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1. 发明授权

US5070150A Process for the solid state (solventless) hydroxylation of vinyl-containing rubbers using a hydroxymercaptan 失效
标题翻译：使用羟基硫醇的含乙烯基橡胶的固态（无溶剂）羟基化方法
公开(公告)号：US5070150A
公开(公告)日：1991-12-03
申请号：US548326
申请日：1990-07-02
申请人： Roger J. Hopper
发明人： Roger J. Hopper
IPC分类号： C08F8/34 , C08C19/20 , C08C19/38 , C08F8/00
CPC分类号： C08C19/20
摘要： The present invention relates to a process for preparing hydroxylated rubber by reacting (a) a rubber having from about 5 to about 75 percent of a 1,2-double bond content with (b) a mercaptan of the formula: ##STR1## wherein n is an integer of from 3 to 19; and wherein the reaction is conducted in the solid state and is catalyzed by a free radical catalyst.

2. 发明授权

US4820780A Modification of rubber with N-chlorothio-sulfonamide 失效
标题翻译：用N-氯硫代磺酰胺改性橡胶
公开(公告)号：US4820780A
公开(公告)日：1989-04-11
申请号：US108654
申请日：1987-10-15
申请人： Roger J. Hopper
发明人： Roger J. Hopper
IPC分类号： C08F210/18 , C08F8/34 , C08F210/16 , C08C19/22
CPC分类号： C08F8/34 , C08F2800/20
摘要： Chlorothio-sulfonamide modified rubbery terpolymers, such as chlorothio-sulfonamide modified EPDM rubbers, have utility in a variety of applications. For example, such modified rubbers can be utilized in the sidewalls of pneumatic tires. Such modified rubbers are prepared by reacting a terpolymer of ethylene, an .alpha.-olefin containing from 3 to 6 carbon atoms, and a non-conjugated diene containing from 6 to 12 carbon atoms with a N-chlorothio-sulfonamide. The present invention is based upon the unexpected finding that the rate of this reaction can be greatly accelerated by conducting it in the presence of a saturated aliphatic carboxylic acid containing from 6 to 30 carbon atoms, such as stearic acid. The present invention accordingly discloses in a method of preparing a N-chlorothio-sulfonamide modified terpolymer by reacting a terpolymer of ethylene, an .alpha.-olefin containing from 3 to 6 carbon atoms, and a non-conjugated diene containing from 6 to 12 carbon atoms with a N-chlorothio-sulfonamide; the improvement which comprises conducting the reaction in the presence of at least one saturated aliphatic carboxylic acid containing from 6 to 30 carbon atoms.

3. 发明授权

US5405985A Preparation of sulfur-containing organosilicon compounds 失效
标题翻译：含硫有机硅化合物的制备
公开(公告)号：US5405985A
公开(公告)日：1995-04-11
申请号：US272366
申请日：1994-07-08
申请人： Dane K. Parker , Richard T. Musleve , Robert C. Hirst , Roger J. Hopper
发明人： Dane K. Parker , Richard T. Musleve , Robert C. Hirst , Roger J. Hopper
IPC分类号： C07F7/18 , C07F7/08
CPC分类号： C07F7/1892
摘要： The present invention relates to a process for the production of organosilicon compounds of the formulaZ-Alk-S.sub.n -Alk-Z (I)in which Z is selected from the group consisting of ##STR1## where R.sub.1 is an alkyl group of 1 to 4 carbon atoms, cyclohexyl or phenyl;R.sub.2 is alkoxy of 1 to 8 carbon atoms, or cycloalkoxy of 5 to 8 carbon atoms;Alk is a divalent hydrocarbon of 1 to 18 carbon atoms and n is an integer of 2 to 8; comprising reacting (A) a compound of the formula:Z-Alk-X (II)when X is Cl, Br or I; with (B) a compound of the formulaMe.sub.2 S.sub.n (III)where Me is ammonium, or an alkali metal;wherein the reaction is conducted in the presence of a phase transfer catalyst and an aqueous phase.
摘要翻译：本发明涉及一种制备式Z-Alk-Sn-Alk-Z（I）的有机硅化合物的方法，其中Z选自下组，其中R 1是1至 4个碳原子，环己基或苯基; R 2是1至8个碳原子的烷氧基或5至8个碳原子的环烷氧基; Alk为1〜18个碳原子的二价烃，n为2〜8的整数，包括当X是Cl，Br或I时，使（A）式：Z-Alk-X（II）的化合物反应; 与（B）式Me2Sn（III）的化合物，其中Me是铵或碱金属; 其中反应在相转移催化剂和水相存在下进行。

4. 发明授权

US4085093A Sulfilimines as premature vulcanization inhibitors 失效
标题翻译：亚磺酰亚胺作为早熟硫化抑制剂
公开(公告)号：US4085093A
公开(公告)日：1978-04-18
申请号：US707970
申请日：1976-07-23
申请人： Roger J. Hopper
发明人： Roger J. Hopper
IPC分类号： C08L7/00 , C07C67/00 , C07C325/00 , C07C381/00 , C08K5/00 , C08K5/43 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C07C143/72 , C07C143/84 , C08F28/00
CPC分类号： C08K5/43 , C08K5/36
摘要： N-sulfonyl-sulfilimine compounds such as S,S-di(isopropyl)-N-(p-toluenesulfonyl) sulfilimine are used as premature vulcanization inhibitors in polymers compounded for sulfur vulcanization.
摘要翻译：在磺化硫化聚合物中使用N-磺酰基 - 亚磺酰亚胺化合物如S，S-二（异丙基）-N-（对甲苯磺酰基）亚硫酰亚胺作为早熟硫化抑制剂。

5. 发明授权

US4017468A N-chlorothiocarboxylic acid amide/imide-modified terpolymers 失效
标题翻译： N-氯代噻唑羧酸酰胺/酰亚胺改性三元共聚物
公开(公告)号：US4017468A
公开(公告)日：1977-04-12
申请号：US591372
申请日：1975-06-30
申请人： Roger J. Hopper
发明人： Roger J. Hopper
IPC分类号： C08L7/00 , B60C1/00 , C08F8/00 , C08F8/34 , C08K5/43 , C08L21/00 , C08L23/00 , C08L101/00 , C08K5/44
CPC分类号： B60C1/0025 , C08F8/34
摘要： A modified rubbery terpolymer, and blends thereof, which comprises the admixture product of a rubbery terpolymer of ethylene, .alpha.-olefin and non-conjugated diene with at least one compound selected from specific types of N-chlorothiocarboxylic acid amides and imides. The sulfur-cured composites are particularly useful in the sidewall portions of pneumatic tires.
摘要翻译：一种改性橡胶三元共聚物及其共混物，其包含乙烯，α-烯烃和非共轭二烯的橡胶状三元共聚物与至少一种选自特定类型的N-氯代硫代羧酸酰胺和酰亚胺的化合物的混合产物。硫固化复合材料在充气轮胎的侧壁部分特别有用。

6. 发明授权

US5216066A Tread compounds containing modified EPDM which exhibit good abrasion resistance and improved hysteresis properties 失效
标题翻译：含有改性EPDM的胎面化合物具有良好的耐磨性和改善的滞后性能
公开(公告)号：US5216066A
公开(公告)日：1993-06-01
申请号：US877576
申请日：1992-05-01
申请人： Paul H. Sandstrom , Leland E. Beyersdorff , Roger J. Hopper
发明人： Paul H. Sandstrom , Leland E. Beyersdorff , Roger J. Hopper
IPC分类号： B60C1/00 , C08L21/00 , C08L23/32
CPC分类号： C08L21/00 , B60C1/0016 , C08L23/32 , Y10S152/905
摘要： A tire tread composition comprises a tread rubber compound containing a sulfonamide modified EPDM terpolymer which imparts improved abrasion resistance, improved ozone resistance, improved hysteresis and the like.
摘要翻译：轮胎胎面组合物包含含有磺酰胺改性的EPDM三元共聚物的胎面橡胶化合物，其赋予改进的耐磨性，改善的耐臭氧性，改善的滞后等。

7. 发明授权

US4877901A Process for synthesizing N,N'-dithiobis(sulfonamides) 失效
标题翻译：合成N，N'-二硫代双（磺酰胺）的方法
公开(公告)号：US4877901A
公开(公告)日：1989-10-31
申请号：US263836
申请日：1988-10-28
申请人： Roger J. Hopper , Niranjan V. Shah , Steven M. Ryba
发明人： Roger J. Hopper , Niranjan V. Shah , Steven M. Ryba
IPC分类号： C07C381/08 , C07C303/40 , C07C311/48
CPC分类号： C07C303/40
摘要： The present invention relates to a process for synthesizing N,N'-dithiobis(sulfonamides) by reacting a sulfonamide of the formula: ##STR1## with sulfur monochloride and caustic in a mixed organic-aqueous mediua, wherein R.sup.1 and R.sup.2 are independently selected from the group consisting of alkyl radicals having from about 1 to about 20 carbon atoms, cycloalkyl radicals having from about 5 to about 20 carbon atoms, phenyl radicals, alkaryl radicals having from about 7 to 20 carbon atoms, and haloaryl radicals having about 6 to about 10 carbon atoms and where R.sup.1 is also selected from radicals having the formula: ##STR2## wherein R.sup.3 and R.sup.4 are individually selected from said alkyl, cycloalkyl, phenyl, alkaryl and haloaryl radicals and wherein R.sup.3 and R.sup.4 can be joined together to represent radicals selected from --CH.sub.2 --.sub.n, where n is an integer of 4 to 7 and --CH.sub.2).sub.2 O--CH.sub.2 --.sub.2.

8. 发明授权

US4374732A Resins for removal of organo-sulfur compounds from organic or aqueous media 失效
标题翻译：用于从有机或含水介质中除去有机硫化合物的树脂
公开(公告)号：US4374732A
公开(公告)日：1983-02-22
申请号：US307348
申请日：1981-09-30
申请人： Roger J. Hopper
发明人： Roger J. Hopper
IPC分类号： B01D15/00 , B01J20/22 , B01J20/26 , C02F1/28 , C08F8/00 , C08F8/42 , C08F8/44 , C10G25/00 , B01D15/04
CPC分类号： C08F8/44 , B01D15/00 , B01J20/22 , C02F1/285 , Y10S210/908
摘要： Organo-sulfur impurities are removed from organic or aqueous solutions by contacting said solutions with polymers containing functional groups consisting of metal salts of N-halosulfonamides.
摘要翻译：通过使所述溶液与含有由N-卤代磺酰胺的金属盐组成的官能团的聚合物接触，从有机或水溶液中除去有机硫杂质。

9. 发明授权

US4727105A Oligomeric amine and phenolic antidegradants 失效
标题翻译：低聚胺和酚类抗降解剂
公开(公告)号：US4727105A
公开(公告)日：1988-02-23
申请号：US605035
申请日：1985-01-25
申请人： Roger J. Hopper
发明人： Roger J. Hopper
IPC分类号： C08K5/36 , C07C7/20 , C07C323/39 , C07C323/51 , C07C327/10 , C08K5/00 , C08K5/372 , C08K5/375 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C07C149/43 , C07C149/32 , C07C149/42
CPC分类号： C08K5/375 , C07C323/00 , C08K5/3725
摘要： There is disclosed a compound having the structureA--S--X--S--A' Iwherein A and A' are radicals independently selected from the group consisting of the following structures: ##STR1## wherein R.sub.1 and R.sub.2 are tertiary alkyl radicals having 4 to 8, preferably 4 to 6 carbon atoms, n is a whole number of 1 to 8, R.sub.3 and R.sub.4 are the same or different radicals selected from the group consisting of hydrogen and alkyl radicals having 1 to 18 carbon atoms, R.sub.5 is hydrogen or methyl and Z is --O-- or ##STR2## A' can also be hydrogen; and X is a divalent oligomeric segmer having the structure: ##STR3## wherein m ranges from an average of 4 to about 24. There is also disclosed a polymeric cmposition comprising a polymer susceptible to the degradative effects of oxidation having incorporated therein an antidegradant amount of a compound of Structure I.
摘要翻译：公开了具有结构ASXS-A'I的化合物，其中A和A'是独立地选自以下结构的基团：其中R 1和R 2是具有4个至8，优选4至6个碳原子，n为1至8的整数，R 3和R 4为选自氢和具有1至18个碳原子的烷基的相同或不同的基团，R 5为氢或甲基和Z是-O-或者也可以是氢; 并且X是具有以下结构的二价低聚分离体：（C 2 H 4 OCH 2 OC 2 H 4 SS）m C 2 H 4 OCH 2 OC 2 H 4 IV其中m的平均值为4至约24.另外还公开了一种聚合物，其包含对氧化降解作用敏感的聚合物，其中掺入抗降解剂结构Ⅰ化合物的量。

10. 发明授权

US4714742A Cyanamide derivatives as vulcanization rate modifiers 失效
标题翻译：氰胺衍生物作为硫化速率调节剂
公开(公告)号：US4714742A
公开(公告)日：1987-12-22
申请号：US920531
申请日：1986-10-20
申请人： Roger J. Hopper , Carl R. Parks
发明人： Roger J. Hopper , Carl R. Parks
IPC分类号： C08J3/24 , C08K5/16 , C08K5/315 , C08L21/00 , C08C19/20 , C08C19/22
CPC分类号： C08K5/315
摘要： There are disclosed cyanamide derivatives as vulcanization rate modifiers which when added to customary cure packages, accelerate the rate of vulcanization and result in vulcanizates having improved characteristics and age resistance.

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