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    • 3. 发明授权
    • Crosslinkable polymer composition
    • 可交联聚合物组合物
    • US06534177B2
    • 2003-03-18
    • US09773960
    • 2001-01-25
    • Klaus KohlhammerKlaus AdlerHerbert EckHermann Lutz
    • Klaus KohlhammerKlaus AdlerHerbert EckHermann Lutz
    • B32B2738
    • C08L63/00C04B24/2641C04B24/281C09D133/068Y10T428/31511Y10T428/31891Y10T428/31895C08L2666/04C08L2666/14
    • Crosslinkable polymer compositions are provided which can be in the form of a polymer powder which is redispersible in water or as an aqueous dispersion. The polymer composition is composed of A) a copolymer of one or more comonomers of vinyl esters of straight-chain or branched alkanecarboxylic acids having 1 to 18 C atoms, acrylates or methacrylates of branched or straight-chain alcohols having 1 to 15 C atoms, dienes, olefins, vinylaromatics and vinyl halides, and of from 0.1 to 10% by weight, based on the total weight of the comonomers, of one or more ethylenically unsaturated comonomers containing epoxide groups, and B) one or more non-copolymerizable compounds having at least two epoxide groups. The invention furthermore relates to a process for the preparation of the crosslinkable polymer compositions and their use in chemical products for the construction industry.
    • 提供可交联的聚合物组合物,其可以是可再分散在水中或作为水分散体的聚合物粉末的形式。 聚合物组合物由以下组成:A)具有1至18个C原子的直链或支链链烷羧酸的乙烯基酯的一种或多种共聚单体的共聚物,具有1至15个C原子的支链或直链醇的丙烯酸酯或甲基丙烯酸酯, 二烯,烯烃,乙烯基芳烃和乙烯基卤化物,和基于共聚单体总重量的0.1至10重量%的一种或多种含有环氧基团的烯属不饱和共聚单体,和B)一种或多种不可共聚的化合物,其具有 至少两个环氧基。 本发明还涉及制备可交联聚合物组合物的方法及其在建筑工业化学产品中的用途。
    • 4. 发明授权
    • Redispersable cross-linkable dispersion powders
    • 可再分散的可交联分散粉末
    • US6114423A
    • 2000-09-05
    • US983506
    • 1998-01-20
    • Herbert EckPeter JohnHermann Lutz
    • Herbert EckPeter JohnHermann Lutz
    • C08F2/22C08F2/24C08F6/22C08F210/00C08F212/06C08F214/06C08F218/04C08F230/08C08F236/04C08J3/12C09D143/04D06M15/356
    • C09D143/04C08F218/04C08J3/122D06M15/3568Y02P30/48
    • A dispersion powder of water-insoluble copolymers of ethylenically unsaturated monomers and optionally, further additives, which are redispersible in water and obtained by:a) emulsion polymerizing, at a pH of 2 to 9, a comonomer mixture of at least one comonomer selected from vinyl esters of unbranched or branched alkylcarboxylic acids having 1 to 18 carbon atoms, methacrylic acid esters of unbranched or branched alcohols having 1 to 18 carbon atoms, acrylic acid esters of unbranched or branched alcohols having 1 to 18 carbon atoms, olefins, dienes, vinylaromatics and vinyl halides, and 0.05 to 15.0% by weight, based on the total weight of the comonomer mixture, of at least one silicon compound of the formulaCH.sub.2 .dbd.CH--(CH.sub.2).sub.m --SiR(OR').sub.2,where m=0-8CH.sub.2 .dbd.CR"--CO.sub.2 --(CH.sub.2).sub.n SiR(OR').sub.2where n=1-6 ##STR1## b) spray drying aqueous dispersion, at a pH of 4 to 8 at a discharge temperature of 55 to 100.degree. C., before or after addition of any additives. The dispersion powders are useful as additives for hydraulic binders and binders in coating compositions and adhesives.
    • PCT No.PCT / EP96 / 03161 Sec。 371日期1998年1月20日 102(e)1998年1月20日PCT PCT 1996年7月18日PCT公布。 公开号WO97 / 04013 日期1997年2月6日一种烯键式不饱和单体的水不溶性共聚物和任选的其它添加剂的分散粉末,其可再分散在水中并通过以下方式获得:a)在pH为2至9的情况下乳液聚合共聚单体混合物 选自具有1至18个碳原子的无支链或支链烷基羧酸的乙烯基酯的至少一种共聚单体,具有1至18个碳原子的无支链或支链醇的甲基丙烯酸酯,具有1至18个碳原子的无支链或支链醇的丙烯酸酯, 至少一种式CH 2(CH 2)m -SiR(OR')2的硅化合物和基于共聚单体混合物的总重量的0.05至15.0重量%的烯烃,二烯,乙烯基芳烃和乙烯基卤化物,和0.05至15.0重量% ,其中m = 0-8CH2 = CR“-CO2-(CH2)nSiR(OR')2其中n = 1-6b)喷雾干燥水分散体,pH为4至8,排出温度为55至100 在加入任何添加剂之前或之后。 分散粉末可用作水性粘合剂和涂料组合物和粘合剂中的粘合剂的添加剂。