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1. 发明授权

US4006201A Process for the production of polyvinyl chloride graft copolymers 失效
标题翻译：生产聚氯乙烯接枝共聚物的方法
公开(公告)号：US4006201A
公开(公告)日：1977-02-01
申请号：US502869
申请日：1974-09-03
申请人： Johann Bauer , Klaus Adler , Gerhard Beier , Heinz Hefner , Alex Sabel
发明人： Johann Bauer , Klaus Adler , Gerhard Beier , Heinz Hefner , Alex Sabel
IPC分类号： C08F14/00 , C08F255/00 , C08F255/02 , C08F263/04 , C08F263/00 , C08L31/04
CPC分类号： C08F255/026 , C08F263/04
摘要： A process for the production of polyvinyl chloride graft copolymers from ethylene/vinyl acetate copolymers and vinyl chloride by graft polymerization in the aqueous phase consisting essentially of adding a water-soluble, free-radical-forming polymerization catalyst to an aqueous dispersion of an ethylene/vinyl acetate copolymer optionally containing additional emulsifiers and/or dispersion stabilizers, heating said dispersion to the polymerization temperature, adding vinyl chloride gas above said agitated heated dispersion at such rate that the pressure is below the saturation pressure of vinyl chloride at the polymerization temperature, and recovering said polyvinyl chloride grafted copolymer.
摘要翻译：一种通过在水相中接枝聚合从乙烯/乙酸乙烯酯共聚物和氯乙烯生产聚氯乙烯接枝共聚物的方法，其基本上是将水溶性形成自由基的聚合催化剂加入到乙烯/ 乙酸乙烯酯共聚物，任选地含有另外的乳化剂和/或分散稳定剂，将所述分散体加热到聚合温度，在聚合温度下，使压力低于氯乙烯饱和压力的速率加入所述搅拌的加热分散体上方的氯乙烯气体，回收所述聚氯乙烯接枝共聚物。

2. 发明授权

US3960986A Impact-resistant molding compositions containing polyvinyl chloride 失效
标题翻译：含有聚氯乙烯的抗冲击成型组合物
公开(公告)号：US3960986A
公开(公告)日：1976-06-01
申请号：US485325
申请日：1974-07-03
申请人： Friedrich Heichele , Georg Vojtechovsky , Georg Hollenbach , Klaus Adler , Johann Bauer
发明人： Friedrich Heichele , Georg Vojtechovsky , Georg Hollenbach , Klaus Adler , Johann Bauer
IPC分类号： C08L27/00 , C08L1/00 , C08L23/00 , C08L27/06 , C08L31/04 , C08L51/00 , C08L51/02 , C08L51/06 , C08L101/00 , C08L91/06
CPC分类号： C08L27/06 , C08L51/003 , C08L31/04 , C08L51/06
摘要： Impact-resistant molding compositions consisting essentially ofA. from 20% to 80% by weight of polyvinyl chloride having a K-value of from 55 to 70,B. from 19.5% to 75% by weight of a vinyl chloride grafted copolymer of ethylene and vinyl acetate, said copolymer having from 30% to 55% by weight of vinyl acetate monomer units and a Mooney viscosity of from 20 to 50, said vinyl chloride grafted copolymer having from 5% to 15% by weight of said copolymer and a K-value of from 55 to 70, andC. from 0.5% to 5% by weight of an ethylene/vinyl acetate copolymer having from 60% to 70% by weight of vinyl acetate monomer units.
摘要翻译：抗冲击成型组合物，主要由A组成，20重量％至80重量％的K值为55至70的聚氯乙烯，B。19.5％至75重量％的乙烯基氯乙烯接枝共聚物和乙酸乙烯酯，所述共聚物具有30重量％至55重量％的乙酸乙烯酯单体单元，门尼粘度为20至50，所述氯乙烯接枝共聚物具有5重量％至15重量％的所述共聚物和K 的值为55至70，C为0.5至5重量％的具有60重量％至70重量％的乙酸乙烯酯单体单元的乙烯/乙酸乙烯酯共聚物。

3. 发明授权

US4043962A Particulated rubber and plastics coverings and binders therefor 失效
标题翻译：颗粒状橡胶和塑料覆盖物及其粘合剂
公开(公告)号：US4043962A
公开(公告)日：1977-08-23
申请号：US618447
申请日：1975-10-01
申请人： Klaus Adler , Engelbert Pichler , Christoph Kemenater , Wilfried Dressler , Johann Bauer
发明人： Klaus Adler , Engelbert Pichler , Christoph Kemenater , Wilfried Dressler , Johann Bauer
IPC分类号： B29C67/00 , B29B11/00 , B29B15/00 , B29B17/00 , B29B17/04 , B29C31/00 , B29C41/00 , B29C65/52 , B29D7/00 , B32B27/14 , C08L61/00 , C08L101/00 , C09J161/00 , E01C13/00 , E01C13/06 , C08L61/10 , C08L61/24 , C10M3/04
CPC分类号： E01C13/065 , C08L101/00 , C08L61/00 , Y10T428/2991 , Y10T428/2998
摘要： A readily dryable adhesive binder for particulated rubber and/or plastics compositions comprising from 1% to 10% by weight of a water-solubleformaldehyde polycondensation resin, from 0.5% to 5% by weight of formaldehyde or a compound liberating formaldehyde, and from 85% to 98.5% by weight of a film-forming plastics dispersion; as well as a composition forming a resilient covering comprising from 40% to 75% by weight of particulated rubber and/or plastics and from 25% to 60% by weight of the above adhesive binder.
摘要翻译：一种用于颗粒状橡胶和/或塑料组合物的容易干燥的粘合剂粘合剂，其包含1重量％至10重量％的水溶性甲醛缩聚树脂，0.5重量％至5重量％的甲醛或释放甲醛的化合物和85重量％至98.5重量％的成膜塑料分散体; 以及形成弹性覆盖物的组合物，其包含40重量％至75重量％的微粒橡胶和/或塑料和25重量％至60重量％的上述粘合剂粘合剂。

4. 发明授权

US4062715A Adhesive composition and method for bonding polyolefin surfaces with metal surfaces 失效
标题翻译：用于将聚烯烃表面与金属表面粘合的粘合剂组合物和方法
公开(公告)号：US4062715A
公开(公告)日：1977-12-13
申请号：US678957
申请日：1976-04-21
申请人： Erich Manner , Klaus Adler , Engelbert Pichler , Johann Bauer , Hans Sommer
发明人： Erich Manner , Klaus Adler , Engelbert Pichler , Johann Bauer , Hans Sommer
IPC分类号： C08J5/12 , C08L9/00 , C09J123/08 , C09J131/04 , C09J5/00
CPC分类号： C09J131/04 , C08J5/127 , C09J123/0853 , C08J2323/02 , C08L9/00 , Y10T428/31696 , Y10T428/31699 , Y10T428/31917 , Y10T428/31928 , Y10T428/31935 , Y10T428/31938
摘要： An adhesion assistant or binder composition for bonding polyolefin surfaces with metal surfaces comprising an aqueous dispersion of an ethylene/vinyl acetate copolymer from 0.5 to 5 parts by weight based on 100 parts of the copolymer of a cross-linking peroxide compound and from 1 to 10 parts by weight based on 100 parts of the copolymer of a low-molecular-weight 1,2-polybutadiene; as well as a process for producing composite bodies by heat and pressure utilizing the above adhesion assistant between polyolefin surfaces and metal surfaces.
摘要翻译：用于将聚烯烃表面与金属表面粘合的粘合助剂或粘合剂组合物，其包含乙烯/乙酸乙烯酯共聚物的水分散体，基于100份交联过氧化物的共聚物和1至10重量份，为0.5至5重量份基于100份低分子量1,2-聚丁二烯的共聚物重量份; 以及利用上述粘合助剂在聚烯烃表面和金属表面之间通过热和压力生产复合体的方法。

5. 发明授权

US4337323A Stabilized aqueous dispersions of vinyl chloride polymers 失效
标题翻译：稳定的氯乙烯聚合物水分散体
公开(公告)号：US4337323A
公开(公告)日：1982-06-29
申请号：US204428
申请日：1980-11-06
申请人： Klaus Adler , Klaus Hafener , Herbert Eck
发明人： Klaus Adler , Klaus Hafener , Herbert Eck
IPC分类号： C08L27/00 , C08K3/18 , C08K5/16 , C08K5/17 , C08L1/00 , C08L33/00 , C08L33/02 , C09D127/04 , C09J127/04
CPC分类号： C08K5/175
摘要： Stabilized aqueous dispersions of vinyl chloride polymer having at least 25% by weight of vinyl chloride units in the polymer and having K values of between 20 and 80, having added as a stabilizing agent 0.3-6% by weight of substances selected from the group of compounds according to the general formula ##STR1## wherein n has the meaning of from 0 to 2 or water-soluble salts thereof. The invention also relates to a process of producing the stabilized products by adding the stabilizing agent after polymerization in aqueous dispersion, and to the use of the stabilized dispersions in binders, coating compositions, paints, adhesives, textile auxiliaries and paper-coating compositions.
摘要翻译：在聚合物中具有至少25重量％氯乙烯单元并且K值在20和80之间的氯乙烯聚合物的稳定水分散体，其中加入作为稳定剂的0.3-6重量％的选自以下的物质：根据通式的化合物，其中n具有0至2的含义或其水溶性盐。本发明还涉及通过在水分散体中聚合后添加稳定剂以及在粘合剂，涂料组合物，油漆，粘合剂，纺织助剂和纸涂层组合物中使用稳定的分散体来生产稳定化产物的方法。

6. 发明授权

US4208319A Process for the preparation and use of silanes 失效
标题翻译：硅烷的制备和使用方法
公开(公告)号：US4208319A
公开(公告)日：1980-06-17
申请号：US852129
申请日：1977-11-16
申请人： Peter August , Peter Huber , Klaus Adler , Wilfried Dressler
发明人： Peter August , Peter Huber , Klaus Adler , Wilfried Dressler
IPC分类号： C08K5/00 , C07F7/18 , C08K5/5425 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L101/00 , C08J3/24 , C08L51/04
CPC分类号： C07F7/182 , C08K5/5425
摘要： Organosilanes containing aliphatic double bonds and a process for preparing the same which comprises reacting an organic compound having more than one aliphatic double bond with a silane having an Si-bonded hydrogen atom and at least one hydrolyzable group and/or at least one group capable of being hydrolyzed more readily than the Si-bonded hydrogen atom in the presence of a catalyst which promotes the addition of Si-bonded hydrogen atoms to aliphatic double bonds.These organosilanes are used as reinforcing agents for compositions containing organic polymers which are crosslinked by means of sulfur or free radicals.
摘要翻译：含有脂族双键的有机硅烷及其制备方法，其包括使具有多于一个脂族双键的有机化合物与具有Si键合氢原子的硅烷和至少一个可水解基团和/或至少一个能够在促进将Si键合的氢原子加成脂族双键的催化剂存在下，比Si键合的氢原子更容易水解。这些有机硅烷用作用于通过硫或自由基交联的含有机聚合物的组合物的增强剂。

7. 发明授权

US06569939B2 Polymer composition for flexibilizing building materials 失效
标题翻译：用于柔性建筑材料的聚合物组合物
公开(公告)号：US06569939B2
公开(公告)日：2003-05-27
申请号：US09799240
申请日：2001-03-05
申请人： Herbert Eck , Klaus Adler , Hermann Lutz , Heinrich Hopf
发明人： Herbert Eck , Klaus Adler , Hermann Lutz , Heinrich Hopf
IPC分类号： C08L8304
CPC分类号： C08K5/54 , C04B24/2641 , C04B24/2688 , C04B24/42 , C04B28/02 , C04B2103/0057 , C04B2111/00663 , C08K5/5419 , C08K5/5455 , Y10S516/04 , Y10S516/05 , Y10S516/06 , Y10S516/07 , Y10S516/906 , Y10S516/914 , Y10S516/917 , C04B14/06 , C04B20/0048 , C04B40/0608 , C04B2103/32 , C04B2103/50
摘要： The invention provides a polymer composition for flexibilizing building materials, in the form of their aqueous dispersion or of powder redispersible in water, containing a) at least one water-insoluble, film-forming polymer of one or more ethylenically unsaturated monomers capable of free radical polymerization, b) at least one compound from the group consisting of the water-soluble polymers of one or more ethylenically unsaturated monomers capable of free radical polymerization, and the ionic and nonionic emulsifiers, and c) a mixture of at least two organosilicon compounds, at least one of which is an amino-functional organosilicon compound present in salt form.
摘要翻译：本发明提供了一种聚合物组合物，用于以其水分散体形式或可再分散于水中的粉末形式的建筑材料的柔性化，其包含：a）至少一种能够自由基聚合的一种或多种烯属不饱和单体的不溶于水的成膜聚合物 b）至少一种由一种或多种能够自由基聚合的烯属不饱和单体的水溶性聚合物组成的组，以及离子和非离子乳化剂，以及c）至少两种有机硅化合物的混合物，至少其中之一是以盐形式存在的氨基官能的有机硅化合物。

8. 发明授权

US06534177B2 Crosslinkable polymer composition 失效
标题翻译：可交联聚合物组合物
公开(公告)号：US06534177B2
公开(公告)日：2003-03-18
申请号：US09773960
申请日：2001-01-25
申请人： Klaus Kohlhammer , Klaus Adler , Herbert Eck , Hermann Lutz
发明人： Klaus Kohlhammer , Klaus Adler , Herbert Eck , Hermann Lutz
IPC分类号： B32B2738
CPC分类号： C08L63/00 , C04B24/2641 , C04B24/281 , C09D133/068 , Y10T428/31511 , Y10T428/31891 , Y10T428/31895 , C08L2666/04 , C08L2666/14
摘要： Crosslinkable polymer compositions are provided which can be in the form of a polymer powder which is redispersible in water or as an aqueous dispersion. The polymer composition is composed of A) a copolymer of one or more comonomers of vinyl esters of straight-chain or branched alkanecarboxylic acids having 1 to 18 C atoms, acrylates or methacrylates of branched or straight-chain alcohols having 1 to 15 C atoms, dienes, olefins, vinylaromatics and vinyl halides, and of from 0.1 to 10% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated comonomers containing epoxide groups, and B) one or more non-copolymerizable compounds having at least two epoxide groups. The invention furthermore relates to a process for the preparation of the crosslinkable polymer compositions and their use in chemical products for the construction industry.
摘要翻译：提供可交联的聚合物组合物，其可以是可再分散在水中或作为水分散体的聚合物粉末的形式。聚合物组合物由以下组成：A）具有1至18个C原子的直链或支链链烷羧酸的乙烯基酯的一种或多种共聚单体的共聚物，具有1至15个C原子的支链或直链醇的丙烯酸酯或甲基丙烯酸酯，二烯，烯烃，乙烯基芳烃和乙烯基卤化物，和基于共聚单体总重量的0.1至10重量％的一种或多种含有环氧基团的烯属不饱和共聚单体，和B）一种或多种不可共聚的化合物，其具有至少两个环氧基。本发明还涉及制备可交联聚合物组合物的方法及其在建筑工业化学产品中的用途。

9. 发明授权

US4397968A Process for the manufacture of copolymers having increased resistance against hydrolysis, the copolymers and their use 失效
标题翻译：具有增加的抗水解性，共聚物及其用途的共聚物的制造方法
公开(公告)号：US4397968A
公开(公告)日：1983-08-09
申请号：US327351
申请日：1981-12-04
申请人： Herbert Eck , Klaus Adler , Manfred Hannebaum , Wilhelm Lechner
发明人： Herbert Eck , Klaus Adler , Manfred Hannebaum , Wilhelm Lechner
IPC分类号： C08L29/00 , C08F2/20 , C08F2/22 , C08F2/44 , C08F12/08 , C08F20/12 , C08L29/04 , C08L33/00 , C08L33/02 , C08L33/04 , C08K9/00
CPC分类号： C08F12/08 , C08F20/12
摘要： A process for the production of an aqueous dispersion stabilized by a water-soluble polyvinyl alcohol and based on copolymers that comprise at least 60% by weight of monomer units selected from the group consisting of esters of acrylic acid, esters of methacrylic acid, styrene, and substituted styrene and mixtures thereof, consisting essentially of subjecting a stabilized dispersion of a monomer mixture containing at least 60% by weight of monomers selected from the group consisting of esters of acrylic acid, esters of methacrylic acid, styrene, substituted styrene and mixtures thereof, said dispersion being an aqueous dispersion stabilized by a water-soluble polyvinyl alcohol, to polymerization at a temperature in excess of 60.degree. C. in the presence of a free-radical-forming catalyst selected from the group consisting of (a) organic catalysts soluble in the monomers and also being at least partially water-soluble, optionally in combination with water-soluble reducing agents and (b) peroxosulfur catalysts, in such a manner that, during the entire duration of the reaction, said monomer mixture is supplied at such a rate by metering in the monomer mixture in the form of a previously obtained emulsion, that the monomer concentration is maintained at less than 20% by weight, based on the total weight of the reaction mixture, and recovering said stabilized dispersion; as well as the aqueous dispersion produced by the process, the use of the aqueous dispersions as a binder in dispersion dyes and adhesives, the said binder having increased resistance against hydrolysis on drying due to the special manufacturing process.
摘要翻译：一种制备由水溶性聚乙烯醇稳定的水性分散体的方法，并且基于共聚物，所述共聚物包含至少60重量％的单体单元，所述单体单元选自丙烯酸的酯，甲基丙烯酸的酯，苯乙烯，和取代的苯乙烯及其混合物，基本上由以下组成的单体混合物的稳定分散体：含有至少60重量％的选自丙烯酸的酯，甲基丙烯酸的酯，苯乙烯，取代的苯乙烯及其混合物的单体的混合物所述分散体是由水溶性聚乙烯醇稳定的水分散体，在自由基形成催化剂存在下，在超过60℃的温度下聚合，所述自由基形成催化剂选自（a）有机催化剂可溶于单体，并且至少部分为水溶性，任选与水溶性还原剂组合，和（b）pe 罗莫硫磺催化剂，使得在反应的整个持续时间期间，所述单体混合物以预先获得的乳液形式的单体混合物中的计量以这样的速率供应，单体浓度保持在小于 20重量％，基于反应混合物的总重量，并回收所述稳定的分散体; 以及通过该方法制备的水分散体，在分散染料和粘合剂中使用水性分散体作为粘合剂，所述粘合剂由于特殊的制造工艺而具有增加的耐干燥水解性。

10. 发明授权

US5753733A Redispersible, silicon-modified dispersion powder composition, process for its preparation and its use 失效
标题翻译：可再分散的硅改性分散粉组合物，其制备方法及其用途
公开(公告)号：US5753733A
公开(公告)日：1998-05-19
申请号：US687507
申请日：1996-09-18
申请人： Herbert Eck , Heinrich Hopf , Klaus Adler , Franz Jodlbauer , Guenter von Au
发明人： Herbert Eck , Heinrich Hopf , Klaus Adler , Franz Jodlbauer , Guenter von Au
IPC分类号： C04B24/42 , C04B103/00 , C04B103/65 , C08F2/24 , C08F8/42 , C08F257/02 , C08F265/04 , C08F291/00 , C08J3/12 , C08K5/49 , C08K5/5419 , C08L25/02 , C08L27/06 , C08L31/02 , C08L31/04 , C08L33/04 , C08L33/06 , C08L43/00 , C08L43/04 , C08L47/00 , C08L51/00 , C08L57/00 , C08L73/00 , C08L83/02 , C08L83/04 , C08L83/16 , C08L87/00 , C09D151/00 , C09J151/00 , C08K3/34
CPC分类号： C09J151/003 , C04B24/2641 , C04B24/42 , C08F2/24 , C08F257/02 , C08F265/04 , C08F291/00 , C08F8/42 , C08J3/122 , C08L51/003 , C09D151/003
摘要： The invention concerns a dispersion powder composition which is redispersible in water and is made from water-insoluble homopolymers or copolymers of preferably ethylenically unsaturated monomers and one or more organosilicon compounds plus, optionally, other additives such as protective colloids and anti-blocking agents. The composition is obtained by: a) polymerizing one or more monomers in the presence of 0.1 to 30% by wt., relative to the total weight of the monomers, of one or more silicon compounds which are dispersible in water and which have a boiling point at normal pressure of >160.degree. C., selected from the group comprising the silanes, polysilanes, oligosiloxanes, polysiloxanes, carbosilanes, polycarbosilanes, carbosiloxanes, polycarbosiloxanes and polysilylenedisiloxanes and: b) spray-drying the product thus obtained, either before or after addition of the additives mentioned.
摘要翻译： PCT No.PCT / EP95 / 00281 Sec。 371日期1996年9月18日 102（e）1996年9月18日PCT PCT 1995年1月26日PCT公布。出版物WO95 / 20626 日期1995年8月3日本发明涉及一种分散粉末组合物，其可再分散于水中，并且由不溶于水的均聚物或优选烯键式不饱和单体与一种或多种有机硅化合物加任选的其它添加剂例如保护胶体和抗阻断剂。该组合物通过以下方法获得：a）在相对于单体的总重量为0.1-30重量％存在下，将一种或多种单体聚合成一种或多种可分散在水中并且具有沸点在常规压力> 160℃下，选自硅烷，聚硅烷，低聚硅氧烷，聚硅氧烷，碳硅烷，聚碳硅烷，碳硅氧烷，聚碳硅氧烷和聚硅氧烷二硅氧烷的组，并且b）在如此获得的产物之前或之后喷雾干燥添加所述添加剂。

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