a change in pH, is converted into an aqueous solution of the addition polymer. The aqueous addition polymer of the addition polymer dispersion can contain protic acid groups, and the state of the dispersion can be converted to an aqueous addition polymer solution by raising the pH of the aqueous medium. Alternatively, the addition polymer may contain basic groups, in particular, amino groups, and its state as a dispersion can be converted into an aqueous addition polymer resolution by lowering the pH of the aqueous medium.
摘要翻译：一种制备可回收纤维复合材料的方法，包括将纤维与作为水性聚合物分散体施加到所述纤维上的聚合物粘合剂粘合，所述聚合粘合剂包含至少一种在水分散体状态下具有成膜性的加成聚合物在加成聚合物与所述纤维组合的温度下的能力，以及当经历pH变化时所述聚合物水分散体转化为加成聚合物的水溶液。加成聚合物分散体的水性加成聚合物可以含有质子酸基团，并且通过提高水性介质的pH可以将分散体的状态转化为含水的加成聚合物溶液。或者，加成聚合物可以含有碱性基团，特别是氨基，并且作为分散体的状态可以通过降低水性介质的pH而转化为水性加聚物分辨率。

3. 发明授权

US06696533B1 Stable N-oxly radical assisted emulsion polymerization under pressure 失效
标题翻译：在压力下稳定的正氧基自由基乳液聚合
公开(公告)号：US06696533B1
公开(公告)日：2004-02-24
申请号：US09446121
申请日：1999-12-27
申请人： Michael Fischer , Bradley Ronald Morrison , Heinz Friedrich Sutoris , Yvon Durant
发明人： Michael Fischer , Bradley Ronald Morrison , Heinz Friedrich Sutoris , Yvon Durant
IPC分类号： C08F400
CPC分类号： C08F4/00
摘要： A process of free-radically initiated aqueous emulsion polymerization, in which monomers are polymerized in the presence of a N-oxyl radical and by means of special free-radical polymerization initiators at more than 100° C. and at pressures above the vapor pressure of the polymerization mixture.
摘要翻译：一种自由基引发的水乳液聚合方法，其中单体在N-氧基自由基的存在下通过特殊的自由基聚合引发剂在超过100℃和高于蒸气压的压力下聚合聚合混合物。

4. 发明授权

US06503983B1 Stable N-oxyl radial assisted mini emulsion polymerization 失效
标题翻译：稳定的N-氧基半辅助微乳液聚合
公开(公告)号：US06503983B1
公开(公告)日：2003-01-07
申请号：US09446119
申请日：1999-12-27
申请人： Bradley Ronald Morrison , Klemens Mathauer , Michael Fischer , Yvon Durant
发明人： Bradley Ronald Morrison , Klemens Mathauer , Michael Fischer , Yvon Durant
IPC分类号： C08F400
CPC分类号： C08F4/00
摘要： A process of free-radically initiated aqueous emulsion polymerization, in which polymerization is conducted in the presence of a stable N-oxyl radical and the diameter of the monomer droplets in disperse distribution in the aqueous medium is ≦500 nm.
摘要翻译：自由基引发的水乳液聚合方法，其中在稳定的N-氧基存在下进行聚合，并且在水性介质中分散分布中单体液滴的直径为<= 500nm。

5. 发明授权

US06660814B1 Preparation of emulsion homo- and copolymers and device therefore 失效
标题翻译：因此制备乳液均聚物和共聚物和装置
公开(公告)号：US06660814B1
公开(公告)日：2003-12-09
申请号：US08940996
申请日：1997-09-30
申请人： Huberrus Kröner , Wolfgang Klanig , Bradley Ronald Morrison , Rainer Klostermann , Holger Schöpke , Walter Kastenhuber
发明人： Huberrus Kröner , Wolfgang Klanig , Bradley Ronald Morrison , Rainer Klostermann , Holger Schöpke , Walter Kastenhuber
IPC分类号： C08F200
CPC分类号： B01J19/1881 , C08F2/22 , Y10S526/92 , Y10S526/922
摘要： In the process and a correspondingly appropriate device for preparing homo- or copolymers of at least one of the, polymerizable monomers of the group consisting of styrene, butadiene, vinyl chloride, vinyl acetate, vinylidene chloride, alkyl (meth)acrylatc (meth)acrylic acid, (meth)acrylonitrile and (meth)acrylamide reaction is carried out at at least 40° C. in the presence of a dispersing auxiliary and of a free-radical polymerization initiator such that at least 85% by weight of the polymer is formed from these monomers. In the multistage process the procedure is such that a) in a first stage water is added as a solvent which is inert in the reaction and dispersing auxiliaries, seed and a first portion of monomer(s) are added if desired, b) in a second stage initiator is added, and c) in a third stage the remainder or all of the monomer(s) is added directly or in emulsion form and in the presence of further water and, if desired, further dispersing auxiliary or other auxiliaries, it also being possible to operate any two of the stages as a single stage. The reaction mixture, which is in emulsion form, is moved in all or some stages through an external circuit which leads from and back to the reaction vessel (2) and comprises at least one low-shear pump (7) and at least one heat exchanger (8) having an essentially laminar flow profile. The products prepared by this process, which involves short preparation times, have good performance properties (for adhesive bonds, for example).
摘要翻译：在该方法中以及用于制备苯乙烯，丁二烯，氯乙烯，乙酸乙烯酯，偏二氯乙烯，（甲基）丙烯酸（甲基）丙烯酸烷基酯，（甲基）丙烯酸烷基酯（甲基）丙烯酸烷基酯中的至少一种可聚合单体的均聚物或共聚物的相应适当的装置酸，（甲基）丙烯腈和（甲基）丙烯酰胺反应在分散助剂和自由基聚合引发剂的存在下在至少40℃下进行，使得形成至少85重量％的聚合物来自这些单体。在多级方法中，a）在第一阶段中加入水作为在反应中为惰性的溶剂，并且分散助剂，如果需要，加入种子和第一部分单体，b）在第二阶段并且c）在第三阶段中，剩余或全部单体直接或以乳液形式加入，并且在另外的水的存在下，如果需要，还可以分散辅助剂或其它助剂，它也是可以将任何两个阶段操作为单一阶段。乳液形式的反应混合物通过从反应容器（2）引出并返回到反应容器（2）的外部回路在所有或某些阶段中移动，并且至少包括一个低剪切泵（7）和至少一个具有基本层流轮廓的热交换器（8）。通过该方法制备的产品，其制备时间短，具有良好的性能（例如粘合剂粘合）。

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