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    • 1. 发明授权
    • Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative and an adjuvant
    • 含有3-杂环基取代的苯甲酰基衍生物和佐剂的除草混合物
    • US06514910B1
    • 2003-02-04
    • US09914873
    • 2001-09-05
    • Matthias BratzRainer BerghausMartina OttenBernd SievernichElmar KiblerHerve Vantieghem
    • Matthias BratzRainer BerghausMartina OttenBernd SievernichElmar KiblerHerve Vantieghem
    • A01N4378
    • A01N43/78A01N43/80A01N37/06A01N37/02A01N25/30A01N2300/00
    • A herbicidal mixture, comprising a) a herbicidally effective amount of a benzoyl compound of formula I  where: R1, R2 are halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkyl-sulfinyl or C1-C6-alkylsulfonyl; R3 is hydrogen, halogen, C1-C6-alkyl; X is 4,5-dihydroisoxazolyl which is unsubstituted or mono- or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R4 is a pyrazole of the formula II  which is attached in the 4-position and where R5 is hydrogen, R6 is methyl, or an environmentally compatible salt thereof; b) an adjuvant comprising i) a C1-C5-alkyl C5-C22-alkanoate, ii) a C10-C20-carboxylic acid, iii) a partial phosphoric ester or a partial sulfuric ester of a monohydroxy-functional polyalkyl ether and iv) optionally an alkyl polyoxyalkylene polyether, wherein the compound of formula I and the adjuvat are present in synergistically effective amounts.
    • 一种除草混合物,其包含a)除草有效量的式I的苯甲酰基化合物,其中:R 1,R 2是卤素,C 1 -C 6烷基,C 1 -C 6烷硫基,C 1 -C 6烷基亚磺酰基或C 1 -C 6烷基磺酰基 R 3是氢,卤素,C 1 -C 6 - 烷基; X是未被取代或被卤素,C 1 -C 6烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 卤代烷基,C 1 -C 6 - 烷氧基取代或被单取代或多取代的4,5-二氢异恶唑基 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基; R 4是连接在4-位的式II的吡唑,其中R 5是氢,R 6是甲基或其环境相容的盐; b)佐剂,其包含:i) C1-C5烷基C5-C22-链烷酸酯,ii)C10-C20羧酸,iii)部分磷酸酯或单羟基官能聚烷基醚的部分硫酸酯,和/或任选的烷基聚氧化烯聚醚,其中化合物 并且佐剂以协同有效量存在。
    • 2. 发明授权
    • Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative
    • 含有3-杂环基取代的苯甲酰基衍生物的除草混合物
    • US06479437B1
    • 2002-11-12
    • US09701875
    • 2000-12-05
    • Matthias BratzRainer BerghausMartina OttenBernd SievernichElmar Kibler
    • Matthias BratzRainer BerghausMartina OttenBernd SievernichElmar Kibler
    • A01N4356
    • C05G3/02A01N43/78A01N43/80A01N2300/00
    • A herbicidal mixture comprising a) a herbicidally active amount of a 3-heterocyclyl-substituted benzoyl derivative of the formula I  in which the variables have the following meanings: R1,R2 are hydrogen, halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy; R3 is hydrogen, halogen, C1-C6-alkyl; X is a heterocycle from amongst the group consisting of isoxazolyl, 4,5-dihydroisoxazolyl and thiazolyl, it being possible for the heterocycle to be optionally monosubstituted or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R5 is hydrogen or C1-C6-alkyl, R6 is C1-C6-alkyl, or their environmentally compatible salts; b) a nitrogenous fertilizer in a synergistically effective amount and c) an adjuvant in a synergistically effective amount.
    • 一种除草混合物,其包含a)除草活性量的式I的3-杂环基取代的苯甲酰基衍生物,其中所述变量具有以下含义:R 1,R 2是氢,卤素,C 1 -C 6 - 烷基,C 1 -C 6 - 烷硫基 ,C 1 -C 6烷基亚磺酰基,C 1 -C 6烷基磺酰基,C 1 -C 6卤代烷基,C 1 -C 6 - 烷氧基,C 1 -C 6卤代烷氧基; R 3是氢,卤素,C 1 -C 6烷基; X是 由异唑基,4,5-二氢异恶唑基和噻唑基组成的组,可以将杂环任选被卤素,C 1 -C 6 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 卤代烷氧基,C 1 -C 4 - 烷硫基; R 5是氢或C 1 -C 6烷基,R 6是C 1 -C 6 - 烷基或其环境相容的盐; b)具有协同有效量的含氮肥料,和c)协同有效的佐剂 量。
    • 3. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20050239653A1
    • 2005-10-27
    • US11079431
    • 2005-03-14
    • Bernd SievernichMax LandesElmar KiblerWolfgang DeynHelmut WalterMartina OttenKarl-Otto WestphalenHerve Vantieghem
    • Bernd SievernichMax LandesElmar KiblerWolfgang DeynHelmut WalterMartina OttenKarl-Otto WestphalenHerve Vantieghem
    • A01N43/40A01N43/72A01N43/78A01N43/80A01N57/00A01N61/00
    • A01N43/78A01N43/80A01N61/00A01N57/20A01N47/36A01N47/30A01N47/12A01N47/06A01N43/90A01N43/88A01N43/82A01N43/76A01N43/707A01N43/70A01N43/653A01N43/58A01N43/54A01N43/50A01N43/42A01N43/40A01N43/18A01N39/04A01N41/10A01N37/48A01N37/46A01N37/40A01N37/26A01N37/22A01N37/18A01N37/12A01N2300/00
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are hydrogen, halogen, alkyl, halogenalkyl, alkoxy, halogenalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a heterocyclic radical selected from the group: thiazol-2-yl, thiazol-4-yl, thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl, it being possible for these to be unsubstituted or mono- or polysubstituted by halogen, alkyl, alkoxy, haloalkyl, haloalkoxy or alkylthio; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of at least one herbicidal compound from the group of the acetyl-CoA carboxylase inhibitors (ACC), acetolactate synthase inhibitors (ALS), amides, auxin herbicides, auxin transport inhibitors, carotenoid biosynthesis inhibitors, enolpyruvylshikimate-3-phosphate synthase inhibitors (ESPS), glutamine synthetase inhibitors, lipid biosynthesis inhibitors, mitosis inhibitors, protophorphyrinogen [sic ] IX oxidase inhibitors, photosynthesis inhibitors, synergists, growth substances, cell wall biosynthesis inhibitors and a variety of other herbicides. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 氢,卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是选自以下的杂环基:噻唑-2-基,噻唑-4-基,噻唑-5-基,异恶唑-3-基,异恶唑-4-基,异恶唑-4-基, 5,5-二氢异恶唑-3-基,4,5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基,这些可能是未被取代的或被卤素单取代或多取代, 烷基,烷氧基,卤代烷基,卤代烷氧基或烷硫基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 乙酰辅酶A羧化酶抑制剂(ACC),乙酰乳酸合酶抑制剂(ALS),酰胺,生长素除草剂,生长素转运抑制剂,类胡萝卜素生物合成抑制剂,烯醇丙酮酸莽草酸-3(3)的协同有效量的至少一种除草化合物 磷酸合成酶抑制剂(ESPS),谷氨酰胺合成酶抑制剂,脂质生物合成抑制剂,有丝分裂抑制剂,原卟啉原IX氧化酶抑制剂,光合作用抑制剂,增效剂,生长物质,细胞壁生物合成抑制剂和各种其它除草剂。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。
    • 8. 发明申请
    • NON-AQUEOUS ACTIVE INGREDIENT CONCENTRATES HAVING AN HERBICIDAL EFFECT
    • 具有除草效果的非水性活性成分浓度
    • US20100227763A1
    • 2010-09-09
    • US12376320
    • 2007-08-03
    • Michael KrappRainer BerghausMatthias BratzElmar KiblerHerve R. Vantieghem
    • Michael KrappRainer BerghausMatthias BratzElmar KiblerHerve R. Vantieghem
    • A01N43/56
    • A01N43/56A01N25/02A01N25/30A01N43/10A01N43/80A01N2300/00
    • The present invention relates to active compound concentrates having herbicidal action, comprising a) from 10 to 100 g/l of at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1, R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts, b) from 200 to 700 g/l of 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide, and c) from 10 to 200 g/l of at least one surfactant S selected from a mixture of at least one anionic surfactant and at least one nonionic surfactant, where the components a), b) and c) are present dissolved in a mixture of organic solvents consisting to at least 95% by weight, based on the solvent mixture, of d1) at least one aprotic polar organic solvent having a miscibility with water at 25° C. and 1 bar of at least 50 g/l, and d2) at least one organic solvent having a solubility in water at 25° C. and 1 bar of less than 5 g/l.
    • 本发明涉及具有除草作用的活性化合物浓缩物,其包含a)10-100g / l至少一种式I的4-苯甲酰基取代的吡唑化合物,其中R 1,R 3彼此独立地为氢,卤素 ,甲基,卤代甲基,甲氧基,卤代甲氧基,甲硫基,甲基亚磺酰基或甲基磺酰基; R2是未取代的或携带1,2,3或4个选自卤素,C 1 -C 6烷基,C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷基,C 1 -C 4的取代基的5元杂环基 - 卤代烷氧基和C 1 -C 4 - 烷硫基; R4是氢,卤素或甲基; R5是C1-C6-烷基,C3-C6-环烷基或C3-C6-环烷基甲基; 和R6是氢或C1-C4-烷基; 或其农业上有用的盐之一,b)200-700g / l的2-氯-N-(2,4-二甲基-3-噻吩基)-N-(2-甲氧基-1-甲基乙基)乙酰胺,和 c)10至200g / l的至少一种选自至少一种阴离子表面活性剂和至少一种非离子表面活性剂的混合物的表面活性剂S,其中组分a),b)和c)存在于 基于溶剂混合物,至少95重量%的有机溶剂为d1)至少一种与25℃的水混合的至少一种非质子极性有机溶剂和至少50g / l的1巴,d2 )至少一种在25℃下在水中的溶解度和小于5g / l的1巴的有机溶剂。
    • 9. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20050239654A1
    • 2005-10-27
    • US10522157
    • 2003-07-22
    • Elmar KiblerWilliam O'NealMatthias WitschelHerve Vantieghem
    • Elmar KiblerWilliam O'NealMatthias WitschelHerve Vantieghem
    • A01N43/50A01N43/647A01N43/70A01N43/713A01N43/72A01N43/80
    • A01N43/80A01N2300/00
    • A synergistic herbicidal mixture comprising: A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula (I) in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) two herbicides selected from the group including imazapyr, imazaquin, imazamethabenz-methyl, imazarnox, imazapic and imazethapyr; or one of its environmentally compatible salts; and, if desired, C) at least one further herbicidal compound; in a synergistically effective amount. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants
    • 一种协同除草混合物,其包含:A)至少一种式(I)的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是任选取代的杂环基,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基, 5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)选自以下的两种除草剂:咪草烟,咪草喹,咪草地嗪 - 甲基,咪草铵,咪唑并咪唑和咪草烟; 或其环境相容的盐之一; 并且如果需要,C)至少一种另外的除草化合物; 协同有效量。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途
    • 10. 发明申请
    • Synergistically acting herbicidal mixtures
    • 协同作用的除草混合物
    • US20060166828A1
    • 2006-07-27
    • US10519978
    • 2003-07-08
    • William O'NealElmar KiblerMatthias WitschelHerve Vantieghem
    • William O'NealElmar KiblerMatthias WitschelHerve Vantieghem
    • A01N43/60
    • A01N43/80A01N47/36A01N2300/00A01N43/56A01N43/70A01N43/88
    • A synergistic herbicidal mixture comprising A) at least one 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1, R3 are halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R2 is a optionally substituted heterocyclic radical selected from the group: isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl; R4 is hydrogen, halogen or alkyl; R5 is alkyl; R6 is hydrogen or alkyl; or one of its environmentally compatible salts; and B) a synergistically effective amount of the compound of formula II or one of its environmentally compatible salts; and, if desired, C) at least one further herbicidal compound; and, if desired, D) at least a safener. Compositions comprising these mixtures, processes for the preparation of these compositions, and their use for controlling undesired plants.
    • 一种协同除草混合物,其包含A)至少一种式I的3-杂环基取代的苯甲酰基衍生物,其中变量具有以下含义:R 1,R 3, 卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,烷硫基,烷基亚磺酰基或烷基磺酰基; R 2是任选取代的杂环基,其选自异恶唑-3-基,异恶唑-4-基,异恶唑-5-基,4,5-二氢异恶唑-3-基, 5-二氢异恶唑-4-基和4,5-二氢异恶唑-5-基; R 4是氢,卤素或烷基; R 5是烷基; R 6是氢或烷基; 或其环境相容的盐之一; 和B)协同有效量的式II化合物或其环境相容的盐之一; 并且如果需要,C)至少一种另外的除草化合物; 并且如果需要,D)至少一个安全剂。 包含这些混合物的组合物,这些组合物的制备方法以及它们用于控制不期望的植物的用途。