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1. 发明授权

US06242382B1 Solid mixtures based on sulfonylureas and adjuvants 有权
标题翻译：基于磺酰脲类和佐剂的固体混合物
公开(公告)号：US06242382B1
公开(公告)日：2001-06-05
申请号：US09381548
申请日：1999-09-21
申请人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus , Hans Ziegler , Thomas Kröhl , Adolf Parg
发明人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus , Hans Ziegler , Thomas Kröhl , Adolf Parg
IPC分类号： A01N4364
CPC分类号： A01N47/36 , A01N25/30 , A01N25/22 , A01N25/14 , A01N2300/00
摘要： A solid ixture comprising a) an active ingredient from the group of the sulfonylureas and b) an alkyl ether of a copolymer of C2-C4-alkylene oxides.
摘要翻译：一种固体，其包含a）来自磺酰脲类的活性成分和b）C 2 -C 4 - 烯化氧的共聚物的烷基醚。

2. 发明授权

US06383987B1 Cyclohexenone oxime ether/(glyphosates/gluphosinates) suspension concentrates 有权
标题翻译：环己烯酮肟醚/（草甘膦/草甘膦）悬浮浓缩物
公开(公告)号：US06383987B1
公开(公告)日：2002-05-07
申请号：US09868072
申请日：2001-08-02
申请人： Jürgen von der Heyde , Reiner Kober , Matthias Bratz , Rainer Berghaus , Karl-Friedrich Jäger , Jürgen Fries , Adolf Parg
发明人： Jürgen von der Heyde , Reiner Kober , Matthias Bratz , Rainer Berghaus , Karl-Friedrich Jäger , Jürgen Fries , Adolf Parg
IPC分类号： A01N4380
CPC分类号： A01N57/20 , A01N2300/00
摘要： A substantially water-free formulation of crop protection agents, comprising essentially a) a cyclohexenone oxime ether of the formula I where R1=ethyl, propyl; R2=hydrogen or an equivalent of an agriculturally useful cation; R3=2-(thioethyl)propyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-(methylthio)cyclopropyl, 5-(isopropyl)isoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl; R4, R5=H, CH3, CO—OCH3; Alk=CH2CH2, CH2CH(CH3), CH2CH═CH, CH2CH═C(Cl), CH2CH2CH═CH; R6=H, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy, dihalophenoxy; b) N-phosphonamethylglycine, or an ester or salt thereof, DL-homoalanin-4-yl(methyl)phosphinic acid or its ammonium salt; c) from 20 to 80% by weight of an aprotic or weakly protic solvent in which the components a) and b) are suspended; d) if desired emulsifiers, surfactants, surface-active and/or activity-enhancing auxiliaries, is described.
摘要翻译：基本上无水的作物保护剂制剂，其基本上包括式I的环己烯酮肟醚，其中R 1 =乙基，丙基; R 2 =氢或相当于农业上可用的阳离子; R 3 = 2-（硫代乙基）丙基，四氢噻喃吡啶-3-基，四氢噻喃-4-基，四氢吡喃-3-基，四氢吡喃-4-基，1-（甲硫基）环丙基，5-（异丙基）异恶唑-3-基，2,5-二甲基吡唑-3-基，2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R4，R5 = H，CH3，CO-OCH3; Alk = CH2CH2，CH2CH（CH3），CH2CH = CH，CH2CH = C（ Cl），CH 2 CH 2 CH = CH; R 6 = H，苯基，卤代苯基，二卤代苯氧基，苯氧基，卤代苯氧基，二卤苯氧基; b）N-膦酰基甲基甘氨酸或其酯或盐，DL-高拉蛋白-4-基（甲基）次膦酸或其铵盐; c）20至80重量％的非质子或弱质子溶剂，其中组分a）和b）悬浮; d）如果需要，乳化剂，表面活性剂，表面活性剂和/或活性增强助剂，被描述。

3. 发明授权

US06218337B1 Solid mixtures of 3-isopropyl-2,1,3-benzothiadiazin-4-one-2,2,-dioxide or its salts 失效
标题翻译： 3-异丙基-2,1,3-苯并噻二嗪-4-酮-2,2-二氧化物或其盐的固体混合物
公开(公告)号：US06218337B1
公开(公告)日：2001-04-17
申请号：US09269334
申请日：1999-03-25
申请人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus , Adolf Parg
发明人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus , Adolf Parg
IPC分类号： A01N4372
CPC分类号： A01N43/88 , A01N25/30 , A01N25/12 , A01N2300/00
摘要： A solid mixture comprising A) 3-isopropyl-2,1,3-benzothiadiazine-4-one 2,2-dioxide or a salt thereof and B) at least one nonionic surfactant, a process for its preparation, and its use for controlling undesirable vegetation.
摘要翻译：一种固体混合物，其包含A）3-异丙基-2,1,3-苯并噻二嗪-4-酮2,2-二氧化物或其盐和B）至少一种非离子表面活性剂，其制备方法及其用于防治不期望的植物。

4. 发明授权

US06559098B1 Sulphonylurea and/adjuvant based solid mixtures 失效
标题翻译：磺酰脲和/佐剂基固体混合物
公开(公告)号：US06559098B1
公开(公告)日：2003-05-06
申请号：US09355743
申请日：1999-08-04
申请人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus
发明人： Matthias Bratz , Karl-Friedrich Jäger , Rainer Berghaus
IPC分类号： A01N4354
CPC分类号： A01N47/36 , A01N25/30 , A01N25/22 , A01N25/14 , A01N2300/00
摘要： Solid mixtures comprising a) an active ingredient from the group of the sulfonylureas and b) a sulfate- or sulfonate-containing surfactant.
摘要翻译：包含a）来自磺酰脲类的活性成分和b）含硫酸盐或磺酸盐的表面活性剂的固体混合物。

5. 发明授权

US06225259B1 Liquid formulation of ethyl-(Z)-2-chloro-3-[2-chloro-5-(4,5,6,7-tetrahydro-1,3-dioxoisoindoledion-2-yl)phenyl]acrylate 失效
标题翻译：乙基 - （Z）-2-氯-3- [2-氯-5-（4,5,6,7-四氢-1,3-二氧代异吲哚啉-2-基）苯基]丙烯酸酯的液体制剂
公开(公告)号：US06225259B1
公开(公告)日：2001-05-01
申请号：US09242125
申请日：1999-12-03
申请人： Rainer Berghaus , Dieter Kleuser , Matthias Bratz , Adolf Parg , Wessel Nuyken
发明人： Rainer Berghaus , Dieter Kleuser , Matthias Bratz , Adolf Parg , Wessel Nuyken
IPC分类号： A01N4338
CPC分类号： A01N37/46 , A01N25/30 , A01N25/02 , A01N2300/00
摘要： A liquid formulation of cinidon-ethyl, i.e., ethyl (Z)-2-chloro-3-[2-chloro-5 -(4,5,6,7-tetrahydro-1,3-dioxoisoindoledion-2-yl)phenyl] acrylate comprising, essentially, in addition to the above crop protection agent, a) an ionic emulsifier, b) a non-ionic emulsifier, c) a non-nucleophilic and non-basic aromatic solvent and, d) if desired, a further herbicidal crop protection agent, and a method of controlling undesirable vegetation using this formulation.
摘要翻译：乙酸乙酯的液体制剂，即（Z）-2-氯-3- [2-氯-5-（4,5,6,7-四氢-1,3-二氧代异吲哚-2-基）苯基乙基 ]丙烯酸酯，其基本上除了上述作物保护剂之外，a）离子乳化剂，b）非离子乳化剂，c）非亲核和非碱性芳族溶剂，和d）如果需要，还可以进一步除草作物保护剂，以及使用该配方控制不希望的植物的方法。

6. 发明授权

US06313070B1 Storage stable aqueous formulations based on N-phenyl-3,4,5,6-tetrahydrophthalimide herbicides 失效
标题翻译：基于N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺除草剂的储存稳定的水性制剂
公开(公告)号：US06313070B1
公开(公告)日：2001-11-06
申请号：US09582883
申请日：2000-07-06
申请人： Matthias Bratz , Rainer Berghaus , August Wigger , Adolf Parg , Wessel Nuyken
发明人： Matthias Bratz , Rainer Berghaus , August Wigger , Adolf Parg , Wessel Nuyken
IPC分类号： A01N2530
CPC分类号： A01N37/32 , A01N37/46 , A01N43/84 , A01N25/04 , A01N2300/00
摘要： Storage-stable aqueous formulations comprising a) 0.1-60% by weight of a tetrahydrophthalimide of the formula I where R1=H, F, Cl; R2=CH═C(Cl)—CO—B or CH═C(Br)—CO—B (B=C1-C6-alkyl, unsubstituted or substituted OH or SH); a group OR5, SR5, COOR5, OCH2COOR5, CH2—CO—OR6 or (C1-C6-alkyl)sulfonylamino; R5=H, C1-C6-alkyl, C3-C7-cycloalkyl, C2-C8-alkenyl, C2-C6-alkynyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl or C1-C6-alkyloximino-C1-C6-alkyl R3=Cl, CN; R6=is H, C1-C6-alkyl, C2-C8-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy-C1-C6-alkyl or C1-C6-alkyloximino-C1-C6-alkyl; b) 0.1-30% by weight of an anionic surfactant; c) 0.1-30% by weight of a non-ionic surfactant; d) 0.01-5% by weight of a thixotroping additive; e) 0-50% by weight of other herbicidal active ingredients; f) 0-20% by weight of other formulation auxiliaries, and g) 1-90% of water. Storage-stable aqueous formulations based on N-phenyl- 3,4,5,6 -tetrahydrophthalimide derivatives, and their use as herbicides in crop protection
摘要翻译：其中R1 = H，F，Cl; R2 = CH = C（C1）-CO-B或CH = C（Br）-CO-B的四氢邻苯二甲酰亚胺， B（B = C1-C6-烷基，未取代或取代的OH或SH）; OR5，SR5，COOR5，OCH2COOR5，CH2-CO-OR6或（C1-C6-烷基）磺酰基氨基; R5 = H，C1-C6 - 烷基，C 3 -C 7 - 环烷基，C 2 -C 8 - 烯基，C 2 -C 6 - 炔基，（C 1 -C 6 - 烷氧基）羰基-C 1 -C 6烷基或C 1 -C 6烷氧基肟基-C 1 -C 6烷基R 3 = CN; R6 =是H，C1-C6-烷基，C2-C8-烯基，C2-C6-炔基，C3-C7-环烷基，C1-C6-烷氧基-C1-C6-烷基或C1-C6-烷氧基肟基C1 -C6-烷基; b）0.1-30重量％的阴离子表面活性剂; c）0.1-30重量％的非离子表面活性剂; d）0.01-5重量％的触变添加剂; e）0- 50重量％的其它除草活性成分; f）0-20重量％的其它制剂助剂，和g）1-90重量％的水。基于N-苯基-3,4,5,6-四氢邻苯二甲酰亚胺衍生物的储存稳定的水性制剂及其作为农作物保护中除草剂的用途

7. 发明授权

US5981440A Stable solid formulations of cyclohexenone oxime ether herbicides 失效
标题翻译：环己烯酮肟醚除草剂稳定的固体制剂
公开(公告)号：US5981440A
公开(公告)日：1999-11-09
申请号：US913779
申请日：1997-09-23
申请人： Matthias Bratz , Karl-Friedrich Jager , Rainer Berghaus , Hans Ziegler
发明人： Matthias Bratz , Karl-Friedrich Jager , Rainer Berghaus , Hans Ziegler
IPC分类号： A01N25/12 , A01N25/22 , A01N35/10 , A01N43/16 , A01N43/18 , A01N43/76 , A01N43/56 , A01N37/00 , A01N43/02
CPC分类号： A01N35/10 , A01N25/12 , A01N43/16 , A01N43/18
摘要： Crop protection active compound formulations, comprising a cyclohexenone oxime ether of the general formula I ##STR1## where the radicals R.sup.1 -R.sup.6 have the following meanings: R.sup.1 is ethyl or propyl;R.sup.2 is hydrogen or an equivalent of an agriculturally utilizable cation;R.sup.3 is 2-thioethylpropyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-methylthiocyclopropyl, 5-isopropylisoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl;R.sup.4 and R.sup.5 independently of one another are hydrogen, methyl or methoxycarbonyl;Alk is CH.sub.2 CH.sub.2, CH.sub.2 CH(CH.sub.3), CH.sub.2 CH.dbd.CH, CH.sub.2 CH.dbd.C(Cl) or CH.sub.2 CH.sub.2 CH.dbd.CH;R.sup.6 is hydrogen, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy or dihalophenoxy;and a water-soluble basic salt of an acid having a pK.sub.a of greater than 5, alkali metal hydroxides and alkali metal carbonates being excluded, their preparation and use as herbicides are described.
摘要翻译： PCT No.PCT / EP96 / 01046 Sec。 371日期1997年9月23日 102（e）1997年9月23日PCT 1996年3月12日PCT公布。公开号WO96 / 29869 日期1996年10月3日保护活性化合物制剂，其包含通式I的环己烯酮肟醚，其中基团R 1 -R 6具有以下含义：R 1是乙基或丙基; R2是氢或相当于农业上可用的阳离子; R 3是2-硫代乙基丙基，四氢噻喃-3-基，四氢噻喃-4-基，四氢吡喃-3-基，四氢吡喃-4-基，1-甲硫基环丙基，5-异丙基异恶唑-3-基，2,5-二甲基吡唑-3-基， 2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R 4和R 5彼此独立地是氢，甲基或甲氧基羰基; Alk是CH 2 CH 2，CH 2 CH（CH 3），CH 2 CH = CH，CH 2 CH = C（Cl）或CH 2 CH 2 CH = CH; R6是氢，苯基，卤代苯基，二卤代苯基，苯氧基，卤代苯氧基或二卤代苯氧基; 和pKa大于5的酸的水溶性碱性盐，不包括碱金属氢氧化物和碱金属碳酸盐，它们作为除草剂的制备和用途被描述。

8. 发明授权

US06831041B2 Oil suspension concentrates based on a cyclohexenone oxime ether lithium salt and the use thereof as plant protection agents 失效
标题翻译：基于环己烯酮肟醚锂盐的油悬浮浓缩物及其作为植物保护剂的用途
公开(公告)号：US06831041B2
公开(公告)日：2004-12-14
申请号：US10380120
申请日：2003-03-11
申请人： Reiner Kober , Rainer Berghaus , Thomas Kröhl , Hans Ziegler , Volker Maywald
发明人： Reiner Kober , Rainer Berghaus , Thomas Kröhl , Hans Ziegler , Volker Maywald
IPC分类号： A01N4318
CPC分类号： A01N43/18 , A01N59/08 , A01N43/42 , A01N25/30 , A01N25/22 , A01N25/04 , A01N25/02 , A01N2300/00
摘要： The present invention relates to oil suspension concentrates based on 2-{1-[2-(4-chlorophenoxy)propoxyimino]butyl}-3-hydroxy-5-(tetrahydrothiopyran-3-yl)cyclohex-2-enone lithium salt and certain formulation auxiliaries and to the use of the oil suspension concentrates as crop protection compositions and in particular as rice herbicides. Preferred formulation auxiliaries are mono- and/or dicarboxylic esters, for example fluid fatty acid esters, anionic surfactants of the sulfonate type, for example alkyl- and alkylarylsulfonates and also sulfosuccinates, and nonionic surfactants of the type of the nonethoxylated or ethoxylated carboxylic acids and esters of mono- or polyfunctional alcohols, for example ethoxylated fatty acids and polyoxyethylene sorbitan fatty acid esters. The oil suspension concentrates described herein are storage-stable and have excellent use properties.
摘要翻译：本发明涉及基于2- {1- [2-（4-氯苯氧基）丙氧基亚氨基]丁基} -3-羟基-5-（四氢噻喃-3-基）环己-2-烯酮锂盐的油悬液浓缩物和某些制剂助剂以及油悬浮浓缩物作为作物保护组合物的用途，特别是作为水稻除草剂。优选的制剂助剂是单酯和/或二羧酸酯，例如流化脂肪酸酯，磺酸盐型阴离子表面活性剂，例如烷基 - 和烷基芳基磺酸盐，以及磺基琥珀酸盐，以及非乙氧基化或乙氧基化羧酸类型的非离子表面活性剂，单官能或多官能醇的酯，例如乙氧基化脂肪酸和聚氧乙烯脱水山梨糖醇脂肪酸酯。本文所述的油悬浮浓缩物是储存稳定的并且具有优异的使用性质。

9. 发明授权

US06479437B1 Herbicidal mixture containing a 3-heterocyclyl-substituted benzoyl derivative 有权
标题翻译：含有3-杂环基取代的苯甲酰基衍生物的除草混合物
公开(公告)号：US06479437B1
公开(公告)日：2002-11-12
申请号：US09701875
申请日：2000-12-05
申请人： Matthias Bratz , Rainer Berghaus , Martina Otten , Bernd Sievernich , Elmar Kibler
发明人： Matthias Bratz , Rainer Berghaus , Martina Otten , Bernd Sievernich , Elmar Kibler
IPC分类号： A01N4356
CPC分类号： C05G3/02 , A01N43/78 , A01N43/80 , A01N2300/00
摘要： A herbicidal mixture comprising a) a herbicidally active amount of a 3-heterocyclyl-substituted benzoyl derivative of the formula I in which the variables have the following meanings: R1,R2 are hydrogen, halogen, C1-C6-alkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy; R3 is hydrogen, halogen, C1-C6-alkyl; X is a heterocycle from amongst the group consisting of isoxazolyl, 4,5-dihydroisoxazolyl and thiazolyl, it being possible for the heterocycle to be optionally monosubstituted or polysubstituted by halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, C1-C4-alkylthio; R5 is hydrogen or C1-C6-alkyl, R6 is C1-C6-alkyl, or their environmentally compatible salts; b) a nitrogenous fertilizer in a synergistically effective amount and c) an adjuvant in a synergistically effective amount.
摘要翻译：一种除草混合物，其包含a）除草活性量的式I的3-杂环基取代的苯甲酰基衍生物，其中所述变量具有以下含义：R 1，R 2是氢，卤素，C 1 -C 6 - 烷基，C 1 -C 6 - 烷硫基，C 1 -C 6烷基亚磺酰基，C 1 -C 6烷基磺酰基，C 1 -C 6卤代烷基，C 1 -C 6 - 烷氧基，C 1 -C 6卤代烷氧基; R 3是氢，卤素，C 1 -C 6烷基; X是由异唑基，4,5-二氢异恶唑基和噻唑基组成的组，可以将杂环任选被卤素，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 卤代烷氧基，C 1 -C 4 - 烷硫基; R 5是氢或C 1 -C 6烷基，R 6是C 1 -C 6 - 烷基或其环境相容的盐; b）具有协同有效量的含氮肥料，和c）协同有效的佐剂量。

10. 发明授权

US07872067B2 Amphiphilic polymer compositions and their use 有权
标题翻译：两亲聚合物组合物及其用途
公开(公告)号：US07872067B2
公开(公告)日：2011-01-18
申请号：US11628609
申请日：2005-06-07
申请人： Günter Oetter , Christian Krüger , Harald Köhle , Maria Scherer , Norbert Wagner , Matthias Bratz , Rainer Berghaus , Richard van Gelder
发明人： Günter Oetter , Christian Krüger , Harald Köhle , Maria Scherer , Norbert Wagner , Matthias Bratz , Rainer Berghaus , Richard van Gelder
IPC分类号： C08G18/08
CPC分类号： A01N25/04 , A01N25/30 , C08G18/283 , C08G18/3876 , C08G18/7831 , C08L33/06 , C08L75/04 , A01N47/24 , A01N43/653 , A01N43/40 , A01N53/00 , C08L2666/04
摘要： The present invention relates to amphiphilic polymer compositions, to a process for their preparation and to their use for preparing aqueous active compound compositions of water-insoluble active compounds, in particular active compounds for crop protection.The amphiphilic polymer compositions can be obtained by reacting a) at least one hydrophobic polymer P1 which carries functional groups R1 which are reactive toward isocyanate groups and which is constructed of ethylenically unsaturated monomers M1, comprising: a1) at least 10% by weight, based on the total amount of monomers M1, of monomers M1a of the formula I in which X is oxygen or a group N—R4; R1, R2, R3 and R4 are as defined in the claims and the description; a2) up to 90% by weight, based on the total amount of monomers M1, of neutral monoethylenically unsaturated monomers M1b whose solubility in water at 25° C. is less than 50 g/l and which are different from the monomers M1a; and a3) up to 30% by weight, based on the total amount of monomers M1, of ethylenically unsaturated monomers M1c which are different from the monomers M1a and M1b, b) at least one hydrophilic polymer P2 which carries functional groups R2 which are reactive toward isocyanate groups, c) with at least one compound V which contains isocyanate groups and, with respect to the isocyanate groups, has a functionality of at least 1.5.
摘要翻译：本发明涉及两亲聚合物组合物，其制备方法及其用于制备水不溶性活性化合物，特别是用于作物保护的活性化合物的水性活性化合物组合物的用途。两亲聚合物组合物可以通过使a）至少一种携带官能团R1的异氰酸酯基团反应的疏水性聚合物P1，其由烯属不饱和单体M1构成，其包含：a1）至少10重量％单体M1的总量，其中X是氧或基团N-R4的式I的单体M1a; R1，R2，R3和R4如权利要求和说明书所定义; a2）高达90重量％，基于单体M1的总量，在25℃下在水中的溶解度小于50g / l且不同于单体M1a的中性单烯属不饱和单体M1b; 和a3）至多30重量％，基于单体M1的总量，不同于单体M1a和M1b的烯键式不饱和单体M1c，b）至少一个带有官能团R2的亲水性聚合物P2，其具有反应性 c）与至少一种含有异氰酸酯基团的化合物V相对于异氰酸酯基具有至少1.5的官能度。

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