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1. 发明授权

US5137653A Alkanoyl ester compounds and their intermediates and method of producing the same 失效
标题翻译：烷酰基酯化合物及其中间体及其制备方法
公开(公告)号：US5137653A
公开(公告)日：1992-08-11
申请号：US778757
申请日：1991-10-18
申请人： Toshihiro Hirai , Atsushi Yoshizawa , Isa Nishiyama , Mitsuo Fukumasa , Nobuyuki Shiratori , Akihisa Yokoyama
发明人： Toshihiro Hirai , Atsushi Yoshizawa , Isa Nishiyama , Mitsuo Fukumasa , Nobuyuki Shiratori , Akihisa Yokoyama
IPC分类号： C07C69/773 , C07C69/80 , C07C69/84 , C07C69/90 , C07C69/92 , C07C69/94 , C07C69/96 , C09K19/20
CPC分类号： C09K19/2021
摘要： This invention provides a novel alkanoyl ester compound represented by general formula (I): ##STR1## (wherein A is of --, --O--, ##STR2## B is ##STR3## l and m are 1 or 2 provided that both are not simultaneously 2, k and n are an integer of 1 or more, respectively, provided that k>n, and R is an alkyl group), a liquid crystal composition containing this compound, a novel alkanoylphenyl compound or a novel alkanoylbiphenyl compound as an intermediate for the production of the above compound, and a method of producing the same. These novel alkanoyl ester compounds are excellent in the stability against light and the like and can take a liquid crystal state at a wide temperature range. Particularly, these compounds form liquid crystals of ferroelectricity having a large spontaneous polarization and a fast response rate by introducing an optically active group into the compound, so that they develop a very excellent effect as a starting material for optoelectronics and its related elements.

2. 发明授权

US5098602A Novel halogen-containing ester compounds, and their intermediates, and method of producing the same as well as liquid crystal compositions containing the same and light switching elements 失效
标题翻译：新型含卤化物酯化合物及其中间体及其生产方法以及含有其的液晶组合物和光开关元件
公开(公告)号：US5098602A
公开(公告)日：1992-03-24
申请号：US346454
申请日：1989-05-02
申请人： Toshihiro Hirai , Atsushi Yoshizawa , Isa Nishiyama , Mitsuo Fukumasa , Nobuyuki Shiratori , Akihisa Yokoyama
发明人： Toshihiro Hirai , Atsushi Yoshizawa , Isa Nishiyama , Mitsuo Fukumasa , Nobuyuki Shiratori , Akihisa Yokoyama
IPC分类号： C07C45/46 , C07C45/67 , C07C45/71 , C07C49/825 , C07C49/83 , C07C49/84 , C07C69/773 , C09K19/20
CPC分类号： C09K19/2021 , C07C45/46 , C07C45/673 , C07C45/71 , C07C49/825 , C07C49/83 , C07C49/84
摘要： This invention provides a novel halogen-containing ester compound represented by the following general formula (I): ##STR1## (wherein R is an alkyl group, A is selected from a single bond, --O--, --COO-- and --CO--, both of X and Y are halogen atoms or either one of X and Y is a halogen atom and the other is a hydrogen atom, each of m and n is 0 or 1, m+n=0 or 1, each of k and l is an integer of 1 or more, provide k

3. 发明授权

US4970023A Biphenyl compounds, method of producing the same as well as liquid crystal compositions and light switch elements each containing the same 失效
标题翻译：联苯化合物，其制备方法以及各自含有它们的液晶组合物和光开关元件
公开(公告)号：US4970023A
公开(公告)日：1990-11-13
申请号：US350700
申请日：1989-05-09
申请人： Toshihiro Hirai , Atsushi Yoshizawa , Isa Nishiyama , Mitsuo Fukumasa , Nobuyuki Shiratori , Akihisa Yokoyama
发明人： Toshihiro Hirai , Atsushi Yoshizawa , Isa Nishiyama , Mitsuo Fukumasa , Nobuyuki Shiratori , Akihisa Yokoyama
IPC分类号： C07C69/003 , C07C45/00 , C07C45/46 , C07C45/67 , C07C49/782 , C07C49/784 , C07C67/00 , C07C69/02 , C07C69/76 , C07C69/96 , C09K19/12 , G02F1/13
CPC分类号： C09K19/126 , C07C45/46 , C07C45/673 , C07C49/782
摘要： This invention provides novel biphenyl compounds represented by the following general formula (I): ##STR1## (wherein R is an alkyl group, A is selected from the single bond, --COO--, --OCO--, --OCOO-- and --CO--, and each of m and n is an integer of 1 or more, provided m

4. 发明授权

US5211879A Ester compounds and liquid crystal compositions containing the same 失效
标题翻译：酯化合物和含有其的液晶组合物
公开(公告)号：US5211879A
公开(公告)日：1993-05-18
申请号：US604827
申请日：1990-10-29
申请人： Nobuyuki Shiratori , Isa Nishiyama , Atsushi Yoshizawa , Toshihiro Hirai
发明人： Nobuyuki Shiratori , Isa Nishiyama , Atsushi Yoshizawa , Toshihiro Hirai
IPC分类号： C07C69/63 , C07C69/773 , C07C69/92 , C07C69/94 , C07D239/26 , C09K19/12 , C09K19/20 , C09K19/34
CPC分类号： C07D239/26 , C07C69/63 , C07C69/92 , C07C69/94 , C09K19/126 , C09K19/2021 , C09K19/3463
摘要： This invention provides novel ester compounds represented by the following general formula (1): ##STR1## (wherein R.sup.1 and R.sup.2 are alkyl groups and may be the same or not, A and B are selected from a single bond and --COO--, X is selected from ##STR2## optically active bodies thereof and liquid crystal compositions containing at least one of these compounds.

5. 发明授权

US5932137A Smectic liquid crystal composition for recording display medium, recording display medium and use thereof 失效
标题翻译：用于记录显示介质的记录液晶组合物，记录显示介质及其用途
公开(公告)号：US5932137A
公开(公告)日：1999-08-03
申请号：US647822
申请日：1996-05-15
申请人： Atsushi Baba , Wataru Saito , Isa Nishiyama , Atsushi Yoshizawa
发明人： Atsushi Baba , Wataru Saito , Isa Nishiyama , Atsushi Yoshizawa
IPC分类号： G02F1/1333 , C09K19/12 , C09K19/44 , C09K19/46 , C09K19/54 , G02F1/13 , C09K19/20
CPC分类号： C09K19/12 , C09K19/46 , C09K19/544 , Y10T428/1036
摘要： A recording display medium is provided which can offer a high display contrast and is less likely to cause a lowering of contrast or disappearance of display even in low temperature and high temperature regions. A smectic liquid crystal composition, for use in the recording display medium, and use of the recording display medium are also provided. The liquid crystal composition comprises: at least one member selected from the group constituting of compounds represented by the following general formula (I): ##STR1## wherein R.sup.1 represents an alkyl or alkoxy group having 8 to 18 carbon atoms; and at least one member selected from the group consisting of compounds represented by the following general formulae (II) to (VII): ##STR2## wherein R.sup.2, R.sup.4, R.sup.5, and R.sup.6 represent an alkyl group having 2 to 18 carbon atoms, R.sup.3, R.sup.7, R.sup.8, R.sup.9, and R.sup.10 represent an alkyl or alkoxy group having 2 to 18 carbon atoms, and X represents a halogen atom or an alkyl or alkoxy group having 2 to 18 carbon atoms.
摘要翻译：提供了能够提供高显示对比度的记录显示介质，并且即使在低温和高温区域中也不太可能引起对比度降低或显示消失。还提供了用于记录显示介质的近晶液晶组合物和记录显示介质的使用。液晶组合物包含：选自由以下通式（I）表示的化合物组成的组中的至少一种：其中R1表示碳原子数为8〜18的烷基或烷氧基; 和选自由以下通式（II）至（VII）表示的化合物中的至少一种：其中R 2，R 4，R 5和R 6表示具有2至18个碳原子的烷基，R 3，R 7， R 8，R 9和R 10表示碳原子数2〜18的烷基或烷氧基，X表示卤素原子或碳原子数2〜18的烷基或烷氧基。

6. 发明授权

US09939555B2 Cinnamic acid derivative, polymer thereof, and liquid crystal alignment layer comprising cured product thereof 有权
公开(公告)号：US09939555B2
公开(公告)日：2018-04-10
申请号：US14123435
申请日：2012-05-31
申请人： Martin Schadt , Sayaka Nose , Masayuki Iwakubo , Masanao Hayashi , Yutaka Nagashima , Isa Nishiyama , Haruyoshi Takatsu
发明人： Martin Schadt , Sayaka Nose , Masayuki Iwakubo , Masanao Hayashi , Yutaka Nagashima , Isa Nishiyama , Haruyoshi Takatsu
IPC分类号： G02B1/04 , C07D257/08 , C07D207/452 , C08F20/40 , C08F22/40 , C07C69/732 , C07C69/92 , C09K19/56 , G02F1/1337 , C09K19/04
CPC分类号： G02B1/04 , C07C69/732 , C07C69/92 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D207/452 , C07D257/08 , C08F20/40 , C08F22/40 , C09K19/56 , C09K2019/0448 , G02F1/133711 , G02F1/133788
摘要： Provided is a liquid crystal alignment layer of which a constituent member is a compound represented by the general formula (I).

7. 发明申请

US20140154428A1 CINNAMIC ACID DERIVATIVE, POLYMER THEREOF, AND LIQUID CRYSTAL ALIGNMENT LAYER COMPRISING CURED PRODUCT THEREOF 有权
公开(公告)号：US20140154428A1
公开(公告)日：2014-06-05
申请号：US14129848
申请日：2012-06-26
申请人： Martin Schadt , Sayaka Nose , Yutaka Nagashima , Isa Nishiyama , Haruyoshi Takatsu
发明人： Martin Schadt , Sayaka Nose , Yutaka Nagashima , Isa Nishiyama , Haruyoshi Takatsu
IPC分类号： G02F1/1337
CPC分类号： G02F1/133711 , C07C69/734 , C07C2601/02 , C07C2601/08 , C07C2601/14 , C07D207/452 , C08F22/40 , C08F122/20 , C08F122/40 , C09K19/56 , C09K2019/0448 , G02F2001/133738 , G02F2001/133742 , Y10T428/1005
摘要： Provided is a liquid crystal alignment layer of which a constituent member is a compound represented by the general formula (I).

8. 发明授权

US06228791B1 Solid catalyst component and catalyst for olefin polymerization 失效
标题翻译：固体催化剂组分和烯烃聚合催化剂
公开(公告)号：US06228791B1
公开(公告)日：2001-05-08
申请号：US09331894
申请日：1999-07-06
申请人： Takuo Kataoka , Masayoshi Saito , Isa Nishiyama
发明人： Takuo Kataoka , Masayoshi Saito , Isa Nishiyama
IPC分类号： B01J2100
CPC分类号： C08F10/00 , C08F4/6567 , C08F4/6555 , C08F4/651 , C08F4/6465
摘要： The present invention is a solid catalyst component for polymerization of olefins prepared by contacting a magnesium compound, a tetravalent halogen-containing titanium compound, a diester of an aromatic dicarboxylic acid, an aromatic hydrocarbon and an organic aluminum compound containing a hydroxyl group represented by the following general formula (R1CO2)mAl(OH)3-m or aluminum hydroxide. The catalyst for polymerization of olefins comprising said solid catalyst component, an organic aluminum compound represented by the general formula R2pAlQ3-p and an organic silicon compound represented by the general formula R3qSi(OR4)4-q can retard the rate of forming a polymer having a low molecular weight or a low stereoregular polymer which is soluble in a polymerization solvent in slurry polymerization and can obtain a high stereoregular polymer in a high yield, and also can obtain a copolymer having an excellent property in a high yield in the copolymerization of olefins.
摘要翻译：本发明是通过使镁化合物，四价含卤素的钛化合物，芳族二羧酸的二酯，芳香族烃和含有羟基的有机铝化合物接触而制备的烯烃聚合用固体催化剂成分遵循通式（R1CO2）mA1（OH）3-m或氢氧化铝。包含所述固体催化剂组分，由通式R2pAlQ3-p表示的有机铝化合物和由通式R3qSi（OR4）4-q表示的有机硅化合物）的烯烃聚合催化剂可以延迟形成具有低分子量或低立构规整性聚合物，其在淤浆聚合中可溶于聚合溶剂，并且可以高产率获得高立构规整性聚合物，并且还可以获得在烯烃共聚合中具有优异性能的共聚物。

9. 发明授权

US09684206B2 Copolymer, and liquid crystal alignment layer including cured product thereof 有权
公开(公告)号：US09684206B2
公开(公告)日：2017-06-20
申请号：US14129236
申请日：2012-06-27
申请人： Martin Schadt , Vladimir Grigorievich Chigrinov , Hoi-Sing Kwok , Sayaka Nose , Masayuki Iwakubo , Masanao Hayashi , Yutaka Nagashima , Isa Nishiyama , Haruyoshi Takatsu
发明人： Martin Schadt , Vladimir Grigorievich Chigrinov , Hoi-Sing Kwok , Sayaka Nose , Masayuki Iwakubo , Masanao Hayashi , Yutaka Nagashima , Isa Nishiyama , Haruyoshi Takatsu
IPC分类号： C09K19/38 , G02F1/1337 , C08F220/10 , C08F220/36 , C08F220/30 , C08F220/24 , C08F222/10
CPC分类号： G02F1/133711 , C08F220/10 , C08F220/24 , C08F220/30 , C08F220/36 , C08F2220/305 , C08F2222/102 , C09K19/3852 , C08F2220/365 , C08F2222/404 , C08F2220/1891 , C08F220/58
摘要： Provided is a liquid crystal alignment layer of which a constituent member is a polymer represented by the general formula (I).

10. 发明授权

US07955665B2 Photoalignment film composition, optically anisotropic medium and method for preparing thereof 有权
标题翻译：光学对准膜组合物，光学各向异性介质及其制备方法
公开(公告)号：US07955665B2
公开(公告)日：2011-06-07
申请号：US12093014
申请日：2006-11-10
申请人： Isa Nishiyama , Yasuhiro Kuwana , Joji Kawamura , Kazuaki Hatsusaka
发明人： Isa Nishiyama , Yasuhiro Kuwana , Joji Kawamura , Kazuaki Hatsusaka
IPC分类号： G02F1/1337
CPC分类号： C09D4/00 , C09K19/2007 , C09K2219/03 , G02B5/3016 , G02F1/133788 , G02F2001/133726 , Y10T428/1005 , Y10T428/105
摘要： The present invention provides a photoalignment film composition containing a compound represented by general formula (1) and a compound having a hydrophilic group and a (meth)acryloyloxy group, an optically anisotropic medium using a photoalignment film comprised of the photoalignment film composition, and a method for preparing thereof: (wherein, R1 and R2 respectively and independently represent a hydrogen atom, halogen atom, carboxyl group or alkali metal salt thereof, halogenated methyl group, halogenated methoxy group, cyano group, nitro group, —OR5, hydroxylalkyl group having 1 to 4 carbon atoms, —CONR6R7 or methoxycarbonyl group, and R3 and R4 respectively and independently represent a carboxyl group or alkali metal salt thereof, sulfo group or alkali metal salt thereof, nitro group, amino group, carbamoyl group, alkoxycarbonyl group, sulfamoyl group or hydroxyl group).
摘要翻译：本发明提供一种含有通式（1）表示的化合物和具有亲水性基团和（甲基）丙烯酰氧基的化合物的光定位膜组合物，使用由光电子对准膜组合物构成的光调整膜的光学各向异性介质，制备方法：（其中，R1和R2分别独立地表示氢原子，卤素原子，羧基或碱金属盐，卤代甲基，卤代甲氧基，氰基，硝基，-OR5，羟基烷基， 1至4个碳原子，-CONR 6 R 7或甲氧基羰基，R 3和R 4分别独立地表示羧基或碱金属盐，磺基或其碱金属盐，硝基，氨基，氨基甲酰基，烷氧基羰基，氨磺酰基团或羟基）。

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