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    • 2. 发明授权
    • Electrochemical sensor structure to determine oxygen content in
combustion exhaust gases
    • 电化学传感器结构来确定燃烧废气中的氧含量
    • US4283261A
    • 1981-08-11
    • US100256
    • 1979-12-04
    • Helmut MaurerKlaus MullerFranz RiegerErnst LinderHermann DietzKarl-Hermann FrieseBodo Ziegler
    • Helmut MaurerKlaus MullerFranz RiegerErnst LinderHermann DietzKarl-Hermann FrieseBodo Ziegler
    • G01N27/407G01N27/416G01N27/46
    • G01N27/4071
    • To measure partial oxygen pressure in gases, particularly exhaust gases of automotive-type combustion engines, a solid electrolyte plate of elongated rectangular configuration has at least one electrode pair applied to a single surface thereof, which is exposed to the measuring gas. Preferably, the gap between electrodes is elongated, by forming the electrodes in comb-interdigited form. A thermocouple - temperature sensor can be applied between connecting tracks for the electrodes which extend longitudinally of the electrolyte plate towards the other end thereof, through a sealing mass holding the plate within a housing, the other end forming, simultaneously, a connection terminal for connection to an electric connector or plug. A heating element can be placed on the obverse side of the plate, preferably in the position in the gap between the electrodes. More than one such sensor element may be secured in the same housing, and, for example, two such plates, back to back, with the heating element therebetween, spaced from each other, or as a common block. The sensor may be used for potentiometric and/or polarographic measurement, depending upon cover coatings on the electrodes which control exposure thereof to the gases, catalytic or non-catalytic action of the electrodes (for example being of platinum or gold, respectively) and whether a voltage is applied across the electrode terminals, or the sensor is to operate as an electrochemical cell. Such sensor can be inexpensively made, are suitable for mass production, and flexible with respect to their mode of operation.
    • 为了测量气体,特别是汽车型内燃机的废气中的部分氧气压力,细长矩形结构的固体电解质板具有至少一个电极对,其被施加到暴露于测量气体的单个表面。 优选地,通过以梳形交错形式形成电极,电极之间的间隙是细长的。 热电偶 - 温度传感器可以被施加在电极的连接轨道之间,电极的连接轨道通过将板保持在壳体内的密封块向另一端延伸,另一端同时形成用于连接的连接端子 电连接器或插头。 加热元件可以放置在板的正面上,优选地位于电极之间的间隙中的位置。 多个这样的传感器元件可以固定在相同的壳体中,并且例如两个这样的板,背对背,加热元件在它们之间,彼此间隔开,或者作为公共块。 传感器可以用于电位和/或极谱测量,这取决于电极上的覆盖物涂层,其控制其暴露于气体,电极的催化或非催化作用(例如分别为铂或金),以及是否 在电极端子上施加电压,或者传感器用作电化学电池。 这种传感器可以廉价地制造,适合于批量生产,并且相对于它们的操作模式是灵活的。
    • 3. 发明授权
    • Flat electrochemical sensor, and method of its manufacture
    • 平面电化学传感器及其制造方法
    • US4294679A
    • 1981-10-13
    • US145738
    • 1980-05-01
    • Helmut MaurerKlaus MullerErnst LinderFranz RiegerGunther Stecher
    • Helmut MaurerKlaus MullerErnst LinderFranz RiegerGunther Stecher
    • G01N27/41B01L3/00G01N27/406G01N27/407G01N27/409G01N27/413G01N27/416G01N27/48G01N27/58
    • G01N27/4071G01N27/4067G01N27/48Y10T29/49002
    • To apply a measured quantity of air to the electrodes applied to a plate-like solid electrolyte body, which may be a chip on a carrier or may, itself, form the carrier, grooves, flutes, ducts, or depressions are formed in the carrier and/or a cover plate, the grooves terminating at an edge portion with access to the gas to be supplied, and having a size such that their clear height is preferably in the lower micron region, and a width, preferably under 1 mm, and particularly between 0.2 and 0.4 mm. The higher limits are applicable to apply, for example, air to a reference electrode, to apply ambient oxygen thereto; the lower limits are appropriate when operating the sensor as a polarographic sensor, in which the diffusion limited current, upon application of a bias voltage, is an analog measure of the oxygen concentration in the gas, and the gas supply to the electrode must be suitably controlled to prevent saturation conditions. The grooves may be formed, for example, by sandblasting or by applying insulating material in the form of posts, ridges, and the like, on the respective element, filling the space therebetween with a filler substance which, upon subsequent sintering, escapes, thus leaving the voids forming the grooves, depressions, and the like.
    • 为了将应用于板状固体电解质体的电极施加测量量的空气,该固体电解质体可以是载体上的芯片,或者可以自身形成载体,在载体中形成凹槽,凹槽,管道或凹陷 和/或盖板,所述槽终止于边缘部分,具有进入待供应气体的通道,并且具有这样的尺寸,使得它们的透明高度优选地在较低的微米区域中,宽度优选地在1mm以下,以及 特别是在0.2和0.4毫米之间。 上限适用于将例如空气施加到参比电极,以向其施加环境氧; 当将传感器作为极谱传感器操作时,下限是适当的,其中在施加偏压时扩散受限电流是气体中氧浓度的模拟测量,并且对电极的气体供应必须适当 控制以防止饱和条件。 凹槽可以例如通过喷砂或通过在各个元件上施加柱状物,脊等的形式的绝缘材料形成,用填充物填充其间的空间,该填充物在随后的烧结时逸出,因此 留下形成凹槽,凹陷等的空隙。
    • 7. 发明授权
    • Spark plug with measuring means
    • 带测量装置的火花塞
    • US4489596A
    • 1984-12-25
    • US478267
    • 1983-03-24
    • Ernst LinderHelmut MaurerKlaus Muller
    • Ernst LinderHelmut MaurerKlaus Muller
    • H01T13/18H01T13/20H01T13/40H01T13/46H01T13/52G01M15/00
    • H01T13/20H01T13/18H01T13/40H01T13/465H01T13/52
    • An elongated plate element, for example of aluminum oxide, or a metal plate which is coated with an insulator such as aluminum oxide, is retained within a hollow spark plug insulator (15) by a sealing mass (38), for example a sinter compound, sintering together the plate element (37) and the insulator body (35). The plate element carries a strip or conductive track layer electrode (25) thereon, located, for example, on one major surface of the plate; at the ignition end, the plate may have a through-hole (52), plated through, so that the ignition electrode will have conductive portions at both sides of the plate, faced by ground electrode portions which likewise can be retained on plate-like carrier elements, and connected to the metal housing (11) of the spark plug via conductive tracks (60, 61) and a conductive sealing ring (17"). The plates can carry heaters (32) and operation sensors, such as gas composition sensor, temperature sensor, pressure sensor or the like, which may, for example, have one electrode connected to ground or chassis, and hence to the metal housing, and the other electrode carried along in strip form to the connecting end portion of the spark plug. The plate and layer-like construction of the insulating elements permits modular combination of required components having the desired operating and/or sensing characteristics, and are suitable for mass production assembly.
    • 例如氧化铝的细长板元件或涂覆有诸如氧化铝的绝缘体的金属板通过密封块(38)保留在中空火花塞绝缘体(15)内,例如烧结体 ,将板元件(37)和绝缘体(35)烧结在一起。 板元件在其上承载条或导电轨道层电极(25),其位于例如板的一个主表面上; 在点火端,板可以具有通孔(52),电镀通孔,使得点火电极在板的两侧将具有导电部分,面对同样可以保持在板状的接地电极部分 并且经由导电轨道(60,61)和导电密封环(17“)连接到火花塞的金属壳体(11)。 板可以携带加热器(32)和操作传感器,例如气体成分传感器,温度传感器,压力传感器等,其可以例如具有连接到地面或底座的一个电极,并且因此连接到金属外壳,以及 另一个电极以带状形式携带到火花塞的连接端部。 绝缘元件的板状和层状结构允许具有所需操作和/或感测特性的所需部件的模块化组合,并且适用于批量生产组装。
    • 9. 发明授权
    • Temperature compensated polarographic oxygen gas sensor and sensing
system, particularly for automotive application
    • 温度补偿极谱氧气传感器和传感系统,特别适用于汽车应用
    • US4391691A
    • 1983-07-05
    • US242579
    • 1981-03-11
    • Ernst LinderHelmut MaurerKlaus MullerFranz Rieger
    • Ernst LinderHelmut MaurerKlaus MullerFranz Rieger
    • G01N27/41F02D41/14G01N27/406G01N27/407G01N27/416G01N27/48G01N27/56G01N27/58
    • G01N27/4071F02D41/1476G01N27/4065G01N27/48
    • To render output of a polarographic sensor essentially independent of aging of electrodes and temperature effects of the solid electrolyte body, within the operating ranges of the sensor to measure the oxygen composition of exhaust gases, the solid electrolyte plate of, for example, 50 mm length, 8 mm width and 1 mm thickness has a sensing electrode system including a cathode (2), and an anode (3) applied thereto, connected to a voltage source (7) of controllable output voltage. An oxygen molecule diffusion barrier (6) is applied to the cathode electrode. Additionally, a further electrode pair (5,4) is applied to the solid electrolyte body (1), serially connected in the current limiting circuit including the control voltage source. The voltage across one (2,3) of the electrode pairs is measured and compared with the voltage across the other electrode pair (4,5) voltage source, since the resistance of the zirconium solid electrolyte body drops with increasing temperature at roughly the same rate as the increase in limit current flow with increasing temperature. Both electrode pairs (2,3; 4,5) on the solid electrolyte body (1) are exposed to the gases, the oxygen content of which is to be analyzed.
    • 为了使极谱传感器的输出基本上独立于电极的老化和固体电解质体的温度效应,在用于测量废气的氧气组成的传感器的操作范围内,固体电解质板例如为50mm长度 宽8mm,厚1mm的感测电极系统具有与可控输出电压的电压源(7)连接的阴极(2)和阳极(3)的检测电极系统。 向阴极施加氧分子扩散阻挡层(6)。 另外,在包括控制电压源的限流电路中串联连接到固体电解质体(1)上的另一电极对(5,4)。 测量一个(2,3)电极对上的电压,并与另一个电极对(4,5)电压源上的电压进行比较,因为锆固体电解质体的电阻随温度升高大致相同而下降 随着温度的升高,限流电流的增加。 将固体电解质体(1)上的两个电极对(2,3; 4,5)暴露于要分析其含氧量的气体。
    • 10. 发明授权
    • Optical engine knock sensing system
    • 光学发动机爆震传感系统
    • US4369748A
    • 1983-01-25
    • US268856
    • 1981-06-01
    • Leo SteinkeErnst LinderHelmut MaurerKlaus MullerFranz Rieger
    • Leo SteinkeErnst LinderHelmut MaurerKlaus MullerFranz Rieger
    • G01M15/00F02P5/152F02P5/153G01H9/00G01H17/00G01L23/22F02P5/04F02B3/00
    • G01L23/22F02P5/1525Y02T10/46
    • A sensor (10) optically coupled to the combustion chamber (10') of an internal combustion (IC) engine is kept free from contaminating or dirt deposits, or the like, by subjecting the sensor to mechanical shocks or vibration. The mechanical shocks or vibration are obtained by the engine itself by controlling the engine to operate for a predetermined time period as set by a monostable flip-flop (FF) (18) under controlled knocking conditions, the shock waves within the combustion chamber causing flaking off or dropping off of contaminating deposits. Controlled knocking can be obtained by advancing ignition timing by additional control of an ignition system (19) in a direction of excessive spark advance, or overriding a knocking inhibiting system already present on the engine. The degree of contamination of the sensor can be determined, for example, by integrating the light received over a predetermined angle of rotation of the engine crankshaft and comparing this rotation with the amount of fuel supplied to the engine for combustion, for example by comparison with timing of a fuel injection pulse, or the like.
    • 光学耦合到内燃机(IC)发动机的燃烧室(10')的传感器(10)通过使传感器受到机械冲击或振动而保持没有污染或污垢沉积物等。 发动机本身通过控制发动机在受控的爆震条件下由单稳态触发器(FF)(18)设定的预定时间段来实现机械冲击或振动,燃烧室内的冲击波引起剥落 脱落或掉落污染沉积物。 可以通过在点火系统(19)的过度火花提前的方向上进一步控制点火正时或者超越已经存在于发动机上的爆震抑制系统来获得控制爆震。 传感器的污染程度可以例如通过将在发动机曲轴的预定旋转角度上接收到的光积分并将该旋转与供给到发动机用于燃烧的燃料量进行比较来确定,例如通过与 燃料喷射脉冲的定时等。