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1. 发明授权

US4133841A Process for upgrading effluents from syntheses of the Fischer-Tropsch type 失效
标题翻译：从费 - 托合成方法提高废水的方法
公开(公告)号：US4133841A
公开(公告)日：1979-01-09
申请号：US781277
申请日：1977-03-25
申请人： Jean Cosyns , Yves Chauvin , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
发明人： Jean Cosyns , Yves Chauvin , Bernard Juguin , Jean-Francois Le Page , Jean Miquel
IPC分类号： C10G57/02 , C10L1/04 , C10L1/06 , C07C9/14 , C07C1/04
CPC分类号： C10G17/095 , C10G29/00 , C10G57/02 , C10L1/04 , C10L1/06 , Y10S208/95
摘要： This process for upgrading effluents from syntheses of the Fischer-Tropsch type comprises several steps applied to the three cuts obtained from these effluents, i.e. a "light fraction", a "light oil" and a "decanted oil". The products are mainly gasoline, kerosene and gasoil cuts.
摘要翻译：用于从费 - 托合成方法提高废水的该方法包括几个步骤，其应用于从这些流出物获得的三个馏分，即“轻馏分”，“轻油”和“倾析油”。产品主要是汽油，煤油和油烟。

2. 发明授权

US4424282A Process for the catalytic synthesis of hydrocarbons, particularly of methane, from hydrogen and carbon monoxide 失效
标题翻译：从氢气和一氧化碳催化合成烃，特别是甲烷的方法
公开(公告)号：US4424282A
公开(公告)日：1984-01-03
申请号：US348890
申请日：1982-02-16
申请人： Yves Chauvin , Dominique Commereuc , Andre Sugier , Jean-Francois Le Page
发明人： Yves Chauvin , Dominique Commereuc , Andre Sugier , Jean-Francois Le Page
IPC分类号： B01J8/02 , B01J23/00 , B01J23/46 , C07B61/00 , C07C1/00 , C07C1/04 , C07C9/04 , C07C67/00
CPC分类号： C07C1/048 , B01J23/462 , B01J8/0285 , C07C1/0425 , C07C1/0435 , C07C1/0445 , C07C1/046 , C07C1/0485 , B01J2208/0007 , B01J2208/00088 , B01J2208/00256 , B01J2208/00283 , C07C2521/04 , C07C2523/46
摘要： Methane is produced by passing hydrogen, carbon monoxide and an aqueous liquid phase downwardly through a fixed bed of a catalyst containing ruthenium on a carrier such as alumina, separating and externally coolng in a heat exchanger the resultant aqueous phase before recycling, thereby limiting the reaction temperature within a range from 200.degree. to 320.degree. C.
摘要翻译：通过将氢气，一氧化碳和水性液相通过载体如氧化铝上的含有钌的催化剂的固定床，在热交换器中分离和外部冷却，生成甲烷，所得水相在再循环之前由此限制反应温度在200〜320℃的范围内。

3. 发明授权

US5874638A Process for hydroformylation of olefinic compounds 失效
标题翻译：烯烃化合物加氢甲酰化方法
公开(公告)号：US5874638A
公开(公告)日：1999-02-23
申请号：US755853
申请日：1996-12-02
申请人： Yves Chauvin , Helene Olivier , Lothar Mussmann
发明人： Yves Chauvin , Helene Olivier , Lothar Mussmann
IPC分类号： B01J31/16 , C07B61/00 , C07C45/50 , C07C47/02 , C07C47/12
CPC分类号： C07C45/50
摘要： A hydroformylation process for unsaturated compounds such as monoolefins and diolefins is carried out in an ionic medium in which the catalytic species is dissolved, but in which the reaction products (aldehydes) formed are only slightly soluble or are insoluble. The ionic medium is liquid at a temperature below 90.degree. C. and comprises at least one quaternary ammonium and/or phosphonium cation and at least one anion which is preferably selected from the group formed by tetrafluoroborate when the cation is ammonium, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, perfluoroalkylsulphonates, fluorosulphonate, bis-perfluoroalkylsulphonyl amides or dichlorocuprate, tetrachlorocuprate, tetrachloroaluminate, or trichlorozincate. At the end of the reaction, the organic phase is separated out and the polar phase containing the catalyst is used again.
摘要翻译：用于不饱和化合物如单烯烃和二烯烃的加氢甲酰化方法在其中溶解催化物质的离子介质中进行，但其中形成的反应产物（醛）仅仅是微溶或不溶解的。离子介质在低于90℃的温度下是液体，并且包含至少一种季铵和/或鏻阳离子和至少一种阴离子，当阳离子是铵，六氟磷酸盐，六氟锑酸盐时，优选选自四氟硼酸盐形成的基团，六氟砷酸盐，全氟烷基磺酸盐，氟磺酸盐，双全氟烷基磺酰胺或二氯磷酸盐，四氯磷酸盐，四氯铝酸盐或三氯酸锌。在反应结束时，分离有机相，再次使用含有催化剂的极性相。

4. 发明授权

US5633416A Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms 失效
$Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms$
标题翻译：通过包含含有5至8个碳原子的烯烃的烃馏分的醚化的方法产生的燃料
公开(公告)号：US5633416A
公开(公告)日：1997-05-27
申请号：US459691
申请日：1995-06-02
申请人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
发明人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
IPC分类号： C10L1/02 , C07C5/22 , C07C5/27 , C07C41/00
CPC分类号： C10L1/023
摘要： An internal combustion engine fuel is produced from a mixture of hydrocarbons comprising olefinic hydrocarbons containing 5 to 8 carbon atoms characterized in that it is produced by a process comprising a) a catalytic etherification step for at least a portion of the etherifiable olefins contained in said hydrocarbon mixture, using at least one alcohol containing 1 to 4 carbon atoms, the quantity of alcohol employed being such that the alcohol:etherifiable olefin molar ratio is at least 1:1, and b) a water washing step for the ether-containing product before recovery as a fuel.
摘要翻译：由含有5-8个碳原子的烯烃的烃的混合物产生内燃机燃料，其特征在于它是通过以下方法生产的：a）催化醚化步骤，用于至少部分所述烃中所含的可醚化烯烃混合物，使用至少一种含有1至4个碳原子的醇，所使用的醇的量使得醇：可醚化烯烃摩尔比至少为1:1，和b）含醚产物的水洗步骤作为燃料的回收。

5. 发明授权

US5589601A Process for the dimerization, co-dimerization and oligomerization of olefins 失效
标题翻译：烯烃二聚，共二聚和低聚的方法
公开(公告)号：US5589601A
公开(公告)日：1996-12-31
申请号：US528519
申请日：1995-09-15
申请人： Yves Chauvin , H el ene Olivier
发明人： Yves Chauvin , H el ene Olivier
IPC分类号： C07C2/30 , C07C2/02 , C07C2/04 , C07C2/24
CPC分类号： C07C2/30 , C07C2527/132 , C07C2531/02 , C07C2531/14 , C07C2531/34
摘要： The invention concerns a process for dimerization, co-dimerization and oligomerization of olefins, in particular .alpha.-olefins, with a catalytic composition resulting from a mixing at least one tungsten oxyhalide, at least one aryl isocyanate of diisocyanate, and at least one alkylaluminum halide.
摘要翻译：本发明涉及烯烃，特别是α-烯烃二聚，共二聚和低聚的方法，其中催化组合物由混合至少一种卤氧化钨，至少一种二异氰酸酯的芳基异氰酸酯和至少一种烷基铝卤化物。

6. 发明授权

US5550306A Catalytic process for the dimerization of olefins 失效
标题翻译：催化二烯化烯烃的方法
公开(公告)号：US5550306A
公开(公告)日：1996-08-27
申请号：US456820
申请日：1995-06-01
申请人： Yves Chauvin , Sandra Einloft , Helene Olivier
发明人： Yves Chauvin , Sandra Einloft , Helene Olivier
IPC分类号： B01J27/125 , B01J31/02 , B01J31/14 , B01J31/24 , C07C2/36 , C07C2/24
CPC分类号： B01J27/125 , B01J31/0284 , B01J31/0288 , B01J31/143 , B01J31/24 , C07C2/36 , B01J2231/20 , B01J2531/847 , C07C2531/22 , C07C2531/24
摘要： The invention is concerned with a process for the dimerization, co-dimerization and oligomerization of olefins with a catalytic composition resulting from mixing at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, at least one aluminum halide, at least one aromatic hydrocarbon and optionally an aluminium organometallic compound.
摘要翻译：本发明涉及一种通过将至少一种季铵卤化物和/或至少一种季鏻卤化物，至少一种卤化铝和至少一种卤化铝混合而得到的催化组合物进行烯烃二聚，共二聚和低聚的方法芳族烃和任选的铝有机金属化合物。

7. 发明授权

US5536689A Catalytic composition and a process for the dimerization of olefins 失效
标题翻译：催化组合物和烯烃二聚的方法
公开(公告)号：US5536689A
公开(公告)日：1996-07-16
申请号：US309702
申请日：1994-09-21
申请人： Yves Chauvin , Sandra Einloft , Helene Olivier
发明人： Yves Chauvin , Sandra Einloft , Helene Olivier
IPC分类号： B01J23/28 , B01J23/30 , B01J27/125 , B01J31/02 , B01J31/14 , B01J31/24 , C07B61/00 , C07C2/32 , C07C2/36 , C07C11/02 , C10G50/00 , B01J31/22
CPC分类号： B01J27/125 , B01J31/0284 , B01J31/0288 , B01J31/143 , B01J31/24 , C07C2/36 , B01J2231/20 , B01J2531/847 , C07C2527/053 , C07C2527/128 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C07C2531/30
摘要： The invention is concerned with a catalytic composition resulting from dissolving a nickel complex mixed or complexed with a tertiary phosphine in the medium resulting from mixing at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, at least one aluminum halide, at least one aromatic hydrocarbon and optionally an aluminum organometallic compound. The invention is also concerned with a process for the dimerization, codimerization and oligomerization of olefins with this composition.
摘要翻译：本发明涉及一种催化组合物，该催化剂组合物是将在混合至少一种季铵卤化物和/或至少一种卤化鏻卤化物（至少一种卤化铝）的混合或与叔膦络合的镍络合物至少一种芳烃和任选的铝有机金属化合物。本发明还涉及使用该组合物进行烯烃二聚，共聚和低聚的方法。

8. 发明授权

US5345023A Process for the production of light alpha olefins by oligomerization of ethylene 失效
标题翻译：通过乙烯低聚生产轻质α-烯烃的方法
公开(公告)号：US5345023A
公开(公告)日：1994-09-06
申请号：US88508
申请日：1993-07-09
申请人： Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
发明人： Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
IPC分类号： C07B61/00 , B01J31/38 , C07C2/30 , C07C11/02 , C07C2/02
CPC分类号： C07C2/30 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/38 , Y02P20/52
摘要： Process for oligomerizing ethylene into light alpha olefins, mainly 1-butene, 1-hexene, 1-octene and 1-decene, in which the ethylene is contacted with a catalyst obtained by mixing a zirconium compound with an organic compound chosen from within the class of acetals and ketals and with a chlorine or bromine-containing compound of aluminum hydrocarbyl.
摘要翻译：将乙烯低聚成轻质α-烯烃，主要是1-丁烯，1-己烯，1-辛烯和1-癸烯的方法，其中乙烯与通过混合锆化合物与选自类中的有机化合物获得的催化剂接触的缩醛和缩酮以及含有氯或溴的铝盐化合物。

9. 发明授权

US5104840A Non-aqueous liquid composition with an ionic character and its use as a solvent 失效
标题翻译：非水性液体组合物，具有离子性，并作为溶剂使用
公开(公告)号：US5104840A
公开(公告)日：1992-04-14
申请号：US672236
申请日：1991-03-20
申请人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
发明人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
IPC分类号： B01J31/22 , B01J31/02 , B01J31/18 , B01J31/24 , B01J31/28 , C07B61/00 , C07C2/32 , C07C11/02 , C07C15/12 , C07F5/06 , C08F10/00
CPC分类号： B01J31/24 , B01J31/0284 , B01J31/0288 , B01J31/1805 , C07F5/06 , C07F5/064 , C08F10/00 , B01J2231/20 , B01J2531/847 , B01J31/0239 , B01J31/0268 , B01J31/2234
摘要： A non-aqueous liquid composition with an ionic character resulting from the contacting of at least one alkylaluminum dihalide with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, said composition being liquid below 80.degree. C., for example, between -70.degree. and +40.degree. C., is useful as a solvent of catalysts for the dimerization, codimerization and oligomerization of olefins.
摘要翻译：由至少一种烷基铝二卤化物与至少一种季铵卤化物和/或至少一种季鏻卤化物接触而产生的具有离子性质的非水性液体组合物，所述组合物在低于80℃的液体下，例如，在-70℃至+ 40℃之间，可用作烯烃二聚，共聚和低聚的催化剂溶剂。

10. 发明授权

US4511743A Process for homologating alcohols through the intermediate production of ketals with cobalt carbonyl complexes as catalysts 失效
标题翻译：通过羰基配合物作为催化剂通过中间体生产缩酮来使醇同步化的方法
公开(公告)号：US4511743A
公开(公告)日：1985-04-16
申请号：US548737
申请日：1983-11-04
申请人： Claude Seite , Dominique Commereuc , Yves Chauvin
发明人： Claude Seite , Dominique Commereuc , Yves Chauvin
IPC分类号： C07C29/14 , B01J31/00 , C07B61/00 , C07C27/00 , C07C29/141 , C07C41/50 , C07C45/00 , C07C45/49 , C07C45/51 , C07C67/00 , C07C27/20
CPC分类号： C07C41/50 , C07C29/141 , C07C45/49 , C07C45/515
摘要： Process for the homologation of an alcohol wherein a ketal of the alcohol is reacted with hydrogen and carbon monoxide in the presence of a cobalt carbonyl complex and the resultant product is hydrolyzed to yield the aldehyde with one more carbon atom.
摘要翻译：醇的同系化方法，其中醇的缩酮在羰基钴络合物的存在下与氢气和一氧化碳反应，并将所得产物水解以产生具有多一个碳原子的醛。

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