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    • 2. 发明授权
    • Method of coloring porous material
    • 多孔材料着色方法
    • US07232467B2
    • 2007-06-19
    • US10525300
    • 2003-08-26
    • Jean-Marie AdamTaher YousafBeate FröhlingVictor Paul Eliu
    • Jean-Marie AdamTaher YousafBeate FröhlingVictor Paul Eliu
    • A61K7/13
    • A61K8/4966A61Q5/065C07C245/24C09B67/0079
    • A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) at least one capped diazonium compound of Formula (1) and/or at least one compound of Formula (2) and/or at least one compound of Formula (3) wherein Q is an unsubstituted or substituted aromatic or heterocyclic residue, R is the radical of an unsubstituted or substituted, water-soluble aliphatic or aromatic amine, and T is an unsubstituted or substituted, water-soluble aliphatic or aromatic residue, wherein at least one of the groups must contain a radical imparting water solubility, and a) at least one water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component
    • 描述了一种着色多孔材料,特别是人发的方法,该方法包括以任何所需顺序依次或同时施用着色的材料,a)至少一种式(1)的封端重氮化合物和/或在 至少一种式(2)的化合物和/或至少一种式(3)的化合物,其中Q是未取代或取代的芳族或杂环残基,R是未取代或取代的水溶性脂族或芳族胺的基团, 并且T是未取代或取代的水溶性脂族或芳族残基,其中所述基团中的至少一个必须含有自由基赋予水溶性,和a)至少一种水溶性偶联组分, 不会发生,然后使存在于材料上的覆盖的重氮化合物与偶联组分反应
    • 6. 发明授权
    • Dye mixtures and the use thereof
    • 染料混合物及其用途
    • US6030420A
    • 2000-02-29
    • US207540
    • 1998-12-08
    • Jean-Marie Adam
    • Jean-Marie Adam
    • C09B1/34C09B29/00C09B67/22D06P1/40D06P1/96D06P3/14D06P3/24D06P3/87D06P5/00
    • C09B67/0038D06P1/40D06P1/96Y10S8/924
    • The invention relates to dye mixtures comprising at least one dye of formula (1) ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy and R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, together with at least one dye of formula (2) ##STR2## wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy, R.sub.4 is hydrogen or C.sub.1 -C.sub.4 alkyl and R.sub.5 is C.sub.2 -C.sub.6 alkyl uninterrupted or interrupted by oxygen, with the proviso that R.sub.1 is not methyl when R.sub.2, R.sub.3 and R.sub.4 are hydrogen and R.sub.5 is ethyl.The dye mixtures are suitable for dyeing or printing natural or synthetic polyamide fibre materials, especially in combination with other dyes and especially from short liquors. The dye mixture is distinguished by generally good properties, especially good uptake and good solubility.
    • 本发明涉及包含至少一种式(1)的染料的染料混合物,其中R1是氢,C1-C4烷基或C1-C4烷氧基,R2是氢或C1-C4烷基,以及至少一种式(2)的染料,其中R3 是氢,C 1 -C 4烷基或C 1 -C 4烷氧基,R 4是氢或C 1 -C 4烷基,R 5是不间断或被中断的C 2 -C 6烷基,条件是当R 2,R 3和R 4是氢时,R 1不是甲基,R 5是乙基 。 染料混合物适用于染色或印刷天然或合成聚酰胺纤维材料,特别是与其他染料,尤其是短酒混合。 染料混合物通常具有良好的性能,特别是良好的吸收性和良好的溶解性。
    • 7. 发明授权
    • Process for trichromatic dyeing or printing
    • 三色染色或印刷方法
    • US5630851A
    • 1997-05-20
    • US609217
    • 1996-03-01
    • Guido JordineJean-Marie Adam
    • Guido JordineJean-Marie Adam
    • C09B29/01C09B29/30C09B67/22D06P3/16D06P3/24
    • C09B67/0051C09B29/0007C09B29/30D06P3/16D06P3/241Y10S8/917Y10S8/924
    • A process for dyeing or printing polyamide material by the trichromatic technique using a dye mixture which contains least two yellow- or orange-dyeing dyes of formula (1) ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, and X is hydrogen or C.sub.1 -C.sub.4 alkyl; together with at least one red-dyeing dye of formulae (2) and (3) ##STR2## wherein R.sub.2 is C.sub.1 -C.sub.6 alkyl, phenyl or cyclohexyl and R.sub.3 is C.sub.1 -C.sub.6 alkyl, or wherein R.sub.2 and R.sub.3, together with the linking nitrogen atom, form an azepinyl ring, and R.sub.4 is hydrogen, C.sub.2 -C.sub.4 alkanoylamino or halogen; and together with at least one of the blue-dyeing dyes of formulae (4) and (5) ##STR3## wherein R.sub.5 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.6 is C.sub.1 -C.sub.4 alkyl or amino, R.sub.7 is hydrogen or methyl, and R.sub.8 is a C.sub.2-4 hydroxyalkylsulfamoyl radical, is disclosed.
    • 一种通过三色技术使用含有至少两种式(1)的黄色或橙色染色染料(1)的染料混合物染色或印刷聚酰胺材料的方法,其中R1是氢,C1-C4烷基,C1-C4烷氧基 或卤素,X为氢或C 1 -C 4烷基; 连同至少一种式(2)和(3)的染色染料,烷基,苯基或环己基,R 3是C 1 -C 6烷基,或其中R 2和R 3与连接氮原子一起形成吖庚因环,R 4 是氢,C 2 -C 4烷酰基氨基或卤素; 并且与至少一种式(4)和(5)的染色染料中的至少一种(5)其中R 5是氢或C 1 -C 4烷基,R 6是C 1 -C 4烷基或氨基, R7是氢或甲基,R8是C2-4羟烷基氨磺酰基。
    • 9. 发明授权
    • Cationic phthalocyanine compounds
    • 阳离子酞菁化合物
    • US4845209A
    • 1989-07-04
    • US229789
    • 1988-08-04
    • Jean-Marie Adam
    • Jean-Marie Adam
    • C07D487/22C09B47/08C09B47/26C09B47/32D06P1/14D06P1/42D21H19/10D21H21/28
    • D21H21/28C09B47/32D06P1/14
    • The invention relates to phthalocyanine compounds of the formula ##STR1## wherein MePc is a copper, cobalt or nickel phthalocyanine radical,R.sub.1 is hydrogen or alkyl,X is alkylene, andR.sub.2, R.sub.3 and R.sub.4, are each independently alkyl which is unsubstituted or substituted by hydroxy, alkoxy, phenyl or amino, or R.sub.1 and R.sub.2, when taken together, are methylene, ethylene or propylene if X is methylene or ethylene, or two or three of R.sub.2, R.sub.3 and R.sub.3, together with the nitrogen atom, form a 5- to 7-membered unsubstituted or substituted heterocyclic ring which may contain one or two additional hetero atoms selected from the group consisting of O, N and S as ring members,An.sup..crclbar. is a cation and M is a cation, and x is greater than y and y is greater than 0, and the sum of x+y is 4 or less than 4.These compounds can be used as dyes, in particular for dyeing and printing cellulosic materials and polyacrylonitrile materials, especially paper.
    • 本发明涉及式(I)的酞菁化合物,其中MePc是铜,钴或镍酞菁基,R 1是氢或烷基,X是亚烷基,R 2,R 3和R 4各自独立地是烷基, 如果X是亚甲基或亚乙基,或者R 2,R 3和R 3的两个或三个与氮原子一起,则它们被羟基,烷氧基,苯基或氨基取代,或者R 1和R 2一起是亚甲基,亚乙基或丙烯 形成5至7元未取代或取代的杂环,其可以含有一个或两个另外的选自O,N和S的杂原子作为环成员,An( - )是阳离子,M是阳离子 ,x大于y且y大于0,x + y之和为4或小于4.这些化合物可用作染料,特别用于染色和印花纤维素材料和聚丙烯腈材料,特别是纸张 。