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1. 发明授权

US5981440A Stable solid formulations of cyclohexenone oxime ether herbicides 失效
标题翻译：环己烯酮肟醚除草剂稳定的固体制剂
公开(公告)号：US5981440A
公开(公告)日：1999-11-09
申请号：US913779
申请日：1997-09-23
申请人： Matthias Bratz , Karl-Friedrich Jager , Rainer Berghaus , Hans Ziegler
发明人： Matthias Bratz , Karl-Friedrich Jager , Rainer Berghaus , Hans Ziegler
IPC分类号： A01N25/12 , A01N25/22 , A01N35/10 , A01N43/16 , A01N43/18 , A01N43/76 , A01N43/56 , A01N37/00 , A01N43/02
CPC分类号： A01N35/10 , A01N25/12 , A01N43/16 , A01N43/18
摘要： Crop protection active compound formulations, comprising a cyclohexenone oxime ether of the general formula I ##STR1## where the radicals R.sup.1 -R.sup.6 have the following meanings: R.sup.1 is ethyl or propyl;R.sup.2 is hydrogen or an equivalent of an agriculturally utilizable cation;R.sup.3 is 2-thioethylpropyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-methylthiocyclopropyl, 5-isopropylisoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl;R.sup.4 and R.sup.5 independently of one another are hydrogen, methyl or methoxycarbonyl;Alk is CH.sub.2 CH.sub.2, CH.sub.2 CH(CH.sub.3), CH.sub.2 CH.dbd.CH, CH.sub.2 CH.dbd.C(Cl) or CH.sub.2 CH.sub.2 CH.dbd.CH;R.sup.6 is hydrogen, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy or dihalophenoxy;and a water-soluble basic salt of an acid having a pK.sub.a of greater than 5, alkali metal hydroxides and alkali metal carbonates being excluded, their preparation and use as herbicides are described.
摘要翻译： PCT No.PCT / EP96 / 01046 Sec。 371日期1997年9月23日 102（e）1997年9月23日PCT 1996年3月12日PCT公布。公开号WO96 / 29869 日期1996年10月3日保护活性化合物制剂，其包含通式I的环己烯酮肟醚，其中基团R 1 -R 6具有以下含义：R 1是乙基或丙基; R2是氢或相当于农业上可用的阳离子; R 3是2-硫代乙基丙基，四氢噻喃-3-基，四氢噻喃-4-基，四氢吡喃-3-基，四氢吡喃-4-基，1-甲硫基环丙基，5-异丙基异恶唑-3-基，2,5-二甲基吡唑-3-基， 2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R 4和R 5彼此独立地是氢，甲基或甲氧基羰基; Alk是CH 2 CH 2，CH 2 CH（CH 3），CH 2 CH = CH，CH 2 CH = C（Cl）或CH 2 CH 2 CH = CH; R6是氢，苯基，卤代苯基，二卤代苯基，苯氧基，卤代苯氧基或二卤代苯氧基; 和pKa大于5的酸的水溶性碱性盐，不包括碱金属氢氧化物和碱金属碳酸盐，它们作为除草剂的制备和用途被描述。

2. 发明授权

US06242382B1 Solid mixtures based on sulfonylureas and adjuvants 有权
标题翻译：基于磺酰脲类和佐剂的固体混合物
公开(公告)号：US06242382B1
公开(公告)日：2001-06-05
申请号：US09381548
申请日：1999-09-21
申请人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus , Hans Ziegler , Thomas Kröhl , Adolf Parg
发明人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus , Hans Ziegler , Thomas Kröhl , Adolf Parg
IPC分类号： A01N4364
CPC分类号： A01N47/36 , A01N25/30 , A01N25/22 , A01N25/14 , A01N2300/00
摘要： A solid ixture comprising a) an active ingredient from the group of the sulfonylureas and b) an alkyl ether of a copolymer of C2-C4-alkylene oxides.
摘要翻译：一种固体，其包含a）来自磺酰脲类的活性成分和b）C 2 -C 4 - 烯化氧的共聚物的烷基醚。

3. 发明授权

US06133202A Cyclohexenone oxime ether metal salts 失效
标题翻译：环己烯酮肟醚金属盐
公开(公告)号：US06133202A
公开(公告)日：2000-10-17
申请号：US77925
申请日：1998-06-05
申请人： Matthias Bratz , Karl-Friedrich Jager , Remy Benoit , Harald Rang , Ulf Misslitz , Karl-Otto Westphalen
发明人： Matthias Bratz , Karl-Friedrich Jager , Remy Benoit , Harald Rang , Ulf Misslitz , Karl-Otto Westphalen
IPC分类号： A01N35/10 , A01N43/10 , A01N43/14 , A01N43/16 , A01N43/18 , C07C239/20 , C07C251/42 , C07C251/50 , C07C323/47 , C07D309/06 , C07D335/02 , A01N43/40 , C07D405/00
CPC分类号： A01N35/10 , A01N43/14 , C07C251/42 , C07C251/50 , C07D335/02
摘要： Herbicidally active cyclohexenone oxime ether metal salts of formula I ##STR1## where R.sup.a, R.sup.b, R.sup.c, R.sup.d, R.sup.e, Alk and R.sup.f are as defined in the specification disclosure, having an improved shelf life and thermal stability and reduced water vapor uptake.
摘要翻译： PCT No.PCT / EP96 / 05255 Sec。 371日期：1998年6月5日 102（e）1998年6月5日PCT 1996年11月28日PCT公布。公开号WO97 / 20807 日期：1992年6月12日，其中Ra，Rb，Rc，Rd，Re，Alk和Rf如说明书公开中所定义的除草活性的式I的环己烯酮肟醚金属盐具有改进的保质期和热稳定性以及降低的水蒸汽吸收。

4. 发明授权

US5972915A Pesticide containing a synergistic combination of active ingredients 失效
标题翻译：含有活性成分的协同组合的农药
公开(公告)号：US5972915A
公开(公告)日：1999-10-26
申请号：US930169
申请日：1997-10-09
申请人： Peter Hofmeister , Ulrich Neumann , Volker Harries , Jurgen von der Heyde , Manfred Schroeder , Jorn Tidow , Matthias Bratz , Karl-Friedrich Jager
发明人： Peter Hofmeister , Ulrich Neumann , Volker Harries , Jurgen von der Heyde , Manfred Schroeder , Jorn Tidow , Matthias Bratz , Karl-Friedrich Jager
IPC分类号： A01N43/08 , A01N43/88 , A01N47/24 , A01N57/12 , A01N57/14 , A01N57/30 , A01N57/32 , A01N57/00 , A01N57/10 , A61K31/54
CPC分类号： A01N43/88
摘要： A pesticide comprising an active ingredient combination consisting ofa) tetrahydro-3,5-dimethyl-1,3,5-thiadiazine-2-thione of the formula ##STR1## and b) O-(O-ethyl-S-n-propylphosphoryl)-O-(N-methylcarbamoyl)pyrocatechol of the formula ##STR2## and/or c) O-ethyl S,S-dipropyl phosphorodithioate of the formula ##STR3## and/or d) 2-methyl-2-methylthiopropionaldehyde O-methylcarbamoyloxime of the formula ##STR4## and/or e) N,N-dimethyl-2-methylcarbamoyloximino-2-methylthioacetamide of the formula ##STR5## and/or f) ethyl-4-methylthio-m-tolylisopropylphosphoramide of the formula ##STR6## and/or g) (RS)-S-sec-butyl O-ethyl 2-oxo-1,3-thiazolidin-3-ylphosphono-thioate of the formula ##STR7## and/or h) 2,3-dihydro-2,2-dimethylbenzofuran-7-yl methylcarbamate of the formula ##STR8## and/or i) S-tert-butylthiomethyl O,O-diethyl phosphorodithioate of the formula ##STR9## and/or j) S,S-di-sec-butyl O-ethyl phosphorodithioate of the formula ##STR10## and/or k) (RS)-O-1-(4-chlorophenyl)pyrazol-4-yl O-ethyl S-propyl phosphorothioate of the formula ##STR11## and its use as a pesticide are described.
摘要翻译： PCT No.PCT / EP96 / 01513 Sec。 371 1997年10月9日第 102（e）1997年10月9日PCT PCT 1996年4月4日PCT公布。出版物WO96 / 33613 日期：1996年10月31日一种农药，其包含由下式的a）四氢-3,5-二甲基-1,3,5-噻二嗪-2-硫酮与b）O-（O-乙基-S- 丙基磷酰基）-O-（N-甲基氨基甲酰基）邻苯二酚和/或c）下式的O-乙基S，S-二丙基二硫代磷酸酯和/或d）下式的2-甲基-2-甲硫基丙醛O-甲基氨基甲酰肟： /或e）下式的N，N-二甲基-2-甲基氨基甲酰氨基-2-甲硫基乙酰胺和/或f）下式的乙基-4-甲硫基 - 间甲苯基异丙基磷酰胺和/或g）（RS）-S- 丁基O-乙基2-氧代-1,3-噻唑烷-3-基膦酰基 - 硫酸酯和/或h）2,3-二氢-2,2-二甲基苯并呋喃-7-基甲基氨基甲酸酯和/或i ）下式的和/或j）S的S-叔丁基硫代甲基O，O-二乙基二硫代磷酸酯和/或j）S，S-二仲丁基O-乙基二硫代磷酸酯和/或k）（RS）-O-1- 4-氯苯基）吡唑-4-基O-乙基S-丙基硫代磷酸酯及其用作杀虫剂 e被描述。

5. 发明申请

US20100160165A1 AQUEOUS ACTIVE INGREDIENT CONCENTRATE HAVING AN HERBICIDAL EFFECT 审中-公开
标题翻译：具有除草效果的水性活性成分浓度
公开(公告)号：US20100160165A1
公开(公告)日：2010-06-24
申请号：US12376310
申请日：2007-08-03
申请人： Matthias Bratz , Rainer Berghaus , Ulrich Steinbrenner
发明人： Matthias Bratz , Rainer Berghaus , Ulrich Steinbrenner
IPC分类号： A01N43/56
CPC分类号： A01N43/56 , A01N25/30 , A01N37/44 , A01N37/40 , A01N37/10 , A01N2300/00
摘要： The present invention relates to aqueous active compound concentrates having herbicidal action. The compound contains, in dissolved form: c) at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1 and R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts; and d) at least one benzoic acid derivative of the formula II in which R7 is hydrogen, halogen, hydroxyl or methoxy and R8 is hydrogen, halogen or amino; or one of its agriculturally useful salts.
摘要翻译：本发明涉及具有除草作用的水性活性化合物浓缩物。该化合物含有溶解形式：c）至少一种其中R 1和R 3彼此独立地为氢，卤素，甲基，卤代甲基，甲氧基，卤代甲氧基，甲硫基，甲基亚磺酰基或甲硫基的式I的4-苯甲酰基取代的吡唑化合物甲基磺酰基; R2是未取代的或携带1,2,3或4个选自卤素，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基和C 1 -C 4的取代基的5元杂环基 - 烷硫基; R4是氢，卤素或甲基; R5是C1-C6-烷基，C3-C6-环烷基或C3-C6-环烷基甲基; 和R6是氢或C1-C4-烷基; 或其农业上有用的盐之一; 和d）至少一种式II的苯甲酸衍生物，其中R 7是氢，卤素，羟基或甲氧基，R 8是氢，卤素或氨基; 或其农业上有用的盐之一。

6. 发明申请

US20080167189A1 Polymer Compositions and Their Use in the Production of Active or Effective Ingredient Compositions 审中-公开
标题翻译：聚合物组合物及其在活性或有效成分组合物生产中的应用
公开(公告)号：US20080167189A1
公开(公告)日：2008-07-10
申请号：US11815567
申请日：2006-02-08
申请人： Guenter Oetter , Christian Kruger , Norbert Wagner , Matthias Bratz , Rainer Berghaus , Peter Dombo
发明人： Guenter Oetter , Christian Kruger , Norbert Wagner , Matthias Bratz , Rainer Berghaus , Peter Dombo
IPC分类号： A01N25/00 , C08F8/30 , A01P3/00 , A01P13/00 , A01P7/00 , A01N25/10
CPC分类号： C08G18/283 , C08G18/6283 , C08G18/7831
摘要： The present invention relates to polymer compositions, to a process for their preparation and to their use for preparing aqueous active compound compositions of water-insoluble active compounds, in particular of active compounds for crop protection.
摘要翻译：本发明涉及聚合物组合物，其制备方法及其用于制备水不溶性活性化合物，特别是用于作物保护的活性化合物的水性活性化合物组合物的用途。

7. 发明授权

US06559098B1 Sulphonylurea and/adjuvant based solid mixtures 失效
标题翻译：磺酰脲和/佐剂基固体混合物
公开(公告)号：US06559098B1
公开(公告)日：2003-05-06
申请号：US09355743
申请日：1999-08-04
申请人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus
发明人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus
IPC分类号： A01N4354
CPC分类号： A01N47/36 , A01N25/30 , A01N25/22 , A01N25/14 , A01N2300/00
摘要： Solid mixtures comprising a) an active ingredient from the group of the sulfonylureas and b) a sulfate- or sulfonate-containing surfactant.
摘要翻译：包含a）来自磺酰脲类的活性成分和b）含硫酸盐或磺酸盐的表面活性剂的固体混合物。

8. 发明授权

US06479437B1 Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative 有权
标题翻译：含有3-杂环基取代的苯甲酰基衍生物的除草混合物
公开(公告)号：US06479437B1
公开(公告)日：2002-11-12
申请号：US09701875
申请日：2000-12-05
申请人： Matthias Bratz , Rainer Berghaus , Martina Otten , Bernd Sievernich , Elmar Kibler
发明人： Matthias Bratz , Rainer Berghaus , Martina Otten , Bernd Sievernich , Elmar Kibler
IPC分类号： A01N4356
CPC分类号： C05G3/02 , A01N43/78 , A01N43/80 , A01N2300/00
摘要： A herbicidal mixture comprising a) a herbicidally active amount of a 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1,R2 are hydrogen, halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy; R3 is hydrogen, halogen, C1-C6-alkyl; X is a heterocycle from amongst the group consisting of isoxazolyl, 4,5-dihydroisoxazolyl and thiazolyl, it being possible for the heterocycle to be optionally monosubstituted or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R5 is hydrogen or C1-C6-alkyl, R6 is C1-C6-alkyl, or their environmentally compatible salts; b) a nitrogenous fertilizer in a synergistically effective amount and c) an adjuvant in a synergistically effective amount.
摘要翻译：一种除草混合物，其包含a）除草活性量的式I的3-杂环基取代的苯甲酰基衍生物，其中所述变量具有以下含义：R 1，R 2是氢，卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷硫基，C 1 -C 6烷基亚磺酰基，C 1 -C 6烷基磺酰基，C 1 -C 6卤代烷基，C 1 -C 6 - 烷氧基，C 1 -C 6卤代烷氧基; R 3是氢，卤素，C 1 -C 6烷基; X是由异唑基，4,5-二氢异恶唑基和噻唑基组成的组，可以将杂环任选被卤素，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基; R 5是氢或C 1 -C 6烷基，R 6是C 1 -C 6 - 烷基或其环境相容的盐; b）具有协同有效量的含氮肥料，和c）协同有效的佐剂量。

9. 发明授权

US07872067B2 Amphiphilic polymer compositions and their use 有权
标题翻译：两亲聚合物组合物及其用途
公开(公告)号：US07872067B2
公开(公告)日：2011-01-18
申请号：US11628609
申请日：2005-06-07
申请人： Günter Oetter , Christian Krüger , Harald Köhle , Maria Scherer , Norbert Wagner , Matthias Bratz , Rainer Berghaus , Richard van Gelder
发明人： Günter Oetter , Christian Krüger , Harald Köhle , Maria Scherer , Norbert Wagner , Matthias Bratz , Rainer Berghaus , Richard van Gelder
IPC分类号： C08G18/08
CPC分类号： A01N25/04 , A01N25/30 , C08G18/283 , C08G18/3876 , C08G18/7831 , C08L33/06 , C08L75/04 , A01N47/24 , A01N43/653 , A01N43/40 , A01N53/00 , C08L2666/04
摘要： The present invention relates to amphiphilic polymer compositions, to a process for their preparation and to their use for preparing aqueous active compound compositions of water-insoluble active compounds, in particular active compounds for crop protection.The amphiphilic polymer compositions can be obtained by reacting a) at least one hydrophobic polymer P1 which carries functional groups R1 which are reactive toward isocyanate groups and which is constructed of ethylenically unsaturated monomers M1, comprising: a1) at least 10% by weight, based on the total amount of monomers M1, of monomers M1a of the formula I in which X is oxygen or a group N—R4; R1, R2, R3 and R4 are as defined in the claims and the description; a2) up to 90% by weight, based on the total amount of monomers M1, of neutral monoethylenically unsaturated monomers M1b whose solubility in water at 25° C. is less than 50 g/l and which are different from the monomers M1a; and a3) up to 30% by weight, based on the total amount of monomers M1, of ethylenically unsaturated monomers M1c which are different from the monomers M1a and M1b, b) at least one hydrophilic polymer P2 which carries functional groups R2 which are reactive toward isocyanate groups, c) with at least one compound V which contains isocyanate groups and, with respect to the isocyanate groups, has a functionality of at least 1.5.
摘要翻译：本发明涉及两亲聚合物组合物，其制备方法及其用于制备水不溶性活性化合物，特别是用于作物保护的活性化合物的水性活性化合物组合物的用途。两亲聚合物组合物可以通过使a）至少一种携带官能团R1的异氰酸酯基团反应的疏水性聚合物P1，其由烯属不饱和单体M1构成，其包含：a1）至少10重量％单体M1的总量，其中X是氧或基团N-R4的式I的单体M1a; R1，R2，R3和R4如权利要求和说明书所定义; a2）高达90重量％，基于单体M1的总量，在25℃下在水中的溶解度小于50g / l且不同于单体M1a的中性单烯属不饱和单体M1b; 和a3）至多30重量％，基于单体M1的总量，不同于单体M1a和M1b的烯键式不饱和单体M1c，b）至少一个带有官能团R2的亲水性聚合物P2，其具有反应性 c）与至少一种含有异氰酸酯基团的化合物V相对于异氰酸酯基具有至少1.5的官能度。

10. 发明授权

US09826739B2 Non-aqueous active ingredient concentrates having an herbicidal effect 有权
公开(公告)号：US09826739B2
公开(公告)日：2017-11-28
申请号：US12376320
申请日：2007-08-03
申请人： Michael Krapp , Rainer Berghaus , Matthias Bratz , Elmar Kibler , Herve R. Vantieghem
发明人： Michael Krapp , Rainer Berghaus , Matthias Bratz , Elmar Kibler , Herve R. Vantieghem
IPC分类号： A01N43/80 , A01N43/56 , A01N43/10 , A01N25/02 , A01N25/30
CPC分类号： A01N43/56 , A01N25/02 , A01N25/30 , A01N43/10 , A01N43/80 , A01N2300/00
摘要： The present invention relates to active compound concentrates having herbicidal action, comprising a) from 10 to 100 g/l of at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1, R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts, b) from 200 to 700 g/l of 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide, and c) from 10 to 200 g/l of at least one surfactant S selected from a mixture of at least one anionic surfactant and at least one nonionic surfactant, where the components a), b) and c) are present dissolved in a mixture of organic solvents consisting to at least 95% by weight, based on the solvent mixture, of d1) at least one aprotic polar organic solvent having a miscibility with water at 25° C. and 1 bar of at least 50 g/l, and d2) at least one organic solvent having a solubility in water at 25° C. and 1 bar of less than 5 g/l.

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