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1. 发明授权

US5407885A Photochromic naphthacenequinones, process for their preparation and the use thereof 失效
标题翻译：光致变色并萘醌，其制备方法及其应用
公开(公告)号：US5407885A
公开(公告)日：1995-04-18
申请号：US12079
申请日：1993-02-01
申请人： Walter Fischer , Jurgen Finter , Heinz Spahni
发明人： Walter Fischer , Jurgen Finter , Heinz Spahni
IPC分类号： C07C67/30 , C07C46/00 , C07C50/24 , C07C50/36 , C07C69/92 , C07C69/94 , C07C253/30 , C07C255/54 , C09B3/58 , C09K9/02 , G03C1/73
CPC分类号： C07C50/36 , C07C50/24 , C09B3/58 , C09K9/02 , G03C1/73
摘要： Compounds of formula I or V or mixtures thereof ##STR1## wherein R is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.5, and R.sub.5 is H, C.sub.1 -C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, and at least one of the substituents R.sub.1 to R.sub.4 is --F, --Cl or --Br, or is independently the group RO--, and the other substituents R.sub.1 to R.sub.4 are H, --F, --Cl or --Br, are reversible photochromic systems which can be used for contrast formation, light absorption or for the reversible optical storage of information.
摘要翻译：式（I）的化合物或其混合物其中R是被C 1 -C 12烷基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，苯基取代的未被取代的C 6 -C 14芳基或C 6 -C 14芳基，苄基，-CN，-CF 3，卤素或-COOR 5，R 5为H，C 1 -C 18烷基，环己基，环戊基，苯基，C 1 -C 12烷基苯基，苄基或C 1 -C 12烷基苄基，并且至少一个取代基R 1至R 4为 - F，-Cl或-Br，或独立地为基团RO-，其它取代基R 1至R 4为H，-F，-Cl或-Br，是可逆的光致变色体系，其可用于对比形成，光吸收或用于信息的可逆光存储。

2. 发明授权

US5225525A Photochromic benzothioxanthone oxides, process for their preparation and the use thereof 失效
标题翻译：光致变色苯并噻吩酮氧化物，其制备方法及其用途
公开(公告)号：US5225525A
公开(公告)日：1993-07-06
申请号：US947647
申请日：1992-09-17
申请人： Walter Fischer , Jurgen Finter , Heinz Spahni
发明人： Walter Fischer , Jurgen Finter , Heinz Spahni
IPC分类号： C07D335/04 , C09B57/14 , G03C1/73 , G03F7/09 , G03F7/095 , G11B7/244
CPC分类号： C07D335/04 , C09B57/14 , G03C1/73 , G03F7/091 , G03F7/0952 , G11B7/244
摘要： Compounds of formula I or III or mixtures thereof ##STR1## wherein R is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.3, x is 1 or 2, and R.sub.1 is H, linear or branched C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or C.sub.2 -C.sub.12 alkynyl, C.sub.7 -C.sub.16 aralkyl, C.sub.8 -C.sub.16 alkaralkyl, --CH.sub.2 COOR.sub.3 or C.sub.1 -C.sub.12 acyl, wherein R.sub.3 is H, C.sub.1 -C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, are reversible photochromic systems which can be used for contrast formation, light absorption or for the reversible optical storage of information.
摘要翻译：式I或III的化合物或其混合物其中R是被C 1 -C 12烷基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，苯基，苄基，-CN - 取代的未取代的C 6 -C 14芳基或C 6 -C 14芳基， CF 3，卤素或-COOR 3，x是1或2，并且R 1是H，直链或支链C 1 -C 12烷基，C 2 -C 12烯基或C 2 -C 12炔基，C 7 -C 16芳烷基，C 8 -C 16烷基烷基，-CH 2 COOR 3或C 1 -C 12酰基，其中R 3 是H，C 1 -C 18烷基，环己基，环戊基，苯基，C 1 -C 12烷基苯基，苄基或C 1 -C 12烷基苄基，是可用于对比形成，光吸收或信息的可逆光学存储的可逆光致变色体系。

3. 发明授权

US5208354A Photochromic naphthacenequinones, process for their preparation and the use thereof 失效
标题翻译：光致变色石墨烯，其制备方法及其用途
公开(公告)号：US5208354A
公开(公告)日：1993-05-04
申请号：US801150
申请日：1991-12-02
申请人： Walter Fischer , Jurgen Finter , Heinz Spahni
发明人： Walter Fischer , Jurgen Finter , Heinz Spahni
IPC分类号： C07C67/30 , C07C46/00 , C07C50/24 , C07C50/36 , C07C69/92 , C07C69/94 , C07C253/30 , C07C255/54 , C09B3/58 , C09K9/02 , G03C1/73
CPC分类号： C07C50/36 , C07C50/24 , C09B3/58 , C09K9/02 , G03C1/73
摘要： Compounds of formula I or V or mixtures thereof ##STR1## whereinR is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.5, and R.sub.5 is H, C.sub.1 -C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, and at least one of the substituents R.sub.1 to R.sub.4 is --F, --Cl or --Br, or is independently the group RO--, and the other substituents R.sub.1 to R.sub.4 are H, --F, --Cl or --Br, are reversible photochromic systems which can be used for contrast formation, light absorption or for the reversible optical storage of information.
摘要翻译：式I或V的化合物或其混合物其中R是被C 1 -C 12烷基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，苯基，苄基，-CN - 取代的未取代的C 6 -C 14芳基或C 6 -C 14芳基， CF 3，卤素或-COOR 5，R 5是H，C 1 -C 18烷基，环己基，环戊基，苯基，C 1 -C 12烷基苯基，苄基或C 1 -C 12烷基苄基，并且至少一个取代基R 1至R 4是-F，-Cl或 - Br或独立地是基团RO-，其它取代基R 1至R 4是H，-F，-Cl或-Br，是可逆的光致变色体系，其可用于对比度形成，光吸收或用于可逆光学存储信息。

4. 发明申请

US20080130474A1 Optical Recording Materials Having High Stroage Density 审中-公开
标题翻译：具有高剧烈密度的光学记录材料
公开(公告)号：US20080130474A1
公开(公告)日：2008-06-05
申请号：US10561392
申请日：2004-06-25
申请人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
发明人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
IPC分类号： G11B7/24 , B32B3/02
CPC分类号： G11B7/248 , C09B47/26
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I). For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 300 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density even at high speeds.
摘要翻译：本发明涉及一种光记录介质，其包括基底，记录层和任选的一个或多个反射层，其中记录层包含式（I）的化合物。关于进一步取代基的详细定义，参见说明书。特别是在300〜500nm的波长下进行记录和回放，例如使用蓝色激光。录音和播放质量极佳，即使在高速下也能保持较高的存储密度。

5. 发明授权

US5641879A Phthalocyanines substituted by phosphorus-containing groups 失效
标题翻译：由含磷基团取代的酞菁
公开(公告)号：US5641879A
公开(公告)日：1997-06-24
申请号：US530971
申请日：1995-09-20
申请人： Heinz Wolleb , Hanspeter Preiswerk , Beat Schmidhalter , Heinz Spahni
发明人： Heinz Wolleb , Hanspeter Preiswerk , Beat Schmidhalter , Heinz Spahni
IPC分类号： B41M5/26 , C07D487/22 , C09B47/04 , C09B47/10 , G11B7/244
CPC分类号： C07D487/22 , C09B47/10
摘要： The invention relates to phthalocyanines and metal complexes thereof with divalent metals or divalent oxo metals, which contain at least one phosphorus-containing substituent bonded to the peripheral carbon skeleton via the phosphorus atom.The compounds preferably conform to the general structural formula (G).sub.k -A-(Q).sub.l, in which A is a phthalocyanine or metal complex thereof with a divalent metal or a divalent oxo metal, G is a phosphorus-containing substituent, Q is a further substituent as defined below, the index k is a number from 1 to 16, and l, independently thereof, is 0 or a number from 1 to 15, with the proviso that the sum of k and l is a number less than or equal to 16.The invention also relates to a material for the optical recording and storage of information, in which at least one storage layer (2) of a novel phthalocyanine compound or a metal complex thereof has been applied to a transparent, dielectric carrier material (1).
摘要翻译：本发明涉及酞菁及其与二价金属或二价氧代金属的金属络合物，其含有至少一个通过磷原子与外围碳骨架结合的含磷取代基。化合物优选符合通式结构式（G）kA-（Q）1，其中A是与二价金属或二价氧代金属的酞菁或其金属络合物，G是含磷取代基，Q是另外的取代基如下所定义，索引k为1至16的数字，且l独立地为0或1至15的数，条件是k和l的和小于或等于本发明还涉及一种用于光学记录和存储信息的材料，其中至少一个新的酞菁化合物或其金属络合物的存储层（2）已经被施加到透明的介电载体材料（ 1）。

6. 发明授权

US5177218A Photochromic benzothioxanthone oxides, process for their preparation and the use thereof 失效
标题翻译：光致变色二氧化硅氧化物，其制备方法及其用途
公开(公告)号：US5177218A
公开(公告)日：1993-01-05
申请号：US814945
申请日：1991-12-30
申请人： Walter Fischer , Jurgen Finter , Heinz Spahni
发明人： Walter Fischer , Jurgen Finter , Heinz Spahni
IPC分类号： C07D335/16 , C07D335/04 , C09B57/14 , C09K9/00 , C09K9/02 , G03C1/73 , G03F7/09 , G03F7/095 , G11B7/244
CPC分类号： G11B7/244 , C07D335/04 , C09B57/14 , G03C1/73 , G03F7/091 , G03F7/0952 , G11B7/2531 , G11B7/2533
摘要： Compounds of formula I or III or mixtures thereof ##STR1## wherein R is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.3, x is 1 or 2, and R.sub.1 is H, linear or branched C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or C.sub.2 -C.sub.12 alkynyl, C.sub.7 -C.sub.16 aralkyl, C.sub.8 -C.sub.16 alkaralkyl, --CH.sub.2 COOR.sub.3 or C.sub.1 -C.sub.12 acyl, wherein R.sub.3 is H, C.sub.1 -C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, are reversible photochromic systems which can be used for contrast formation, light absorption or for the reversible optical storage of information.
摘要翻译：式I或III的化合物或其混合物其中R是被C 1 -C 12烷基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，苯基，苄基，-CN - 取代的未取代的C 6 -C 14芳基或C 6 -C 14芳基， CF 3，卤素或-COOR 3，x是1或2，并且R 1是H，直链或支链C 1 -C 12烷基，C 2 -C 12烯基或C 2 -C 12炔基，C 7 -C 16芳烷基，C 8 -C 16烷基烷基，-CH 2 COOR 3或C 1 -C 12酰基，其中R 3 是H，C 1 -C 18烷基，环己基，环戊基，苯基，C 1 -C 12烷基苯基，苄基或C 1 -C 12烷基苄基，是可用于对比形成，光吸收或信息的可逆光学存储的可逆光致变色体系。

7. 发明申请

US20070172624A1 Optical recording materials writable using blue lasers 审中-公开
标题翻译：光学记录材料可使用蓝色激光器写入
公开(公告)号：US20070172624A1
公开(公告)日：2007-07-26
申请号：US10590021
申请日：2005-02-16
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
IPC分类号： B32B3/02
CPC分类号： G11B7/2492 , C09B47/045 , G11B7/2472 , G11B7/2475 , G11B7/2478 , G11B7/248 , G11B7/2534 , G11B7/259 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I) or a tautomeric or mesomeric form thereof, wherein G1 and G2 are each independently of the other C(R5) or N; M1 is a lanthanide or transition metal of groups 4 to 10; P is a phthalocyanino diradical; and R1 to R5 are substituents as defined in the description and the claims. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density.
摘要翻译：本发明涉及一种包括基底，记录层和任选的一个或多个反射层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或介导体形式，其中G 1， / SUB和G 2各自独立地为C（R 5 N）或N; M 1是第4至10族的镧系元素或过渡金属; P是酞菁双基; 和R 1至R 5是如说明书和权利要求书中所定义的取代基。记录和回放特别是在350至500nm的波长下进行，例如使用蓝色激光。录制和播放质量非常好，可以保持较高的存储密度。

8. 发明申请

US20050250942A1 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US20050250942A1
公开(公告)日：2005-11-10
申请号：US11169126
申请日：2005-06-28
申请人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jurgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： B41M5/26 , C09B47/12 , C09B47/18 , C09B47/24 , C09B67/22 , G11B7/244 , G11B7/248 , G11B7/26 , C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

9. 发明授权

US5206395A Photochromic naphthacenequinones, process for their preparation and the use thereof 失效
标题翻译：光致变色并萘醌，其制备方法及其应用
公开(公告)号：US5206395A
公开(公告)日：1993-04-27
申请号：US880458
申请日：1992-05-08
申请人： Walter Fischer , Evelyn Fischer , Ernst Minder , Manfred Hofmann , Jurgen Finter , Heinz Spahni
发明人： Walter Fischer , Evelyn Fischer , Ernst Minder , Manfred Hofmann , Jurgen Finter , Heinz Spahni
IPC分类号： C07C317/24 , C07C323/22 , C09K9/02 , G03C1/73
CPC分类号： C07C317/24 , C07C323/22 , C09K9/02 , G03C1/73 , C07C2103/44
摘要： Compounds of the formula I or V, or mixtures thereof, ##STR1## wherein R is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.5, and R.sub.5 is H, C.sub.16 l-C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, and at least one of the substituents R.sub.1 to R.sub.4 is an organic thio, sulfoxyl or sulfonyl group, and the other members R.sub.1 to R.sub.4 are H, F, Cl or Br, are reversible photochromic systems which can be used for contrast formation or light absorption.
摘要翻译：式（I）的化合物或其混合物，其中R是未取代的C 1 -C 14芳基或C 1 -C 12烷基取代的C 6 -C 14芳基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，苯基，苄基，-CN，-CF 3，卤素或-COOR 5，并且R 5是H，C 16 C 18烷基，环己基，环戊基，苯基，C 1 -C 12烷基苯基，苄基或C 1 -C 12烷基苄基，以及至少一个取代基R 1 R 4为有机硫代，亚砜基或磺酰基，其他成员R1〜R4为H，F，Cl或Br，为可用于造影或光吸收的可逆光致变色体系。

10. 发明授权

US07378221B2 Metallocenyl phthalocyanines as optical recording media 失效
标题翻译：金属茂基酞菁作为光记录介质
公开(公告)号：US07378221B2
公开(公告)日：2008-05-27
申请号：US11169126
申请日：2005-06-28
申请人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
发明人： Jürgen Beyrich , Rudolf Blattner , Jean-Luc Budry , Wolfgang Freitag , Colin Morton , Gerald Anthony Murphy , Beat Schmidhalter , Michael Schulz , Heinz Spahni , Christian Stern , Annemarie Wolleb , Heinz Wolleb , Roland Zoelper
IPC分类号： C09B47/04 , G11B7/24
CPC分类号： G11B7/248 , C09B67/0035 , G11B7/26 , Y10S430/146
摘要： Mixtures of metallocenyl phthalocyanines obtainable by reacting a mixture A comprising two phthalocyanines: with a metallocene derivative in the presence of a catalyst, and also oligomeric metallocenyl phthalocyanines, processes for preparing them, their use for, inter alia, optical recording and optical recording media.
摘要翻译：通过使包含两种酞菁的混合物A与茂金属衍生物在催化剂存在下反应获得的金属茂合酞菁的混合物，以及低聚金属茂基酞菁，其制备方法，尤其用于光学记录和光学记录介质。

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