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    • 3. 发明授权
    • Herbicidal mixtures having a synergistic effect
    • 具有协同效应的除草混合物
    • US6054410A
    • 2000-04-25
    • US43314
    • 1998-02-17
    • Max LandesBernd SievernichElmar KiblerWessel NuykenHelmut WalterKarl-Otto WestphalenHorst MayerEgon HadenChristiaan MulderAlfons SchonhammerGerhard Hamprecht
    • Max LandesBernd SievernichElmar KiblerWessel NuykenHelmut WalterKarl-Otto WestphalenHorst MayerEgon HadenChristiaan MulderAlfons SchonhammerGerhard Hamprecht
    • A01N47/36A01N43/54A01N43/66
    • A01N47/36
    • A composition comprising at least one sulfonylurea of the formula I ##STR1## wherein R.sup.1 is substituted alkyl; halogen; a group ER.sup.6 (E=O, S or NR.sup.7); COOR.sup.8 ; NO.sub.2 ; S(O).sub.o R.sup.9 ; SO.sub.2 NR.sup.10 R.sup.11 ; or CONR.sup.10 R.sup.11 ;R.sup.2 is hydrogen, alkyl, alkenyl, alkynyl, halogen, alkoxy, haloalkoxy, haloalkyl, alkylsulfonyl, nitro, cyano or alkylthio;R.sup.3 is F, CF.sub.3, CF.sub.2 Cl, CF.sub.2 H, OCF.sub.3, OCF.sub.2 Cl, or, if R.sup.1 is CO.sub.2 CH.sub.3 and R.sup.2 is simultaneously fluorine, R.sup.3 is Cl, or, if R.sup.1 is CH.sub.2 CF.sub.3 or CF.sub.2 CF.sub.3, R.sup.3 is methyl, or, if R.sup.4 is OCF.sub.3 or OCF.sub.2 Cl, R.sup.3 is OCF.sub.2 H or OCF.sub.2 Br;R.sup.4 is alkoxy, alkyl, alkylthio, alkylamino, dialkylamino, halogen, haloalkyl or haloalkoxy; andR.sup.5 is hydrogen, alkoxy or alkyl;or an enviromentally compatible salt of I, and an aryloxyalkanoic acid selected from the group consisting of 2,4-D, 2,4-DB, clomeprop, dichlorprop, dichlorprop-P, dichlorprop-P (2,4-DP-P), fenoprop (2,4,5-TP), fluoroxypyr, MCPA, MCPB, mecoprop, mecoprop-P, napropamide, napropanilide, triclopyr, and an enviromentally compatible salt thereof exhibits a synergistic herbicidal effect.
    • PCT No.PCT / EP96 / 03996 Sec。 371日期1998年2月17日 102(e)1998年2月17日PCT PCT 1996年9月12日PCT公布。 公开号WO97 / 10714 PCT 日期1997年3月27日包含至少一种式I的磺酰脲的组合物,其中R 1是取代的烷基; 卤素; 组ER6(E = O,S或NR7); COOR8; NO2; S(O)oR9; SO2NR10R11; 或CONR10R11; R 2是氢,烷基,烯基,炔基,卤素,烷氧基,卤代烷氧基,卤代烷基,烷基磺酰基,硝基,氰基或烷硫基; R3为F,CF3,CF2Cl,CF2H,OCF3,OCF2Cl,或者,如果R1为CO2CH3且R2为氟,R3为Cl,或者如果R1为CH2CF3或CF2CF3,则R3为甲基,或者,如果R4为OCF3或 OCF 2 Cl,R 3是OCF 2 H或OCF 2 Br; R4是烷氧基,烷基,烷硫基,烷基氨基,二烷基氨基,卤素,卤代烷基或卤代烷氧基; R5是氢,烷氧基或烷基; 或I环境的环境相容的盐,和选自2,4-D,2,4-DB,氯米普龙,二氯丙酸,二氯丙酸-P,二氯丙烷(2,4-DP-P)的芳氧基烷酸, ,异丙基(2,4,5-TP),氟氧吡啶,MCPA,MCPB,mecoprop,mecoprop-P,napropamide,萘丙酰苯胺,triclopyr及其环境相容的盐表现出协同的除草效果。
    • 6. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20050239653A1
    • 2005-10-27
    • US11079431
    • 2005-03-14
    • Bernd SievernichMax LandesElmar KiblerWolfgang DeynHelmut WalterMartina OttenKarl-Otto WestphalenHerve Vantieghem
    • Bernd SievernichMax LandesElmar KiblerWolfgang DeynHelmut WalterMartina OttenKarl-Otto WestphalenHerve Vantieghem
    • A01N43/40A01N43/72A01N43/78A01N43/80A01N57/00A01N61/00
    • A01N43/78A01N43/80A01N61/00A01N57/20A01N47/36A01N47/30A01N47/12A01N47/06A01N43/90A01N43/88A01N43/82A01N43/76A01N43/707A01N43/70A01N43/653A01N43/58A01N43/54A01N43/50A01N43/42A01N43/40A01N43/18A01N39/04A01N41/10A01N37/48A01N37/46A01N37/40A01N37/26A01N37/22A01N37/18A01N37/12A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are hydrogen, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a heterocyclic radical selected from the group: thiazol-2-yl, thiazol-4-yl, thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl, it being possible for these to be unsubstituted or mono- or polysubstituted by halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or alkylthio; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least one herbicidal compound from the group of the acetyl-CoA carboxylase inhibitors (ACC), acetolactate synthase inhibitors (ALS), amides, auxin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, enolpyruvylshikimate-3-phosphate synthase inhibitors (ESPS), glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protophorphyrinogen [sic ] IX oxidase inhibitors, photosynthesis inhibitors, synergists, growth substances, cell wall biosynthesis inhibitors and a variety of other herbicides. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 氢,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是选自以下的杂环基:噻唑-2-基,噻唑-4-基,噻唑-5-基,异恶唑-3-基,异恶唑-4-基,异恶唑-4-基, 5,5-二氢异恶唑-3-基,4,5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基,这些可能是未被取代的或被卤素单取代或多取代, 烷基,烷氧基,卤代烷基,卤代烷氧基或烷硫基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 乙酰辅酶A羧化酶抑制剂(ACC),乙酰乳酸合酶抑制剂(ALS),酰胺,生长素除草剂,生长素转运抑制剂,类胡萝卜素生物合成抑制剂,烯醇丙酮酸莽草酸-3(3)的协同有效量的至少一种除草化合物 磷酸合成酶抑制剂(ESPS),谷氨酰胺合成酶抑制剂,脂质生物合成抑制剂,有丝分裂抑制剂,原卟啉原IX氧化酶抑制剂,光合作用抑制剂,增效剂,生长物质,细胞壁生物合成抑制剂和各种其它除草剂。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。
    • 9. 发明申请
    • Piperazine Compounds Having Herbicidal Action
    • 具有除草作用的哌嗪化合物
    • US20100173777A1
    • 2010-07-08
    • US12663781
    • 2008-06-11
    • Eike HupeThomas SeitzMatthias WitschelDschun SongWilliam Karl MobergLiliana Parra RapadoFrank StelzerAndrea VescoviTrevor William NewtonRobert ReinhardBernd SievernichKlaus GrossmannThomas EhrhardtMichael RackElmar Kibler
    • Eike HupeThomas SeitzMatthias WitschelDschun SongWilliam Karl MobergLiliana Parra RapadoFrank StelzerAndrea VescoviTrevor William NewtonRobert ReinhardBernd SievernichKlaus GrossmannThomas EhrhardtMichael RackElmar Kibler
    • A01N43/60C07D241/04A01P13/00
    • C07D241/08A01N43/60
    • The present invention relates to piperazine compounds of the general formula I defined below and to their use as herbicides. Moreover, the invention relates to compositions for crop protection and to a method for controlling unwanted vegetation. R1 is selected from the group consisting of halogen, cyano, nitro, Z—C(═O)—R12, phenyl and a 5- or 6-membered heterocyclic radical which has 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S as ring atoms, where phenyl and the heterocyclic radical are unsubstituted or may have 1, 2, 3 or 4 substituents R1a; Z is a covalent bond or a CH2 group; R12 is hydrogen, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C5-C6-cycloalkenyl, C2-C6-alkynyl and the like; R2 is hydrogen, halogen, nitro, cyano, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy, C1-C4-haloalkoxy, benzyl or a group S(O)nR21 in which R21 is C1-C4-alkyl or C1-C4-haloalkyl and n is 0, 1 or 2; R3 is hydrogen or halogen; R4 is C1-C4-alkyl, C3-C4-alkenyl or C3-C4-alkynyl; R5 is hydrogen, C1-C4-alkyl, C3-C4-alkenyl, C3-C4-alkynyl or a group C(═O)R51 in which R51 is hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy; R6 is C1-C4-alkyl, C1-C4-hydroxyalkyl or C1-C4-haloalkyl; R7, R8 independently of one another are hydrogen, OH, C1-C4-alkoxy, C1-C4-haloalkyloxy, C1-C4-alkyl or C1-C4-haloalkyl; R9, R10 independently of one another are selected from the group consisting of hydrogen, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C1-C4-alkoxy and C1-C4-haloalkoxy; and R11 is hydrogen or C1-C4-alkyl; and the agriculturally useful salts of these compounds.
    • 本发明涉及下面定义的通式I的哌嗪化合物及其作为除草剂的用途。 此外,本发明涉及用于作物保护的组合物和用于防治不想要的植物的方法。 R 1选自卤素,氰基,硝基,Z-C(= O)-R 12,苯基和具有1,2,3或4个杂原子的5或6元杂环基,所述杂原子选自 的O,N和S作为环原子,其中苯基和杂环基是未取代的或可以具有1,2,3或4个取代基R 1a; Z是共价键或CH2基; R12是氢,C1-C6-烷基,C3-C6-环烷基,C2-C6-烯基,C5-C6-环烯基,C2-C6-炔基等; R2是氢,卤素,硝基,氰基,C1-C4-烷基,C1-C4卤代烷基,C2-C4-烯基,C1-C4-烷氧基,C1-C4-卤代烷氧基,苄基或基团S(O) 其中R 21为C 1 -C 4烷基或C 1 -C 4卤代烷基,n为0,1或2; R3是氢或卤素; R4是C1-C4-烷基,C3-C4-烯基或C3-C4-炔基; R 5为氢,C 1 -C 4 - 烷基,C 3 -C 4 - 烯基,C 3 -C 4 - 炔基或C(= O)R 51,其中R 51为氢,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基, C 4 - 烷氧基或C 1 -C 4 - 卤代烷氧基; R 6是C 1 -C 4烷基,C 1 -C 4羟基烷基或C 1 -C 4卤代烷基; R 7,R 8彼此独立地是氢,OH,C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4 - 烷基或C 1 -C 4卤代烷基; R 9,R 10彼此独立地选自氢,卤素,CN,NO 2,C 1 -C 4 - 烷基,C 1 -C 4 - 卤代烷基,C 2 -C 4 - 烯基,C 1 -C 4 - 烷氧基和C 1 -C 4 - 卤代烷氧基 和R 11是氢或C 1 -C 4 - 烷基; 和这些化合物的农业上有用的盐。
    • 10. 发明授权
    • Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative and an adjuvant
    • 含有3-杂环基取代的苯甲酰基衍生物和佐剂的除草混合物
    • US06514910B1
    • 2003-02-04
    • US09914873
    • 2001-09-05
    • Matthias BratzRainer BerghausMartina OttenBernd SievernichElmar KiblerHerve Vantieghem
    • Matthias BratzRainer BerghausMartina OttenBernd SievernichElmar KiblerHerve Vantieghem
    • A01N4378
    • A01N43/78A01N43/80A01N37/06A01N37/02A01N25/30A01N2300/00
    • A herbicidal mixture, comprising a) a herbicidally effective amount of a benzoyl compound of formula I  where: R1, R2 are halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkyl-sulfinyl or C1-C6-alkylsulfonyl; R3 is hydrogen, halogen, C1-C6-alkyl; X is 4,5-dihydroisoxazolyl which is unsubstituted or mono- or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R4 is a pyrazole of the formula II  which is attached in the 4-position and where R5 is hydrogen, R6 is methyl, or an environmentally compatible salt thereof; b) an adjuvant comprising i) a C1-C5-alkyl C5-C22-alkanoate, ii) a C10-C20-carboxylic acid, iii) a partial phosphoric ester or a partial sulfuric ester of a monohydroxy-functional polyalkyl ether and iv) optionally an alkyl polyoxyalkylene polyether, wherein the compound of formula I and the adjuvat are present in synergistically effective amounts.
    • 一种除草混合物,其包含a)除草有效量的式I的苯甲酰基化合物,其中:R 1,R 2是卤素,C 1 -C 6烷基,C 1 -C 6烷硫基,C 1 -C 6烷基亚磺酰基或C 1 -C 6烷基磺酰基 R 3是氢,卤素,C 1 -C 6 - 烷基; X是未被取代或被卤素,C 1 -C 6烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 卤代烷基,C 1 -C 6 - 烷氧基取代或被单取代或多取代的4,5-二氢异恶唑基 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基; R 4是连接在4-位的式II的吡唑,其中R 5是氢,R 6是甲基或其环境相容的盐; b)佐剂,其包含:i) C1-C5烷基C5-C22-链烷酸酯,ii)C10-C20羧酸,iii)部分磷酸酯或单羟基官能聚烷基醚的部分硫酸酯,和/或任选的烷基聚氧化烯聚醚,其中化合物 并且佐剂以协同有效量存在。