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    • 3. 发明授权
    • Tire with tread of elastomer composition
    • 轮胎与弹性体组成的胎面
    • US5504140A
    • 1996-04-02
    • US315476
    • 1994-09-30
    • David J. ZanzigPaul H. SandstromJohn J. A. VertheRaymond R. DiRossiGregory M. Holtzapple
    • David J. ZanzigPaul H. SandstromJohn J. A. VertheRaymond R. DiRossiGregory M. Holtzapple
    • B60C1/00C08K3/00C08K3/04C08K3/36C08L7/00C08L9/00C08L9/06C08L21/00
    • C08L9/00B60C1/0016C08L9/06C08L7/00Y02T10/862
    • Pneumatic rubber tire with a tread composed of a rubber blend of a base of at least two synthetic elastomers composed of (i) specialized isoprene/butadiene copolymer elastomer having a low Tg in a range of about -70.degree. to about -100.degree. C. and (ii) a diene based elastomer having a Tg in a range of about -5.degree. to about -30.degree. C. together with a minor amount of natural cis 1,4-polyisoprene rubber. Selection of the base of the said two synthetic elastomers having spaced apart, or spatially defined, Tg's of at least 40.degree. C. is an important feature of the tread rubber blend. Representative examples of contemplated elastomers with Tg's in a range of about -5.degree. to about -30.degree. C. are 3,4-polyisoprene elastomer, styrene/isoprene copolymer elastomer and high vinyl polybutadiene elastomers.In one aspect, the tread rubber blend is reinforced with reinforcing filler composed of carbon black or a combination of carbon black and silica accompanied by a coupling agent.
    • 具有胎面的气动橡胶轮胎,其由至少两种合成弹性体的基底的橡胶共混物组成,所述合成弹性体由(i)具有约-70℃至约-100℃范围内的低Tg的特殊异戊二烯/丁二烯共聚物弹性体组成。 和(ii)Tg在约-5℃至约-30℃范围内的二烯基弹性体以及少量天然顺式1,4-聚异戊二烯橡胶。 具有至少40℃的间隔或空间限定的Tg的所述两种合成弹性体的基底的选择是胎面橡胶共混物的重要特征。 具有Tg在约-5℃至约-30℃范围内的预期弹性体的代表性实例是3,4-聚异戊二烯弹性体,苯乙烯/异戊二烯共聚物弹性体和高乙烯基聚丁二烯弹性体。 在一个方面,胎面橡胶共混物用伴随着偶联剂的炭黑或炭黑和二氧化硅的组合的增强填料增强。
    • 6. 发明授权
    • Tire with tread composition
    • 轮胎与胎面组成
    • US5341863A
    • 1994-08-30
    • US062263
    • 1993-05-17
    • Paul H. SandstromRaymond B. Roennau
    • Paul H. SandstromRaymond B. Roennau
    • B60C1/00C08L21/00C08L7/00C08L9/00C08L23/06
    • C08L21/00Y10S152/905
    • A pneumatic tire having a sulfur cured tread is provided comprised of at least one diene rubber and a low density polyethylene having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C., wherein the said LDPE is mixed with the said rubber at a temperature of about 120.degree. C. to about 170.degree. C. prior to sulfur vulcanizing the blend.A process is also provided for producing a tire in which a hot cured tire is removed from its rigid mold where the tread is comprised of at least one diene rubber and a low density polyethylene (LDPE) having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C.; and wherein the said LDPE is mixed with the said unvulcanized rubber at a temperature of about 120.degree. C. to about 170.degree. C.
    • 提供了具有硫硫化胎面的充气轮胎,其由至少一种二烯橡胶和具有约104℃至约115℃范围内的结晶熔点的低密度聚乙烯组成,其中所述LDPE与 所述橡胶在硫化硫化混合物之前在约120℃至约170℃的温度下进行。 还提供了一种用于生产轮胎的方法,其中热硬化轮胎从其刚性模具中去除,其中胎面由至少一种二烯橡胶和低密度聚乙烯(LDPE)组成,其中结晶熔点在约 104℃至约115℃。 并且其中所述LDPE与所述未硫化橡胶在约120℃至约170℃的温度下混合。
    • 9. 发明授权
    • Secondary vulcanization accelerator
    • 二次硫化促进剂
    • US4855364A
    • 1989-08-08
    • US302521
    • 1989-01-27
    • Paul H. Sandstrom
    • Paul H. Sandstrom
    • C08K5/17
    • C08K5/17
    • It is often desirable to utilize accelerators in the sulfur vulcanization of unsaturated rubbers. In many cases a primary accelerator is used in combination with another accelerator, called a secondary accelerator or activator, which further increases the rate of vulcanization. It has been determined that compounds having the structural formula:NH.sub.2 --A--NH--(CH.sub.2).sub.x NH].sub.n A--NH.sub.2wherein x is 2 or 3, wherein n is an integer from 1 to 100, and wherein A represents an alkylene group containing from 1 to 20 carbons atoms, act as secondary accelerators in the vulcanization of unsaturated rubbers. For example, it has been determined that 4,7-diaza-decane-1,10-diamine is a particularly desirable secondary accelerator.
    • 通常希望在不饱和橡胶的硫磺硫化中使用促进剂。 在许多情况下,主促进剂与另一促进剂(称为次级促进剂或活化剂)组合使用,这进一步提高了硫化速率。 已经确定具有以下结构式的化合物:NH 2 -A-NH-(CH2)xNH] nA-NH2其中x为2或3,其中n为1至100的整数,并且其中A表示含有 1〜20个碳原子,作为不饱和橡胶硫化的二次加速剂。 例如,已经确定4,7-二氮杂 - 癸烷-1,10-二胺是特别期望的二次加速剂。