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1. 发明授权

US4645817A Preparation of hydroxyl group-containing alkoxylation products of organic carboxylic acids 失效
标题翻译：有机羧酸的含羟基烷氧基化产物的制备
公开(公告)号：US4645817A
公开(公告)日：1987-02-24
申请号：US722567
申请日：1985-04-11
申请人： Joachim Probst , Michael Sonntag , Roland Richter , Hanns P. Muller
发明人： Joachim Probst , Michael Sonntag , Roland Richter , Hanns P. Muller
IPC分类号： C08G18/00 , C07B31/00 , C07B41/12 , C07C67/00 , C08F8/00 , C08G18/42 , C08G18/48 , C08G18/62 , C08G65/10 , C08G65/26 , C08G18/80 , C08F20/62 , C08G18/16 , C08G63/42
CPC分类号： C08G65/2645 , C08F8/00 , C08G18/6258 , C08G65/105 , C08G65/2615 , C08G65/2669
摘要： The present invention relates to a process for the preparation of alkoxylation products of organic carboxylic acids containing alcoholic hydroxyl groups by the reaction of any organic compounds containing at least one carboxyl group with alkylene oxides in an alkoxylation reaction in the presence of catalysts, characterized in that the catalysts used are phase transfer catalysts selected from the group consisting of(a) tetraalkylammonium or tetraalkylphosphonium halides in which the sum of carbon atoms of the alkyl groups is at least 8,(b) basic alkali metal compounds converted into complexes with crown ethers and(c) complexes of (i) basic alkali metal compounds and (ii) acyclic organic compounds containing at least 5 alkylene oxide units of the formula --R--O-- (R=C.sub.1 -C.sub.4 -alkylene) in the form of one or more polyether chains having at least 3 alkylene oxide units, said compounds having a molecular weight of at least 238 and containing a total of at least 40% by weight of alkylene oxide units of the type indicated in polyether chains having at least 3 alkylene oxide units.The present invention also relates to the use of these alkoxylation products for the production of polyurethanes by reaction with organic polyisocyanates.
摘要翻译：本发明涉及一种在催化剂存在下通过烷氧基化反应中含有至少一个羧基的任何有机化合物与烯化氧的反应来制备含醇羟基的有机羧酸的烷氧基化产物的方法，其特征在于：所使用的催化剂是选自（a）四烷基铵或四烷基鏻卤化物的相转移催化剂，其中烷基的碳原子总数至少为8，（b）碱基碱金属化合物与冠醚转化为络合物，（c）碱性碱金属化合物和（ii）含有至少5个式-RO-（R = C 1 -C 4 - 亚烷基）的氧化烯单元的一种或多种聚醚链形式的无环有机化合物的络合物具有至少3个烯化氧单元，所述化合物的分子量至少为238，并且含有至少40重量％的环氧烷烃具有至少3个氧化烯单元的聚醚链中所示类型的单元。本发明还涉及这些烷氧基化产物通过与有机多异氰酸酯反应生产聚氨酯的用途。

2. 发明授权

US4918135A Process for the preparation of aqueous polymer dispersions the dispersions obtained by the process and their use for the production of coatings 失效
标题翻译：制备聚合物水性聚合物的方法分散了通过该方法获得的分散体及其用于生产涂料的用途
公开(公告)号：US4918135A
公开(公告)日：1990-04-17
申请号：US335816
申请日：1989-04-10
申请人： Joachim Probst , Walter Schafer , Klaus Schuster , Heinrich Alberts , Hanns P. Muller , Adolf Schmidt , Wolfhart Wieczorrek
发明人： Joachim Probst , Walter Schafer , Klaus Schuster , Heinrich Alberts , Hanns P. Muller , Adolf Schmidt , Wolfhart Wieczorrek
IPC分类号： B01F17/52 , C08F2/24 , C08F2/26 , C09D133/06
CPC分类号： C08F2/24 , C09D133/06
摘要： An improved coating for heat resistant substrates is an aqueous dispersion of polymers prepared by polymerization of olefinically unsaturated monomers in an aqueous medium in the presence of radical formers and emulsifiers, wherein the emulsifiers are polyisocyanate addition products having a molecular weight below 20,000 and containing from 5 to 1000 milliequivalents of anionic structures corresponding to the following formula--NH--CO--N.sup..crclbar. --C.tbd.Nincorporated therein per 100 g of solids content.
摘要翻译：用于耐热基材的改进的涂层是通过在自由基形成剂和乳化剂存在下在水性介质中聚合烯属不饱和单体制备的聚合物的水分散体，其中乳化剂是分子量低于20,000的多异氰酸酯加成产物，并含有5 至每1000克固体含量相应于下式-NH-CO-N（ - ） - C 3BOND N的1000毫当量阴离子结构。

3. 发明授权

US06962953B2 Aqueous secondary dispersions 有权
标题翻译：水性二次分散体
公开(公告)号：US06962953B2
公开(公告)日：2005-11-08
申请号：US10174034
申请日：2002-06-18
申请人： Joachim Probst , Martin Melchiors , Wieland Hovestadt , Michael Sonntag , Burkhard Köhler , Bernhard Jansen
发明人： Joachim Probst , Martin Melchiors , Wieland Hovestadt , Michael Sonntag , Burkhard Köhler , Bernhard Jansen
IPC分类号： C08L53/00 , C09D153/00 , C08F2/00 , C08L33/14 , C08L47/10
CPC分类号： C08L53/00 , C09D153/00 , Y10T428/31855 , C08L2666/04 , C08L2666/02
摘要： The present invention relates to heat and storage stable vinyl polymer polyol secondary dispersions containing A) at least one vinyl polymer resin having functional groups selected from hydroxyl, carboxyl and/or sulfonic acid groups and dispersed in a water/solvent mixture in the presence of a neutralizing agent, and B) at least one amphiphilic polymer built up from a hydrophobic and a hydrophilic segment. The invention also relates to a process for the preparation of the vinyl polymer polyol secondary dispersions by preparing vinyl polymer resin A) by polymerizing a mixture of ethylenically unsaturated monomers a) in the presence of an initiator b) in a water/solvent mixture and adding at least one amphiphilic polymer B), then at least partly neutralizing and dispersing the resulting product, optionally after the addition of a further amount of water.
摘要翻译：本发明涉及储存稳定的乙烯基聚合物多元醇二次分散体，其包含A）至少一种具有选自羟基，羧基和/或磺酸基团的官能团的乙烯基聚合物树脂，并分散在水/溶剂混合物中中和剂，和B）由疏水和亲水链段构成的至少一种两亲性聚合物。本发明还涉及通过制备乙烯基聚合物多元醇二次分散体来制备乙烯基聚合物多元醇二次分散体的方法，其通过在引发剂b）存在下在水/溶剂混合物中聚合烯键式不饱和单体a）的混合物并加入至少一种两亲聚合物B），然后至少部分地中和和分散所得产物，任选地在加入另外量的水之后。

4. 发明授权

US5331039A Water-based binder composition and its use for the production of coating or sealing compositions 失效
标题翻译：水性粘合剂组合物及其用于生产涂料或密封组合物的用途
公开(公告)号：US5331039A
公开(公告)日：1994-07-19
申请号：US973368
申请日：1992-11-09
申请人： Harald Blum , Werner Kubitza , Joachim Probst , Michael Sonntag , Volker Schneider
发明人： Harald Blum , Werner Kubitza , Joachim Probst , Michael Sonntag , Volker Schneider
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/40 , C08G18/42 , C08G18/46 , C08G18/70 , C08L75/04 , C09D175/04 , C09D175/06 , C09J175/00 , C09J175/06 , H01L23/29 , H01L23/31 , C08L67/00
CPC分类号： C09D175/06 , C08G18/0819 , C08G18/10 , C08G18/4063 , C08G18/4202 , C08G18/706 , C08G2170/80
摘要： The present invention relates to a water-based binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containing a mixture of at least 5% by weight each of at least two hydroxy-functional polymers selected fromA1) polyester resins containing hydroxyl, urethane and carboxylate groups,A2) polyester resins containing hydroxyl and carboxylate groups, but no urethane or sulfonate groups,A3) polyester resins containing hydroxyl and sulfonate groups and, optionally, carboxylate groups and/or urethane groups,A4) polyacrylate resins containing hydroxyl, carboxylate and/or sulfonate groups,A5) acrylate-grafted polyester resins containing hydroxyl, carboxylate and/or sulfonate groups, andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.s and contains at least one organic polyisocyanate,wherein the NCO:OH equivalent ratio, based on the isocyanate groups of component B) and the hydroxyl groups of the polyol component present in A), is 0.2:1 to 5:1.The present invention also relates to a process for the production of a coating or sealing composition containing this aqueous binder composition.
摘要翻译：本发明涉及水性粘合剂组合物，其包含A）水可稀释有机多元醇组分的水溶液或分散体，其含有至少5重量％的至少两种羟基官能聚合物的混合物，所述羟基官能聚合物选自A1）含有羟基，氨基甲酸酯和羧酸酯基团的聚酯树脂，A2）含有羟基和羧酸酯基团但不含氨基甲酸酯基或磺酸酯基团的聚酯树脂，A3）含有羟基和磺酸酯基团以及任选的羧酸酯基团和/或氨基甲酸酯基团的聚酯树脂，A4）含有羟基，羧酸酯和/或磺酸酯基的聚丙烯酸酯树脂，A5）含有羟基，羧酸酯和/或磺酸酯基团的丙烯酸酯接枝的聚酯树脂，和B）在水溶液或分散体A）中乳化的多异氰酸酯组分具有粘度在23℃下为50至10,000mPa.s并含有至少一种有机多异氰酸酯，其中NCO:OH当量比基于异氰酸酯组分B）的组分和A）中存在的多元醇组分的羟基为0.2:1至5:1。本发明还涉及一种生产包含该含水粘合剂组合物的涂料或密封组合物的方法。

5. 发明授权

US4293661A Low molecular weight acrylate resins containing hydroxyl and tertiary amino groups 失效
标题翻译：含有羟基和叔氨基的低分子量丙烯酸酯树脂
公开(公告)号：US4293661A
公开(公告)日：1981-10-06
申请号：US108349
申请日：1979-12-31
申请人： Joachim Probst , Michael Sonntag , Gunter Kolb
发明人： Joachim Probst , Michael Sonntag , Gunter Kolb
IPC分类号： C08F8/00 , C08F8/32 , C08G18/00 , C08G18/62 , C08G59/12 , C08G59/14 , C09D175/04 , C08F8/08
CPC分类号： C08G18/6237 , C08F8/32 , C08F2800/20
摘要： A reaction product of an acrylate resin containing glycidyl groups and secondary mono-amines containing hydroxyl groups, obtained by reacting of said acrylate resin of copolymerized, statistically distributed units of(A) 3 to 30% by weight of the glycidyl ester of (meth)acrylic acid and/or of vinyl glycidyl ether;(B) 0 to 20% by weight of at least a hydroxy C.sub.2 -C.sub.4 alkyl ester of (meth)acrylic acid;(C) 5 to 80% by weight of at least an optionally substituted styrene, methyl methacrylate, (meth)acrylonitrile or any mixture thereof;(D) 5 to 70% by weight of an acrylic acid C.sub.1 -C.sub.12 -alkyl-or of a methacrylic acid C.sub.2 -C.sub.12 -alkyl ester or any mixture thereof; and(E) 0 to 10% by weight of an .alpha.,.beta.-mono-olefinically unsaturated monocarboxylic or dicarboxylic acid containing from 3 to 5 carbon atoms or of a maleic acid C.sub.2 -C.sub.14 -mono ester or any mixture thereof,with at least one secondary mono-amine containing at least one secondary hydroxyl group. The reaction products are useful for crosslinking polyisocyanates.
摘要翻译：由（A）3〜30重量％的（甲基）丙烯酸缩水甘油酯的共聚统计分布单位的所述丙烯酸酯树脂与所述含有缩水甘油基的丙烯酸酯树脂和含有羟基的二次一元胺反应，丙烯酸和/或乙烯基缩水甘油醚; （B）0〜20重量％的（甲基）丙烯酸的至少羟基C 2 -C 4烷基酯; （C）5至80重量％的至少任选取代的苯乙烯，甲基丙烯酸甲酯，（甲基）丙烯腈或其任何混合物; （D）5-70重量％的丙烯酸C 1 -C 12烷基或甲基丙烯酸C 2 -C 12烷基酯或其任何混合物; 和（E）0至10重量％的含有3至5个碳原子的α，β-单烯属不饱和单羧酸或二羧酸或马来酸C2-C14-单酯或其任何混合物，至少具有一个含有至少一个仲羟基的二次单胺。反应产物可用于交联多异氰酸酯。

6. 发明授权

US6130285A Binder composition and its use for coating metallic and mineral substrates 失效
标题翻译：粘合剂组合物及其用于涂覆金属和矿物基材的用途
公开(公告)号：US6130285A
公开(公告)日：2000-10-10
申请号：US911510
申请日：1997-08-14
申请人： Martin Melchiors , Jurgen Schwindt , Gerhard Ruttmann , Wieland Hovestadt , Joachim Probst , Josef Pedain
发明人： Martin Melchiors , Jurgen Schwindt , Gerhard Ruttmann , Wieland Hovestadt , Joachim Probst , Josef Pedain
IPC分类号： C08G18/62 , C08G18/40 , C08G18/63 , C09D175/04 , C08L75/00
CPC分类号： C08G18/632 , C08G18/4063 , C08G18/638 , C08G2150/90
摘要： The present invention relates to a solvent-free, low viscosity binder composition which contains, in amounts sufficient to provide an NCO:OH equivalent ratio of 0.5:1 to 2.0:1,A) a polyisocyanate component containing one or more organic polyisocyanates andB) a solvent-free polyhydroxy component having a hydroxyl group content of 3.0 to 18 wt. % and a viscosity at 23.degree. C. of 200 to 10,000 mPa.s, which containsB.sub.1) a hydroxy-functional polyacrylate component which is prepared by polymerizing a mixture of olefinically unsaturated monomers in which at least one monomer is hydroxy-functional in the presence ofB.sub.2) a compound containing ether groups and having one or more hydroxy groups.The invention also relates to the use of this binder composition in solvent-free two-component polyurethane coating compositions for coating metallic or mineral substrates.
摘要翻译：本发明涉及无溶剂的低粘度粘合剂组合物，其含量足以提供0.5：1至2.0：1的NCO:OH当量比，A）含有一种或多种有机多异氰酸酯和B ）无羟基含量为3.0-18重量％的无溶剂多羟基组分％，在23℃下的粘度为200至10,000mPa.s，其含有B1）羟基官能的聚丙烯酸酯组分，其通过聚合烯属不饱和单体的混合物而制备，其中至少一种单体在存在B2）含有醚基并具有一个或多个羟基的化合物。本发明还涉及这种粘合剂组合物在无溶剂双组分聚氨酯涂料组合物中用于涂覆金属或矿物基材的用途。

7. 发明授权

US5468804A Water-soluble or water-dispersible polyisocyanate composition, a process for its preparation and its use in coating compositions 失效
标题翻译：水溶性或水分散性多异氰酸酯组合物，其制备方法及其在涂料组合物中的应用
公开(公告)号：US5468804A
公开(公告)日：1995-11-21
申请号：US306335
申请日：1994-09-15
申请人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
发明人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
IPC分类号： C08G18/10 , C08G18/28 , C08G18/32 , C08G18/48 , C08G18/62 , C08G18/70 , C08G18/76 , C08G18/80 , C09D175/00 , C09D175/04 , C08J3/00 , B32B27/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/283 , C08G18/706 , C08G18/8035 , C08G18/8064 , Y10T428/31551
摘要： A water-dispersible polyisocyanate composition obtained by the partial urethanization of the isocyanate groups of 2,4- and/or 2,6-diisocyanatotoluene with monohydric and polyhydric alcohols, a process for its production, its use as the binder for an aqueous two-component coating composition in combination with a water-soluble or water-dispersible polyhydroxyl component and coatings for water-resistant sheet-form substrates prepared from this coating composition.
摘要翻译：通过2,4-和/或2,6-二异氰酸基甲苯与一元醇和多元醇的异氰酸酯基团的部分氨基甲酸酯化获得的水分散性多异氰酸酯组合物，其生产方法，其用作二级和多元醇的粘合剂，组合涂料组合物与水溶性或水分散性多羟基组分的组合以及由该涂料组合物制备的用于防水片状基材的涂料。

8. 发明授权

US4997873A Copolymers containing perfluoroalkyl groups 失效
标题翻译：含全氟烷基的共聚物
公开(公告)号：US4997873A
公开(公告)日：1991-03-05
申请号：US355727
申请日：1989-05-22
申请人： Carlhans Suling , Jutta Rottger , Henning Bachem , Joachim Probst , Wilfried Kortmann
发明人： Carlhans Suling , Jutta Rottger , Henning Bachem , Joachim Probst , Wilfried Kortmann
IPC分类号： B01F17/52 , C08F2/16 , C08F2/22 , C08F2/28 , C08F20/34 , C08F20/52 , C08F212/00 , C08F212/08 , C08F220/24 , C08F220/34 , C08F220/60 , C08F265/00 , C08F267/06 , D06M13/02 , D06M13/07 , D06M13/224 , D06M13/236 , D06M13/322 , D06M13/402 , D06M13/41 , D06M15/277 , D06M101/00 , D06M101/16 , D06M101/30 , D06M101/34
CPC分类号： C08F220/24 , C08F265/00 , D06M15/277
摘要： Aqueous dispersions of copolymers and graft copolymers which are formed from ethylenically unsaturated perfluoroalkyl monomers and ethylenically unsaturated monomers from from perfluoroalkyl groups and which are prepared in the presence of emulsifiers containing cationic groups are used for imparting a water-repellent and oleo-repellent finish to textiles, leather and paper.
摘要翻译：由烯属不饱和全氟烷基单体和烯属不饱和单体由全氟烷基形成并且在含有阳离子基团的乳化剂存在下制备的共聚物和接枝共聚物的水分散体用于赋予纺织品拒水拒油，皮革和纸张。

9. 发明授权

US4806591A Cationic sizing agents for paper 失效
标题翻译：阳离子上胶剂纸
公开(公告)号：US4806591A
公开(公告)日：1989-02-21
申请号：US921173
申请日：1986-10-20
申请人： Joachim Probst , Heinz Baumgen , Bruno Bomer , Joachim Konig , Renke Mottweiler
发明人： Joachim Probst , Heinz Baumgen , Bruno Bomer , Joachim Konig , Renke Mottweiler
IPC分类号： C08F2/28 , C08F2/24 , C08F257/02 , D21H17/35 , D21H17/37 , D21H17/45 , C08L33/20
CPC分类号： D21H17/455 , C08F2/24 , C08F257/02 , D21H17/35 , D21H17/37
摘要： Cationic sizing agents for paper, obtainable by a process in which a water-soluble cationic terpolymer compound, built up in a chemically uniform manner, of (a) 7 to 40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate, (b) 40 to 80% by weight of styrene and (c) 4 to 50% by weight of acrylonitrile, the sum of components (a) to (c) always being 100% by weight and at least 10% of the dimethylamino groups of the terpolymer being quaternized with monoepoxides, with the exception of epihalogenohydrins, and the remainder being protonated, is dissolved in an aqueous medium and, in the presence of 10 to 70% by weight--based on the following monomer mixture--of this emulsifier, (d) 5 to 95% by weight of acrylonitrile, meth-acrylonitrile or styrene or mixtures thereof and (e) 5 to 95% by weight of acrylic acid ester and/or methacrylic acid ester with 1 to 12 C atoms in the alcohol radical--the sum of components (d) and (e) always being 100% by weight--are emulsified and the emulsion thus obtained is subjected to emulsion polymerization, initiated by free radicals, at temperatures of 20.degree. to 150.degree. C.
摘要翻译：可通过以下方法获得的阳离子上胶剂：其中以（a）7〜40重量％的N，N-二甲基氨基乙基丙烯酸酯和/或甲基丙烯酸酯组成的以化学均匀的方式构成的水溶性阳离子三元共聚物，（b）40至80重量％的苯乙烯和（c）4至50重量％的丙烯腈，组分（a）至（c）的总和总是100重量％，并且至少10重量％的二甲基氨基的三元共聚物被单过氧化物季铵化，除了表卤代醇，其余的被质子化，溶解在水性介质中，并且在该乳化剂的基于下列单体混合物的10至70重量％的存在下，（d）5至95重量％的丙烯腈，甲基丙烯腈或苯乙烯或其混合物，和（e）5至95重量％的醇基中具有1至12个C原子的丙烯酸酯和/或甲基丙烯酸酯组分（d）和（e）总是为100重量％的总和被乳化和乳液由此获得的乳液聚合在20℃至150℃的温度下由自由基引发。

10. 发明授权

US4165431A Chlorination of polyolefins in the presence of complex formers 失效
标题翻译：在复合成型剂存在下氯化聚烯烃
公开(公告)号：US4165431A
公开(公告)日：1979-08-21
申请号：US881675
申请日：1978-02-27
申请人： Franz Alfes , Diez Heine , Reinhard Kaiser , Gunter Kolb , Joachim Probst , Franz Weider
发明人： Franz Alfes , Diez Heine , Reinhard Kaiser , Gunter Kolb , Joachim Probst , Franz Weider
IPC分类号： C08F8/00 , C08F8/20 , C08F8/22
CPC分类号： C08F8/22
摘要： A chlorinated colorless polyolefin, preferably a chlorinated colorless isotactic polypropylene, soluble in carbon tetrachloride and having a chlorine content of from 60% to 70% by weight and an average degree of polymerization of from 2000 to 6000, produced by chlorinating polyolefins having a degree of polymerization of from 2000 to 20,000 in suspension or solution or in suspension and solution at 40 to 60.degree. C. in the presence of a halogen transfer agent, a chlorination catalyst and from 0.2 to 0.5% by weight, based on polyolefin, of at least one compound corresponding to the general Formula (I):h.sub.2 n--r--nh>.sub.n H (I)in which R represents the ethylene, propylene or butylene group and n=1-6.
摘要翻译：氯化无色聚烯烃，优选氯化无色全同立构聚丙烯，其可溶于四氯化碳，氯含量为60〜70重量％，平均聚合度为2000〜6000，通过氯化具有一定程度的聚烯烃在卤素转移剂，氯化催化剂和基于聚烯烃的0.2至0.5重量％的存在下，在悬浮液或溶液中或悬浮液和溶液中在40至60℃下聚合2000至20,000，至少对应于通式（I）的一种化合物：

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