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    • 2. 发明授权
    • Cyclohexenone oxime ether/(glyphosates/gluphosinates) suspension concentrates
    • 环己烯酮肟醚/(草甘膦/草甘膦)悬浮浓缩物
    • US06383987B1
    • 2002-05-07
    • US09868072
    • 2001-08-02
    • Jürgen von der HeydeReiner KoberMatthias BratzRainer BerghausKarl-Friedrich JägerJürgen FriesAdolf Parg
    • Jürgen von der HeydeReiner KoberMatthias BratzRainer BerghausKarl-Friedrich JägerJürgen FriesAdolf Parg
    • A01N4380
    • A01N57/20A01N2300/00
    • A substantially water-free formulation of crop protection agents, comprising essentially a) a cyclohexenone oxime ether of the formula I  where R1=ethyl, propyl; R2=hydrogen or an equivalent of an agriculturally useful cation; R3=2-(thioethyl)propyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-(methylthio)cyclopropyl, 5-(isopropyl)isoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl; R4, R5=H, CH3, CO—OCH3; Alk=CH2CH2, CH2CH(CH3), CH2CH═CH, CH2CH═C(Cl), CH2CH2CH═CH; R6=H, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy, dihalophenoxy; b) N-phosphonamethylglycine, or an ester or salt thereof, DL-homoalanin-4-yl(methyl)phosphinic acid or its ammonium salt; c) from 20 to 80% by weight of an aprotic or weakly protic solvent in which the components a) and b) are suspended; d) if desired emulsifiers, surfactants, surface-active and/or activity-enhancing auxiliaries, is described.
    • 基本上无水的作物保护剂制剂,其基本上包括式I的环己烯酮肟醚,其中R 1 =乙基,丙基; R 2 =氢或相当于农业上可用的阳离子; R 3 = 2-(硫代乙基)丙基,四氢噻喃 吡啶-3-基,四氢噻喃-4-基,四氢吡喃-3-基,四氢吡喃-4-基,1-(甲硫基)环丙基,5-(异丙基)异恶唑-3-基,2,5-二甲基吡唑-3-基 ,2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R4,R5 = H,CH3,CO-OCH3; Alk = CH2CH2,CH2CH(CH3),CH2CH = CH,CH2CH = C( Cl),CH 2 CH 2 CH = CH; R 6 = H,苯基,卤代苯基,二卤代苯氧基,苯氧基,卤代苯氧基,二卤苯氧基; b)N-膦酰基甲基甘氨酸或其酯或盐,DL-高拉蛋白-4-基(甲基)次膦酸或其 铵盐; c)20至80重量%的非质子或弱质子溶剂,其中组分a)和b)悬浮; d)如果需要,乳化剂,表面活性剂,表面活性剂和/或活性增强助剂, 被描述。
    • 5. 发明授权
    • Storage stable aqueous formulations based on N-phenyl-3,4,5,6-tetrahydrophthalimide herbicides
    • 基于N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺除草剂的储存稳定的水性制剂
    • US06313070B1
    • 2001-11-06
    • US09582883
    • 2000-07-06
    • Matthias BratzRainer BerghausAugust WiggerAdolf PargWessel Nuyken
    • Matthias BratzRainer BerghausAugust WiggerAdolf PargWessel Nuyken
    • A01N2530
    • A01N37/32A01N37/46A01N43/84A01N25/04A01N2300/00
    • Storage-stable aqueous formulations comprising a) 0.1-60% by weight of a tetrahydrophthalimide of the formula I  where R1=H, F, Cl; R2=CH═C(Cl)—CO—B or CH═C(Br)—CO—B (B=C1-C6-alkyl, unsubstituted or substituted OH or SH); a group OR5, SR5, COOR5, OCH2COOR5, CH2—CO—OR6 or (C1-C6-alkyl)sulfonylamino; R5=H, C1-C6-alkyl, C3-C7-cycloalkyl, C2-C8-alkenyl, C2-C6-alkynyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl or C1-C6-alkyloximino-C1-C6-alkyl R3=Cl, CN; R6=is H, C1-C6-alkyl, C2-C8-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy-C1-C6-alkyl or C1-C6-alkyloximino-C1-C6-alkyl; b) 0.1-30% by weight of an anionic surfactant; c) 0.1-30% by weight of a non-ionic surfactant; d) 0.01-5% by weight of a thixotroping additive; e) 0-50% by weight of other herbicidal active ingredients; f) 0-20% by weight of other formulation auxiliaries, and g) 1-90% of water. Storage-stable aqueous formulations based on N-phenyl- 3,4,5,6 -tetrahydrophthalimide derivatives, and their use as herbicides in crop protection
    • 其中R1 = H,F,Cl; R2 = CH = C(C1)-CO-B或CH = C(Br)-CO-B的四氢邻苯二甲酰亚胺, B(B = C1-C6-烷基,未取代或取代的OH或SH); OR5,SR5,COOR5,OCH2COOR5,CH2-CO-OR6或(C1-C6-烷基)磺酰基氨基; R5 = H,C1-C6 - 烷基,C 3 -C 7 - 环烷基,C 2 -C 8 - 烯基,C 2 -C 6 - 炔基,(C 1 -C 6 - 烷氧基)羰基-C 1 -C 6烷基或C 1 -C 6烷氧基肟基-C 1 -C 6烷基R 3 = CN; R6 =是H,C1-C6-烷基,C2-C8-烯基,C2-C6-炔基,C3-C7-环烷基,C1-C6-烷氧基-C1-C6-烷基或C1-C6-烷氧基肟基C1 -C6-烷基; b)0.1-30重量%的阴离子表面活性剂; c)0.1-30重量%的非离子表面活性剂; d)0.01-5重量%的触变添加剂; e)0- 50重量%的其它除草活性成分; f)0-20重量%的其它制剂助剂,和g)1-90重量%的水。 基于N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺衍生物的储存稳定的水性制剂及其作为农作物保护中除草剂的用途