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1. 发明授权

US4165431A Chlorination of polyolefins in the presence of complex formers 失效
标题翻译：在复合成型剂存在下氯化聚烯烃
公开(公告)号：US4165431A
公开(公告)日：1979-08-21
申请号：US881675
申请日：1978-02-27
申请人： Franz Alfes , Diez Heine , Reinhard Kaiser , Gunter Kolb , Joachim Probst , Franz Weider
发明人： Franz Alfes , Diez Heine , Reinhard Kaiser , Gunter Kolb , Joachim Probst , Franz Weider
IPC分类号： C08F8/00 , C08F8/20 , C08F8/22
CPC分类号： C08F8/22
摘要： A chlorinated colorless polyolefin, preferably a chlorinated colorless isotactic polypropylene, soluble in carbon tetrachloride and having a chlorine content of from 60% to 70% by weight and an average degree of polymerization of from 2000 to 6000, produced by chlorinating polyolefins having a degree of polymerization of from 2000 to 20,000 in suspension or solution or in suspension and solution at 40 to 60.degree. C. in the presence of a halogen transfer agent, a chlorination catalyst and from 0.2 to 0.5% by weight, based on polyolefin, of at least one compound corresponding to the general Formula (I):h.sub.2 n--r--nh>.sub.n H (I)in which R represents the ethylene, propylene or butylene group and n=1-6.
摘要翻译：氯化无色聚烯烃，优选氯化无色全同立构聚丙烯，其可溶于四氯化碳，氯含量为60〜70重量％，平均聚合度为2000〜6000，通过氯化具有一定程度的聚烯烃在卤素转移剂，氯化催化剂和基于聚烯烃的0.2至0.5重量％的存在下，在悬浮液或溶液中或悬浮液和溶液中在40至60℃下聚合2000至20,000，至少对应于通式（I）的一种化合物：

2. 发明授权

US4331573A Aqueous dispersions of urethane-modified polyesters, a process for their production and their use for the production of lacquers 失效
标题翻译：氨基甲酸酯改性聚酯的水分散体，其生产方法及其用于生产漆的用途
公开(公告)号：US4331573A
公开(公告)日：1982-05-25
申请号：US167203
申请日：1980-07-09
申请人： Karl Zabrocki , Ludwig Bottenbruch , Franz Weider
发明人： Karl Zabrocki , Ludwig Bottenbruch , Franz Weider
IPC分类号： C08G18/00 , C08G18/08 , C08G18/83 , C08J3/05 , C08L75/00 , C09D175/06 , C08L91/00
CPC分类号： C08J3/05 , C08G18/0823 , C08G18/831 , C08J2375/06
摘要： Melts of Urethane-modified oligoesters and 1 or polyesters can easily be dispersed in an aqueous phase in the presence of a dispersing agent combination comprising a polyether-modified polyester and a non-ionic dispersing agent having a particular HLB value.
摘要翻译：在包含聚醚改性聚酯和具有特定HLB值的非离子分散剂的分散剂组合的存在下，聚氨酯改性的低聚酯和1或聚酯的熔体可以容易地分散在水相中。

3. 发明授权

US4284544A Process for the preparation of water-dispersible or water-soluble blocked polyisocyanates, the blocked polyisocyanates obtainable by this process and lacquer binders containing these blocked polyisocyanates as isocyanate component 失效
标题翻译：用于制备水分散性或水溶性封闭多异氰酸酯的方法，通过该方法获得的封端多异氰酸酯和含有这些封端多异氰酸酯作为异氰酸酯组分的漆基粘合剂
公开(公告)号：US4284544A
公开(公告)日：1981-08-18
申请号：US102059
申请日：1979-12-10
申请人： Christian Wegner , Kurt Findeisen , Franz Weider
发明人： Christian Wegner , Kurt Findeisen , Franz Weider
IPC分类号： C08G18/00 , C08G18/08 , C08G18/62 , C08G18/80 , C08G18/83 , C09D175/00 , C09D175/04 , C08L75/06
CPC分类号： C08G18/8061 , C08G18/0828 , C08G18/8054
摘要： Blocked polyisocyanates with improved water-dispersible or water-soluble properties are prepared by reacting polyisocyanates, in which 50 to 99.8% of the isocyanate groups are blocked, optionally in a solvent-free environment with an organic polyaminosulphonate or an organic polyaminosulphonic acid in sufficient quantities to provide an end product containing from 0.1 to 10%, by weight, of sulphonate groups (SO.sub.3.sup.-). The blocked polyisocyanates have particular utility when used in combination with hydrophobic polyhydroxyl compounds as binders in aqueous coating compounds.
摘要翻译：具有改善的水分散性或水溶性的封闭多异氰酸酯通过使多异氰酸酯反应来制备，其中50-99.8％的异氰酸酯基团被任选地在无溶剂的环境中与有机聚氨基磺酸盐或有机聚氨基磺酸足够量以提供含有0.1至10重量％的磺酸盐基团（SO 3 - ）的最终产物。当与疏水性多羟基化合物结合使用时，封端的多异氰酸酯在水性涂料化合物中作为粘合剂具有特别的用途。

4. 发明授权

US4321170A Aqueous polyester dispersions 失效
标题翻译：水性聚酯分散体
公开(公告)号：US4321170A
公开(公告)日：1982-03-23
申请号：US206880
申请日：1980-11-14
申请人： Karl Zabrocki , Rolf Dhein , Franz Weider , Klaus Hohne , Kurt Schorn
发明人： Karl Zabrocki , Rolf Dhein , Franz Weider , Klaus Hohne , Kurt Schorn
IPC分类号： C08G63/00 , C08G18/28 , C08G63/46 , C08G63/553 , C08G63/78 , C09D167/00 , C09D167/02 , C09D167/08 , C08L61/28 , C08L91/00 , C09D5/02
CPC分类号： C08G63/553 , C08G18/283 , C09D167/00
摘要： Aqueous dispersions of polyesters or alkyd resins for coatings are prepared by co-condensation of 10 to 100 mol-%, calculated on the sum of polybasic carboxylic acids, of polybasic acids whose carboxyl groups are attached to secondary and/or tertiary carbon atoms. Said dispersions are excellently stable and yield coatings with outstanding properties.
摘要翻译：用于涂层的聚酯或醇酸树脂的水分散体是通过以羧基连接到仲碳原子和/或叔碳原子上的多元羧酸的多元羧酸之和共计缩合10-100摩尔％来制备的。所述分散体具有优异的稳定性和具有优异性能的产率涂料。

5. 发明授权

US4318832A Aqueous dispersions of epoxide compounds 失效
标题翻译：环氧化合物的水分散体
公开(公告)号：US4318832A
公开(公告)日：1982-03-09
申请号：US181066
申请日：1980-08-25
申请人： Karl Zabrocki , Hans Schulze , Franz Weider , Wolfgang Wellner , Wolfgang Schartau
发明人： Karl Zabrocki , Hans Schulze , Franz Weider , Wolfgang Wellner , Wolfgang Schartau
IPC分类号： C08G59/00 , B01F17/00 , C08J3/03 , C08L63/00 , C09D163/00 , C08L63/02
CPC分类号： C08J3/03 , B01F17/0028 , B01F17/0092 , C08J2363/00 , Y10T428/2938
摘要： An aqueous dispersion of an epoxide compound comprising water, one or more water-insoluble 1,2-epoxide compounds having mol weights Mn of from between 150 and 3000 and an emulsifying system comprising:(A) from 9.5 to 35% by weight of at least one polyester resin containing carboxyl groups having an acid number of from 10 to 50 mg KOH/g substance and a molecular weight Mn of from 400 to 4000, at least 30% of the carboxyl groups being neutralized;(B) from 0.5 to 25% by weight of at least one emulsifier having an HLB-value.gtoreq.15 and represented by the formula: ##STR1## wherein R.sup.1 represents a C.sub.1 -C.sub.16 -alkyl group,R.sup.2 represents H or a C.sub.1 -C.sub.16 -alkyl group,R.sup.3 represents H or methyl,n represents a number from 10 to 50;(C) from 40 to 90% by weight of at least one emulsifier having an HLB-value of 15 and the general formula: ##STR2## wherein R.sup.2 is previously defined, R.sup.4 represents C.sub.1 -C.sub.4 -alkyl group, x is a number of from 2 to 3, and m is a number from 15 to 100, the total of the percentage contents from A, B, and C being 100%.
摘要翻译：一种环氧化合物的水分散体，其包含水，一种或多种具有150至3000的摩尔重量Mn的水不溶性1,2-环氧化物化合物和乳化体系，其包含：（A）9.5至35重量％含有酸值为10〜50mg KOH / g物质和分子量Mn为400〜4000的羧基的至少一种聚酯树脂，至少30％的羧基被中和; （B）0.5至25重量％的至少一种具有HLB值> / = 15的乳化剂，由下式表示：其中R1表示C1-C16 - 烷基，R2表示H或C1 C 1-6 - 烷基，R 3表示H或甲基，n表示10〜50的数。（C）40至90重量％的至少一种HLB值为15的乳化剂，通式为：其中R 2为前述定义，R 4表示C 1 -C 4 - 烷基，x为 2〜3，m为15〜100的数，A，B，C的百分比含量为100％。

6. 发明授权

US4507427A Process for production of polyisocyanates containing at least partly blocked isocyanate groups, compounds obtainable by this process and their use in production of polyurethanes, stoving lacquers or aqueous polyisocyanate solutions or dispersions 失效
标题翻译：生产含有至少部分封端的异氰酸酯基团的多异氰酸酯的方法，可通过该方法获得的化合物及其在生产聚氨酯，烘烤漆或多异氰酸酯多异氰酸酯溶液或分散体
公开(公告)号：US4507427A
公开(公告)日：1985-03-26
申请号：US628372
申请日：1984-07-05
申请人： Terry A. Potter , Klaus Nachtkamp , Franz Weider
发明人： Terry A. Potter , Klaus Nachtkamp , Franz Weider
IPC分类号： C08G18/00 , C07D319/06 , C08G18/08 , C08G18/80
CPC分类号： C08G18/0819 , C08G18/8093 , C09D5/084 , C08K2003/321 , C08K3/20
摘要： The present invention relates to a process for the production of organic polyisocyanates containing at least partly blocked isocyanate groups characterized in that specific cyclic dicarbonyl compounds are used as the blocking agent. The present invention also relates to the polyisocyanates containing at least partly blocked isocyanate groups obtainable by this process and to the use of the polyisocyanates containing at least partly blocked isocyanate groups obtainable by this process as reactants for isocyanate-reactive compounds for the production of isocyanate polyaddition products.The present invention also relates to the use of polyisocyanates containing at least partly blocked isocyanate groups obtainable by the above process for the production of aqueous stoving lacquers and to the use of these polyisocyanates for the production of aqueous polyisocyanate solutions or dispersions. The aqueous stoving lacquers and aqueous polyisocyanate solutions or dispersions are mixed with water in the presence of a base used in a quantity which is sufficient to guarantee the solubility or dispersibility of the polyisocyanates.
摘要翻译：本发明涉及一种制备含有至少部分封端的异氰酸酯基团的有机多异氰酸酯的方法，其特征在于使用特定的环状二羰基化合物作为封闭剂。本发明还涉及含有至少部分封闭的异氰酸酯基团的多异氰酸酯，该异氰酸酯基团可通过该方法获得，以及使用通过该方法可获得的至少部分封端的异氰酸酯基团的多异氰酸酯作为用于生产异氰酸酯加聚物的异氰酸酯反应性化合物的反应物产品。本发明还涉及含有至少部分封闭的异氰酸酯基团的多异氰酸酯在上述方法中可用于生产含水烘烤漆的用途以及这些多异氰酸酯用于制备多异氰酸酯水溶液或分散体的用途。水性烘烤漆和多异氰酸酯水溶液或分散体在碱的存在下与水混合，其用量足以保证多异氰酸酯的溶解度或分散性。

7. 发明授权

US4452834A Process for the preparation of aqueous dispersions or solutions of polyurethane polyureas containing heat activated cross-linking agents, the dispersions or solutions obtainable by this process, and their use for the production of coatings 失效
标题翻译：用于制备含有热活化交联剂的聚氨酯聚脲的水性分散体或溶液的方法，通过该方法获得的分散体或溶液及其在涂料生产中的用途
公开(公告)号：US4452834A
公开(公告)日：1984-06-05
申请号：US420172
申请日：1982-09-17
申请人： Klaus Nachtkamp , Franz Weider , Klaus Noll , Josef Pedain , Klaus Hoehne
发明人： Klaus Nachtkamp , Franz Weider , Klaus Noll , Josef Pedain , Klaus Hoehne
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/32 , C08G18/42 , C08G18/65 , C08G18/80 , C08J3/02 , C09D175/00 , C09D175/04 , B05D3/02 , C08L75/06
CPC分类号： C08G18/4238 , C08G18/0804 , C08G18/10
摘要： This invention relates to a new process for the preparation of storage stable aqueous dispersions or solutions of cross-linkable polyurethane polyureas containing heat activated cross-linking agents, in which mixtures of hydrophilically modified prepolymers containing isocyanate groups, hydrophobic polyisocyanates which contain blocked isocyanate groups and are neither soluble nor dispersible in water, and compounds containing at the most one free aminic or hydrazinic primary or secondary amino group and at least one blocked group which under the influence of water forms a free aminic or hydrazinic primary or secondary amino group and a total of at least two such amino groups are prepared in the absence of water and then mixed with water, and it also relates to the aqueous dispersions or solutions obtained by this process and to their use for the production of coatings on heat-resistant substrates.
摘要翻译：本发明涉及一种制备含有热活化交联剂的可交联聚氨酯聚脲的储存稳定水性分散体或溶液的新方法，其中含有异氰酸酯基的亲水改性预聚物的混合物，含有封端异氰酸酯基的疏水性多异氰酸酯和在水中既不溶解也不分散，含有最多一个游离氨基或肼基伯或仲氨基的化合物和至少一个受水影响的封闭基团形成游离氨基或肼基伯或仲氨基，至少两个这样的氨基在不存在水的情况下制备，然后与水混合，并且还涉及通过该方法获得的水性分散体或溶液及其在耐热基材上生产涂层的用途。

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