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    • 3. 发明授权
    • Moisture curing, one-component coating compositions and their use for
the production of coatings
    • 水分固化,单组分涂料组合物及其在涂料生产中的应用
    • US5468833A
    • 1995-11-21
    • US359493
    • 1994-12-20
    • Jurgen SchwindtKarl-Heinz HentschelLutz Schmalstieg
    • Jurgen SchwindtKarl-Heinz HentschelLutz Schmalstieg
    • C08G18/10C08G18/72C08G18/76C08G18/78C08G18/79C09D175/00C09D175/04C08G18/00B32B27/00C08G18/70
    • C08G18/10Y10T428/31551
    • Moisture-curing, one-component coating compositions wherein the binder contains a mixture of A) 100 parts by weight of a polyisocyanate or polyisocyanate mixture of the diphenylmethane series, B) 40 to 150 parts by weight of NCO prepolymers with an NCO content of 1.5 to 12% by weight based on aromatic polyisocyanates and C) 10 to 90 parts by weight of at least one aliphatic lacquer polyisocyanate and the use of the coating compositions for the production of coatings on various substrates.The present invention relates to moisture-curing one-component coating compositions containing as binder a polyisocyanate component containingA) 100 parts by weight of a polyisocyanate or polyisocyanate mixture of the diphenyl methane series having an NCO content of 20 to 33% by weight,B) 40 to 150 parts by weight of one or more NCO prepolymers which have an NCO content of 1.5 to 12% by weight prepared from aromatic polyisocyanates andC) 10 to 90 parts by weight of an aliphatic polyisocyanate component containing one or more lacquer polyisocyanates based on hexamethylene diisocyanate.The present invention also relates to the use of these one-component coating compositions for coating various substrates.
    • 水分固化单组分涂料组合物,其中粘合剂含有A)100重量份的多异氰酸酯或二苯基甲烷系列的多异氰酸酯混合物的混合物,B)40至150重量份NCO含量为1.5的NCO预聚物 至12重量%,以及C)10至90重量份的至少一种脂肪族漆多异氰酸酯以及用于在各种基材上生产涂料的涂料组合物的用途。 本发明涉及含有A)100重量份NCO含量为20〜33重量%的二苯甲烷系聚异氰酸酯或多异氰酸酯混合物的100重量份聚乙烯 )40至150重量份的一种或多种NCO预聚物,其NCO含量为由芳族多异氰酸酯制备的1.5至12重量%,C)10至90重量份的含有一种或多种漆多异氰酸酯基的脂族多异氰酸酯组分 对六亚甲基二异氰酸酯。 本发明还涉及这些单组分涂料组合物用于涂覆各种基材的用途。
    • 7. 发明授权
    • Process for the production of elastic, optionally cellular, polyurethane
ureas
    • 用于生产弹性,任选细胞的聚氨酯脲的方法
    • US4294934A
    • 1981-10-13
    • US164752
    • 1980-06-30
    • Gerhard GroglerJurgen SchwindtOtto GansterHans-Joachim MeinersHans-Dieter Ruprecht
    • Gerhard GroglerJurgen SchwindtOtto GansterHans-Joachim MeinersHans-Dieter Ruprecht
    • C08G18/00C08G18/10C08G18/72C08G18/76C08G18/18C08G18/22
    • C08G18/7671C08G18/10C08G2101/0008C08G2350/00C08G2380/00C08G2410/00Y10S528/906
    • The instant invention is directed to a process for the production of polyurethane urea elastomers having a gross density of more than 200 kg/m.sup.3 comprising: casting a reaction mixture of(A) an isocyanate prepolymer produced from(a) 1 mole of a compound containing at least 2 Zerewitinoff-active hydrogen atoms and having a molecular weight of from 400 to 10,000 and(b) 2 to 10 moles of diisocyanatodiphenylmethane,(B) an aromatic diamine, and(C) 0 to 50 mole percent, based on component (B), of a polyol containing primary hydroxyl groups and having a molecular weight of from 62 to 6000, the equivalent ratio between component (A) and components (B) + (C) amounting to between 0.9:1 and 1.3:1,into a mold, hardening the reaction mixture in the mold and subsequently removing it from the mold, the improvement wherein said isocyanate prepolymer (A) has been produced using an isomer mixture comprising:from 15 to 80 mole percent of 2,4'-diisocyanatodiphenylmethane,from 20 to 85 mole percent of 4,4'-diisocyanatodiphenylmethane, andfrom 0 to 20 mole percent of 2,2'-diisocyanatodiphenylmethane.
    • 本发明涉及生产总密度大于200kg / m 3的聚氨酯脲弹性体的方法,包括:浇铸(A)异氰酸酯预聚物的反应混合物,该异氰酸酯预聚物由(a)1摩尔含有 至少2个Zerewitinoff活性氢原子,分子量为400至10,000,和(b)2至10摩尔二异氰酸二苯基甲烷,(B)芳族二胺和(C)0至50摩尔%,基于组分( B),含有伯羟基并且分子量为62至6000的多元醇,组分(A)和组分(B)+(C)之间的当量比为0.9:1至1.3:1,转化为 模具,使模具中的反应混合物硬化,随后将其从模具中除去,改进之处在于所述异氰酸酯预聚物(A)已经使用异构体混合物制备,所述异构体混合物包含:15至80摩尔%的2,4'-二异氰酸根合二苯基甲烷, 20至85摩尔%o f 4,4'-二异氰酸二苯基甲烷和0至20摩尔%的2,2'-二异氰酸二苯基甲烷。
    • 10. 发明授权
    • Process for the preparation of polyurethane casting elastomers
    • 制备聚氨酯浇铸弹性体的方法
    • US4263423A
    • 1981-04-21
    • US057936
    • 1979-07-16
    • Jurgen SchwindtHolger MeyborgGerhard GroglerKlaus Recker
    • Jurgen SchwindtHolger MeyborgGerhard GroglerKlaus Recker
    • C08G18/00C08G18/22C08G18/72C08G18/73C08G18/16C08G18/24C08G18/26
    • C08G18/72C08G18/22
    • The instant invention is directed to a process for the production of a light fast, transparent polyurethane elastomer comprising reacting:(A) from 90 to 50% by weight, based on the polyurethane solids content, of a compound having a molecular weight of from 400 to 10,000 which has at least two Zerewitinoff active hydrogen atoms;(B) from 50 to 10% by weight, based on the polyurethane solids content, of an aliphatic and/or alicyclic polyisocyanate; and(C) from 0 to 20% by weight, based on the polyurethane solids content, of a chain-lengthening agent having a molecular weight of from 60 to 400; in the presence of:(D) catalysts for the isocyanate polyaddition reaction, the improvement wherein said catalysts, component (D), is a catalyst combination of:(a) an alkali metal hydroxide and/or alkaline earth metal hydroxide; and(b) an organometallic compound selected from the group consisting of the acetyl acetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetyl acetonates of metals of the 4th main group or sulfur-containing compounds of metals of the 4th main group, in which compounds the sulfur is directly attached to the metal atom.
    • 本发明涉及一种生产轻质,透明的聚氨酯弹性体的方法,包括使(A)基于聚氨酯固体含量的90至50重量%的分子量为400的化合物 至10,000具有至少两个Zerewitinoff活性氢原子; (B)基于聚氨酯固体含量为50至10重量%的脂族和/或脂环族多异氰酸酯; 和(C)基于聚氨酯固体含量为0至20重量%的分子量为60至400的链延长剂; 在(D)用于异氰酸酯加聚反应的催化剂的存在下,其中所述催化剂组分(D)是以下的催化剂组合:(a)碱金属氢氧化物和/或碱土金属氢氧化物; 和(b)选自第四主要金属的第四主要金属的第四主要金属的乙酰丙酮酸铁,C 1 -C 8醇盐,酚盐,烯醇化物和/或乙酰丙酮化物的有机金属化合物或第四主要金属的含硫化合物 基团,其中化合物硫直接连接到金属原子上。