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1. 发明授权

US5468804A Water-soluble or water-dispersible polyisocyanate composition, a process for its preparation and its use in coating compositions 失效
标题翻译：水溶性或水分散性多异氰酸酯组合物，其制备方法及其在涂料组合物中的应用
公开(公告)号：US5468804A
公开(公告)日：1995-11-21
申请号：US306335
申请日：1994-09-15
申请人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
发明人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
IPC分类号： C08G18/10 , C08G18/28 , C08G18/32 , C08G18/48 , C08G18/62 , C08G18/70 , C08G18/76 , C08G18/80 , C09D175/00 , C09D175/04 , C08J3/00 , B32B27/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/283 , C08G18/706 , C08G18/8035 , C08G18/8064 , Y10T428/31551
摘要： A water-dispersible polyisocyanate composition obtained by the partial urethanization of the isocyanate groups of 2,4- and/or 2,6-diisocyanatotoluene with monohydric and polyhydric alcohols, a process for its production, its use as the binder for an aqueous two-component coating composition in combination with a water-soluble or water-dispersible polyhydroxyl component and coatings for water-resistant sheet-form substrates prepared from this coating composition.
摘要翻译：通过2,4-和/或2,6-二异氰酸基甲苯与一元醇和多元醇的异氰酸酯基团的部分氨基甲酸酯化获得的水分散性多异氰酸酯组合物，其生产方法，其用作二级和多元醇的粘合剂，组合涂料组合物与水溶性或水分散性多羟基组分的组合以及由该涂料组合物制备的用于防水片状基材的涂料。

2. 发明授权

US06376602B1 Coating compositions, a process for their production and their use for coating water-resistant substrates 失效
标题翻译：涂料组合物，其制备方法及其用于涂覆耐水基材的用途
公开(公告)号：US06376602B1
公开(公告)日：2002-04-23
申请号：US08432560
申请日：1995-05-01
申请人： Joachim Probst , Werner Kubitza , Rolf Roschu , Hans Josef Laas
发明人： Joachim Probst , Werner Kubitza , Rolf Roschu , Hans Josef Laas
IPC分类号： C08J300
CPC分类号： C08G18/6245 , C08G18/0819 , C08G18/283 , C08G18/6229 , C08G18/706 , C08G18/8064
摘要： The present invention relates to water-borne coating compositions wherein the binder contains a mixture of a) a polyol component dispersed in water or a water/solvent mixture which contains at least one polymer prepared from olefinically unsaturated monomers and having a molecular weight (Mn) of at least 500, at least two alcoholic hydroxyl groups per molecule, a hydroxyl value of 15 to 250 mg KOH/g, an acid value of 0 to 7 mg KOH/g and a total content of sulfonate and carboxylate groups of 0 to 4.5 milliquivalents per 100 g of solid resin and b) a polyisocyanate component which is emulsified in the dispersion of polyol component a), has a viscosity at 23° C. of 50 to 10,000 mPa.s and an average NCO functionality of 1.8 to 4.2, and contains 12.0 to 21.5% by weight of (cyclo)aliphatically bound isocyanate groups and, optionally, 2 to 20% by weight of ethylene oxide units present within polyether chains, the polyether chains containing a statistical average of 5 to 70 ethylene oxide units, wherein the components are present in quantities corresponding to an equivalent ratio of isocyanate groups of component b) to alcoholic hydroxyl groups of component a) of 0.2:1 to 5:1. The present invention also relates to a process for the production of these coating compositions and to coated water-resistant substrates prepared from these coating compositions.
摘要翻译：本发明涉及水性涂料组合物，其中粘合剂含有分散在水中的多元醇组分或含有至少一种由烯属不饱和单体制备的聚合物的水/溶剂混合物的混合物，其分子量（Mn）为每分子至少500个，至少两个醇羟基，羟基值为15-250mg KOH / g，酸值为0-7mg KOH / g，磺酸盐和羧酸酯基团的总含量为0-4.5毫克每100g固体树脂和b）在多元醇组分a）的分散体中乳化的多异氰酸酯组分，其在23℃下的粘度为50至10,000mPa.s，平均NCO官能度为1.8至4.2，并且包含 12.0至21.5重量％的（环）脂族结合的异氰酸酯基团和任选地2至20重量％存在于聚醚链内的环氧乙烷单元，所述聚醚链含有5-70个环氧乙烷单元的统计平均值其中组分以对应于组分b）的异氰酸酯基团与组分a）的醇羟基的当量比为0.2:1至5:1存在。本发明还涉及制备这些涂料组合物的方法和由这些涂料组合物制备的涂覆的耐水基材。

3. 发明授权

US06319981B1 Coating compounds, a process for their production and their use for the production of coatings 失效
标题翻译：涂料化合物，其生产工艺及其在涂料生产中的应用
公开(公告)号：US06319981B1
公开(公告)日：2001-11-20
申请号：US08211698
申请日：1994-04-13
申请人： Rolf Dhein , Knud Reuter , Lothar Bäcker , Joachim Probst , Werner Kubitza , Rainer Rettig
发明人： Rolf Dhein , Knud Reuter , Lothar Bäcker , Joachim Probst , Werner Kubitza , Rainer Rettig
IPC分类号： C08K320
CPC分类号： C08G18/706 , C08G18/0823 , C08G18/4063 , C08G18/4263 , C08G18/4288 , C08G18/7831
摘要： The present invention relates to coating compounds of which the binder consists essentially of a combination of a) a polyol component dissolved and/or dispersed in water or a water/solvent mixture, and b) a polyisocyanate component emulsified in the solution and/or dispersion of the polyol component with a viscosity at 23° C. of 50 to 10,000 mPa.s, in quantities corresponding to an equivalent ratio of isocyanate groups of component a) to alcoholic hydroxyl groups of component b) of 0.5:1 to 5:1, characterized in that component consists essentially of a1) a water-dilutable, hydroxyfunctional polycondensate resin free from urethane and sulfonate groups and having a molecular weight Mn above 500 or a2) a mixture of such a polycondensation resin with up to 100% by weight, based on the weight of the polycondensation resin, of at least one water-dilutable, hydroxyfunctional polymerization resin having a molecular weight Mn above 500. The present invention also relates to a process for the preparation of these coating compounds and to their use for the production of coatings.
摘要翻译：本发明涉及涂料化合物，其粘合剂基本上由以下组合组成：a）溶解和/或分散在水中的多元醇组分或水/溶剂混合物，和b）在溶液和/或分散体中乳化的多异氰酸酯组分多元醇组分，其在23℃下的粘度为50至10,000mPa.s，其量对应于组分a）的异氰酸酯基团与组分b）的醇羟基的当量比为0.5:1至5:1，其特征在于该组分基本上由以下组分组成：a）不含氨基甲酸酯基和磺酸酯基团并具有分子量Mn在500以上的水可稀释的羟基官能团的缩聚物树脂2）这种缩聚树脂与至多100重量％的混合物，基于重量的缩聚树脂，其至少一种分子量Mn高于500的水可稀释的羟基官能聚合树脂。本发明还涉及制备方法这些涂料化合物及其用于生产涂料的用途。

4. 发明授权

US4711918A Use of polyisocyanates or polyisocyanate mixtures as additives for aqueous emulsion paints 失效
标题翻译：使用多异氰酸酯或多异氰酸酯混合物作为水性乳液漆的添加剂
公开(公告)号：US4711918A
公开(公告)日：1987-12-08
申请号：US892220
申请日：1986-07-31
申请人： Werner Kubitza , Gerhard Mennicken
发明人： Werner Kubitza , Gerhard Mennicken
IPC分类号： C09D175/00 , C08G18/78 , C08G18/79 , C09D5/02 , C09D157/00 , C08K5/29
CPC分类号： C09D5/024 , C08G18/7831 , C08G18/79 , C09D157/00
摘要： The present invention is directed to a process for improving the coatings properties of aqueous emulsion paints having a binder based on homo or copolymers of olefinically unsaturated monomers substantially free from urethane groups by adding at least one organic polyisocyanate having a viscosity at 23.degree. C. of about 50 to 4000 mPa.s, wherein the organic polyisocyanate has aliphatically and/or cycloaliphatically bound isocyanate groups and an isocyanate functionality of at least 3, optionally in combination with other organic polyisocyanates containing aliphatically and/or cycloaliphatically bound isocyanate groups and having an isocyanate functionality of 2, provided that the average functionality is at least 2.2.The present invention is also directed to the ready for use aqueous emulsion paints prepared by the above process.
摘要翻译：本发明涉及一种改进水性乳液漆的涂料性能的方法，该水性乳液漆具有基于基本上不含氨基甲酸酯基的烯属不饱和单体的均聚物或共聚物的粘合剂，通过将至少一种在23℃下具有粘度的有机多异氰酸酯加入到约50至4000mPa.s，其中所述有机多异氰酸酯具有脂族和/或环脂族结合的异氰酸酯基团和至少3的异氰酸酯官能度，任选与含有脂族和/或环脂族结合的异氰酸酯基团并且具有异氰酸酯的其它有机多异氰酸酯组合功能为2，前提是平均功能至少为2.2。本发明还涉及通过上述方法制备的即用型水性乳液漆。

5. 发明授权

US5985986A Process for the preparation of coatings from moisture-curing coating compositions 失效
标题翻译：从湿固化涂料组合物制备涂料的方法
公开(公告)号：US5985986A
公开(公告)日：1999-11-16
申请号：US318328
申请日：1994-10-05
申请人： Werner Kubitza , Rolf Roschu , Ferdinand Zollner , Hans Josef Laas
发明人： Werner Kubitza , Rolf Roschu , Ferdinand Zollner , Hans Josef Laas
IPC分类号： B05D7/24 , C08G18/28 , C08G18/30 , C08G18/70 , C08G18/79 , C09D5/02 , C09D175/00 , C09D175/02 , C08J3/00 , B05D1/36 , C08K3/20 , C08L75/00
CPC分类号： C08G18/792 , C08G18/283 , C08G18/307 , C08G18/706 , C09D175/02
摘要： The present invention relates to a process for the preparation of a coating bya) applying to a water-resistant substrate an aqueous coating composition containing water and a binder which consists essentially of at least one hydrophilically-modified organic polyisocyanate or polyisocyanate mixture which has an NCO content of 5 to 30, preferably 10 to 23% by weight, and is dispersible in water andb) curing the composition in the presence of moisture to form a polyurea coating.
摘要翻译：本发明涉及一种制备涂层的方法，该方法是：a）向耐水性基材施加含有水和粘合剂的水性涂料组合物，该组合物基本上由至少一种亲水改性的有机多异氰酸酯或多异氰酸酯混合物组成， NCO含量为5至30，优选10至23重量％，并且可分散在水中，b）在水分存在下固化该组合物以形成聚脲涂层。

6. 发明授权

US5508372A Isocyanate prepolymers, a process for their production and their use in one-component coating compositions 失效
标题翻译：异氰酸酯预聚物，其制备方法及其在单组分涂料组合物中的应用
公开(公告)号：US5508372A
公开(公告)日：1996-04-16
申请号：US49750
申请日：1993-04-19
申请人： Martin Brahm , Lutz Schmalstieg , Werner Kubitza , Wieland Hovestadt , Josef Pedain
发明人： Martin Brahm , Lutz Schmalstieg , Werner Kubitza , Wieland Hovestadt , Josef Pedain
IPC分类号： C08G18/08 , C08G18/10 , C08G18/62 , C08G18/73 , C08G18/75 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04 , C09D133/08 , C08G18/72 , C09D175/06
CPC分类号： C08G18/8016 , C08G18/089 , C08G18/10 , C08G18/6229 , C08G18/6254 , C08G18/73 , C08G18/792 , C08G18/798
摘要： The present invention relates to a process for the production of storage stable prepolymers containing free isocyanate groups by reactinga) an organic polyisocyanate component having (cyclo)aliphatically bound isocyanate groups and a maximum functionality of 4.5 withb) one or more hydroxy-functional polyacrylate resins having a content of alcoholic hydroxy groups of 0.05 to 7% by weight at an equivalent ratio of isocyanate groups of component a) to hydroxyl groups of component b) of 3:1 to 40:1, wherein components a) and b) are selected to provide a value B of at most 4 when calculated in accordance with the formula: ##EQU1## wherein F.sub.1 and F.sub.2 represent the NCO and OH functionalities of components a) and b), F.sub.1 representing the component with the lower functionality when the components differ in functionality andval.sub.A /val.sub.I represents the OH/NCO equivalent ratio of components a) and b). The invention also relates to the NCO prepolymers obtained by this process and to their use for the production of one-component, moisture-curing coating compositions.
摘要翻译：本发明涉及通过使具有（环）脂族结合的异氰酸酯基团和最大官能度为4.5的有机多异氰酸酯组分与b）一种或多种羟基官能聚丙烯酸酯反应生产含有游离异氰酸酯基团的储存稳定的预聚物的方法醇成分含量为0.05〜7重量％，成分a）的异氰酸酯基与成分b）的羟基的比例为3：1〜40：1的树脂，其中a）和b）成分为其选择为当根据以下公式计算时提供至多为4的值B：其中F1和F2表示组分a）和b）的NCO和OH官能度，F1表示当组分具有较低官能度的组分时功能不同，ValA / ValI代表组分a）和b）的OH / NCO当量比。本发明还涉及通过该方法获得的NCO预聚物及其用于生产单组分湿固化涂料组合物的用途。

7. 发明授权

US4929724A Process for the production of uretdione group-containing compounds, the compounds obtained according to this process and the use thereof in the production of polyurethane plastics material 失效
标题翻译：用于生产含脲二酮基的化合物的方法，根据该方法获得的化合物及其在生产聚氨酯塑料材料中的用途
公开(公告)号：US4929724A
公开(公告)日：1990-05-29
申请号：US783704
申请日：1985-10-03
申请人： Theodor Engbert , Jurg Frohlich , Werner Kubitza , Peter Breidenbach , Gerhard Mennicken
发明人： Theodor Engbert , Jurg Frohlich , Werner Kubitza , Peter Breidenbach , Gerhard Mennicken
IPC分类号： C08G18/00 , B01J31/02 , C07B61/00 , C07D229/00 , C08G18/76 , C08G18/78 , C08G18/79
CPC分类号： C08G18/798
摘要： The invention is directed to a process for the production of uretdione group-containing compounds by dimerizing at least a part of the isocyanate groups of organic isocyanates in the presence of compounds containing phosphorus-nitrogen bonds as dimerization catalysts, characterized in that the reaction is carried out in the presence, as co-catalysts, of H-active organic compounds having a pKa-value of at least 6, which have at least one hydrogen atom bound to oxygen, sulphur or nitrogen.The invention also relates to the uretdione group-containing compounds obtained according to this process and to their use for the production of plastics materials according to the isocyanate-polyaddition process.
摘要翻译：本发明涉及一种通过在含有磷 - 氮键的化合物存在下将有机异氰酸酯的至少一部分异氰酸酯基团二聚化作为二聚催化剂来生产含脲二酮基的化合物的方法，其特征在于反应进行作为助催化剂存在具有pKa值至少为6的H活性有机化合物，其具有至少一个与氧，硫或氮结合的氢原子。本发明还涉及根据该方法获得的含脲二酮基的化合物及其根据异氰酸酯加聚方法生产塑料的用途。

8. 发明授权

US4305977A Use of hydroxyl alkyl amines optionally containing ether groups or their salts as additives reducing resistance to the diffusion of water vapor in polyurethane-based coating compositions 失效
标题翻译：任选地含有醚基的羟基烷基胺或其盐作为添加剂的用途，降低了在聚氨酯基涂料组合物中水蒸气扩散的抗性
公开(公告)号：US4305977A
公开(公告)日：1981-12-15
申请号：US78327
申请日：1979-09-24
申请人： Werner Kubitza , Gerhard Mennicken
发明人： Werner Kubitza , Gerhard Mennicken
IPC分类号： C08G18/00 , C08G18/08 , C08G18/32 , C08G18/50 , C08G18/65 , C08K5/17 , C08L75/00 , C08L75/04 , C09D7/12 , C09D175/00 , C09D175/12 , B05D5/00
CPC分类号： C08G18/0814 , C08G18/3271 , C08G18/5021 , C08G18/6535 , C09D175/12 , Y10S521/905 , Y10S528/904
摘要： A process for improving the water vapor permeability of polyurethane coatings by incorporating a hydroxy alkyl amine, an alkoxylated amine or the salt of either with an inorganic or organic acid into the coating composition is taught. Coating compositions including this water vapor diffusion enhancing additive are also taught as is a process for coating water vapor permeable substrates.
摘要翻译：教导了通过将羟基烷基胺，烷氧基化胺或其与无机或有机酸的盐掺入涂料组合物来改善聚氨酯涂层的水蒸气透过性的方法。包括这种水蒸汽扩散增强添加剂的涂料组合物也被教导为涂覆水蒸气可渗透基材的方法。

9. 发明授权

US4292350A Isocyanate mixture and its use as binder in one-component lacquers 失效
标题翻译：异氰酸酯混合物及其在单组分漆中的用作粘合剂
公开(公告)号：US4292350A
公开(公告)日：1981-09-29
申请号：US84021
申请日：1979-10-12
申请人： Werner Kubitza , Gerhard Mennicken , Josef Pedain
发明人： Werner Kubitza , Gerhard Mennicken , Josef Pedain
IPC分类号： C08G18/00 , C07D251/34 , C08G18/71 , C08G18/72 , C08G18/73 , C08G18/79 , C08G18/80 , C09D175/00 , C08L75/04
CPC分类号： C07D251/34 , C08G18/721 , C08G18/8064
摘要： Isocyanate mixtures which are stable in the absence of moisture, and are curable by atmospheric moisture and which have low viscosities are obtained by mixing polyisocyanates containing biuret, allophanate or urethane bonds and functionalities in excess of 2 with monoisocyanates. These mixtures are used to coat substrates and the exposure of the coated substrates to atmospheric moisture results in cured coatings.
摘要翻译：通过将含有缩二脲，脲基甲酸酯或氨基甲酸酯键的多异氰酸酯和超过2的官能团与单异氰酸酯混合，可获得在无水分下稳定并且可通过大气湿度固化并且具有低粘度的异氰酸酯混合物。这些混合物用于涂覆基材，并且将涂覆的基材暴露于大气湿气中导致固化的涂层。

10. 发明授权

US5459197A Coating compositions, a process for their production and their use for coating water-resistant substrates 失效
标题翻译：涂料组合物，其制备方法及其用于涂覆耐水基材的用途
公开(公告)号：US5459197A
公开(公告)日：1995-10-17
申请号：US251876
申请日：1994-06-01
申请人： Jurgen Schwindt , Helmut Reiff , Werner Kubitza
发明人： Jurgen Schwindt , Helmut Reiff , Werner Kubitza
IPC分类号： C08G18/08 , C08G18/28 , C08G18/62 , C08G18/66 , C08G18/70 , C08G18/75 , C08G18/79 , C08J3/00 , B32B27/00 , C08J3/20 , C08J7/00
CPC分类号： C08G18/6283 , C08G18/0814 , C08G18/283 , C08G18/6655 , C08G18/706 , C08G18/758 , C08G18/792 , Y10T428/31551
摘要： The present invention relates to an aqueous two-component coating composition wherein the binder contains(a) a component which is dissolved and/or dispersed in water, has an average hydroxyl number of 15 to 200 mg KOH/g, and contains(a1) a polyol component having a content of 8 to 450 milliequivalents, per 100 g of component (a1) solids, of chemically incorporated ammonium groups, .dbd.N.dbd..sup.+, comprising one or more polyaddition resins which are water-dilutable, contain hydroxyl groups, and have a molecular weight (M.sub.n) of 500 to 20,000 and(a2) up to 10 wt %, based on the weight of component (a1), of one or more reactive diluents which are water-soluble, have a molecular weight (M.sub.n) below 500, and contain at least one isocyanate-reactive group, and(b) a polyisocyanate component having an NCO content of 5 to 25 wt % comprising one or more polyisocyanates which are emulsified in the aqueous solution and/or dispersion of hydroxyl group-containing component (a),wherein components (a) and (b) are present in an amount sufficient to provide an equivalent ratio of isocyanate groups of component (b) to isocyanate-reactive groups of component (a) of 0.5:1 to 5:1.The present invention also relates to a process for the production of this coating composition and to their use for the production of coatings on water-resistant substrates.
摘要翻译：本发明涉及水性双组分涂料组合物，其中粘合剂含有（a）溶解和/或分散在水中的组分，其平均羟值为15-200mg KOH / g，并含有（a1）含有8至450毫当量的多元醇组分，每100g组分（a1）固体，化学掺入的铵基，= N = +，包含一种或多种可水稀释的加聚树脂，含有羟基，和基于组分（a1）的重量，分子量（Mn）为500至20,000的（a2）至多10重量％，一种或多种水溶性的具有分子量（Mn）的反应性稀释剂，低于500，并且含有至少一个异氰酸酯反应性基团，和（b）NCO含量为5至25重量％的多异氰酸酯组分，其包含在水溶液中乳化的一种或多种多异氰酸酯和/或羟基 - （a），其中组分（a）和（b）以足以提供组分（b）的异氰酸酯基与组分（a）的异氰酸酯反应性基团的当量比为0.5:1至5:1的量存在。本发明还涉及一种生产该涂料组合物的方法及其在耐水基材上生产涂料的用途。

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