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    • 1. 发明授权
    • Nanoporous material fabricated using polymeric template strands
    • 使用聚合物模板链制造的纳米多孔材料
    • US6156812A
    • 2000-12-05
    • US544723
    • 2000-04-06
    • Kreisler LauTian-An ChenBoris Korolev
    • Kreisler LauTian-An ChenBoris Korolev
    • C08J9/26C08J9/02
    • C08J9/26C08J2201/046
    • Compositions and methods are provided in which nanoporous polymeric materials are produced via stable, polymeric template strands having reactive groups that can be used for forming crosslinking functionalities and/or adding thermolabile groups, wherein at least some of the thermolabile groups are thermolyzed to produce voids. The template strands preferably comprise aromatic systems and vicinal keto groups, such as a polybenzil formed from fluorene bisphenol or 3,3'-dihydroxytolane with 4,4'-difluorobenzil. At least some of the reactive groups preferably react using an addition-elimination reaction. Especially preferred thermolabile groups comprise poly(propylene oxide), and especially preferred crosslinkers comprise ethynyl-moiety and tetracyclone moieties.
    • 提供了组合物和方法,其中纳米多孔聚合物材料通过具有可用于形成交联官能团和/或添加不耐热基团的反应性基团的稳定的聚合物模板链产生,其中至少一些不耐热基团被热分解以产生空隙。 模板链优选包含芳族体系和连位酮基,例如由芴双酚或3,3'-二羟基乙内酯与4,4'-二氟苯甲醛形成的聚苯乙烯。 至少一些反应性基团优选使用加成 - 消除反应进行反应。 特别优选的热不稳定基团包括聚(环氧丙烷),并且特别优选的交联剂包括乙炔基部分和四环酮部分。
    • 2. 发明授权
    • Nanoporous polymers comprising macrocycles
    • 包含大环的纳米多孔聚合物
    • US06380347B1
    • 2002-04-30
    • US09544504
    • 2000-04-06
    • Kreisler LauTian-An ChenBoris Korolev
    • Kreisler LauTian-An ChenBoris Korolev
    • C08G6538
    • C08G65/4081C08G2650/64H05K1/0326
    • Compositions and methods are provided in which an electrical device is fabricated by incorporating macrocycles in a polymer on a substrate portion of the device, and crosslinking the polymer to form a crosslinked polymer. It is preferred that at least some of the macrocycles are relatively large, including at least six rings in the backbone of a macrocycle. It is also preferred that rings used in forming the macrocycles may be relatively large, preferably having at least six members as in phenyl rings. The intermacrocyclic links can be relatively complex, such as where four macrocycles may be coupled to a single atom or a single phenyl group. In yet other aspects, macrocycles can be heavily conjugated, with more preferred macrocycles having a completely conjugated backbone. In yet other aspects the macrocycles can have backbones with ether, carboxyl, and ethynyl groups, some of which can be used in crosslinking without reliance on an extrinsic crosslinker. In still another aspect, the macrocycles can be fabricated from a bisphenol and a difluoroaromatic compound.
    • 提供了组合物和方法,其中通过在装置的基材部分上的聚合物中引入大环来制造电气装置,并交联聚合物以形成交联聚合物。 优选至少一些大环化合物相对较大,包括在大环的主链中的至少六个环。 还优选用于形成大环的环可以相对较大,优选在苯环中具有至少六个成员。 杂环连接可以是相对复杂的,例如四个大环可以连接到单个原子或单个苯基上。 在另一方面,大环可以重共轭,更优选的大环化合物具有完全共轭的主链。 在其它方面,大环可以具有醚,羧基和乙炔基的主链,其中一些可以用于交联而不依赖于外在交联剂。 另一方面,大环可以由双酚和二氟芳族化合物制备。
    • 4. 发明授权
    • Nanoporous polymers crosslinked via cyclic structures
    • 通过环状结构交联的纳米多孔聚合物
    • US06172128B2
    • 2001-01-09
    • US09544722
    • 2000-04-06
    • Kreisler LauTian-An ChenRoger Leung
    • Kreisler LauTian-An ChenRoger Leung
    • C08J902
    • C08J3/246C08J9/26C08J2201/046
    • Nanoporous polymeric materials are fabricated in which polymeric strands are crosslinked via ring structures. Preferred ring structures are formed de novo during crosslinking, and at least some of the ring structures are preferably included in the backbones of the strands. At least one of the ring structures may advantageously comprise an aromatic structure, and may more advantageously comprise a benzyl moiety. Especially preferred polymers comprise a poly(arylene ether) synthesized from a difluoroaromatic portion and an aromatic bisphenolic portion. In another preferred aspect, the difluoroaromatic portions of the poly(arylene ether) carry at least two different crosslinking functionalities. In an even more preferred aspect, the crosslinking functionalities comprise an ethynyl and a tetracyclone. Nanoporosity is preferably introduced by thermolyzing one or more thermolabile portions in the crosslinked polymer. An especially preferred thermolabile portion comprises ethylene glycol-poly(caprolactone).
    • 制造纳米多孔聚合材料,其中聚合物链通过环结构交联。 优选的环结构在交联期间从头形成,并且至少一些环结构优选包含在该链的主链中。 至少一个环结构可以有利地包含芳族结构,并且可以更有利地包含苄基部分。 特别优选的聚合物包括由二氟芳族部分和芳族双酚部分合成的聚(亚芳基醚)。 在另一个优选的方面,聚(亚芳基醚)的二氟芳香族部分携带至少两种不同的交联官能团。 在更优选的方面,交联官能团包括乙炔基和四环。 优选通过热交换聚合物中的一个或多个热不稳定部分来引入纳米孔。 特别优选的耐热不稳定部分包括乙二醇 - 聚(己内酯)。
    • 5. 发明授权
    • Polymers having backbones with reactive groups employed in crosslinking as precursors to nanoporous thin film structures
    • 具有反应性基团的骨架的聚合物用作交联作为纳米多孔薄膜结构的前体
    • US06313185B1
    • 2001-11-06
    • US09538276
    • 1998-09-24
    • Kreisler LauTian-An ChenRoger Leung
    • Kreisler LauTian-An ChenRoger Leung
    • C08J902
    • C08J9/26C08J2201/046H05K1/0313
    • Nanoporous materials are fabricated from polymers having backbones with reactive groups used in crosslinking. In one aspect of preferred methods and compositions, the reactive groups in the backbone comprise a diene and a dienophile. The diene may advantageously comprise a tetracyclone, and the dienophile may advantageously comprise an ethynyl. In another aspect of preferred methods and compositions, the reactive groups in the backbone are included in a conjugated system. Especially preferred polymeric strands comprise a poly(arylene ether) synthesized from a difluoroaromatic portion and an aromatic bisphenolic portion. It is still more preferred that the difluoroaromatic portions of the poly(arylene ether) are modified in such a way that some difluoroaromatic portions carry a thermolabile portion. In still other aspects crosslinking may advantageously occur without reliance on an exogenous crosslinker.
    • 纳米多孔材料由具有用于交联的反应性基团的主链的聚合物制成。 在优选的方法和组合物的一个方面,主链中的反应性基团包含二烯和亲二烯体。 二烯可有利地包含四环,并且亲二烯体可有利地包含乙炔基。 在优选方法和组合物的另一方面,骨架中的反应性基团包括在共轭体系中。 特别优选的聚合物链包含由二氟芳族部分和芳族双酚部分合成的聚(亚芳基醚)。 更优选的是,聚(亚芳基醚)的二氟芳香族部分以使得一些二氟芳香族部分携带不可热热部分的方式被改性。 在其它方面,交联可有利地发生,而不依赖于外源交联剂。
    • 9. 发明授权
    • Organic compositions
    • 有机成分
    • US07060204B2
    • 2006-06-13
    • US10404047
    • 2003-04-02
    • Bo LiNancy IwamotoBoris KorolevPaul G. ApenKreisler LauJohn G. SikoniaAnanth NamanAmauel GebrebrhanNassrin SleimanRuslan Zherebin
    • Bo LiNancy IwamotoBoris KorolevPaul G. ApenKreisler LauJohn G. SikoniaAnanth NamanAmauel GebrebrhanNassrin SleimanRuslan Zherebin
    • H01B1/12C08J9/38C08J9/00
    • H01L21/02126C08G61/02C08L65/00H01L21/02203H01L21/02282H01L21/31695H05K1/0313
    • The present invention provides a composition comprising: (a) dielectric material; and (b) porogen comprising at least two fused aromatic rings wherein each of the fused aromatic rings has at least one alkyl substituent thereon and a bond exists between at least two of the alkyl substituents on adjacent aromatic rings. Preferably, the dielectric material is a composition comprising (a) thermosetting component comprising (1) optionally monomer of Formula I as set forth below and (2) at least one oligomer or polymer of Formula II as set forth below where Q, G, h, I, I, and w are as set forth below and (b) porogen. Preferably, the porogen is selected from the group consisting of unfunctionalized polyacenaphthylene homopolymer, functionalized polyacenaphthylene homopolymer, polyacenaphthylene copolymer, polynorbornene, polycaprolactone, poly(2-vinylnaphthalene), vinyl anthracene, polystyrene, polystyrene derivatives, polysiloxane, polyester, polyether, polyacrylate, aliphatic polycarbonate, polysulfone, polylactide, and blends thereof. The present compositions are particularly useful as dielectric substrate material in microchips, multichip modules, laminated circuit boards, and printed wiring boards.
    • 本发明提供一种组合物,其包含:(a)电介质材料; 和(b)包含至少两个稠合芳环的致孔剂,其中每个稠合芳环在其上具有至少一个烷基取代基,并且在相邻芳环上的至少两个烷基取代基之间存在键。 优选地,电介质材料是包含(a)热固性组分的组合物,其包含(1)如下所述的任选的式I的单体和(2)至少一种如下所述的式II的低聚物或聚合物,其中Q,G,h ,I,I和w如下所述,(b)致孔剂。 优选地,致孔剂选自非官能化聚苊烯均聚物,官能化聚苊烯均聚物,聚苊烯共聚物,聚降冰片烯,聚己内酯,聚(2-乙烯基萘),乙烯基蒽,聚苯乙烯,聚苯乙烯衍生物,聚硅氧烷,聚酯,聚醚,聚丙烯酸酯,脂族 聚碳酸酯,聚砜,聚丙交酯及其共混物。 本发明的组合物特别可用作微芯片,多芯片模块,层叠电路板和印刷线路板中的介电基板材料。