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    • 2. 发明授权
    • Method and composition for reducing gate oxide damage during RF sputter
clean
    • 用于在RF溅射清洗期间减少栅极氧化物损伤的方法和组合物
    • US5994211A
    • 1999-11-30
    • US976033
    • 1997-11-21
    • Zhihai WangWei-Jen HsiaWilbur Catabay
    • Zhihai WangWei-Jen HsiaWilbur Catabay
    • H01L21/02H01L21/3213H01L21/768H01L21/70
    • H01L21/02071H01L21/76814H01L21/76843H01L21/76844
    • Provided is a method and composition for RF sputter cleaning of contact and via holes which provides substantially uniform charge distribution in the holes and minimizes electron shadowing. This is accomplished by isotropically depositing, such as by PVD, a layer of conductive material at the wafer surface surrounding a hole and down the sides of the hole. Isotropic deposition is such that in high aspect ratio trenches and holes deposition is heaviest at the top and minimal at the bottom (due to the deposition shadowing effect). The deposited conductive material is preferably a metal that is also used as a liner in the holes prior to depositing the plug material. The conductive material provides path for negative charge otherwise accumulating at the top of a hole during RF sputter cleaning to reach the bottom of the hole and thereby prevents accumulations of charge of one polarity in and around the hole. Thus, the stress on the gate oxide caused by conventional RF sputtering, described above, is relieved.
    • 提供了用于RF溅射清洗接触孔和通孔的方法和组合物,其在孔中提供基本上均匀的电荷分布并使电子阴影最小化。 这通过诸如PVD的各向同性地沉积在围绕孔的晶片表面和孔的侧面的导电材料层来实现。 各向同性沉积使得在高纵横比下,沟槽和孔沉积在顶部最重,底部最小(由于沉积阴影效应)。 沉积的导电材料优选是在沉积插塞材料之前也用作孔中的衬垫的金属。 导电材料提供用于负电荷的路径,否则在RF溅射清洗期间积聚在孔的顶部以到达孔的底部,从而防止在孔内和周围累积一种极性的电荷。 因此,如上所述,通过常规RF溅射引起的栅极氧化物上的应力得以缓解。
    • 3. 发明授权
    • Method and composition for reducing gate oxide damage during RF sputter clean
    • 用于在RF溅射清洗期间减少栅极氧化物损伤的方法和组合物
    • US06204550B1
    • 2001-03-20
    • US09251702
    • 1999-02-17
    • Zhihai WangWei-Jen HsiaWilbur Catabay
    • Zhihai WangWei-Jen HsiaWilbur Catabay
    • H01L23495
    • H01L21/02071H01L21/76814H01L21/76843H01L21/76844
    • Provided is a method and composition for RF sputter cleaning of contact and via holes which provides substantially uniform charge distribution in the holes and minimizes electron shadowing. This is accomplished by isotropically depositing, such as by PVD, a layer of conductive material at the wafer surface surrounding a hole and down the sides of the hole. Isotropic deposition is such that in high aspect ratio trenches and holes deposition is heaviest at the top and minimal at the bottom (due to the deposition shadowing effect). The deposited conductive material is preferably a metal that is also used as a liner in the holes prior to depositing the plug material. The conductive material provides path for negative charge otherwise accumulating at the top of a hole during RF sputter cleaning to reach the bottom of the hole and thereby prevents accumulations of charge of one polarity in and around the hole. Thus, the stress on the gate oxide caused by conventional RF sputtering, described above, is relieved.
    • 提供了用于RF溅射清洗接触孔和通孔的方法和组合物,其在孔中提供基本上均匀的电荷分布并使电子阴影最小化。 这通过诸如PVD的各向同性地沉积在围绕孔的晶片表面和孔的侧面的导电材料层来实现。 各向同性沉积使得在高纵横比下,沟槽和孔沉积在顶部最重,底部最小(由于沉积阴影效应)。 沉积的导电材料优选是在沉积插塞材料之前也用作孔中的衬垫的金属。 导电材料提供用于负电荷的路径,否则在RF溅射清洗期间积聚在孔的顶部以到达孔的底部,从而防止在孔内和周围累积一个极性的电荷。 因此,如上所述,通过常规RF溅射引起的栅极氧化物上的应力得以缓解。