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1. 发明授权

US5534574A Silica reinforced rubber preparation and tire with tread thereof 失效
标题翻译：二氧化硅增强橡胶制品和具有胎面的轮胎
公开(公告)号：US5534574A
公开(公告)日：1996-07-09
申请号：US401844
申请日：1995-03-10
申请人： Paul H. Sandstrom , David J. Zanzig , Mark S. Sinsky
发明人： Paul H. Sandstrom , David J. Zanzig , Mark S. Sinsky
IPC分类号： B60C1/00 , C08K3/00 , C08K3/06 , C08K3/36 , C08K5/36 , C08K5/548 , C08L9/00 , C08L21/00 , C08K5/54
CPC分类号： C08K3/36 , C08K5/548 , Y10S152/905
摘要： A rubber composition comprised of elastomer, silica, a silica coupler, 2-mercaptobenzothiazole and, optionally, carbon black, in which the silica, silica coupler and at least a portion of the 2-mercaptobenzothiazole are added in a non-productive mix stage.Pneumatic tires having treads comprised of such rubber composition are provided.
摘要翻译：橡胶组合物由弹性体，二氧化硅，二氧化硅偶合剂，2-巯基苯并噻唑和任选的炭黑组成，其中二氧化硅，二氧化硅偶联剂和至少一部分2-巯基苯并噻唑以非生产性混合阶段加入。提供具有这种橡胶组合物的胎面的气动轮胎。

2. 发明授权

US5504140A Tire with tread of elastomer composition 失效
标题翻译：轮胎与弹性体组成的胎面
公开(公告)号：US5504140A
公开(公告)日：1996-04-02
申请号：US315476
申请日：1994-09-30
申请人： David J. Zanzig , Paul H. Sandstrom , John J. A. Verthe , Raymond R. DiRossi , Gregory M. Holtzapple
发明人： David J. Zanzig , Paul H. Sandstrom , John J. A. Verthe , Raymond R. DiRossi , Gregory M. Holtzapple
IPC分类号： B60C1/00 , C08K3/00 , C08K3/04 , C08K3/36 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00
CPC分类号： C08L9/00 , B60C1/0016 , C08L9/06 , C08L7/00 , Y02T10/862
摘要： Pneumatic rubber tire with a tread composed of a rubber blend of a base of at least two synthetic elastomers composed of (i) specialized isoprene/butadiene copolymer elastomer having a low Tg in a range of about -70.degree. to about -100.degree. C. and (ii) a diene based elastomer having a Tg in a range of about -5.degree. to about -30.degree. C. together with a minor amount of natural cis 1,4-polyisoprene rubber. Selection of the base of the said two synthetic elastomers having spaced apart, or spatially defined, Tg's of at least 40.degree. C. is an important feature of the tread rubber blend. Representative examples of contemplated elastomers with Tg's in a range of about -5.degree. to about -30.degree. C. are 3,4-polyisoprene elastomer, styrene/isoprene copolymer elastomer and high vinyl polybutadiene elastomers.In one aspect, the tread rubber blend is reinforced with reinforcing filler composed of carbon black or a combination of carbon black and silica accompanied by a coupling agent.
摘要翻译：具有胎面的气动橡胶轮胎，其由至少两种合成弹性体的基底的橡胶共混物组成，所述合成弹性体由（i）具有约-70℃至约-100℃范围内的低Tg的特殊异戊二烯/丁二烯共聚物弹性体组成。和（ii）Tg在约-5℃至约-30℃范围内的二烯基弹性体以及少量天然顺式1,4-聚异戊二烯橡胶。具有至少40℃的间隔或空间限定的Tg的所述两种合成弹性体的基底的选择是胎面橡胶共混物的重要特征。具有Tg在约-5℃至约-30℃范围内的预期弹性体的代表性实例是3,4-聚异戊二烯弹性体，苯乙烯/异戊二烯共聚物弹性体和高乙烯基聚丁二烯弹性体。在一个方面，胎面橡胶共混物用伴随着偶联剂的炭黑或炭黑和二氧化硅的组合的增强填料增强。

3. 发明授权

US5488077A Sulfur cured rubber composition containing epoxidized natural rubber and carboxylated nitrile rubber 失效
标题翻译：硫化橡胶组合物含有环氧化天然橡胶和羧化丁腈橡胶
公开(公告)号：US5488077A
公开(公告)日：1996-01-30
申请号：US452929
申请日：1995-05-30
申请人： Paul H. Sandstrom
发明人： Paul H. Sandstrom
IPC分类号： B60C1/00 , C08K3/36 , C08L21/00 , C08L9/00 , C08L13/00 , C08L15/00
CPC分类号： C08K3/36 , B60C1/0016 , C08L21/00 , Y10S152/905
摘要： The present invention relates to a sulfur cured rubber composition particularly suited for use in tire treads. The sulfur cured rubber composition is composed of based on 100 parts by weight of rubber, from about 1.0 to 15 parts by weight of epoxidized rubber; from about 1.0 to 15 parts by weight of a carboxylated nitrile rubber; and 98 to 70 parts by weight of a rubber selected from the group consisting of medium vinyl polybutadiene, styrene-butadiene rubber, synthetic cis-1,4-polyisoprene, synthetic 3,4-polyisoprene, natural rubber, cis-polybutadiene, styrene-isoprene rubber, styrene-isoprene-butadiene rubber, acrylonitrile-butadiene rubber and mixtures thereof.
摘要翻译：本发明涉及一种特别适用于轮胎胎面的硫化橡胶组合物。硫化橡胶组合物由100重量份橡胶，约1.0-15重量份环氧化橡胶组成，约1.0至15重量份的羧化丁腈橡胶; 和98〜70重量份选自中等乙烯基聚丁二烯，苯乙烯 - 丁二烯橡胶，合成顺式-1,4-聚异戊二烯，合成3,4-聚异戊二烯，天然橡胶，顺式聚丁二烯，苯乙烯 - 异戊二烯橡胶，苯乙烯 - 异戊二烯 - 丁二烯橡胶，丙烯腈 - 丁二烯橡胶及其混合物。

4. 发明授权

US5434206A Silica reinforced rubber compositions containing diaminodirosinate salts 失效
标题翻译：含有二氨基二磺酸盐的二氧化硅增强橡胶组合物
公开(公告)号：US5434206A
公开(公告)日：1995-07-18
申请号：US303902
申请日：1994-09-09
申请人： Lawson G. Wideman , Paul H. Sandstrom
发明人： Lawson G. Wideman , Paul H. Sandstrom
IPC分类号： C08K3/34 , C08K5/19 , C08K3/20
CPC分类号： C08K3/34 , C08K5/19
摘要： The present invention relates to the use of diaminodirosinate salts as coupling agents for siliceous fillers in rubber polymers.
摘要翻译：本发明涉及二氨基二磺酸盐作为橡胶聚合物中硅质填料的偶联剂的用途。

5. 发明授权

US5341863A Tire with tread composition 失效
标题翻译：轮胎与胎面组成
公开(公告)号：US5341863A
公开(公告)日：1994-08-30
申请号：US062263
申请日：1993-05-17
申请人： Paul H. Sandstrom , Raymond B. Roennau
发明人： Paul H. Sandstrom , Raymond B. Roennau
IPC分类号： B60C1/00 , C08L21/00 , C08L7/00 , C08L9/00 , C08L23/06
CPC分类号： C08L21/00 , Y10S152/905
摘要： A pneumatic tire having a sulfur cured tread is provided comprised of at least one diene rubber and a low density polyethylene having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C., wherein the said LDPE is mixed with the said rubber at a temperature of about 120.degree. C. to about 170.degree. C. prior to sulfur vulcanizing the blend.A process is also provided for producing a tire in which a hot cured tire is removed from its rigid mold where the tread is comprised of at least one diene rubber and a low density polyethylene (LDPE) having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C.; and wherein the said LDPE is mixed with the said unvulcanized rubber at a temperature of about 120.degree. C. to about 170.degree. C.
摘要翻译：提供了具有硫硫化胎面的充气轮胎，其由至少一种二烯橡胶和具有约104℃至约115℃范围内的结晶熔点的低密度聚乙烯组成，其中所述LDPE与所述橡胶在硫化硫化混合物之前在约120℃至约170℃的温度下进行。还提供了一种用于生产轮胎的方法，其中热硬化轮胎从其刚性模具中去除，其中胎面由至少一种二烯橡胶和低密度聚乙烯（LDPE）组成，其中结晶熔点在约 104℃至约115℃。并且其中所述LDPE与所述未硫化橡胶在约120℃至约170℃的温度下混合。

6. 发明授权

US5246998A Dicyclopentadiene alcohol rosin acid derivatives 失效
标题翻译：二环戊二烯醇松香酸衍生物
公开(公告)号：US5246998A
公开(公告)日：1993-09-21
申请号：US873258
申请日：1992-04-24
申请人： Lawson G. Wideman , Paul H. Sandstrom , Denise J. Keith
发明人： Lawson G. Wideman , Paul H. Sandstrom , Denise J. Keith
IPC分类号： C08L21/00 , C09F1/04
CPC分类号： C09F1/04 , C08L21/00 , C08L9/00 , C08K5/101 , C08L7/00 , C08L93/04
摘要： The present invention relates to dicyclopentadiene alcohol resin acid derivatives which are useful as a rubber additive. In one embodiment, the ester linked rosin acid derivative may serve as a total or partial replacement for oil and/or wax. The dicyclopentadiene alcohol rosin acid derivatives are prepared by reacting abietic acid and/or dehydroabietic acid with dicyclopentadiene alcohol under esterification conditions.

7. 发明授权

US5049607A Rubber composition comprising alkyl (C.sub.6 -C.sub.22) amides of rosin acid 失效
标题翻译：包含松香酸烷基（C6-C22）酰胺的橡胶组合物
公开(公告)号：US5049607A
公开(公告)日：1991-09-17
申请号：US411981
申请日：1989-09-25
申请人： Lawson G. Wideman , Paul H. Sandstrom
发明人： Lawson G. Wideman , Paul H. Sandstrom
IPC分类号： C08L21/00 , C09F1/04
CPC分类号： C09F1/04 , C08L21/00 , C08L9/00 , C08K5/20 , C08L7/00 , C08L93/04
摘要： The present invention relates to alkyl (C.sub.6 -C.sub.22) amides of rosin acids which are useful as a total or partial replacement for extender or processing oil in rubber formulations. Addition of the alkyl (C.sub.6 -C.sub.22) amides of rosin acid also significantly reduce rheometer t25 and t90 values.
摘要翻译：本发明涉及松香酸的烷基（C6-C22）酰胺，其可用作橡胶制剂中的增量剂或加工油的全部或部分替代物。加入松香酸的烷基（C6-C22）酰胺也显着降低了流变仪t25和t90值。

8. 发明授权

US4855364A Secondary vulcanization accelerator 失效
标题翻译：二次硫化促进剂
公开(公告)号：US4855364A
公开(公告)日：1989-08-08
申请号：US302521
申请日：1989-01-27
申请人： Paul H. Sandstrom
发明人： Paul H. Sandstrom
IPC分类号： C08K5/17
CPC分类号： C08K5/17
摘要： It is often desirable to utilize accelerators in the sulfur vulcanization of unsaturated rubbers. In many cases a primary accelerator is used in combination with another accelerator, called a secondary accelerator or activator, which further increases the rate of vulcanization. It has been determined that compounds having the structural formula:NH.sub.2 --A--NH--(CH.sub.2).sub.x NH].sub.n A--NH.sub.2wherein x is 2 or 3, wherein n is an integer from 1 to 100, and wherein A represents an alkylene group containing from 1 to 20 carbons atoms, act as secondary accelerators in the vulcanization of unsaturated rubbers. For example, it has been determined that 4,7-diaza-decane-1,10-diamine is a particularly desirable secondary accelerator.
摘要翻译：通常希望在不饱和橡胶的硫磺硫化中使用促进剂。在许多情况下，主促进剂与另一促进剂（称为次级促进剂或活化剂）组合使用，这进一步提高了硫化速率。已经确定具有以下结构式的化合物：NH 2 -A-NH-（CH2）xNH] nA-NH2其中x为2或3，其中n为1至100的整数，并且其中A表示含有 1〜20个碳原子，作为不饱和橡胶硫化的二次加速剂。例如，已经确定4,7-二氮杂 - 癸烷-1,10-二胺是特别期望的二次加速剂。

9. 发明授权

US4491655A Rubber containing esters of rosin acid 失效
标题翻译：含橡胶的松香酸酯
公开(公告)号：US4491655A
公开(公告)日：1985-01-01
申请号：US568964
申请日：1984-01-06
申请人： Paul H. Sandstrom
发明人： Paul H. Sandstrom
IPC分类号： C08L7/00 , C08J3/20 , C08J3/24 , C08L9/00 , C08L21/00 , C08L33/00 , C08L33/02 , C08L93/00 , C08L93/04
CPC分类号： C08L9/06 , C08L21/00 , C08K5/101 , C08L9/00 , C08L93/04
摘要： There is disclosed the use of esters especially methyl esters of rosin acids as total or partial replacements for oil in rubber formulations. Vulcanizate properties, low temperature performance, and processibility are comparable when using either the rosin ester or an aromatic oil, however, the rosin ester extended rubber demonstrates improved abrasion resistance and flex resistance.
摘要翻译：公开了使用酯，特别是松香酸的甲基酯作为橡胶制剂中的油的全部或部分替代物。当使用松香酯或芳香油时，硫化特性，低温性能和加工性是相当的，然而，松香酯延长橡胶表现出改善的耐磨性和抗挠曲性。

10. 发明授权

US4374941A Particle size control of SBR/carbon black powder 失效
标题翻译： SBR /炭黑粉末的粒度控制
公开(公告)号：US4374941A
公开(公告)日：1983-02-22
申请号：US297035
申请日：1981-08-27
申请人： Paul H. Sandstrom
发明人： Paul H. Sandstrom
IPC分类号： C08J3/12 , C08J3/215 , C08K3/04 , C08J3/16 , C08J3/22 , C08K9/04
CPC分类号： C08J3/124 , C08J3/215 , C08K3/04 , C08J2321/00 , Y10S524/904
摘要： There is disclosed a process for the production of tack-free, pourable, filler containing elastomer powder which comprises(a) dispersing a carbon black filler in water;(b) mixing the thus dispersed carbon black filler with an elastomer latex;(c) coagulating the thus produced mixture of elastomer latex and carbon black with a two-stage coagulation solution;(d) partitioning the thus coagulated suspension with a coating resin; and(e) filtering, washing and drying of the resultant powder, the improvement comprising using as a coating resin a mixture of a styrene/butadiene resin and a styrene/.alpha.-methylstyrene or a polystyrene resin wherein the weight ratio of the styrene/butadiene resin to the styrene/.alpha.-methylstyrene or polystyrene resin ranges between 4/1 and 1/4, said resins containing a mixture of added surfactants, the first being sodium lauryl sulfate and the second being a nonionic isooctyl phenoxy polyethoxy ethanol which contains 10 moles of ethylene oxide in the polyethoxy portion thereof, said mixture of surfactants being added in an amount at least 4 percent by weight and being in a weight ratio of sodium lauryl sulfate to the nonionic surfactant ranging from 2/1 to 1/2, and wherein the coagulation temperature ranges from 70.degree. to 90.degree. C., and a further improvement of using the coagulating step in (c) a two-step coagulating process, the first being acid/salt and then next using an acid/alum coagulating solution.
摘要翻译：公开了一种生产无粘性，可倾倒的填料的弹性体粉末的方法，其包括（a）将炭黑填料分散在水中; （b）将由此分散的炭黑填料与弹性体胶乳混合; （c）用两阶段凝结溶液凝结由此制备的弹性体胶乳和炭黑的混合物; （d）用涂布树脂分配如此凝结的悬浮液; 和（e）所得粉末的过滤，洗涤和干燥，其改进包括使用苯乙烯/丁二烯树脂和苯乙烯/α-甲基苯乙烯或聚苯乙烯树脂的混合物作为涂层树脂，其中苯乙烯/丁二烯的重量比树脂与苯乙烯/α-甲基苯乙烯或聚苯乙烯树脂的比例在4/1和1/4之间，所述树脂含有添加的表面活性剂的混合物，第一种是十二烷基硫酸钠，第二种是非离子型异辛基苯氧基聚乙氧基乙醇，其含有10摩尔的环氧乙烷在其聚乙氧基部分中，所述表面活性剂混合物以至少4重量％的量加入，并且以月桂基硫酸钠与非离子表面活性剂的重量比为2/1至1/2，其中凝固温度为70〜90℃，进一步提高了（c）两步凝固工序中的凝固工序，首先是酸/盐，然后再使用丙烯酸 d /明矾凝结液。

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