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1. 发明授权

US4067724A N-(1,2,4-Triazin-5-on-4-yl)-glycines and herbicidal compositions 失效
标题翻译： N-（1,2,4-三嗪-5-基-4-基） - 甘氨酸和除草组合物
公开(公告)号：US4067724A
公开(公告)日：1978-01-10
申请号：US717715
申请日：1976-08-25
申请人： Wilfried Draber , Karlfried Dickore , Helmut Timmler , Ludwig Eue , Robert Rudolf Schmidt
发明人： Wilfried Draber , Karlfried Dickore , Helmut Timmler , Ludwig Eue , Robert Rudolf Schmidt
IPC分类号： C07D253/06 , A01N43/707 , C07D253/07 , C07D253/075 , A01N9/22
CPC分类号： C07D253/075 , A01N43/707 , C07D253/07
摘要： N-(1,2,4-Triazin-5-on-4-yl)-glycine compounds of the formula ##STR1## in which R.sup.1 is alkyl, alkoxy, alkylthio or alkylamino,R.sup.2 is alkyl, cycloalkyl, phenyl or substituted phenyl,R.sup.3 is hydrogen, alkyl, alkenyl or alkynyl andR.sup.4 is hydroxyl, alkoxy, alkythio, amino, alkylamino or dialkylamino,Possess outstanding selective herbicidal properties.
摘要翻译：其中R 1是烷基，烷氧基，烷硫基或烷基氨基，R 2是烷基，环烷基，苯基或取代的苯基的N-（1,2,4-三嗪-5-基） - 甘氨酸化合物 R3是氢，烷基，烯基或炔基，R4是羟基，烷氧基，链炔基，氨基，烷基氨基或二烷基氨基，具有优异的选择性除草性质。

2. 发明授权

US3978068A Azomethine compounds of 4-amino-5-H-1,2,4-triazin-5-ones and herbicidal compositions containing them 失效
标题翻译： 4-氨基-5-H-1,2,4-三嗪-5-酮的偶氮甲碱化合物和含有它们的除草组合物
公开(公告)号：US3978068A
公开(公告)日：1976-08-31
申请号：US382243
申请日：1973-07-24
申请人： Karlfried Dickore , Wilfried Draber , Helmut Timmler , Ludwig Eue , Robert R. Schmidt
发明人： Karlfried Dickore , Wilfried Draber , Helmut Timmler , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07D253/06 , A01N43/707 , A01N47/40 , A01P13/00 , C07D405/12 , C07D409/12 , C07D251/42
CPC分类号： A01N43/707
摘要： Azomethine compounds of 4-amino-5-H-1,2,4-triazin-5-ones of the formula ##SPC1##Wherein:R.sup.1 is alkyl, cycloalkyl or phenyl;R.sup.2 is hydrogen or alkyl;R.sup.3 is alkyl, alkoxy, cycloalkyl, cycloalkenyl, aralkyl, aryl or heteroaryl, or dialkylamino;R.sup.2 and R.sup.3 jointly can be an alkylene bridge, optionally interrupted by a hetero atom; andR.sup.4 is alkyl or optionally substituted phenyl,Are markedly effective herbicides, particularly selective herbicides for weeds growing in oats, wheat, cotton, maize, tomatoe, potatoe, soybean, and especially in beet cultivations.
摘要翻译： 4-氨基-5-H-1,2,4-三嗪-5-酮的亚甲基化合物，其结构式如下：

3. 发明授权

US4057417A 6-Sec.-butyl-1,2,4-triazin-5(4H)-one compounds and herbicidal compositions 失效
标题翻译： 6 - 仲丁基-1,2,4-三嗪-5（4H） - 酮化合物和除草组合物
公开(公告)号：US4057417A
公开(公告)日：1977-11-08
申请号：US562293
申请日：1975-03-26
申请人： Karlfried Dickore , Ludwig Eue , Robert Rudolf Schmidt
发明人： Karlfried Dickore , Ludwig Eue , Robert Rudolf Schmidt
IPC分类号： C07D253/06 , A01N43/707 , A01P13/00 , C07D253/075 , C07D405/12 , C07D409/12 , A01N9/22 , A01N9/00
CPC分类号： C07D253/075 , A01N43/707
摘要： New 6-sec.-butyl-1,2,4-triazin-5(4H)-one compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each hydrogen, orR.sup.1 and R.sup.2 together represent alkylidene or substituted alkylidene of the formula: ##STR2## wherein R.sup.3 is hydrogen, alkyl or cycloalkyl, and R.sup.4 is alkyl, alkenyl, cycloalkyl, cycloalkenyl, aralkyl, aralkenyl, optionally substituted aryl or an optionally substituted heterocyclic radical, orR.sup.3 and R.sup.4 together with the carbon atom shown from a 5-membered to 7-membered ring, andY is sulfur, NH or NCH.sub.3 ;are outstandingly active herbicides.
摘要翻译：具有下式的新的6-仲丁基-1,2,4-三嗪-5（4H） - 酮化合物：其中R 1和R 2各自为氢，或者R 1和R 2一起代表亚烷基或取代的其中R 3为氢，烷基或环烷基，且R 4为烷基，烯基，环烷基，环烯基，芳烷基，芳烯基，任选取代的芳基或任选取代的杂环基，或R 3和R 4与碳原子显示为5元至7元环，Y为硫，NH或NCH 3; 是非常活跃的除草剂。

4. 发明授权

US3940391A 3,4-Dihydro-1,2,4-triazine compounds 失效
标题翻译： 3,4-二氢-1,2,4-三嗪化合物
公开(公告)号：US3940391A
公开(公告)日：1976-02-24
申请号：US502249
申请日：1974-08-29
申请人： Wilfried Draber , Helmut Timmler , Ludwig Eue , Robert R. Schmidt
发明人： Wilfried Draber , Helmut Timmler , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07D253/06 , A01N43/707 , C07D253/07 , C07D405/12
CPC分类号： A01N43/707 , C07D253/07
摘要： Novel 3,4-dihydro-1,2,4-triazine compounds of the formula ##SPC1##In whichR.sup.1 is alkyl or cycloalkyl;R.sup.2 is methyl, amino, alkylideneamino, methylamino, .beta.-hydroxyethylamino, 2-furylmethylamino, aralkylamino or substituted aralkylamino; and R.sup.3 is alkyl, aryl or substituted aryl;Are prepared by reacting the corresponding 1,2,4-triazin-5-one with sodium borohydride in the presence of a polar solvent at a temperature between -10.degree. and +25.degree.C. The novel compounds are outstandingly effective as herbicides and display particularly selective action.
摘要翻译：式III的新型3,4-二氢-1,2,4-三嗪化合物，其中R1是烷基或环烷基; R2是甲基，氨基，亚烷基氨基，甲基氨基，β-羟乙基氨基，2-呋喃甲基氨基，芳烷基氨基或取代的芳烷基氨基; 并且R 3是烷基，芳基或取代的芳基; 在-10℃和+ 25℃之间的温度下，在极性溶剂存在下，用硼酸钠反应相应的1,2,4-三唑-5-酮。这种新型化合物作为除草剂和显示效果显着特别是选择性行动。

5. 发明授权

US4127404A 4-Amino-1,2,4-triazin-5-one compounds and herbicidal compositions 失效
标题翻译： 4-氨基-1,2,4-三嗪-5-酮化合物和除草组合物
公开(公告)号：US4127404A
公开(公告)日：1978-11-28
申请号：US837340
申请日：1977-09-28
申请人： Helmut Timmler , Wilfried Draber , Ludwig Eue
发明人： Helmut Timmler , Wilfried Draber , Ludwig Eue
IPC分类号： A01N43/707 , C07D333/00 , C07D333/24 , C07D403/04 , C07D405/04 , C07D409/04 , C07D253/06 , A01N9/12 , A01N9/22
CPC分类号： A01N43/707 , C07D333/24
摘要： New heterocyclically-substituted 4-amino-1,2,4-triazin-5-one compounds, herbicidal compositions containing them and their use as herbicides are disclosed.It is known that 1,2,4-triazionones, such as, for example, 4-amino-3-methyl-6-phenyl-1,2,4-triazine-5-one, can be used for combatting weeds, especially for selectively combatting weeds, from German Offenlegungsschrift (German Published Specification) 2,224,161. Their general herbicidal action is, however, not always entirely statisfactory, especially when low amounts and low concentrations are used.
摘要翻译：公开了新的杂环取代的4-氨基-1,2,4-三嗪-5-酮化合物，含有它们的除草组合物及其作为除草剂的用途。

6. 发明授权

US4457774A Selectively herbicidal 4-amino-6-tert.-butyl-3-ethylthio-1,2,4-triazin-5(4H)-one 失效
标题翻译：选择性除草的4-氨基-6-叔丁基-3-乙硫基-1,2,4-三嗪-5（4H） - 酮
公开(公告)号：US4457774A
公开(公告)日：1984-07-03
申请号：US303658
申请日：1981-09-18
申请人： Ludwig Eue , Robert Schmidt , Karlfried Dickore
发明人： Ludwig Eue , Robert Schmidt , Karlfried Dickore
IPC分类号： A01N43/707 , A01N47/12 , A01N43/64
CPC分类号： A01N43/707 , A01N47/12
摘要： A selectively herbicidal composition of matter comprising a herbicidally effective amount of(i) 4-amino-6-tert.-butyl-3-ethylthio-1,2,4-triazin-5(4H)-one, and(ii) at least one ofS-2,3,3-trichloroallyl diisopropyl-thiolcarbamate,S-2,3-dichloroallyl diisopropyl-thiolcarbamate,1-amino-6-ethylthio-3-(2,2-dimethylpropyl)-1,3,5-triazine-2,4(1H,3H)-dione,1,2-dimethyl-3,5-diphenyl-pyrazolium methyl-sulphate,ethyl N-benzoyl-N-(3,4-dichlorophenyl)-2-amino-propionate,isopropyl N-benzoyl-N-(3-chloro-4-fluorophenyl)-2-amino-propionate,methyl N-benzoyl-N-(3-chloro-4-fluorophenyl)-2-amino-propionate,methyl 2-[4-(2,4-dichlorophenoxy)-phenoxy]-propionate, andmethyl 2-chloro-3-(4-chlorophenyl)-propionate.Ingredient (i) above as well as the compositions are especially suited for selectively killing monocotyledon and dicotyledon weeds in the cultivation of cereals and leguminous plants.
摘要翻译：一种选择性除草组合物，其包含除草有效量的（i）4-氨基-6-叔丁基-3-乙硫基-1,2,4-三嗪-5（4H） - 酮，和（ii）在 S-2,3,3-三氯烯丙基二异丙基硫代氨基甲酸酯，S-2,3-二氯烯丙基二异丙基硫代氨基甲酸酯，1-氨基-6-乙硫基-3-（2,2-二甲基丙基）-1,3,5 - 三嗪-2,4（1H，3H） - 离子，1,2-二甲基-3,5-二苯基 - 吡唑鎓甲基硫酸盐，N-苯甲酰基-N-（3,4-二氯苯基）-2-氨基丙酸酯，N-苯甲酰基-N-（3-氯-4-氟苯基）-2-氨基丙酸异丙酯，N-苯甲酰基-N-（3-氯-4-氟苯基）-2-氨基丙酸甲酯，甲基 2- [4-（2,4-二氯苯氧基） - 苯氧基]丙酸酯和2-氯-3-（4-氯苯基）丙酸甲酯。上述成分（i）以及组合物特别适用于在种植谷物和豆科植物中选择性杀死单子叶植物和双子叶植物杂草。

7. 发明授权

US4447258A 3-Dimethylamino-4-methyl-1,2,4-triazin-5(4H)-ones and herbicidal compositions 失效
标题翻译： 3-二甲基氨基-4-甲基-1,2,4-三嗪-5（4H） - 酮和除草组合物
公开(公告)号：US4447258A
公开(公告)日：1984-05-08
申请号：US120174
申请日：1980-02-11
申请人： Karlfried Dickore , Klaus Sasse , Ludwig Eue , Robert R. Schmidt
发明人： Karlfried Dickore , Klaus Sasse , Ludwig Eue , Robert R. Schmidt
IPC分类号： A01N43/707 , C07D253/075 , C07D277/20 , C07D277/36 , C07D253/06 , A01N43/64
CPC分类号： C07D253/075 , A01N43/707 , C07D277/20
摘要： 3-Dimethylamino-4-methyl-1,2,4-triazin-5(4H)-one compounds of the formula ##STR1## in which R.sup.1 is t-butyl, sec.-butyl or cyclohexyl;are effective herbicides.
摘要翻译：式（Ⅰ）的3-二甲基氨基-4-甲基-1,2,4-三嗪-5（4H） - 酮化合物，其中R 1是叔丁基，仲丁基或环己基; 是有效的除草剂。

8. 发明授权

US3941800A N-benzyltriazole compounds 失效
标题翻译： N-苄基三唑化合物
公开(公告)号：US3941800A
公开(公告)日：1976-03-02
申请号：US405969
申请日：1973-10-12
申请人： Wilfried Draber , Erik Regel , Karl-Heinz Buchel , Ludwig Eue , Robert R. Schmidt
发明人： Wilfried Draber , Erik Regel , Karl-Heinz Buchel , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07D249/08 , C07D261/08 , C07D521/00
CPC分类号： C07D233/56 , C07D231/12 , C07D249/08 , C07D261/08
摘要： Novel N-benzyltriazoles of the formula ##SPC1##In whichTriazolyl is 1,2,4 or 1,2,3 triazolyl which may be substituted;X is halogen, trifluoromethyl, lower alkyl, lower alkoxy, lower alkylthio, aryl, nitro, cyano or (alkylated) amino;m is 0, 1 or 2;A is optionally substituted phenyl, pyridyl, alkyl or cycloalkyl; andB is a 5-membered heterocyclic ring, e.g., N-heterocycle;And their salts are outstandingly effective in regulating plant growth, e.g., inhibiting, stimulating or altering plant growth.

9. 发明授权

US4565566A Imidazo-pyrrolo-pyridine derivatives useful as herbicidal agents 失效
标题翻译：用作除草剂的咪唑并吡咯并吡啶衍生物
公开(公告)号：US4565566A
公开(公告)日：1986-01-21
申请号：US752214
申请日：1985-07-03
申请人： Wilfried Draber , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
发明人： Wilfried Draber , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/90 , A01N55/00 , C07D471/14 , C07F7/10 , A01N43/48 , C07D487/00 , C07F7/02
CPC分类号： C07D471/14 , A01N43/90 , A01N55/00 , C07F7/10
摘要： Novel herbicides of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is alkyl,X is cyano, alkoxycarbonyl or aminocarbonyl, andY is hydrogen or, if X is cyano, may also be trimethylsilyl,can be prepared by reacting an imidazo-pyrrolo-pyridine of the formula ##STR2## with trimethylsilyl cyanide of the formula(CH.sub.3).sub.3 Si--CN.
摘要翻译：式中，R 1和R 2各自独立地为烷基，X为氰基，烷氧基羰基或氨基羰基，Y为氢或X为氰基的新颖除草剂为三甲基甲硅烷基，可以通过使咪唑并 - 吡咯并吡唑与式（CH3）3Si-CN的三甲基甲硅烷基氰化合物。

10. 发明授权

US4282388A Cyclic 1,2-diol benzyl ether compounds 失效
标题翻译：环状1,2-二醇苄基醚化合物
公开(公告)号：US4282388A
公开(公告)日：1981-08-04
申请号：US964415
申请日：1978-11-28
申请人： Wilfried Draber , Wolf Reiser , Thomas Schmidt , Ludwig Eue , Robert R. Schmidt
发明人： Wilfried Draber , Wolf Reiser , Thomas Schmidt , Ludwig Eue , Robert R. Schmidt
IPC分类号： C07C43/18 , A01N31/04 , A01N31/06 , C07C29/12 , C07C29/40 , C07C29/48 , C07C41/00 , C07C43/188 , C07C43/192 , C07C43/196 , C07C43/21 , C07C43/225 , C07C43/267 , C07C45/58 , C07C67/00 , C07C313/00 , C07C319/20 , C07C323/19
CPC分类号： C07C29/48 , A01N31/06 , C07C29/12 , C07C29/40 , C07C43/188 , C07C43/192 , C07C43/196 , C07C43/21 , C07C43/225 , C07C43/267 , C07C45/58 , C07C2101/04 , C07C2101/08 , C07C2101/14
摘要： Novel benzyl ethers of cyclic 1,1-diols, of the formula ##STR1## wherein R.sup.1 is phenyl or substituted phenyl,R.sup.2 is hydrogen, alkyl, alkenyl, alkynyl, haloalkyl or --CHX--R.sup.1,X is hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, phenyl or substituted phenyl,Y and Y' are individually selected from hydrogen, alkyl, phenyl and substituted phenyl andA is saturated or unsaturated alkylene or substituted alkylene;have been found outstandingly effective as herbicides, particularly as selective herbicides.
摘要翻译：其中R1是苯基或取代的苯基，R2是氢，烷基，烯基，炔基，卤代烷基或-CHX-R1的环状1,1-二醇的新型苄基醚，X是氢，烷基，链烯基，炔基，卤代烷基，苯基或取代的苯基，Y和Y'分别选自氢，烷基，苯基和取代的苯基，A是饱和或不饱和的亚烷基或取代的亚烷基; 已经被发现作为除草剂非常有效，特别是作为选择性除草剂。

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