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1. 发明授权

US4457774A Selectively herbicidal 4-amino-6-tert.-butyl-3-ethylthio-1,2,4-triazin-5(4H)-one 失效
标题翻译：选择性除草的4-氨基-6-叔丁基-3-乙硫基-1,2,4-三嗪-5（4H） - 酮
公开(公告)号：US4457774A
公开(公告)日：1984-07-03
申请号：US303658
申请日：1981-09-18
申请人： Ludwig Eue , Robert Schmidt , Karlfried Dickore
发明人： Ludwig Eue , Robert Schmidt , Karlfried Dickore
IPC分类号： A01N43/707 , A01N47/12 , A01N43/64
CPC分类号： A01N43/707 , A01N47/12
摘要： A selectively herbicidal composition of matter comprising a herbicidally effective amount of(i) 4-amino-6-tert.-butyl-3-ethylthio-1,2,4-triazin-5(4H)-one, and(ii) at least one ofS-2,3,3-trichloroallyl diisopropyl-thiolcarbamate,S-2,3-dichloroallyl diisopropyl-thiolcarbamate,1-amino-6-ethylthio-3-(2,2-dimethylpropyl)-1,3,5-triazine-2,4(1H,3H)-dione,1,2-dimethyl-3,5-diphenyl-pyrazolium methyl-sulphate,ethyl N-benzoyl-N-(3,4-dichlorophenyl)-2-amino-propionate,isopropyl N-benzoyl-N-(3-chloro-4-fluorophenyl)-2-amino-propionate,methyl N-benzoyl-N-(3-chloro-4-fluorophenyl)-2-amino-propionate,methyl 2-[4-(2,4-dichlorophenoxy)-phenoxy]-propionate, andmethyl 2-chloro-3-(4-chlorophenyl)-propionate.Ingredient (i) above as well as the compositions are especially suited for selectively killing monocotyledon and dicotyledon weeds in the cultivation of cereals and leguminous plants.
摘要翻译：一种选择性除草组合物，其包含除草有效量的（i）4-氨基-6-叔丁基-3-乙硫基-1,2,4-三嗪-5（4H） - 酮，和（ii）在 S-2,3,3-三氯烯丙基二异丙基硫代氨基甲酸酯，S-2,3-二氯烯丙基二异丙基硫代氨基甲酸酯，1-氨基-6-乙硫基-3-（2,2-二甲基丙基）-1,3,5 - 三嗪-2,4（1H，3H） - 离子，1,2-二甲基-3,5-二苯基 - 吡唑鎓甲基硫酸盐，N-苯甲酰基-N-（3,4-二氯苯基）-2-氨基丙酸酯，N-苯甲酰基-N-（3-氯-4-氟苯基）-2-氨基丙酸异丙酯，N-苯甲酰基-N-（3-氯-4-氟苯基）-2-氨基丙酸甲酯，甲基 2- [4-（2,4-二氯苯氧基） - 苯氧基]丙酸酯和2-氯-3-（4-氯苯基）丙酸甲酯。上述成分（i）以及组合物特别适用于在种植谷物和豆科植物中选择性杀死单子叶植物和双子叶植物杂草。

2. 发明授权

US4057417A 6-Sec.-butyl-1,2,4-triazin-5(4H)-one compounds and herbicidal compositions 失效
标题翻译： 6 - 仲丁基-1,2,4-三嗪-5（4H） - 酮化合物和除草组合物
公开(公告)号：US4057417A
公开(公告)日：1977-11-08
申请号：US562293
申请日：1975-03-26
申请人： Karlfried Dickore , Ludwig Eue , Robert Rudolf Schmidt
发明人： Karlfried Dickore , Ludwig Eue , Robert Rudolf Schmidt
IPC分类号： C07D253/06 , A01N43/707 , A01P13/00 , C07D253/075 , C07D405/12 , C07D409/12 , A01N9/22 , A01N9/00
CPC分类号： C07D253/075 , A01N43/707
摘要： New 6-sec.-butyl-1,2,4-triazin-5(4H)-one compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each hydrogen, orR.sup.1 and R.sup.2 together represent alkylidene or substituted alkylidene of the formula: ##STR2## wherein R.sup.3 is hydrogen, alkyl or cycloalkyl, and R.sup.4 is alkyl, alkenyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl, optionally substituted aryl or an optionally substituted heterocyclic radical, orR.sup.3 and R.sup.4 together with the carbon atom shown from a 5-membered to 7-membered ring, andY is sulfur, NH or NCH.sub.3 ;are outstandingly active herbicides.
摘要翻译：具有下式的新的6-仲丁基-1,2,4-三嗪-5（4H） - 酮化合物：其中R 1和R 2各自为氢，或者R 1和R 2一起代表亚烷基或取代的其中R 3为氢，烷基或环烷基，且R 4为烷基，烯基，环烷基，环烯基，芳烷基，芳烯基，任选取代的芳基或任选取代的杂环基，或R 3和R 4与碳原子显示为5元至7元环，Y为硫，NH或NCH 3; 是非常活跃的除草剂。

3. 发明授权

US4067724A N-(1,2,4-Triazin-5-on-4-yl)-glycines and herbicidal compositions 失效
标题翻译： N-（1,2,4-三嗪-5-基-4-基） - 甘氨酸和除草组合物
公开(公告)号：US4067724A
公开(公告)日：1978-01-10
申请号：US717715
申请日：1976-08-25
申请人： Wilfried Draber , Karlfried Dickore , Helmut Timmler , Ludwig Eue , Robert Rudolf Schmidt
发明人： Wilfried Draber , Karlfried Dickore , Helmut Timmler , Ludwig Eue , Robert Rudolf Schmidt
IPC分类号： C07D253/06 , A01N43/707 , C07D253/07 , C07D253/075 , A01N9/22
CPC分类号： C07D253/075 , A01N43/707 , C07D253/07
摘要： N-(1,2,4-Triazin-5-on-4-yl)-glycine compounds of the formula ##STR1## in which R.sup.1 is alkyl, alkoxy, alkylthio or alkylamino,R.sup.2 is alkyl, cycloalkyl, phenyl or substituted phenyl,R.sup.3 is hydrogen, alkyl, alkenyl or alkynyl andR.sup.4 is hydroxyl, alkoxy, alkythio, amino, alkylamino or dialkylamino,Possess outstanding selective herbicidal properties.
摘要翻译：其中R 1是烷基，烷氧基，烷硫基或烷基氨基，R 2是烷基，环烷基，苯基或取代的苯基的N-（1,2,4-三嗪-5-基） - 甘氨酸化合物 R3是氢，烷基，烯基或炔基，R4是羟基，烷氧基，链炔基，氨基，烷基氨基或二烷基氨基，具有优异的选择性除草性质。

4. 发明授权

US3978068A Azomethine compounds of 4-amino-5-H-1,2,4-triazin-5-ones and herbicidal compositions containing them 失效
标题翻译： 4-氨基-5-H-1,2,4-三嗪-5-酮的偶氮甲碱化合物和含有它们的除草组合物
公开(公告)号：US3978068A
公开(公告)日：1976-08-31
申请号：US382243
申请日：1973-07-24
申请人： Karlfried Dickore , Wilfried Draber , Helmut Timmler , Ludwig Eue , Robert R. Schmidt
发明人： Karlfried Dickore , Wilfried Draber , Helmut Timmler , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07D253/06 , A01N43/707 , A01N47/40 , A01P13/00 , C07D405/12 , C07D409/12 , C07D251/42
CPC分类号： A01N43/707
摘要： Azomethine compounds of 4-amino-5-H-1,2,4-triazin-5-ones of the formula ##SPC1##Wherein:R.sup.1 is alkyl, cycloalkyl or phenyl;R.sup.2 is hydrogen or alkyl;R.sup.3 is alkyl, alkoxy, cycloalkyl, cycloalkenyl, aralkyl, aryl or heteroaryl, or dialkylamino;R.sup.2 and R.sup.3 jointly can be an alkylene bridge, optionally interrupted by a hetero atom; andR.sup.4 is alkyl or optionally substituted phenyl,Are markedly effective herbicides, particularly selective herbicides for weeds growing in oats, wheat, cotton, maize, tomatoe, potatoe, soybean, and especially in beet cultivations.
摘要翻译： 4-氨基-5-H-1,2,4-三嗪-5-酮的亚甲基化合物，其结构式如下：

5. 发明授权

US4447258A 3-Dimethylamino-4-methyl-1,2,4-triazin-5(4H)-ones and herbicidal compositions 失效
标题翻译： 3-二甲基氨基-4-甲基-1,2,4-三嗪-5（4H） - 酮和除草组合物
公开(公告)号：US4447258A
公开(公告)日：1984-05-08
申请号：US120174
申请日：1980-02-11
申请人： Karlfried Dickore , Klaus Sasse , Ludwig Eue , Robert R. Schmidt
发明人： Karlfried Dickore , Klaus Sasse , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/707 , C07D253/075 , C07D277/20 , C07D277/36 , C07D253/06 , A01N43/64
CPC分类号： C07D253/075 , A01N43/707 , C07D277/20
摘要： 3-Dimethylamino-4-methyl-1,2,4-triazin-5(4H)-one compounds of the formula ##STR1## in which R.sup.1 is t-butyl, sec.-butyl or cyclohexyl;are effective herbicides.
摘要翻译：式（Ⅰ）的3-二甲基氨基-4-甲基-1,2,4-三嗪-5（4H） - 酮化合物，其中R 1是叔丁基，仲丁基或环己基; 是有效的除草剂。

6. 发明授权

US4564704A Production of 3,3-dimethyl-2-oxo-butyric acid salt 失效
标题翻译：制备3,3-二甲基-2-氧代 - 丁酸盐
公开(公告)号：US4564704A
公开(公告)日：1986-01-14
申请号：US227552
申请日：1981-01-22
申请人： Karlfried Dickore , Hans D. Engels , Hans Kratzer , Walter Merz
发明人： Karlfried Dickore , Hans D. Engels , Hans Kratzer , Walter Merz
IPC分类号： C07C45/63 , C07C51/00 , C07C59/185 , C07C51/285 , C07C51/373
CPC分类号： C07C59/185 , C07C45/63 , C07C51/00
摘要： Dichloropinacolone is produced by introducing into pinacolone twice the molar amount of chlorine, the exothermic reaction mass being cooled initially to maintain the temperature below about 50.degree. C. until about 60 to 80% of the chlorine has been introduced, and then heating the reaction mass to a temperature above 50.degree. C. during introducing of the remainder of the chlorine, thereby to produce dichloropinacolone, and terminating chlorine introduction when the dichloropinacolone content of the reaction mass is at least about 97%. The molten product is added to an aqueous solution of an alkali maintained at a temperature of at least about 50.degree. C., the alkali being present in more than three times the molar amount of the dichloropinacolone. To the resulting solution of a salt of 3,3-dimethyl-2-hydroxy-butyric acid, brought to a pH of about 9 to 12, there is added approximately the stoichiometric amount of potassium permanganate. Solid MnO.sub.2 precipitates out and is separated from the substantially pure dissolved salt of 3,3-dimethyl-2-oxo-butyric acid. The product is a known compound suited for further syntheses.
摘要翻译：通过将频倍他康酮引入两倍于氯的摩尔量来产生二氯可乐乐，最初冷却放热反应物质以保持温度低于约50℃，直到引入约60至80％的氯，然后加热反应物质在导入剩余的氯的过程中温度高于50℃，从而产生二氯靛那烯，并且当反应物质的二氯新戊酮酮含量为至少约97％时终止氯引入。将熔融产物加入到保持在至少约50℃温度的碱的水溶液中，碱的存在量是氯苯腈的摩尔量的三倍以上。向所得到的3,3-二甲基-2-羟基 - 丁酸的盐溶液中加入大约9-12的pH，加入大约化学计量的高锰酸钾。固体MnO 2析出并与3,3-二甲基-2-氧代 - 丁酸的基本上纯的溶解盐分离。该产物是适用于进一步合成的已知化合物。

7. 发明授权

US4426523A Preparation of 1-amino-1,3,5-triazine-2,4(1H, 3H)-diones 失效
标题翻译： 1-氨基-1,3,5-三嗪-2,4（1H，3H） - 二酮的制备
公开(公告)号：US4426523A
公开(公告)日：1984-01-17
申请号：US346341
申请日：1982-02-05
申请人： Karlfried Dickore , Engelbert Kuhle
发明人： Karlfried Dickore , Engelbert Kuhle
IPC分类号： A01N43/64 , C07C67/00 , C07C313/00 , C07C337/08 , C07D251/38
CPC分类号： C07D251/38
摘要： Herbicidal 1-amino-1,3,5-triazine-2,4(1H, 3H)-diones of the general formula ##STR1## are obtained in good yields if an N-substituted O-aryl N-chlorocarbonyl carbamate of the general formula ##STR2## is reacted with an isothiosemicarbazone of the general formula ##STR3## or hydrohalide thereof, (R.sup.1 to R.sup.4 in formulae (I) to (III) having the meanings given in the description), at a temperature between 0.degree. and 50.degree. C., in the presence of an acid-binding agent, the open-chain intermediate products formed thereby are then heated (if appropriate without intermediate isolation), in a second stage, to a temperature between 50.degree. and 150.degree. C. and, finally, in a third stage, the 1-alkylideneamino-1,3,5-triazine-2,4(1H, 3H)-dione formed thereby is hydrolyzed (if appropriate again without intermediate isolation) in an acid medium.
摘要翻译：如果N-取代的O-芳基N-氯羰基氨基甲酸酯，得到具有通式“IMAGE”（I）的除草剂1-氨基-1,3,5-三嗪-2,4（1H，3H） - 二酮（II）的异硫代缩氨基脲与其描述中给出的含义的式（I）至（III）中的R 1至R 4在式（III）的异硫代缩氨基脲或其氢卤化物反应：在0℃和50℃之间的温度下，在酸结合剂的存在下，由此形成的开链中间产物然后在第二阶段加热（如果合适而不中间分离），温度在50℃至150℃之间，最后在第三阶段中由此形成的1-亚烷基氨基-1,3,5-三嗪-2,4（1H，3H） - 二酮水解分离）在酸性介质中。

8. 发明授权

US4348331A Process for the preparation of N-substituted imido-dicarboxylic acid diaryl esters 失效
标题翻译：制备N-取代的亚氨基二羧酸二芳基酯的方法
公开(公告)号：US4348331A
公开(公告)日：1982-09-07
申请号：US233249
申请日：1981-02-10
申请人： Karlfried Dickore , Engelbert Kuhle
发明人： Karlfried Dickore , Engelbert Kuhle
IPC分类号： A01N43/64 , C07C271/66 , C07D251/38 , C07D307/52 , C07D309/04 , C07C125/073 , C07C125/075
CPC分类号： A01N43/64 , C07C271/66 , C07D251/38 , C07D307/52 , C07D309/04
摘要： This invention relates to a process for the preparation of N-substituted imido-dicarboxylic acid diaryl ester compound of the formulaR.sup.1 --N(CO--OR.sup.2).sub.2 (I)whereinR.sup.1 is an optionally substituted aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical, andR.sup.2 is an optionally substituted aryl radical,which can be used as intermediates for the production of known herbicides, which process comprises reacting an amine salt of the formulaR.sup.1 --NH.sub.2.HX.sup.1 (II)wherein X.sup.1 is a halogen, with a carbonic acid aryl ester halide of the formulaR.sup.2 --O--CO--X.sup.2 (III)wherein X.sup.2 is halogen, at a temperature from 100.degree. C. to 300.degree. C.
摘要翻译：本发明涉及制备式R 1 -N（CO-OR 2）2（I）的N-取代的亚氨基二羧酸二芳基酯化合物的方法，其中R 1是任选取代的脂族，脂环族，芳脂族，芳族或杂环并且R 2是任选取代的芳基，其可以用作制备已知除草剂的中间体，该方法包括使其中X 1为卤素的式R 1 -NH 2 H 2（II）的胺盐与在其中X 2是卤素的式R 2 -O-CO-X 2（III）的碳酸芳酯卤化物，在100℃至300℃的温度下进行。

9. 发明授权

US4524205A Process for the preparation of 1-amino-1,3,5-triazine-2,4(1H,3H)-diones 失效
标题翻译： 1-氨基-1,3,5-三嗪-2,4（1H，3H） - 二酮的制备方法
公开(公告)号：US4524205A
公开(公告)日：1985-06-18
申请号：US544334
申请日：1983-10-21
申请人： Gerhard Bonse , Reinhard Lantzsch , Henning Dorr , Wolfgang Kreiss , Karlfried Dickore , Klaus Ditgens , Eckart Kranz
发明人： Gerhard Bonse , Reinhard Lantzsch , Henning Dorr , Wolfgang Kreiss , Karlfried Dickore , Klaus Ditgens , Eckart Kranz
IPC分类号： A01N43/64 , C07D213/20 , C07D251/38 , C07D251/26
CPC分类号： C07D213/20 , A01N43/64 , C07D251/38
摘要： A process for the preparation of a herbicidally active 1-amino-1,3,5-triazone-2,4 (1H,3H)-dione of the formula ##STR1## comprising in a first stage at a temperature from about 0.degree. to 100.degree. C. reacting an isocyanate of the formulaR.sup.1 - NCO (II)with an isothio semicarbazone of the tautomeric formulas ##STR2## in which R.sup.3 and R.sup.4 each independently is hydrogen, alkyl, cycloalkyl, aralkyl o alkyl, cycloalkyl, aralkyl or aryl,thereby to form a urea derivative of the tautomeric formulas ##STR3## in a second stage at a temperature between about -50.degree. and 0.degree. C. reacting the urea derivative with phosgene (COCl.sub.2) in the presence of an auxiliary organic base and in the presence of a diluent, at least about 2 mols of phosgene and at least about 2 mols of the auxiliary base being used per mol of urea derivative, thereby to form a 1-alkylideneamino-1,3,5-triazine-2,4(1H,3H)-dione of the formula V ##STR4## and in a third stage converting the 1-alkylideneamino group to a 1-amino group.
摘要翻译：制备式（I）的除草活性1-氨基-1,3,5-三嗪-2,4（1H，3H） - 二酮的方法，其包含在第一阶段中在约使式R 1 -NCO（II）的异氰酸酯与互变异构结构式（III）的异噻唑烷酮反应，其中R 3和R 4各自独立地为氢，烷基，环烷基，芳烷基烷基，环烷基，芳烷基或芳基，从而在约-50℃至0℃的温度下在第二阶段中形成互变异构体式（IV）的脲衍生物。将脲衍生物与光气（COCl 2）在辅助有机碱的存在和在稀释剂存在下，每摩尔脲衍生物使用至少约2摩尔的光气和至少约2摩尔的辅助碱，从而形成1-亚烷基氨基-1，（V）的3,5-三嗪-2,4（1H，3H） - 二酮，在第一阶段将1-亚烷基氨基转化为1-氨基没有组。

10. 发明授权

US4451406A N-Substituted imido-dicarboxylic acid diaryl ester method of preparation 失效
标题翻译： N-取代的亚氨基二羧酸二芳基酯的制备方法
公开(公告)号：US4451406A
公开(公告)日：1984-05-29
申请号：US520704
申请日：1983-08-05
申请人： Karlfried Dickore , Engelbert Kuhle
发明人： Karlfried Dickore , Engelbert Kuhle
IPC分类号： C07C67/00 , C07C239/00 , C07C269/06 , C07C271/08 , C07C271/66 , C07C313/00 , C07C323/43 , C07D251/38 , C07C125/067
CPC分类号： C07D251/38
摘要： Novel N-substituted imido-dicarboxylic acid diaryl ester compounds of the general formula ##STR1## in which R.sup.1 represents an optionally substituted aliphatic, cycloaliphatic, araliphatic, aromatic, heterocyclic radical andR.sup.2 and R.sup.3 can be identical or different and represent an optionally substituted aryl radical,and a process for their preparation characterized in that a carbamic acid aryl ester of the general formula:R.sup.1 --NH--CO--OR.sup.2 (II)in which R.sup.1 and R.sup.2 have the abovementioned meanings, is reacted with a carbonic acid aryl ester halide of the general formulaX--CO--OR.sup.3 (III)in whichR.sup.3 has the abovementioned meaning andX represents a halogen atom, optionally in the presence of a diluent, optionally at a temperature between 100.degree. and 300.degree. C.The new compounds (I) can be used as intermediate products for the preparation of known herbicidal active compounds from the 1,3,5-triazine,2,4-(1H,3H)-dione series.
摘要翻译：通式（I）的新型N-取代的亚氨基二羧酸二芳基酯化合物，其中R 1表示任选取代的脂族，脂环族，芳脂族，芳族，杂环基团，R 2和R 3可以相同或不同，表示任选取代的芳基，以及其制备方法，其特征在于将具有上述含义的R 1和R 2的通式为R 1 -NH-CO-OR 2（II）的氨基甲酸芳基酯与碳酸任选在稀释剂存在下，任选地在100℃和300℃之间的温度下，通式X-CO-OR 3（III）的芳基酯卤化物，其中R 3具有上述含义并且X代表卤素原子。新化合物（I）可用作从1,3,5-三嗪，2,4-（1H，3H） - 二酮系列制备已知除草活性化合物的中间产物。

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