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1. 发明授权

US4980500A Process for the preparation of biuret polyisocyanates, the compounds obtained by this process and their use 失效
标题翻译：制备缩二脲多异氰酸酯的方法，通过该方法获得的化合物及其用途
公开(公告)号：US4980500A
公开(公告)日：1990-12-25
申请号：US281159
申请日：1988-12-07
申请人： Josef Pedain , Manfred Schonfelder , Manfred Schmidt
发明人： Josef Pedain , Manfred Schonfelder , Manfred Schmidt
IPC分类号： C07C273/18 , C07C275/62 , C08G18/10 , C08G18/42 , C08G18/77 , C08G18/78 , C08G18/79 , C08G18/80
CPC分类号： C08G18/8045 , C08G18/10 , C08G18/42 , C08G18/7831 , C08G18/8016 , C08G18/8038
摘要： The present invention is directed to a process for the preparation of urethane-modified biuret polyisocyanates by the reaction of(a) 1,6-diisocyanatohexane with subequivalent quantities of(b) biuretizing agents based on water and/or organic compounds which react with isocyanate groups to form biuret groups,to form biurets followed by removal of the unreacted, excess 1,6-diisocyanatohexane and any volatile components present, characterized in that at any stage before removal of the excess 1,6-diisocyanate,(c) at least one diol containing ester groups and having an average molecular weight of about 350 to 950 is added to the reaction mixture in a quantity of about 1 to 50% by weight, based on the weight of the 1,6-diisocyanatohexane, the diol reacting with part of the isocyanate groups present to form urethane groups.The invention is also directed to the urethane-modified biuret polyisocyanates obtained by this process and their use as polyisocyanate components in two-component polyurethane lacquers.
摘要翻译：本发明涉及通过（a）1,6-二异氰酸根合己烷与基于与异氰酸酯反应的水和/或有机化合物的（b）缩二脲化合物的反应制备氨基甲酸酯改性的缩二脲多异氰酸酯的方法组合形成缩二脲基团，形成缩二脲，然后除去未反应的过量1,6-二异氰酸根合己烷和存在的任何挥发性组分，其特征在于在去除过量的1,6-二异氰酸酯之前的任何阶段，（c）至少一元醇含有酯基并且平均分子量为约350至950的反应混合物中加入约1至50重量％，基于1,6-二异氰酸根合己烷的重量，二醇与存在的部分异氰酸酯基团形成氨基甲酸酯基团。本发明还涉及通过该方法获得的氨基甲酸酯改性的缩二脲多异氰酸酯及其在双组分聚氨酯漆中作为多异氰酸酯组分的用途。

2. 发明授权

US5130466A Diisocyanate, a process for its production and its use 失效
标题翻译：二异氰酸酯，其生产工艺及其使用
公开(公告)号：US5130466A
公开(公告)日：1992-07-14
申请号：US463713
申请日：1990-01-11
申请人： Manfred Schmidt , Klaus Konig , Peter Heitkamper , Josef Pedain
发明人： Manfred Schmidt , Klaus Konig , Peter Heitkamper , Josef Pedain
IPC分类号： C08G18/73 , C07C67/00 , C07C69/00 , C07C241/00 , C07C263/10 , C07C265/02 , C07C265/04 , C07C265/14 , C08G18/77 , C08G18/80
CPC分类号： C07C265/00 , C08G18/771
摘要： The present invention is directed to a diisocyanate which corresponds to the formula ##STR1## The present invention is also directed to the preparation of this diisocyanate and to its use for the production of polyisocyanate polyaddition products.
摘要翻译：本发明涉及对应于下式的二异氰酸酯。本发明还涉及该二异氰酸酯的制备及其在多异氰酸酯加成产物的制备中的应用。

3. 发明授权

US4742125A Process for the production of mercapto group-containing oligourethanes, oligourethanes obtainable by this process and their use in various polymer systems 失效
标题翻译：用于生产含巯基的低聚氨酯的方法，可通过该方法获得的低聚氨酯及其在各种聚合物体系中的应用
公开(公告)号：US4742125A
公开(公告)日：1988-05-03
申请号：US831776
申请日：1986-02-20
申请人： Manfred Schmidt , Wolfgang Wellner , Josef Pedain , Hermann Gruber
发明人： Manfred Schmidt , Wolfgang Wellner , Josef Pedain , Hermann Gruber
IPC分类号： C08G18/00 , C08G18/10 , C08G18/16 , C08G18/28 , C08G18/38 , C08G18/65 , C08G59/66 , C08G75/04 , C08K5/37 , C07C149/437 , C08F279/00
CPC分类号： C08K5/37 , C08G18/10 , C08G18/168 , C08G18/288 , C08G18/3876 , C08G59/66 , C08G75/04 , C08G2190/00
摘要： The present invention is directed to a process for the production of oligourethanes having terminal mercapto groups by reacting organic polyisocyanates with sub-equivalent quantities of organic polyhydroxyl compounds and a mercapto-alkanol in the presence of at least one ester of phosphoric acid containing at least one hydroxyl group bound to phosphorus. The present invention is also directed to the mercapto group-containing oligourethanes obtainable by this process and their use as binders for oxidatively-hardenable coating and sealing compositions, additives for epoxide resins and cross-linking agents for plastics materials and plastics crude products containing olefinic double bonds.
摘要翻译：本发明涉及一种制备具有末端巯基的低聚氨酯的方法，其通过使有机多异氰酸酯与次当量的有机多羟基化合物和巯基链烷醇在至少一种含至少一种羟基结合磷。本发明还涉及通过该方法获得的含巯基的聚氨酯，它们可用作氧化可硬化涂料和密封组合物的粘合剂，用于环氧树脂的添加剂和用于塑料材料的交联剂和含有烯属双酚的塑料原料债券。

4. 发明授权

US4639499A Cross-linkable polymer resins and use thereof as binders for coating agents 失效
标题翻译：可交联聚合物树脂及其作为涂布剂的粘合剂的用途
公开(公告)号：US4639499A
公开(公告)日：1987-01-27
申请号：US756483
申请日：1985-07-18
申请人： Peter Hohlein , Manfred Schmidt , Josef Pedain , Bernd Riberi , Michael Sonntag
发明人： Peter Hohlein , Manfred Schmidt , Josef Pedain , Bernd Riberi , Michael Sonntag
IPC分类号： C09D201/06 , C08F216/00 , C08F246/00 , C09D133/04 , C09D157/04 , C09D175/00 , C08F238/00 , C08F220/04
CPC分类号： C08F246/00 , C08F216/00 , C09D157/04
摘要： The present invention is directed to cross-linkable, hydroxyl group-containing polymer resins which are obtained by copolymerizing olefinically-unsaturated monomers and are suitable as binder components for lacquers, the polymer resins having a hydroxyl number of about 20 to 400, an average osmometrically-determined molecular weight of about 500 to 30,000 and a molecular inhomogeneity U of about 0.5 to 15, characterized in that they contain about 0.2 to 80% by weight, preferably about 10 to 70% by weight, based on the total weight of the copolymers, of incorporated monomers selected from olefinically- and acetylenically-unsaturated aliphatic diols having 4 carbon atoms, the ether group-containing alkoxylation products thereof with a hydroxyl number of about 50 to 900, the reaction products of these diols with .epsilon.-caprolactone in a mol ratio of diol:-caprolactone of about 1:0.2 to 1:10 and any mixtures of these components.The present invention is also directed to the use of the above polymer resins as binders for coating compositions.
摘要翻译：本发明涉及可交联的含羟基的聚合物树脂，其通过使烯属不饱和单体共聚合而获得，并且适合作为漆的粘合剂组分，聚合物树脂的羟值为约20至400，平均渗透压约500至30,000的测定分子量和约0.5至15的分子不均匀性U，其特征在于它们含有约0.2至80重量％，优选约10至70重量％，基于共聚物的总重量包含选自具有4个碳原子的烯属和炔属不饱和脂族二醇的单体，其含醚基的烷氧基化产物的羟值为约50至900，这些二醇与ε-己内酯的摩尔比为摩尔二醇：己内酯的比例为约1:0.2至1:10，以及这些组分的任何混合物。本发明还涉及上述聚合物树脂作为涂料组合物的粘合剂的用途。

5. 发明授权

US09487616B2 Lightly modified prepolymers and uses thereof 有权
标题翻译：轻度改性预聚物及其用途
公开(公告)号：US09487616B2
公开(公告)日：2016-11-08
申请号：US13809147
申请日：2011-07-11
申请人： Hans-Georg Pirkl , Manfred Schmidt , Reinhard Albers , Johannes Braak , Rolf Roers
发明人： Hans-Georg Pirkl , Manfred Schmidt , Reinhard Albers , Johannes Braak , Rolf Roers
IPC分类号： C08G18/42 , C08G18/83 , C08G18/10 , C08G18/44 , C08G18/48 , C08G18/50 , C08G18/76 , B32B5/18 , B32B15/04 , B32B15/18 , B32B27/06 , B32B27/40 , C08G101/00
CPC分类号： C08G18/4216 , B32B5/022 , B32B5/18 , B32B11/046 , B32B15/046 , B32B15/18 , B32B15/20 , B32B21/08 , B32B27/06 , B32B27/08 , B32B27/40 , B32B29/002 , B32B2266/0278 , B32B2307/50 , C08G18/10 , C08G18/44 , C08G18/4833 , C08G18/4841 , C08G18/4887 , C08G18/5024 , C08G18/7664 , C08G18/831 , C08G2101/0025 , C08G2105/02 , Y10T428/31547 , Y10T442/674 , C08G18/40
摘要： An isocyanate-terminated prepolymer C having an NCO content of from ≧26% by mass to ≦31.0% by mass is obtainable from the reaction of an isocyanate composition A having a viscosity at 25° C. of from ≧60 mPas to ≦800 mPas, comprising from ≧25% by mass to ≦60% by mass MDI and from ≧40% by mass to ≦75% by mass pMDI, wherein the sum of the amounts of those components is ≦100% by mass, with a bifunctional polyester ether polyol B having an OH number of ≧200 mg(KOH)/g and ≦500 mg(KOH)/g, obtained from the reaction of a dicarboxylic acid/dicarboxylic acid derivative with at least one polyol and with an epoxide, wherein the polyester ether polyol B is used in amounts of from ≧1.5% by mass to ≦6.0% by mass, based on the sum of the masses of A and B. The invention further provides a PUR/PIR polymer produced from the prepolymer C, its use and composite elements based thereon.
摘要翻译： NCO含量为≥26质量％〜31.0质量％的异氰酸酯封端的预聚物C可以通过在25℃下的粘度为≥60mPa·s至≤800mPa·s的异氰酸酯组合物A ，其包含：≥25质量％至≤60质量％的MDI，和≥40质量％至≤75质量％的pMDI，其中这些组分的量的总和为≤100质量％，与双官能聚酯由二羧酸/二羧酸衍生物与至少一种多元醇与环氧化物的反应获得的羟值为≥200mg（KOH）/ g和≤500mg（KOH）/ g的乙醚多元醇B，其中，基于A和B的质量之和，聚酯醚多元醇B的使用量为≥1.5质量％至≤6.0质量％。本发明还提供由预聚物C制备的PUR / PIR聚合物，其使用和复合元件。

6. 发明申请

US20150253205A1 MEASURING DEVICE AND MEASURING METHOD FOR REGISTERING AN AMBIENT TEMPERATURE OF A MEDICAL MACHINE, AND DEVICE AND METHOD FOR MEDICAL INSUFFLATION 有权
标题翻译：用于注册医疗机器的环境温度的测量装置和测量方法，以及用于医疗消除的装置和方法
公开(公告)号：US20150253205A1
公开(公告)日：2015-09-10
申请号：US14636678
申请日：2015-03-03
申请人： Walter Hauser , Manfred Schmidt , Otmar Stillhard
发明人： Walter Hauser , Manfred Schmidt , Otmar Stillhard
IPC分类号： G01K13/02 , A61M13/00 , G01K7/16
CPC分类号： G01K13/02 , A61M13/003 , A61M2202/0225 , A61M2205/3368 , A61M2205/3372 , A61M2205/36 , A61M2209/02 , G01K1/20 , G01K7/16 , G01K7/42 , G01K7/427 , G01K2013/024 , A61M2202/0007
摘要： A measuring device and method according to the invention for registering an ambient temperature Ta of a medical machine including a measuring housing, which is arranged on an outer wall of the machine and in which at least one temperature sensor remote from the machine and at least one temperature sensor (16, 16′) near to the machine are held, wherein the at least one temperature sensor remote from the machine registers a first temperature T1 and the at least one temperature sensor near to the machine registers a second temperature T2, and an evaluation apparatus configured to establish the ambient temperature Ta using a difference between the first temperature T1 registered by the at least one temperature sensor remote from the machine and the second temperature T2 registered by the at least one temperature sensor near to the machine.
摘要翻译：根据本发明的用于记录包括测量壳体的医疗机器的环境温度Ta的测量装置和方法，该测量壳体布置在机器的外壁上，并且其中至少一个远离机器的温度传感器和至少一个保持靠近机器的温度传感器（16,16'），其中远离机器的至少一个温度传感器注册第一温度T1，并且靠近机器的至少一个温度传感器注册第二温度T2，以及评估装置，其被配置为使用远离机器的至少一个温度传感器登记的第一温度T1与靠近机器的至少一个温度传感器登记的第二温度T2之间的差建立环境温度Ta。

7. 发明申请

US20130345330A1 METHOD FOR PRODUCING FLEXIBLE POLYURETHANE FOAMS 审中-公开
标题翻译：生产柔性聚氨酯泡沫塑料的方法
公开(公告)号：US20130345330A1
公开(公告)日：2013-12-26
申请号：US13988311
申请日：2011-11-18
申请人： Hartmut Nefzger , Erika Bauer , Bert Klesczewski , Jüergen Schlossmacher , Sven Meyer-Ahrens , Manfred Schmidt
发明人： Hartmut Nefzger , Erika Bauer , Bert Klesczewski , Jüergen Schlossmacher , Sven Meyer-Ahrens , Manfred Schmidt
IPC分类号： C08G18/68 , C07C67/08
CPC分类号： C08G18/68 , C07C67/08 , C08G18/36 , C08G18/4018 , C08G18/4288 , C08G18/4841 , C08G18/6696 , C08G18/7664 , C08G63/06 , C08G63/78 , C08G63/823 , C08G2101/0008 , C08G2101/0075 , C08G2101/0083
摘要： A process for the preparation of polyricinoleic acid esters comprising the step of reaction of ricinoleic acid with an alcohol component which comprises mono- and/or polyfunctional alcohols having a molecular weight of ≧32 g/mol to ≦40 g/mol, wherein the reaction is carried out at least partly in the presence of a catalyst. The amount of catalyst, based on the total weight of the ricinoleic acid and the alcohol component, is in a range of from ≧10 ppm to ≦100 ppm. The reaction is ended when the acid number of the reaction product obtained is ≧5 mg of KOH/g to ≦100 mg of KOH/g. The invention furthermore relates to a polyurethane polymer, in particular a flexible polyurethane foam, which is obtainable using these polyricinoleic acid esters.
摘要翻译：一种制备聚亚油酸酯的方法，包括蓖麻油酸与醇组分反应的步骤，所述醇组分包含分子量≥32g/ mol至40g / mol的单和/或多官能醇，其中至少部分地在催化剂存在下进行反应。基于蓖麻油酸和醇组分的总重量，催化剂的量在> = 10ppm至@ 100ppm的范围内。当所得反应产物的酸值> KOH = 5mg KOH / g至100mg KOH / g时，反应结束。本发明还涉及可使用这些聚亚油酸酯获得的聚氨酯聚合物，特别是柔性聚氨酯泡沫。

8. 发明授权

US08097675B2 2,2′-MDI-based isocyanate mixtures, polyisocyanate polyaddition products prepared therefrom, processes for making the same and methods for their use 失效
标题翻译： 2,2'-MDI-异氰酸酯混合物，由其制备的聚异氰酸酯加聚产物，其制备方法及其使用方法
公开(公告)号：US08097675B2
公开(公告)日：2012-01-17
申请号：US12411472
申请日：2009-03-26
申请人： Zdenka Finder , Jens Krause , Friedhelm Faehling , Manfred Schmidt , Dirk Wegener
发明人： Zdenka Finder , Jens Krause , Friedhelm Faehling , Manfred Schmidt , Dirk Wegener
IPC分类号： C07C265/12 , C08G18/00 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/32 , C08G18/70 , C08G18/71 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/4854 , C08G18/0852 , C08G18/10 , C08G18/307 , C08G18/3821 , C08G18/4238 , C08G18/4825 , C08G18/4845 , C08G18/7671 , D06N7/0071 , C08G18/3814
摘要： Isocyanate mixtures comprising: (a) NCO prepolymers having an NCO content of 1.5 to 18 wt. %; and (b) 1 to 40 wt. % of monomeric 2,2′-diisocyanatodiphenylmethane, based on the isocyanate mixture; wherein the isocyanate mixture has a total NCO content of from 2 to 22 wt. %; polyisocyanate polyaddition products prepared therefrom; and methods of making the same.
摘要翻译：异氰酸酯混合物包含：（a）NCO含量为1.5-18重量％的NCO预聚物％; 和（b）1〜40wt。％的单体2,2'-二异氰酸二苯基甲烷，基于异氰酸酯混合物; 其中所述异氰酸酯混合物的总NCO含量为2至22重量％。％; 由其制备的多异氰酸酯加成产物; 和制作相同的方法。

9. 发明申请

US20110256589A1 T7 RNA POLYMERASE VARIANTS WITH ENHANCED THERMOSTABILITY 有权
标题翻译：具有增强热稳定性的T7 RNA聚合酶变体
公开(公告)号：US20110256589A1
公开(公告)日：2011-10-20
申请号：US13069514
申请日：2011-03-23
申请人： Harald Sobek , Johann-Peter Thalhofer , Rainer Mueller , Manfred Schmidt , Michael Greif , Armin Ruf , Christian Rudolph
发明人： Harald Sobek , Johann-Peter Thalhofer , Rainer Mueller , Manfred Schmidt , Michael Greif , Armin Ruf , Christian Rudolph
IPC分类号： C12P19/34 , C12N5/10 , C12N15/63 , C12N9/10 , C07H21/00
CPC分类号： C12N9/1247 , C12P19/34 , C12Y207/07006
摘要： The present invention provides improved variants of T7 RNA polymerase by introducing novel mutations which lead to improved thermostability of the enzyme. According to the invention, amino acid substitutions at the positions Val426, Ser633, Val650, Thr654, Ala702, Val795, and combinations thereof are advantageous.
摘要翻译：本发明通过引入导致酶的热稳定性的新突变来提供T7RNA聚合酶的改进变体。根据本发明，位置Val426，Ser633，Val650，Thr654，Ala702，Val795及其组合的氨基酸取代是有利的。

10. 发明申请

US20090149621A1 Polyurethanes cured with amines and their preparation 失效
标题翻译：用胺固化的聚氨酯及其制备方法
公开(公告)号：US20090149621A1
公开(公告)日：2009-06-11
申请号：US12009873
申请日：2008-01-23
申请人： Jens Krause , James-Michael Barnes , Manfred Schmidt , Wieland Hovestadt
发明人： Jens Krause , James-Michael Barnes , Manfred Schmidt , Wieland Hovestadt
IPC分类号： C08G18/10 , C08G18/28
CPC分类号： C08G18/4854 , C08G18/10 , C08G18/3814 , C08G18/4238 , C08G18/758 , C08G18/7671 , C08G2380/00
摘要： Polyurethane prepolymers are described which are prepared from 2,4′-diiso-cyanate diphenylmethane (2,4′-MDI), a polyol component and an aliphatic diisocyanate. These prepolymers can be cured with aliphatic, cycloaliphatic and/or aromatic amines to form a cured urethane elastomer. In comparison to cured urethane elastomers based on monomeric 2,4′-MDI, these prepolymers provide elastomers with extended pour life, i.e. they exhibit a slower rate of viscosity buildup after curative and prepolymer are mixed which results in a reduced propensity to crack during the curing process and gives the opportunity to cast larger parts. In comparison to polyurea/urethanes prepared from cured TDI-prepolymers and which optionally include H12-MDI, the prepolymers of the invention have better health and safety aspects.
摘要翻译：描述了由2,4'-二异氰酸酯二苯基甲烷（2,4'-MDI），多元醇组分和脂族二异氰酸酯制备的聚氨酯预聚物。这些预聚物可以用脂肪族，脂环族和/或芳族胺固化以形成固化的聚氨酯弹性体。与基于单体2,4'-MDI的固化的聚氨酯弹性体相比，这些预聚物提供具有延长的浇注寿命的弹性体，即它们在固化剂和预聚物混合后表现出较慢的粘度增长速率，这导致在固化过程，给予机会铸造更大的零件。与由固化的TDI-预聚物制备并且任选地包括H12-MDI的聚脲/聚氨酯相比，本发明的预聚物具有更好的健康和安全性。

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