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    • 5. 发明授权
    • Multi-anode system for uniform plating of alloys
    • 用于均匀电镀合金的多阳极系统
    • US08551303B2
    • 2013-10-08
    • US13406679
    • 2012-02-28
    • Charles L. ArvinRaschid J. BezamaHarry D. CoxKrystyna W. Semkow
    • Charles L. ArvinRaschid J. BezamaHarry D. CoxKrystyna W. Semkow
    • C25B9/00C25B9/06
    • C25D17/008C25D17/007C25D17/12
    • Disclosed are embodiments of an electroplating system and an associated electroplating method that allow for depositing of metal alloys with a uniform plate thickness and with the means to alter dynamically the alloy composition. Specifically, by using multiple anodes, each with different types of soluble metals, the system and method avoid the need for periodic plating bath replacement and also allow the ratio of metals within the deposited alloy to be selectively varied by applying different voltages to the different metals. The system and method further avoids the uneven current density and potential distribution and, thus, the non-uniform plating thicknesses exhibited by prior art methods by selectively varying the shape and placement of the anodes within the plating bath. Additionally, the system and method allows for fine tuning of the plating thickness by using electrically insulating selectively placed prescribed baffles.
    • 公开了电镀系统和相关电镀方法的实施例,其允许沉积具有均匀板厚度的金属合金以及动态地改变合金组成的手段。 具体来说,通过使用具有不同类型的可溶性金属的多个阳极,该系统和方法避免了对周期性电镀浴更换的需要,还允许通过向不同的金属施加不同的电压来选择性地改变沉积合金中的金属比例 。 该系统和方法进一步避免了不均匀的电流密度和电势分布,并且因此通过选择性地改变阳极在电镀槽内的形状和位置,现有技术方法表现出不均匀的电镀厚度。 此外,该系统和方法允许通过使用电绝缘的选择性放置的规定的挡板来微调电镀厚度。
    • 8. 发明授权
    • Electroless plating of metallic features on nonmetallic or semiconductor
layer without extraneous plating
    • 在非金属或半导体层上进行金属化学镀无电镀
    • US5846598A
    • 1998-12-08
    • US815337
    • 1997-03-11
    • Krystyna W. SemkowEugene J. O'Sullivan
    • Krystyna W. SemkowEugene J. O'Sullivan
    • C23C18/16C23C18/36H01L21/288H01L21/48H01L21/768B05D5/12
    • H01L21/288C23C18/161C23C18/165C23C18/36H01L21/4846H01L21/76838
    • In the manufacture of a microelectronic component having metallic features on a polyimide layer, the metallic features being spaced from one another by gaps, at least some of which gaps have widths in a range from about one micron to about 500 microns, corrosion protection is provided by plating those features by electroless deposition of a nickel-phosphorus alloy forming a layer having a thickness in a range from about 200 .ANG. to about 3000 .ANG., at a rate of about 100 .ANG. per minute, in an aqueous plating bath comprising nickel sulfate hexahydrate in an amount of about 5.5 grams per liter, sodium hypophosphite in an amount of about six grams per liter, boric acid in an amount of about 30 grams per liter, sodium citrate in an amount of about 45 grams per liter, lead acetate in an amount of about one part per million by weight of lead, and a surfactant in an amount of about 0.1 grams per liter. The bath has a temperature of about 72.degree. C. and a pH of about 8.1. The gaps having widths of at least one micron remain essentially free of extraneous plating.
    • 在制造具有在聚酰亚胺层上具有金属特征的微电子部件时,金属特征通过间隙彼此间隔开,其中至少一些间隙的宽度在约1微米至约500微米的范围内,提供了腐蚀保护 通过在包含硫酸镍六水合物的水性电镀浴中以约100安格姆每分钟的速率无电沉积形成厚度在约200安培姆至约3000安培的层的镍 - 磷合金进行电镀这些特征 约5.5克/升的次磷酸钠,每升约6克的次磷酸钠,硼酸的量为约30克/升,柠檬酸钠的量为约45克/升,乙酸铅在一 量为铅重量百万分之一份左右,表面活性剂的量为约0.1克/升。 浴的温度为约72℃,pH为约8.1。 具有至少1微米宽度的间隙基本上不含外部电镀。
    • 9. 发明授权
    • Multi-anode system for uniform plating of alloys
    • 用于均匀电镀合金的多阳极系统
    • US08623194B2
    • 2014-01-07
    • US13604666
    • 2012-09-06
    • Charles L. ArvinRaschid J. BezamaHarry D. CoxKrystyna W. Semkow
    • Charles L. ArvinRaschid J. BezamaHarry D. CoxKrystyna W. Semkow
    • C25D3/56
    • C25D17/008C25D17/007C25D17/12
    • Disclosed are embodiments of an electroplating system and an associated electroplating method that allow for depositing of metal alloys with a uniform plate thickness and with the means to alter dynamically the alloy composition. Specifically, by using multiple anodes, each with different types of soluble metals, the system and method avoid the need for periodic plating bath replacement and also allow the ratio of metals within the deposited alloy to be selectively varied by applying different voltages to the different metals. The system and method further avoids the uneven current density and potential distribution and, thus, the non-uniform plating thicknesses exhibited by prior art methods by selectively varying the shape and placement of the anodes within the plating bath. Additionally, the system and method allows for fine tuning of the plating thickness by using electrically insulating selectively placed prescribed baffles.
    • 公开了电镀系统和相关电镀方法的实施例,其允许沉积具有均匀板厚度的金属合金以及动态地改变合金组成的手段。 具体来说,通过使用具有不同类型的可溶性金属的多个阳极,该系统和方法避免了对周期性电镀浴更换的需要,还允许通过向不同的金属施加不同的电压来选择性地改变沉积合金中的金属比例 。 该系统和方法进一步避免了不均匀的电流密度和电势分布,并且因此通过选择性地改变阳极在电镀槽内的形状和位置,现有技术方法表现出不均匀的电镀厚度。 此外,该系统和方法允许通过使用电绝缘的选择性放置的规定的挡板来微调电镀厚度。