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    • 6. 发明授权
    • Polyamide and film made from at least one monomolecular layer of a
polyamide
    • 聚酰胺和薄膜从一个单一分子层聚酰胺制成
    • US5166307A
    • 1992-11-24
    • US402863
    • 1989-09-05
    • Harald CherdronWerner PrassUde ScheunemannDonald Lupo
    • Harald CherdronWerner PrassUde ScheunemannDonald Lupo
    • B05D1/20B32B27/34C08G69/26C08J5/18
    • B05D1/202B82Y30/00B82Y40/00C08G69/26Y10T428/265Y10T428/31725Y10T428/31728
    • Polyamides of the general formula [N(A)-X-N(B)-CO-Y-CO-].sub.n are described, in which Y denotes a divalent group, X a divalent radical whose chain contains at least two carbon atoms, A and B independently of one another denote H or a C.sub.1 to C.sub.26 alkyl group and n denotes an integer greater than 4. The said polyamides contain at least one alkyl group of C.sub.6 to C.sub.26 per repeating unit. The groups X and/or Y contain at leat one CH.sub.2 group in the chain. The polyamides are prepared by reaction of a diamine of the formula NHA-X-NHB with an about equimolar amount of a reactive derivative of a dicarboxylic acid of the formula COOH-Y-COOH. The polyamides obtained can be used in order to prepare highly ordered monomolecular LB films on a support. For this purpose, the polyamide is dissolved in a volatile organic solvent which is immiscible with water and the solution is spread on the water/air interface. After evaporation of the solvent the layer is compressed and transferred to a solid support by the LB technique. The film is very stable and can be used to prepare optical waveguide systems, filters for optical purposes or protective layers.
    • 描述了通式[N(A)-XN(B)-CO-Y-CO-] n的聚酰胺,其中Y表示二价基团,X是其链含有至少两个碳原子的二价基团,A和 B彼此独立地表示H或C1至C26烷基,n表示大于4的整数。所述聚酰胺每个重复单元含有至少一个C6至C26的烷基。 基团X和/或Y在链中含有一个CH 2基团。 聚酰胺通过式NHA-X-NHB的二胺与约等摩尔量的式COOH -Y-COOH的二羧酸的活性衍生物的反应来制备。 获得的聚酰胺可用于在载体上制备高度有序的单分子LB膜。 为此,将聚酰胺溶解在与水不混溶的挥发性有机溶剂中,并将溶液铺展在水/空气界面上。 溶剂蒸发后,将层压缩并通过LB技术转移至固体支持物。 该膜非常稳定,可用于制备光波导系统,用于光学目的的滤光片或保护层。
    • 9. 发明授权
    • Conjugated polymers containing heterospiro atoms and their use as
electroluminescence materials
    • 含有杂环原子的共轭聚合物及其作为电致发光材料的用途
    • US5859211A
    • 1999-01-12
    • US840843
    • 1997-04-17
    • Willi KreuderDonald LupoJosef SalbeckHermann SchenkThomas Stehlin
    • Willi KreuderDonald LupoJosef SalbeckHermann SchenkThomas Stehlin
    • C08G61/00C08G61/12C08G73/06C09K11/06H01L51/50H05B33/10C08G59/00
    • H01L51/0043C08G61/00C08G73/0672C08G73/0688C09K11/06H01L51/5012
    • A conjugated polymer comprising repeating units of the formula (I), ##STR1## where the symbols and indices have the following meanings: .PSI. is an element of the 4th main group of the Periodic Table with the exception of carbon;D, E, F, G are identical or different and are --CR.sup.1 R.sup.2 --, --O--, --S--, --NR.sup.3 -- or a chemical bond;U is --CR.sup.4 .dbd.CR.sup.5 -- or a chemical bond;V is as defined for U or is --CR.sup.1 R.sup.2 --, --O--, --S--, --NR.sup.3 --, --SiR.sup.1 R.sup.2 --, --SO.sub.2 --, --O--, --CO--;A are identical or different and are H, a C.sub.1 --C.sub.20 -hydrocarbon radical which can also contain heteroatoms;T is --O--, --S--, --NR.sup.3 --, --CR.sup.1 R.sup.2 --, --CH.dbd.N--, --CA.dbd.CA--, --CH.dbd.CA--, --CH.dbd.CF-- or --CF.dbd.CF--;K, Q are identical or different hydrocarbon radicals which can contain heteroatoms and have conjugated electron systems;M, L are H or a straight-chain or branched alkyl group having from 1 to 22 carbon atoms, Br, Cl, F, CN, NO.sub.2 or CF.sub.3 ;m, n are identical or different and are 0, 1, 2, 3 or 4; and wherein said polymer is suitable as an electroluminescence material.
    • 包含式(I),(I)的重复单元的共轭聚合物,其中符号和指数具有以下含义:PSI是元素周期表第4主要组分的元素,除了碳; D,E,F,G相同或不同,为-CR1R2-,-O - , - S-,-NR3-或化学键; U是-CR4 = CR5-或化学键; V如对于U或为-CR 1 R 2 - , - O - , - S - , - NR 3 - , - SiR 1 R 2 - , - SO 2 - , - O - , - CO- A相同或不同,为H,也可含有杂原子的C 1 -C 20烃基; T是-O - , - S - , - NR 3 - , - CR 1 R 2 - , - CH = N-,-CA = CA-,-CH = CA-,-CH = CF-或-CF = CF-; K,Q是可以含有杂原子并具有共轭电子系统的相同或不同的烃基; M,L是H或具有1至22个碳原子的直链或支链烷基,Br,Cl,F,CN,NO 2或CF 3; m,n相同或不同,为0,1,2,3或4; 并且其中所述聚合物适合作为电致发光材料。