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    • 2. 发明授权
    • Flat electrochemical sensor, and method of its manufacture
    • 平面电化学传感器及其制造方法
    • US4294679A
    • 1981-10-13
    • US145738
    • 1980-05-01
    • Helmut MaurerKlaus MullerErnst LinderFranz RiegerGunther Stecher
    • Helmut MaurerKlaus MullerErnst LinderFranz RiegerGunther Stecher
    • G01N27/41B01L3/00G01N27/406G01N27/407G01N27/409G01N27/413G01N27/416G01N27/48G01N27/58
    • G01N27/4071G01N27/4067G01N27/48Y10T29/49002
    • To apply a measured quantity of air to the electrodes applied to a plate-like solid electrolyte body, which may be a chip on a carrier or may, itself, form the carrier, grooves, flutes, ducts, or depressions are formed in the carrier and/or a cover plate, the grooves terminating at an edge portion with access to the gas to be supplied, and having a size such that their clear height is preferably in the lower micron region, and a width, preferably under 1 mm, and particularly between 0.2 and 0.4 mm. The higher limits are applicable to apply, for example, air to a reference electrode, to apply ambient oxygen thereto; the lower limits are appropriate when operating the sensor as a polarographic sensor, in which the diffusion limited current, upon application of a bias voltage, is an analog measure of the oxygen concentration in the gas, and the gas supply to the electrode must be suitably controlled to prevent saturation conditions. The grooves may be formed, for example, by sandblasting or by applying insulating material in the form of posts, ridges, and the like, on the respective element, filling the space therebetween with a filler substance which, upon subsequent sintering, escapes, thus leaving the voids forming the grooves, depressions, and the like.
    • 为了将应用于板状固体电解质体的电极施加测量量的空气,该固体电解质体可以是载体上的芯片,或者可以自身形成载体,在载体中形成凹槽,凹槽,管道或凹陷 和/或盖板,所述槽终止于边缘部分,具有进入待供应气体的通道,并且具有这样的尺寸,使得它们的透明高度优选地在较低的微米区域中,宽度优选地在1mm以下,以及 特别是在0.2和0.4毫米之间。 上限适用于将例如空气施加到参比电极,以向其施加环境氧; 当将传感器作为极谱传感器操作时,下限是适当的,其中在施加偏压时扩散受限电流是气体中氧浓度的模拟测量,并且对电极的气体供应必须适当 控制以防止饱和条件。 凹槽可以例如通过喷砂或通过在各个元件上施加柱状物,脊等的形式的绝缘材料形成,用填充物填充其间的空间,该填充物在随后的烧结时逸出,因此 留下形成凹槽,凹陷等的空隙。
    • 3. 发明授权
    • Process for producing PTC temperature sensor elements for PTC
temperature sensor
    • 用于生产PTC温度传感器PTC温度传感器元件的工艺
    • US5172466A
    • 1992-12-22
    • US715798
    • 1991-06-14
    • Karl-Hermann FrieseHans-Martin WiedenmannGunther Stecher
    • Karl-Hermann FrieseHans-Martin WiedenmannGunther Stecher
    • G01K7/16G01J5/02G01J5/20G01K7/18G01K7/22G01N27/416G01N27/417H01C1/024H01C1/034H01C7/02
    • G01K7/183H01C7/021Y10T29/49085
    • A PTC temperature sensor and a process for producing PTC temperature sensing elements from ceramic films for a PTC temperature sensor are proposed. The PTC temperature sensing elements are so designed that the PTC resistor track is hermetically encapsulated with respect to the gas being measured and the ambient air. Ceramic films based on an insulator ceramic, in particular based on Al.sub.2 O.sub.3, and ceramic films based on a solid electrolyte can be used to produce the temperature sensing elements. The PTC temperature sensor according to the invention is distinguished, in particular, by the fact that, while the manufacturing procedure is cheap, it is not subject to aging due to the effect of varying O.sub.2 partial pressures, has a high resistance to aging of the resistance characteristic in rich and lean gas mixtures, for example in motor vehicle exhaust gases, at 300.degree.-1000.degree. C. and has a construction free from extraneous potential, is characterized by short response times owning to its low heat capacity and is suitable for incorportion in very narrow housing as a consequence of small dimensions.
    • 提出了一种用于PTC温度传感器的PTC温度传感器和用于从陶瓷膜生产PTC温度传感元件的工艺。 PTC温度感测元件被设计成使得PTC电阻轨道相对于被测量的气体和环境空气被气密地封装。 可以使用基于绝缘体陶瓷,特别是基于Al 2 O 3的陶瓷膜和基于固体电解质的陶瓷膜来制造温度感测元件。 根据本发明的PTC温度传感器的特征在于,特别是由于制造过程便宜,由于变化的O2分压的影响,其不会老化,因此具有高耐老化性 富含和贫气混合物的阻力特性,例如在机动车排气中,在300°-1000℃,具有无外力的结构,其特征在于具有低热容量的响应时间短,适用于 由于小尺寸,狭窄房屋的配额不合。
    • 4. 发明授权
    • NTC temperature sensor and process for producing NTC temperature sensing
elements
    • NTC温度传感器和生产NTC温度传感元件的工艺
    • US5142266A
    • 1992-08-25
    • US466286
    • 1990-03-26
    • Karl-Hermann FrieseGunther StecherHans-Martin Wiedenmann
    • Karl-Hermann FrieseGunther StecherHans-Martin Wiedenmann
    • G01K7/16G01K7/22G01N27/406G01N27/416H01C7/04
    • H01C7/043G01K7/223G01N27/4067
    • The NTC temperature sensor includes a NTC temperature sensing element having an NTC resistor and made of a laminated composite of ceramic films, which is so designed that the ambient air or oxygen supplied by electrolytic pumping has free access, via a channel in the laminated composite, to the NTC resistor. The NTC resistor is hermetically sealed from a gas being measured. Solid electrolyte films which conduct O.sup.-2 ions, and films based on Al.sub.2 O.sub.3 can be used to make the laminated composite. The NTC resistor characteristic curve is independent of the composition of the gas being measured. The laminated composite can be formed of at least three solid electrolyte ceramic films including a base film provided with punched-out interconnection holes and conductor tracks printed by thick film technology, an intermediate film having a punched-out channel and a channel enlargement around the ends of the conductor tracks forming the electrodes of the NTC resistor, and a covering film.
    • PCT No.PCT / DE88 / 00528 Sec。 371 1990年3月26日第 102(e)1990年3月26日PCT PCT公布1988年8月30日PCT。 出版物WO89 / 03115 日期2004年4月6日。NTC温度传感器包括NTC温度感测元件,其具有NTC电阻器并由陶瓷膜的层压复合材料制成,其被设计成使得通过电解泵送供应的环境空气或氧气可以自由通过, 一个通道在叠层复合材料中,到NTC电阻。 NTC电阻器与被测气体气密密封。 可以使用导电O-2离子的固体电解质膜和基于Al2O3的膜来制备层压复合材料。 NTC电阻特性曲线与被测气体的组成无关。 层压复合体可以由至少三个固体电解质陶瓷膜形成,该固体电解质陶瓷膜包括设置有冲孔互连孔的底膜和通过厚膜技术印刷的导体轨迹,具有冲压通道的中间膜和在端部周围的通道放大 的形成NTC电阻器的电极的导体轨迹以及覆盖膜。
    • 7. 发明授权
    • Pressure sensor
    • 压力传感器
    • US4382247A
    • 1983-05-03
    • US181839
    • 1980-08-27
    • Gunther StecherKurt SpitzenbergerKlaus Muller
    • Gunther StecherKurt SpitzenbergerKlaus Muller
    • G01L7/08G01L9/00
    • G01L9/0055G01L9/0044G01L9/0075
    • A deformable membrane is made by applying, by thick-film technology, a glass-ceramic paste over a vaporizable or burnable filler material, containing primarily carbon black in a binder which, in turn, is located on a substrate, for example of ceramic, glass, enameled metal or the like. The substrate for example is about 1.5 cm square, the membrane glass ceramic being applied as a circular dot of about 0.5 cm diameter. After solidifying the paste forming the membrane in a protective gas atmosphere, for example at about 950.degree. C., the filler is burned out in an oxidizing atmosphere, to escape through pores in the membrane material. By selecting a membrane material which has a lower thermal coefficient of expansion than that of the substrate, after burning, the membrane will assume a convex shape leaving a hollow space (8) beneath it and the substrate. The membrane is pressure-sensitive, for example when a predetermined quantity of a predetermined gas under a predetermined pressure is sealed therein, or if access to the interior of the space is provided through the substrate, for example by a tiny duct which is connected to a flange or stub connection. Electrical output can be obtained by applying either a metallic layer cover the membrane and utilizing the capacity of the metallic layer with respect to a counter electrode, or applying strain-compression sensitive resistors on the membrane. The membrane, after the electrodes or resistors are applied, is coated with a protective glass glaze (6). The pressure transducer is particularly for determining the pressure conditions in the induction pipe of an internal combustion engine.
    • 通过厚膜技术将玻璃陶瓷浆料涂覆在可蒸发或可燃的填充材料上制成可变形膜,该填充材料主要在粘合剂中包含炭黑,粘合剂又位于例如陶瓷的基材上, 玻璃,搪瓷金属等。 基板例如是约1.5cm 2正方形,膜玻璃陶瓷作为约0.5cm直径的圆点施加。 在保护气体气氛中,例如在约950℃下固化形成膜的糊料之后,填充剂在氧化气氛中燃烧,以通过膜材料中的孔逸出。 通过选择具有比基板更低的热膨胀系数的膜材料,在燃烧之后,膜将呈现凸形,在其下方留下中空空间(8)和基板。 膜是压敏的,例如当预定量的预定压力下的预定气体被密封在其中时,或者如果通过衬底提供对空间内部的接近,例如通过连接到 法兰或短线连接。 通过施加金属层覆盖膜并利用相对于对电极的金属层的能力,或在膜上施加应变压敏敏感电阻,可以获得电输出。 在施加电极或电阻器之后,膜被涂覆有保护性玻璃釉(6)。 压力传感器特别用于确定内燃机的感应管中的压力状况。