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    • 3. 发明授权
    • Process for coloring high molecular weight organic material and
polycyclic pigments
    • 高分子量有机材料和多环颜料的着色方法
    • US06126735A
    • 2000-10-03
    • US155733
    • 1998-10-05
    • Thomas EichenbergerMax Hugin
    • Thomas EichenbergerMax Hugin
    • C07D475/02C07D487/14C08K5/00C08K5/34C08L101/00C09B17/00C09B57/00D06P1/00
    • C07D487/14C08K5/0041C09B17/00C09B57/00
    • A process for mass coloring high molecular weight organic material by using a pyrimidopteridine of formula I and/or II ##STR1## or a mixture thereof, wherein A, B, C and D are each independently of one another --NH.sub.2, --OH, hydrogen, C.sub.1 -C.sub.4 -alkyl; phenyl, biphenyl or naphthyl which are unsubstituted or substituted by halogen, --OH, --NH.sub.2, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy; --NHR.sub.1, --N(R.sub.1).sub.2 or ##STR2## wherein R.sub.1 is C.sub.1 -C.sub.4 alkyl; phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 -alkoxy, or --COXR.sub.2,X is a direct bond, --O-- or --NH--, andR.sub.2 is C.sub.1 -C.sub.4 alkyl; phenyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 -alkoxy, with the proviso that at least two of the radicals A, B, C and D are --NH.sub.2 or --OH.
    • PCT No.PCT / EP97 / 05739 Sec。 371日期:1998年10月5日 102(e)日期1998年10月5日PCT 1997年10月17日PCT公布。 公开号WO98 / 18866 日期1998年5月7日A通过使用式I和/或II的嘧啶并哒嗪或其混合物大量着色高分子量有机材料的方法,其中A,B,C和D各自彼此独立地为-NH 2,-OH, 氢,C 1 -C 4 - 烷基; 苯基,联苯基或萘基,其未被取代或被卤素,-OH,-NH 2,C 1 -C 4烷基或C 1 -C 4烷氧基取代; -NHR1,-N(R1)2或其中R1是C1-C4烷基; 未被取代或被卤素,C 1 -C 4烷基或C 1 -C 4 - 烷氧基取代的苯基或-COXR 2,X是直接键,-O-或-NH-,并且R 2是C 1 -C 4烷基; 苯基,其未被取代或被卤素,C 1 -C 4烷基或C 1 -C 4 - 烷氧基取代,条件是基团A,B,C和D中的至少两个是-NH 2或-OH。
    • 5. 发明授权
    • Organic black pigments and their preparation
    • 有机黑色颜料及其制备方法
    • US08691002B2
    • 2014-04-08
    • US13144940
    • 2009-12-28
    • Thomas EichenbergerThomas RuchRalf BauerChristoph KrebsUrsula LuterbacherMarc Maurer
    • Thomas EichenbergerThomas RuchRalf BauerChristoph KrebsUrsula LuterbacherMarc Maurer
    • C09D11/02C08K5/3417C07D405/14
    • C09B57/00C07D405/04C07D493/04C08K5/0041C09B67/0034Y10T428/2982Y10T442/30
    • A process for preparing a black colorant, preferably a black pigment, characterized in that a compound of the Formula (I) is reacted with a compound of the Formula (II) in a molar ratio of 1:2, in the presence of a catalyst which in water at 25° C. has a pK≦4.5. For the definition of R1 to R7, refer to the description; preferably all are H. Likewise claimed are new crystal polymorphs obtainable by this process, and preferably single-phase mixed crystals. Also claimed are synergistic compositions. These compositions exhibit increased light stability in plastics stabilized with basic light stabilizers when they are pigmented with colorants of the invention rather than with known black pigments such as carbon black. The specification also relates, furthermore, to the use of the black colorants of the invention for coloring paints, printing inks and plastics in the mass, and to mulch film, instrument panels, woven fabrics, garden furniture items or elements for the construction industry that are pigmented with said colorants.
    • 一种制备黑色着色剂,优选黑色颜料的方法,其特征在于使式(I)化合物与摩尔比为1:2的式(II)化合物在催化剂存在下反应 其在25℃的水中具有pK≦̸ 4.5。 关于R1〜R7的定义,请参考说明书; 优选全部为H.同样要求保护的是通过该方法可获得的新晶体多晶型物,优选单相混合晶体。 还要求的是协同组合物。 当用本发明的着色剂着色时,这些组合物在用碱性光稳定剂稳定的塑料中显示增强的光稳定性,而不是已知的黑色颜料如炭黑。 此外,本说明书还涉及本发明的黑色着色剂用于在油漆中着色油漆,印刷油墨和塑料的用途,以及用于建筑行业的膜,仪表板,机织织物,花园家具或元件的覆盖 用着色剂着色。
    • 7. 发明授权
    • Benzimidazole-pyridone-based azo dyes
    • 苯并咪唑 - 吡啶酮基偶氮染料
    • US07217803B2
    • 2007-05-15
    • US10537063
    • 2003-11-26
    • Leonhard FeilerThomas RaimannThomas EichenbergerMax Hügin
    • Leonhard FeilerThomas RaimannThomas EichenbergerMax Hügin
    • C09B31/14C09B29/36C09B69/04D06P3/60
    • C09B69/045C09B29/3617C09B31/14Y10S8/922
    • The present invention relates to azo dyes of formula (1) which are soluble in organic solvents, wherein R1 is —CN, —COOR5, —CONR6R7 or a heterocyclic ring, R2 is unsubstituted or substituted alkyl, unsubstituted or substituted aryl, —CF3, —COOR5, —CONR6R7 or —COR5, R3 is hydrogen, —SO3M, alkyl, alkoxy, alkylcarbonyl, —NO2 or halogen, R4 is substituted aryl, substituted heteroaryl or an aryl-N═N-aryl radical, wherein one or both of the aryl radicals in aryl-N═N-aryl is/are unsubstituted or substituted, or a radical heteroaryl-N═N-heteroaryl, wherein one or both of the heteroaryl radicals in heteroaryl-N═N-heteroaryl is/are unsubstituted or substituted, R5 is hydrogen, alkyl or unsubstituted or substituted aryl, R6 is hydrogen, alkyl or unsubstituted or substituted aryl, R7 is hydrogen, alkyl or unsubstituted or substituted aryl, M+ is a cation, n is a number 1, 2 or 3 and m is a number 1, 2 or 3, to a process for the preparation thereof and to the use thereof in the production of colored plastics or polymeric color particles, and as printing inks, printing dyes, coating compositions and wood stains
    • 本发明涉及可溶于有机溶剂的式(1)的偶氮染料,其中R 1是-CN,-COOR 5,-CONR 6 R 7或杂环R 2是未取代或取代的烷基,未取代或取代的芳基,-CF 3 - , - COOR 5,-CONR 6 R 7或-COR 5,R 3, 是氢,-SO 3 M,烷基,烷氧基,烷基羰基,-NO 2或卤素,R 4是取代的芳基,取代的杂芳基或 芳基-NH-芳基,其中芳基-NH-芳基中的一个或两个芳基是未被取代或取代的,或者是杂芳基-NH-杂芳基,其中杂芳基-NN中的一个或两个杂芳基 - 杂芳基是未取代或取代的,R 5是氢,烷基或未取代或取代的芳基,R 6是氢,烷基或未取代或取代的芳基,R SUB > 7是氢,烷​​基或未取代的 取代或取代的芳基,M + +是一种阳离子,n是数字1,2或3,m是数字1,2或3,其制备方法及其用途 在生产有色塑料或聚合彩色颗粒时,以及作为印刷油墨,印刷染料,涂料组合物和木材污渍
    • 10. 发明授权
    • Use of pyrimido[5,4-g]pteridines as shading component in color filter colorant compositions
    • 在滤色剂着色剂组合物中使用嘧啶并[5,4-g]蝶啶作为遮光组分
    • US07731791B2
    • 2010-06-08
    • US11663823
    • 2005-09-21
    • Takashi DenoThomas EichenbergerJoachim Voigt
    • Takashi DenoThomas EichenbergerJoachim Voigt
    • C09B67/22C09B67/20G02F1/1335G02B5/22C08K5/00
    • C08K5/0041C09B67/0033G02B5/223
    • The present invention relates to the field of color filters and LCDs. More specifically, the invention relates to a colorant composition for making color filters comprising pyrimido[5,4-g]pteridine derivatives of formula (I) wherein A1, A2, A3, and A4 are each independently of the others —NR1R2, wherein R1 and R2 are each independently of the others hydrogen, CrC8alkyl, —CO—C1-C8alkyl, —CO—Ce—Cuaryl, —COO—C1-C8alkyl, —COO—Ce—CMaryl, —CONH-d-Cβalkyl or —CONH—Ce-CMaryl, Or A1, A2, A3, and A4 are each independently of the others —OH, —SH, hydrogen, CrC8alkyl, CrC8alkoxy, or C6-C14aryl or —O—C6-C14aryl each unsubstituted or mono- or poly-substituted by halogen, nitro, cyano, —OR10, —SR10, —NR10R11, —CONR10R11, —COOR10, —SO2R10, —SO2NR10R11, —SO3R10, —NR11COR10 or by —NR11COOR10, wherein R10 and R11 are each independently of the others hydrogen, CrC8alkyl, C5-C12cycloalkyl or C2-C8-alkenyl; and to their use for color filter production and to color filters comprising said pyrimido[5,4-g]pteridine derivatives of formula (I).
    • 本发明涉及滤色器和LCD的领域。 更具体地,本发明涉及一种用于制备包含式(I)的嘧啶并[5,4-g]蝶啶衍生物的滤色剂的着色剂组合物,其中A1,A2,A3和A4各自独立地为-NR1R2,其中R1 -CO-C 1 -C 8烷基,-CO-C 1 -C 6芳基,-COO-C 1 -C 8烷基,-COO-C 1 -C 10芳基,-CONH-d-C 1 -C 8烷基或 - CONH-C 1 -C 10芳基或者A 1,A 2,A 3和A 4各自独立地为-OH,-SH,氢,C 1 -C 8烷基,C 1 -C 8烷氧基或C 6 -C 14芳基或者-O-C 6 -C 14芳基, 被卤素,硝基,氰基,-OR10,-SR10,-NR10R11,-CONR10R11,-COOR10,-SO2R10,-SO2NR10R11,-SO3R10,-NR11COR10或-NR11COOR10多取代,其中R10和R11各自独立地为 其它氢,C 1 -C 8烷基,C 5 -C 12环烷基或C 2 -C 8 - 烯基; 以及它们用于滤色器生产的用途以及包含式(I)的所述嘧啶并[5,4-g]蝶啶衍生物的滤色片。