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1. 发明授权

US06207853B1 Homogeneous asymmetric hydrogenation using phosphine ligands of transition metals 有权
标题翻译：使用过渡金属膦配体的均相不对称氢化
公开(公告)号：US06207853B1
公开(公告)日：2001-03-27
申请号：US09213745
申请日：1998-12-17
申请人： Mark Joseph Burk , Frank Bienewald , Martin Edward Fox , Antonio Zanotti-Gerosa
发明人： Mark Joseph Burk , Frank Bienewald , Martin Edward Fox , Antonio Zanotti-Gerosa
IPC分类号： C07C6976
CPC分类号： C07C67/303 , C07C69/34
摘要： A process for the preparation of an enantiomerically enriched 2-substituted succinic acid derivative of formula 2, which comprises asymmetric hydrogenation of the dehydro precursor of formula 7 or 8, or a mixture thereof wherein R1 and R2 are independently H, a salt-forming cation, or an organic group of up to 30 C atoms, and R3 and R4 are independently H or an organic group of up to 30 C atoms, provided that R3 and R4 are not both H, in the presence of a transition metal complex of a chiral phosphine ligand having the partial formula 10 wherein n is 0 to 6 and R represents at least one non-hydrogen organic group of up to 30 C atoms.
摘要翻译：制备式2的对映体富集的2-取代琥珀酸衍生物的方法，其包括式7或8的脱氢前体或其混合物的不对称氢化，其中R1和R2独立地为H，成盐阳离子，或至多30个C原子的有机基团，并且R3和R4独立地为H或至多30个C原子的有机基团，条件是在手性的过渡金属络合物存在下，R 3和R 4不同时为H 具有部分式10的膦配体，其中n为0至6，R表示至多一个至多30个C原子的非氢有机基团。

2. 发明授权

US06414187B1 Asymmetric hydrogenation 有权
标题翻译：不对称氢化
公开(公告)号：US06414187B1
公开(公告)日：2002-07-02
申请号：US09673119
申请日：2000-12-05
申请人： Mark Joseph Burk , Frank Bienewald , Antonio Zanotti-Gerosa
发明人： Mark Joseph Burk , Frank Bienewald , Antonio Zanotti-Gerosa
IPC分类号： C07C5750
CPC分类号： C07C67/303 , C07C69/34
摘要： The present invention pertains to a process for the preparation of an enantiomerically enriched chiral carboxylic acid derivative having the partial formula: C—C—C—COOX wherein X is a cation, comprising formation of a dehydro precursor salt having the partial formula: C═C—C—COOX by reaction of the corresponding precursor acid with an at least substantially stoichiometric amount of base, and asymmetric hydrogenation of the salt in the presence of a transition metal complex of a chiral phosphine ligand.
摘要翻译：本发明涉及制备具有部分分子式：CCC-COOX的对映异构体富集的手性羧酸衍生物的方法，其中X是阳离子，包括通过以下步骤形成具有部分分子式：C = CC-COOX的脱氢前体盐相应的前体酸与至少基本上化学计量的碱的反应，以及在手性膦配体的过渡金属络合物存在下不对称地加氢盐。

3. 发明授权

US08404864B2 Pyrrolopyrrole derivatives, their manufacture and use 有权
标题翻译：吡咯并吡咯衍生物，其制造和使用
公开(公告)号：US08404864B2
公开(公告)日：2013-03-26
申请号：US12680904
申请日：2008-09-22
申请人： Zhimin Hao , Beat Schmidhalter , Jean-Luc Budry , Margherita Fontana , Mathieu Turbiez , Frank Bienewald , Mathias Düggeli , Oliver Frédéric Aebischer , Pascal Hayoz , Marta Fonrodona Turon
发明人： Zhimin Hao , Beat Schmidhalter , Jean-Luc Budry , Margherita Fontana , Mathieu Turbiez , Frank Bienewald , Mathias Düggeli , Oliver Frédéric Aebischer , Pascal Hayoz , Marta Fonrodona Turon
IPC分类号： C07D487/02
CPC分类号： H01L51/0071 , C07D487/04 , C09B57/004 , H01L51/0053 , H01L51/0058 , H01L51/0068 , H01L51/0095 , Y02E10/549
摘要： The present invention relates to compounds of the formula (I) wherein the substituents are as defined in claim 1, and their use as organic semiconductor in organic devices, like diodes, organic field effect transistors and/or a solar cells. The compounds of the formula I have excellent solubility in organic solvents. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when said compounds are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：本发明涉及式（I）化合物，其中取代基如权利要求1中所定义，及其作为有机半导体在有机器件中的用途，如二极管，有机场效应晶体管和/或太阳能电池。式I的化合物在有机溶剂中具有优异的溶解性。当所述化合物用于半导体器件或有机光伏（PV）器件（太阳能电池））时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性。

4. 发明申请

US20090101890A1 Azaperylenes as organic semiconductors 有权
标题翻译：亚萘基作为有机半导体
公开(公告)号：US20090101890A1
公开(公告)日：2009-04-23
申请号：US11919605
申请日：2006-05-03
申请人： Frank Bienewald , Beat Schmidhalter , Ulrich Berens , Hans Jurg Kirner
发明人： Frank Bienewald , Beat Schmidhalter , Ulrich Berens , Hans Jurg Kirner
IPC分类号： H01L51/00 , C07D471/04 , H01L51/40 , C07D409/14
CPC分类号： C09B5/028 , C07D471/06 , H01L51/0067 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0512 , H01L51/0541 , H01L51/5012 , Y10S428/93
摘要： A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I (I) wherein each of R1, R2, R3 and R4 independently is selected from H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, halogen, Si(RH)3, XR6; or one or more of R1 and R2, R2 and R3, R3 and R4, together with the carbon atoms they are bonding to, form a saturated or unsaturated, unsubstituted or substituted carbocyclic or heterocyclic ring; R5 is OR7, SR7, NR7R8, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, or unsubstituted or substituted aryl; R6 is Si(R11)3, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; R7 is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; X is O, S, NR8; Rδ is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, R11 being C1-C20-alkyl or -alkoxy.
摘要翻译：一种新颖的半导体器件包括式I（I）的氮杂伯有机半导体，其中R1，R2，R3和R4各自独立地选自H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，卤素，Si（RH）3，XR6; 或R 1和R 2，R 2和R 3，R 3和R 4中的一个或多个与它们键合的碳原子一起形成饱和或不饱和的未取代或取代的碳环或杂环; R5是OR7，SR7，NR7R8，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，或未取代或取代的芳基; R6是Si（R11）3，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; R 7为H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; X是O，S，NR8; Rdelta是H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，R11为C1-C20烷基或 - 烷氧基。

5. 发明申请

US20070172624A1 Optical recording materials writable using blue lasers 审中-公开
标题翻译：光学记录材料可使用蓝色激光器写入
公开(公告)号：US20070172624A1
公开(公告)日：2007-07-26
申请号：US10590021
申请日：2005-02-16
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
IPC分类号： B32B3/02
CPC分类号： G11B7/2492 , C09B47/045 , G11B7/2472 , G11B7/2475 , G11B7/2478 , G11B7/248 , G11B7/2534 , G11B7/259 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I) or a tautomeric or mesomeric form thereof, wherein G1 and G2 are each independently of the other C(R5) or N; M1 is a lanthanide or transition metal of groups 4 to 10; P is a phthalocyanino diradical; and R1 to R5 are substituents as defined in the description and the claims. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density.
摘要翻译：本发明涉及一种包括基底，记录层和任选的一个或多个反射层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或介导体形式，其中G 1， / SUB和G 2各自独立地为C（R 5 N）或N; M 1是第4至10族的镧系元素或过渡金属; P是酞菁双基; 和R 1至R 5是如说明书和权利要求书中所定义的取代基。记录和回放特别是在350至500nm的波长下进行，例如使用蓝色激光。录制和播放质量非常好，可以保持较高的存储密度。

6. 发明授权

US08471019B2 Quinoid systems as organic semiconductors 有权
标题翻译：醌类系统作为有机半导体
公开(公告)号：US08471019B2
公开(公告)日：2013-06-25
申请号：US12226182
申请日：2007-04-04
申请人： Ulrich Berens , Arno Stassen , Beat Schmidhalter , Wolfgang Kalb , Frank Bienewald
发明人： Ulrich Berens , Arno Stassen , Beat Schmidhalter , Wolfgang Kalb , Frank Bienewald
IPC分类号： H01L51/00 , C07D409/14 , C07D211/18 , C07D319/00 , C07D413/14
CPC分类号： H01L51/0074 , C07D493/04 , C07D493/22 , C07D495/04 , H01L51/0055 , H01L51/0073 , H01L51/0529 , H01L51/0533 , H01L51/0545 , Y02E10/549
摘要： A semiconducting layer comprising a non-polymeric quinoid heteroacene compound of the formula (I) wherein X stands for O, S or NR, each of R, R1, R2, R3, R4, R5, R6, R7, R8 being independently selected from hydrogen and an organic residue, or 2 or more thereof together forming one or more annealed rings, which may be substituted or unsubstituted, carbocyclic or helerocyclic, aromatic, quinoid or aliphatic, may be used e.g. for the manufacture of a diode, an organic field effect transistor, an organic thin film transistor, or a device containing a diode and/or an organic field effect transistor and/or organic thin film transistor.
摘要翻译：一种半导体层，其包含式（I）的非聚合醌型杂炔化合物，其中X代表O，S或NR，R，R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8中的每一个独立地选自氢和有机残基，或其中2个或更多个一起形成可以是取代或未取代的碳环或环丙基，芳族，醌型或脂族的一个或多个退火环，例如用于制造二极管，有机场效应晶体管，有机薄膜晶体管或包含二极管和/或有机场效应晶体管和/或有机薄膜晶体管的器件。

7. 发明授权

US08044058B2 Merocyanine derivatives 有权
标题翻译：梅花菁衍生物
公开(公告)号：US08044058B2
公开(公告)日：2011-10-25
申请号：US12715839
申请日：2010-03-02
申请人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
发明人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
IPC分类号： A61K31/517 , A61K31/445 , A61K31/16
CPC分类号： A61K8/498 , A61K8/4913 , A61K8/494 , A61Q17/04
摘要： Disclosed is the use of merocyanine derivatives of formula Q is hydrogen; C1-C22alkyl; —OH; —OR7; —NR7R8; or —N═R9; R1 is hydrogen; C1-C22alkyl; —OR7, —SR7; —NR7R8; C1-C22alkyl; C2-C12 alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl, C2-C11heteroaralkyl; C6-C10aryl; or C1-C9heteroaryl; R4 is cyano; COR7, COOR7; CONR7R8; SO2(C6-C12)aryl; C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl; C3-C5heterocycloalkyl; C6-C10aryl; or C1-C9heteroaryl; R5 is —COR7; —COOR7; —OR7; —SR7, —NHR7, —NR7R8; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12alkylphenyl; C1-C12alkoxy-C6-C10aryl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C3-C12cycloheteroalkyl; C6-C10aryl; C1-C12alkoxy-C6-C10aryl; or C1-C9heteroaryl; R6 is hydrogen; C1-C22alkyl; C1-C22alkoxy; or COR7; R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; —(CH2)tCOOH; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; C1-C9heteroaryl; Si—R10R11R12; Si(OR10)(OR11)(OR12); SiR10(OR11)(OR12); SiR10R11(OR12); —(CH2)u—O—(CH2)v—SiR10R11R12; or a radical X-Sil; t, u and v, independently from each other are a number from 1 to 5; R9 is a (C1-C6)alkylidene radical; R10, R11, R12 independently form each other are C1-C22alkyl; X is a linker; for protecting of human hair and skin against the damaging effect of UV radiation.
摘要翻译：披露式Q的部花青衍生物的用途是氢; C 1 -C 22烷基; -哦; -OR7; -NR7R8; 或-N = R9; R1是氢; C 1 -C 22烷基; -OR7，-SR7; -NR7R8; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; C7-C12芳烷基; C 1 -C 12杂烷基，C 2 -C 11杂芳烷基; C6-C10芳基; 或C 1 -C 9杂芳基; R4是氰基; COR7，COOR7; CONR7R8; SO2（C6-C12）芳基; C2-C12烷-1-烯基; C 3 -C 12环烯-1-烯基; C2-C12alk-1-inyl; C 2 -C 12杂烷基; C3-C5杂环烷基; C6-C10芳基; 或C 1 -C 9杂芳基; R5为-COR7; -COOR7; -OR7; -SR 7，-NHR 7，-NR 7 R 8; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; C7-C12芳烷基; C 1 -C 12烷基苯基; C 1 -C 12烷氧基-C 6 -C 10芳基; C 1 -C 12杂烷基; C 2 -C 11杂芳烷基; C 3 -C 12环杂烷基; C6-C10芳基; C 1 -C 12烷氧基-C 6 -C 10芳基; 或C 1 -C 9杂芳基; R6是氢; C 1 -C 22烷基; C1-C22烷氧基; 或COR7; R 7和R 8彼此独立地是氢; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; - （CH 2）t COOH; C7-C12芳烷基; C 1 -C 12杂烷基; C 2 -C 11杂芳烷基; C6-C10芳基; C1-C9杂芳基; Si-R10R11R12; Si（OR10）（OR11）（OR12）; SiR10（OR11）（OR12）; SiR10R11（OR12）; - （CH 2）u -O-（CH 2）v -SiR 10 R 11 R 12; 或基团X-Sil; t，u和v彼此独立地为1至5的数; R9是（C1-C6）亚烷基; R 10，R 11，R 12彼此独立地为C 1 -C 22烷基; X是一个连接子; 用于保护人的头发和皮肤免受紫外线辐射的破坏作用。

8. 发明申请

US20100297405A1 KETOPYRROLES AS ORGANIC SEMICONDUCTORS 有权
标题翻译：作为有机半导体的KETOPYRROLOL
公开(公告)号：US20100297405A1
公开(公告)日：2010-11-25
申请号：US12680920
申请日：2008-10-16
申请人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jurg Kirner , Mathieu G.R. Turbiez
发明人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jurg Kirner , Mathieu G.R. Turbiez
IPC分类号： C07D403/04 , C08F226/06 , B32B3/10
CPC分类号： H01L51/0036 , C08G61/123 , C08G61/124 , H01L51/0043 , H01L51/0545 , Y02E10/549 , Y10T428/24802
摘要： Monomeric or polymeric compounds comprising at least one moiety of the formula (Ia) wherein X is CR, where R is H or a substituent as defined in claim 1, or is another ketopyrrole moiety e.g. of the formula (1b) or (1c) with this moiety and all other symbols are as defined in claim 1, show good solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：包含至少一个式（Ia）部分的单体或聚合化合物，其中X是CR，其中R是H或如权利要求1所定义的取代基，或者是另一个酮基吡咯部分。的式（1b）或（1c）与所有其它符号如权利要求1中所定义，在有机溶剂中表现出良好的溶解性和优异的成膜性能。此外，当根据本发明的聚合物用于半导体器件或有机光伏（PV）器件时，可以观察到高的能量转换效率，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性太阳能电池）。

9. 发明申请

US20080130474A1 Optical Recording Materials Having High Stroage Density 审中-公开
标题翻译：具有高剧烈密度的光学记录材料
公开(公告)号：US20080130474A1
公开(公告)日：2008-06-05
申请号：US10561392
申请日：2004-06-25
申请人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
发明人： Beat Schmidhalter , John S. Zambounis , Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Jean-Luc Budry , Heinz Spahni
IPC分类号： G11B7/24 , B32B3/02
CPC分类号： G11B7/248 , C09B47/26
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I). For the detailed definitions of the further substituents, see the description. Recording and playback are effected especially at a wavelength of from 300 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density even at high speeds.
摘要翻译：本发明涉及一种光记录介质，其包括基底，记录层和任选的一个或多个反射层，其中记录层包含式（I）的化合物。关于进一步取代基的详细定义，参见说明书。特别是在300〜500nm的波长下进行记录和回放，例如使用蓝色激光。录音和播放质量极佳，即使在高速下也能保持较高的存储密度。

10. 发明授权

US07141697B2 Process for the preparation of phenethylamine derivatives 有权
标题翻译：苯乙胺衍生物的制备方法
公开(公告)号：US07141697B2
公开(公告)日：2006-11-28
申请号：US10130196
申请日：2001-12-12
申请人： Niranjan Paingankar , Vilas N. Mumbaikar , Vadiraj S. Ekkundi , Hans-Peter Jalett , Urs Siegrist , Paul Adriaan Van Der Schaaf , Frank Bienewald , Martin Studer , Stefan Burkhardt
发明人： Niranjan Paingankar , Vilas N. Mumbaikar , Vadiraj S. Ekkundi , Hans-Peter Jalett , Urs Siegrist , Paul Adriaan Van Der Schaaf , Frank Bienewald , Martin Studer , Stefan Burkhardt
IPC分类号： C07C211/00
CPC分类号： C07C213/02 , C07C217/74 , C07C2601/14
摘要： Disclosed is a process for the preparation of a compound of formula wherein R1 is hydrogen, hydroxyl, or unsubstituted or substituted alkyl or alkoxy, R2 is hydrogen or a substituent which can be converted to hydrogen, and n is 0, 1 or 2, comprising hydrogenating a compound of formula wherein R1, R2 and n are as defined above, in the presence of a nickel or cobalt catalyst.
摘要翻译：公开了一种制备下式化合物的方法，其中R 1是氢，羟基或未取代或取代的烷基或烷氧基，R 2是氢或取代基，可以转化为氢，并且n为0,1或2，包括将下式化合物其中R 1，R 2，N和n如上定义的氢化，存在镍或钴催化剂。

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