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1. 发明授权

US5504140A Tire with tread of elastomer composition 失效
标题翻译：轮胎与弹性体组成的胎面
公开(公告)号：US5504140A
公开(公告)日：1996-04-02
申请号：US315476
申请日：1994-09-30
申请人： David J. Zanzig , Paul H. Sandstrom , John J. A. Verthe , Raymond R. DiRossi , Gregory M. Holtzapple
发明人： David J. Zanzig , Paul H. Sandstrom , John J. A. Verthe , Raymond R. DiRossi , Gregory M. Holtzapple
IPC分类号： B60C1/00 , C08K3/00 , C08K3/04 , C08K3/36 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00
CPC分类号： C08L9/00 , B60C1/0016 , C08L9/06 , C08L7/00 , Y02T10/862
摘要： Pneumatic rubber tire with a tread composed of a rubber blend of a base of at least two synthetic elastomers composed of (i) specialized isoprene/butadiene copolymer elastomer having a low Tg in a range of about -70.degree. to about -100.degree. C. and (ii) a diene based elastomer having a Tg in a range of about -5.degree. to about -30.degree. C. together with a minor amount of natural cis 1,4-polyisoprene rubber. Selection of the base of the said two synthetic elastomers having spaced apart, or spatially defined, Tg's of at least 40.degree. C. is an important feature of the tread rubber blend. Representative examples of contemplated elastomers with Tg's in a range of about -5.degree. to about -30.degree. C. are 3,4-polyisoprene elastomer, styrene/isoprene copolymer elastomer and high vinyl polybutadiene elastomers.In one aspect, the tread rubber blend is reinforced with reinforcing filler composed of carbon black or a combination of carbon black and silica accompanied by a coupling agent.
摘要翻译：具有胎面的气动橡胶轮胎，其由至少两种合成弹性体的基底的橡胶共混物组成，所述合成弹性体由（i）具有约-70℃至约-100℃范围内的低Tg的特殊异戊二烯/丁二烯共聚物弹性体组成。和（ii）Tg在约-5℃至约-30℃范围内的二烯基弹性体以及少量天然顺式1,4-聚异戊二烯橡胶。具有至少40℃的间隔或空间限定的Tg的所述两种合成弹性体的基底的选择是胎面橡胶共混物的重要特征。具有Tg在约-5℃至约-30℃范围内的预期弹性体的代表性实例是3,4-聚异戊二烯弹性体，苯乙烯/异戊二烯共聚物弹性体和高乙烯基聚丁二烯弹性体。在一个方面，胎面橡胶共混物用伴随着偶联剂的炭黑或炭黑和二氧化硅的组合的增强填料增强。

2. 发明授权

US5087668A Rubber blend and tire with tread thereof 失效
标题翻译：橡胶混合物和具有胎面的轮胎
公开(公告)号：US5087668A
公开(公告)日：1992-02-11
申请号：US698007
申请日：1991-05-09
申请人： Paul H. Standstrom , J. Dale Massie, II , John J. A. Verthe , Gregory M. Holtzapple , Raymond R. DiRossi
发明人： Paul H. Standstrom , J. Dale Massie, II , John J. A. Verthe , Gregory M. Holtzapple , Raymond R. DiRossi
IPC分类号： B60C1/00 , C08L7/00 , C08L9/00 , C08L21/00
CPC分类号： B60C1/0016 , C08L7/00 , C08L9/00 , C08L9/06 , Y10S152/905
摘要： A pneumatic tire with a tread composed of a blend of 3,4-polyisoprene rubber, cis 1,4 polyisoprene rubber and at least one additional diene based rubber.
摘要翻译：一种具有由3,4-聚异戊二烯橡胶，顺式1,4-聚异戊二烯橡胶和至少一种另外的二烯基橡胶的共混物组成的胎面的充气轮胎。

3. 发明授权

US5300577A Rubber blend and tire with tread thereof 失效
标题翻译：橡胶混合物和具有胎面的轮胎
公开(公告)号：US5300577A
公开(公告)日：1994-04-05
申请号：US832113
申请日：1992-02-06
申请人： Raymond R. DiRossi , Gregory M. Holtzapple , Joseph K. Hubbell , Mark H. Seloover , John J. A. Verthe
发明人： Raymond R. DiRossi , Gregory M. Holtzapple , Joseph K. Hubbell , Mark H. Seloover , John J. A. Verthe
IPC分类号： B60C1/00 , C08L7/00 , C08L9/00 , C08L21/00 , C08L9/06
CPC分类号： B60C1/0016 , C08L7/00 , C08L9/00 , C08L9/06 , Y10S152/905
摘要： A pneumatic tire with a tread comprising a blend of 3,4-polyisoprene rubber, cis 1,4-polybutadiene rubber, and a terpolymer of styrene/isoprene/butadiene. The triblend of the three basic elastomers when compounded and cured into a polymer network gives a high tan delta at 0.degree. C. associated with good wet traction and a low tan delta at 60.degree. C. which has been associated with low rolling resistance.
摘要翻译：一种具有胎面的充气轮胎，其包含3,4-聚异戊二烯橡胶，顺式1,4-聚丁二烯橡胶和苯乙烯/异戊二烯/丁二烯的三元共聚物的共混物。当混合并固化成聚合物网络时，三种基本弹性体的三元组在0摄氏度下提供了高的tanδ，与良好的湿牵引力相关，并且在60℃下具有低滚动阻力的低tanδ。

4. 发明授权

US5614580A Tire with silica reinforced tread 失效
标题翻译：轮胎与二氧化硅加强胎面
公开(公告)号：US5614580A
公开(公告)日：1997-03-25
申请号：US469114
申请日：1995-06-06
申请人： David J. Zanzig , Paul H. Sandstrom , Michael J. Crawford , John J. A. Verthe , Cheryl A. Losey
发明人： David J. Zanzig , Paul H. Sandstrom , Michael J. Crawford , John J. A. Verthe , Cheryl A. Losey
IPC分类号： B29D30/00 , B29K9/06 , B29K103/00 , B60C1/00 , C08K3/00 , C08K3/36 , C08K5/00 , C08K5/548 , C08L9/00 , C08L21/00
CPC分类号： C08K3/36 , B60C1/0016 , C08L9/00 , C08L2205/02 , C08L7/00
摘要： The invention relates to a tire with a tread which is quantitatively reinforced with silica where the tread is composed of cis 1,4-polybutadiene rubber, a high vinyl polybutadiene rubber and, optionally a medium vinyl polybutadiene rubber. In one aspect, the tread rubber can also contain a minor amount of cis 1,4-polyisoprene natural rubber.
摘要翻译：本发明涉及一种具有胎面的轮胎，其胎面由二氧化硅定量增强，其中胎面由顺式1,4-聚丁二烯橡胶，高乙烯基聚丁二烯橡胶和任选的中等乙烯基聚丁二烯橡胶组成。一方面，胎面橡胶还可以含有少量的顺式1,4-聚异戊二烯天然橡胶。

5. 发明授权

US5552490A Styrene-isoprene rubber for tire tread compounds 失效
标题翻译：用于轮胎胎面胶的苯乙烯 - 异戊二烯橡胶
公开(公告)号：US5552490A
公开(公告)日：1996-09-03
申请号：US439753
申请日：1995-05-12
申请人： David J. Zanzig , Paul H. Sandstrom , Joseph K. Hubbell , Wen-Liang Hsu , Adel F. Halasa , John J. A. Verthe
发明人： David J. Zanzig , Paul H. Sandstrom , Joseph K. Hubbell , Wen-Liang Hsu , Adel F. Halasa , John J. A. Verthe
IPC分类号： C08F2/06 , C08F4/48 , C08F236/10 , C08L9/06 , C08K3/36
CPC分类号： C08F236/10 , Y10S152/905
摘要： The subject invention relates to a technique for synthesizing rubbery copolymers of styrene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire tread rubber compounds. By utilizing these styrene-isoprene rubbers in tire treads, tires having improved wet skid resistance can be built without sacrificing rolling resistance or tread wear characteristics. This invention more specifically discloses a process for the synthesis of styrene-isoprene rubbers which exhibit essentially a single glass transition temperature and which are particularly useful in tire tread rubber compounds, said process comprising copolymerizing a monomer mixture containing from about 2 weight percent to about 15 weight percent styrene monomer and from about 85 weight percent to about 98 weight percent isoprene monomer in an organic solvent in the presence of a catalyst system which is comprised of (a) a lithium initiator and (b) a modifier having the structural formula: ##STR1## wherein n represents an integer within the range of 3 to 6, wherein R represents an alkyl group containing from 1 to about 10 carbon atoms, and wherein the molar ratio of the modifier to the lithium initiator is within the range of 2:1 to 40:1.
摘要翻译：本发明涉及一种合成苯乙烯和异戊二烯橡胶共聚物的技术。这些橡胶状共聚物在轮胎胎面橡胶化合物中表现出优异的性能组合。通过在轮胎胎面中使用这些苯乙烯 - 异戊二烯橡胶，可以在不牺牲滚动阻力或胎面磨损特性的情况下构建具有改善的抗湿滑性的轮胎。本发明更具体地公开了一种用于合成苯乙烯 - 异戊二烯橡胶的方法，其表现出基本上单一的玻璃化转变温度，并且其特别可用于轮胎胎面橡胶化合物，所述方法包括使包含约2重量％至约15 重量百分比的苯乙烯单体和约85重量％至约98重量％的异戊二烯单体在有机溶剂中，在由（a）锂引发剂和（b）具有以下结构式的改性剂组成的催化剂体系的存在下，其中n表示3〜6的整数，其中R表示含有1〜约10个碳原子的烷基，其中改性剂与锂引发剂的摩尔比在2:1的范围内至40：1。

6. 发明授权

US5470929A Process for synthesizing styrene-isoprene rubber 失效
标题翻译：合成苯乙烯 - 异戊二烯橡胶的方法
公开(公告)号：US5470929A
公开(公告)日：1995-11-28
申请号：US300907
申请日：1994-09-06
申请人： David J. Zanzig , Paul H. Sandstrom , Joseph K. Hubbell , Wen-Liang Hsu , Adel F. Halasa , John J. A. Verthe
发明人： David J. Zanzig , Paul H. Sandstrom , Joseph K. Hubbell , Wen-Liang Hsu , Adel F. Halasa , John J. A. Verthe
IPC分类号： C08F2/06 , C08F4/48 , C08F236/10
CPC分类号： C08F236/10 , Y10S152/905
摘要： The subject invention relates to a technique for synthesizing rubbery copolymers of styrene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire tread rubber compounds. By utilizing these styrene-isoprene rubbers in tire treads, tires having improved wet skid resistance can be built without sacrificing rolling resistance or tread wear characteristics. This invention more specifically discloses a process for the synthesis of styrene-isoprene rubbers which exhibit essentially a single glass transition temperature and which are particularly useful in tire tread rubber compounds, said process comprising copolymerizing a monomer mixture containing from about 2 weight percent to about 15 weight percent styrene monomer and from about 85 weight percent to about 98 weight percent isoprene monomer in an organic solvent in the presence of a catalyst system which is comprised of (a) a lithium initiator and (b) a modifier having the structural formula: ##STR1## wherein n represents an integer within the range of 3 to 6, wherein R represents an alkyl group containing from 1 to about 10 carbon atoms, and wherein the molar ratio of the modifier to the lithium initiator is within the range of 2:1 to 40:1.
摘要翻译：本发明涉及一种合成苯乙烯和异戊二烯橡胶共聚物的技术。这些橡胶状共聚物在轮胎胎面橡胶化合物中表现出优异的性能组合。通过在轮胎胎面中使用这些苯乙烯 - 异戊二烯橡胶，可以在不牺牲滚动阻力或胎面磨损特性的情况下构建具有改善的抗湿滑性的轮胎。本发明更具体地公开了一种用于合成苯乙烯 - 异戊二烯橡胶的方法，其表现出基本上单一的玻璃化转变温度，并且其特别可用于轮胎胎面橡胶化合物，所述方法包括使包含约2重量％至约15 重量百分比的苯乙烯单体和约85重量％至约98重量％的异戊二烯单体在有机溶剂中，在由（a）锂引发剂和（b）具有以下结构式的改性剂组成的催化剂体系的存在下，其中n表示3〜6的整数，其中R表示含有1〜约10个碳原子的烷基，其中改性剂与锂引发剂的摩尔比在2:1的范围内至40：1。

7. 发明授权

US5396940A Sulfur cured rubber composition containing epoxidized natural rubber and silica filler 失效
标题翻译：硫化橡胶组合物含有环氧化天然橡胶和二氧化硅填料
公开(公告)号：US5396940A
公开(公告)日：1995-03-14
申请号：US122082
申请日：1993-09-17
申请人： Thomas J. Segatta , Paul H. Sandstrom , John J. A. Verthe
发明人： Thomas J. Segatta , Paul H. Sandstrom , John J. A. Verthe
IPC分类号： C08J3/24 , B60C1/00 , C08K3/00 , C08K3/36 , C08K5/00 , C08K5/548 , C08L9/00 , C08L15/00 , C08L21/00 , C08K5/36
CPC分类号： C08L15/00 , B60C1/0016 , C08L21/00 , C08L7/00 , C08L9/00 , C08L9/02 , C08L9/06 , Y10S152/905
摘要： The present invention relates to a sulfur cured rubber composition particularly suited for use in tire treads and carcass ply compounds. The sulfur cured rubber composition is composed of, based on 100 parts by weight of rubber, from about 5 to 95 parts by weight of epoxidized rubber; from about 5 to 85 parts of a silica filler; from about 0.5 to 8.5 parts by weight of a silica coupling agent; and 95 to 5 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof.
摘要翻译：本发明涉及特别适用于轮胎胎面和胎体帘布层化合物的硫化橡胶组合物。硫固化橡胶组合物由100重量份的橡胶组成，约5〜95重量份的环氧化橡胶; 约5至85份二氧化硅填料; 约0.5至8.5重量份的二氧化硅偶联剂; 和95〜5重量份选自中等乙烯基聚丁二烯，苯乙烯 - 丁二烯橡胶，合成顺式-1,4-聚异戊二烯，合成3,4-聚异戊二烯，天然橡胶，顺式聚丁二烯，苯乙烯 - 异戊二烯橡胶，苯乙烯 - 异戊二烯 - 丁二烯橡胶，丙烯腈 - 丁二烯橡胶及其混合物。

8. 发明授权

US5378754A Tires having improved rolling resistance 失效
标题翻译：具有改善滚动阻力的轮胎
公开(公告)号：US5378754A
公开(公告)日：1995-01-03
申请号：US128441
申请日：1993-09-28
申请人： Richard G. Bauer , Donald J. Burlett , Johnny D. Massie, II , Paul H. Sandstrom , Thomas J. Segatta , John J. A. Verthe
发明人： Richard G. Bauer , Donald J. Burlett , Johnny D. Massie, II , Paul H. Sandstrom , Thomas J. Segatta , John J. A. Verthe
IPC分类号： B29D30/00 , B29K7/00 , B29K9/06 , B29K77/00 , B60C1/00 , C08L9/00 , C08L21/00 , C08K3/04 , C08L7/00
CPC分类号： C08L21/00 , B60C1/0016 , C08L7/00 , C08L9/00
摘要： A pneumatic tire is provided having good rolling resistance properties without sacrificing traction. The tire has a tread that contains 2 to 15 phr thermoplastic reinforcing polymer as a replacement for 5 to 25 phr carbon black.
摘要翻译：提供了具有良好滚动阻力性能而不牺牲牵引力的充气轮胎。该轮胎具有含有2至15phr热塑性增强聚合物的胎面，以代替5至25phr的炭黑。

9. 发明授权

US5361818A Polyester/polyepoxide/rubber alloys 失效
标题翻译：聚酯/聚环氧化物/橡胶合金
公开(公告)号：US5361818A
公开(公告)日：1994-11-08
申请号：US126866
申请日：1993-09-27
申请人： Deborah A. Tung , Thomas J. Segatta , John J. A. Verthe , Paul H. Sandstrom , Richard G. Bauer , Mark A. Marinko
发明人： Deborah A. Tung , Thomas J. Segatta , John J. A. Verthe , Paul H. Sandstrom , Richard G. Bauer , Mark A. Marinko
IPC分类号： B60C1/00 , C08G59/42 , C08L21/00 , C08L23/16 , C08L63/00 , C08L7/00 , C08L9/00
CPC分类号： C08L21/00 , B60C1/0016 , C08L63/00 , C08L7/00 , C08L9/00 , C08L2205/03 , Y10S152/905 , Y10T152/1081 , Y10T152/10846
摘要： The present invention relates to polymeric alloys which comprise the reaction product of a mixture of:(a) a polyester resin produced from the precondensation reaction of a diol and a dicarboxylic compound, said polyester subsequently condensed and having an intrinsic viscosity from about 0.13 to about 0.35 dl/g, a glass transition temperature of at least 50.degree. C., an acid number from about 5 to 50;(b) at least one polyepoxide having at least two epoxy groups per molecule; and(c) an unvulcanized rubber.
摘要翻译：本发明涉及聚合物合金，其包含以下混合物的混合物的反应产物：（a）由二醇和二羧酸化合物的预缩合反应制备的聚酯树脂，所述聚酯随后缩合，其特性粘度为约0.13至约 0.35dl / g，玻璃化转变温度至少为50℃，酸值为约5至50; （b）每分子具有至少两个环氧基团的至少一种聚环氧化物; 和（c）未硫化橡胶。

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