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1. 发明授权

US09005430B2 Process and apparatus for integration of a high-pressure hydroconversion process and a medium-pressure middle distillate hydrotreatment process, whereby the two processes are independent 有权
标题翻译：用于整合高压加氢转化过程和中压中间馏分加氢处理过程的方法和装置，由此两个过程是独立的
公开(公告)号：US09005430B2
公开(公告)日：2015-04-14
申请号：US12635466
申请日：2009-12-10
申请人： Antoine Fournier , Jean Luc Nocca
发明人： Antoine Fournier , Jean Luc Nocca
IPC分类号： C10G69/14 , C10G49/00 , C10G49/16 , C10G65/12
CPC分类号： C10G49/007 , C10G49/16 , C10G65/12 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/301 , C10G2300/4012 , C10G2300/4081 , C10G2300/42
摘要： The invention relates to the integration of a process for hydrotreatment of distillates (light and/or middle), that operates under a hydrogen partial pressure of 0.5 to 6.0 MPa, with a process for hydrotreatment/hydroconversion of middle and/or heavy distillates that operates at a hydrogen partial pressure that is at least 4.0 MPa higher than the hydrogen partial pressure of the process for hydrotreatment of distillates (light and/or middle). The integration resides in the use of the hydrogen-rich gas, obtained from the hydrotreatment/hydroconversion effluents, in the process for hydrotreatment of distillates (light and/or middle) and in the adjustment of the pressure level of this hydrogen-rich gas removed from the hydrotreatment/hydroconversion. This invention makes it possible to considerably reduce the net consumption of make-up hydrogen in the process for hydrotreatment of distillates (light and/or middle).
摘要翻译：本发明涉及在0.5至6.0MPa的氢分压下运行的馏出物（轻质和/或中间）的加氢处理方法与用于中和/或重馏分的加氢处理/加氢转化的方法的整合在氢分压比馏出物（轻和/或中）的加氢处理方法的氢分压高至少4.0MPa。在加氢处理馏出物（轻和/或中）的过程中以及在去除了这种富氢气体的压力水平的调节中，使用从加氢处理/加氢转化废水获得的富氢气体的使用来自加氢处理/加氢转化。本发明使得在馏出物（轻质和/或中部）的加氢处理过程中，可以显着地减少补充氢的净消耗。

2. 发明授权

US5633416A Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms 失效
$Fuel produced by a process comprising etherification of a hydrocarbon fraction comprising olefins containing 5 to 8 carbon atoms$
标题翻译：通过包含含有5至8个碳原子的烯烃的烃馏分的醚化的方法产生的燃料
公开(公告)号：US5633416A
公开(公告)日：1997-05-27
申请号：US459691
申请日：1995-06-02
申请人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
发明人： Yves Chauvin , Alain Forestiere , Marie-Claire Marion , H el ene Olivier , Patrick Sarrazin , Jean-Luc Nocca
IPC分类号： C10L1/02 , C07C5/22 , C07C5/27 , C07C41/00
CPC分类号： C10L1/023
摘要： An internal combustion engine fuel is produced from a mixture of hydrocarbons comprising olefinic hydrocarbons containing 5 to 8 carbon atoms characterized in that it is produced by a process comprising a) a catalytic etherification step for at least a portion of the etherifiable olefins contained in said hydrocarbon mixture, using at least one alcohol containing 1 to 4 carbon atoms, the quantity of alcohol employed being such that the alcohol:etherifiable olefin molar ratio is at least 1:1, and b) a water washing step for the ether-containing product before recovery as a fuel.
摘要翻译：由含有5-8个碳原子的烯烃的烃的混合物产生内燃机燃料，其特征在于它是通过以下方法生产的：a）催化醚化步骤，用于至少部分所述烃中所含的可醚化烯烃混合物，使用至少一种含有1至4个碳原子的醇，所使用的醇的量使得醇：可醚化烯烃摩尔比至少为1:1，和b）含醚产物的水洗步骤作为燃料的回收。

3. 发明授权

US4847431A Process for manufacturing a tertiary alkyl ether by reactive distillation 失效
标题翻译：通过反应蒸馏制备叔烷基醚的方法
公开(公告)号：US4847431A
公开(公告)日：1989-07-11
申请号：US171340
申请日：1988-03-21
申请人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
发明人： Jean-Luc Nocca , Jacques Leonard , Jean-Ferdinand Gaillard , Pierre Amigues
IPC分类号： C07B61/00 , B01D3/00 , B01D3/14 , B01D3/22 , B01D3/24 , B01J8/04 , B01J31/10 , C07C41/00 , C07C41/06 , C07C41/42 , C07C43/04 , C07C67/00
CPC分类号： B01J8/0492 , B01D3/009 , B01D3/22 , B01D3/24 , B01J8/0453 , C07C41/06 , C07C41/42 , Y02P20/127 , Y10S203/06
摘要： Process for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with isobutene-containing hydrocarbons in a reaction zone comprising alternate beds of sulfonated resin catalyst and catalyst-free distillation zones, said zones also comprising liquid redistribution plates.
摘要翻译：在包含磺化树脂催化剂和无催化剂的蒸馏区的交替床的反应区中使甲醇与含异丁烯的烃反应制备甲基叔丁基醚（MTBE）的方法，所述区域还包括液体再分布板。

4. 发明授权

US06334948B1 Process for producing gasoline with a low sulphur content 有权
标题翻译：生产硫含量低的汽油的方法
公开(公告)号：US06334948B1
公开(公告)日：2002-01-01
申请号：US09443152
申请日：1999-11-18
申请人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Jean Cosyns
发明人： Blaise Didillon , Denis Uzio , Jean-Luc Nocca , Jean Cosyns
IPC分类号： C10G4506
CPC分类号： C10G65/16
摘要： A process for producing a gasoline with a low sulphur content comprises: separating a sulphur-containing gasoline into a light fraction and a heavy fraction, hydrodesulphurising the light gasoline on a nickel-based catalyst, hydrodesulphurising the heavy fraction on a catalyst comprising at least one group VIII metal and/or at least one group VIB metal, and mixing the desulphurised fractions.
摘要翻译：一种生产低硫含量的汽油的方法包括：将含硫汽油分离成轻馏分和重馏分，将轻汽油加氢脱硫在镍基催化剂上，对重馏分进行加氢脱硫，所述催化剂包含至少一种 VIII族金属和/或至少一种VIB族金属，并混合脱硫馏分。

5. 发明授权

US6048450A Process for the selective reduction to the content of benzene and light unsaturated compounds in a hydrocarbon cut 失效
标题翻译：在烃切割中选择性还原苯和轻不饱和化合物的含量的方法
公开(公告)号：US6048450A
公开(公告)日：2000-04-11
申请号：US774926
申请日：1996-12-27
申请人： Paul Mikitenko , Christine Travers , Jean Cosyns , Charles Cameron , Jean-Luc Nocca , Fran.cedilla.oise Montecot
发明人： Paul Mikitenko , Christine Travers , Jean Cosyns , Charles Cameron , Jean-Luc Nocca , Fran.cedilla.oise Montecot
IPC分类号： C10G35/09 , C10G45/36 , C10G45/40 , C10G45/48 , C10G45/52 , C10G65/08 , C10G69/08 , C10G45/00
CPC分类号： C10G65/08 , C10G2400/02
摘要： A process for treating a feed comprising C.sub.5.sup.+ hydrocarbons and comprising at least one unsaturated C.sub.6.sup.+ compound including benzene, is such that the feed is treated in a distillation zone, associated with a hydrogenation zone, comprising at least one catalytic bed, in which the hydrogenation is carried out of unsaturated C.sub.6.sup.+ compounds contained in the feed, and whereof a charge for the hydrogenation step is removed at the height of a removal level and represents at least part of the liquid flowing in the distillation zone, and the effluent from the hydrogenation reaction zone is at least in part reintroduced into the distillation zone to ensure continuity of the distillation operation, the effluents at the top and bottom on the distillation zone being very depleted of unsaturated C.sub.6.sup.+ compounds. The effluent drawn off from the top of the distillation zone is treated in a zone for the isomerisation of C.sub.5 and/or C.sub.6 paraffins.
摘要翻译：用于处理包含C5 +烃并且包含至少一种包含苯的不饱和C 6 +化合物的进料的方法使得在与包含至少一个催化床的氢化区相关联的蒸馏区中处理进料，其中氢化是由进料中含有的不饱和C6 +化合物进行，并且在去除水平的高度处除去氢化步骤的装料，并且代表在蒸馏区中流动的液体的至少一部分，以及来自氢化反应区的流出物至少部分地重新引入蒸馏区以确保蒸馏操作的连续性，蒸馏区顶部和底部的流出物非常耗尽不饱和C6 +化合物。从蒸馏区顶部排出的流出物在一个区域中进行处理，以使C5和/或C6链烷烃异构化。

6. 发明授权

US4847430A Process for manufacturing a tertiary alkyl ether by reactive distillation 失效
标题翻译：通过反应蒸馏制备叔烷基醚的方法
公开(公告)号：US4847430A
公开(公告)日：1989-07-11
申请号：US171339
申请日：1988-03-21
申请人： Dang Vu Quang , Pierre Amigues , Jean-Ferdinand Gaillard , Jacques Leonard , Jean-Luc Nocca
发明人： Dang Vu Quang , Pierre Amigues , Jean-Ferdinand Gaillard , Jacques Leonard , Jean-Luc Nocca
IPC分类号： C07B61/00 , B01D3/00 , B01J8/04 , B01J31/10 , C07C41/00 , C07C41/06 , C07C41/42 , C07C43/04 , C07C67/00
CPC分类号： C07C41/06 , B01D3/009 , B01J8/0453 , C07C41/42 , Y02P20/127 , Y10S203/06
摘要： The invention concerns a process for manufacturing methyl tert-butyl ether (MTBE) by reacting methanol with an isobutene-containing hydrocarbon mixture.This process is characterized by the steps of:introducing the reactants into a reaction-distillation zone containing at least two superposed and non-contiguous fixed beds (2a, 2b) of catalyst of the sulfonated resin type, wherein passage-ways are provided for a vapor phase, at least one distillation tray (4a), at least one liquid redistribution tray (5),maintaining distillation conditions in said zone so as to have a descending liquid phase and an ascending vapor phase,maintaining a continuous liquid phase in the lower part of said beds,discharging a vapor phase containing a high proportion of unconverted hydrocarbons from the top (8) of said zone, andwithdrawing a liquid phase of high MTBE content from the bottom (10) of said zone.
摘要翻译：本发明涉及通过使甲醇与含异丁烯的烃混合物反应制备甲基叔丁基醚（MTBE）的方法。该方法的特征在于以下步骤：将反应物引入含有至少两个磺化树脂类型的催化剂的重叠和不连续的固定床（2a，2b）的反应 - 蒸馏区，其中为蒸气相，至少一个蒸馏塔板（4a），至少一个液体再分配托盘（5），保持所述区域中的蒸馏条件以具有下降的液相和上升的气相，将下一个液相保持在下部所述床的一部分，从所述区域的顶部（8）排出含有高比例未转化烃的气相，并从所述区域的底部（10）排出高MTBE含量的液相。

7. 发明申请

US20110259792A1 Process for selective reduction of the contents of benzene and light unsaturated compounds of different hydrocarbon fractions 有权
$Process for selective reduction of the contents of benzene and light unsaturated compounds of different hydrocarbon fractions$
标题翻译：选择性还原不同烃馏分苯和轻不饱和化合物含量的方法
公开(公告)号：US20110259792A1
公开(公告)日：2011-10-27
申请号：US12765962
申请日：2010-04-23
申请人： Jean-Luc NOCCA , Quentin Debuisschert
发明人： Jean-Luc NOCCA , Quentin Debuisschert
IPC分类号： C10G45/44
CPC分类号： C10G45/44 , C10G2300/1044 , C10G2300/305 , C10G2300/4087 , C10G2400/02
摘要： Process for treatment of a feedstock, such as hydrocarbons that comprise at least 4 carbon atoms per molecule and that comprise at least one unsaturated compound including benzene, such that said feedstock is treated in a distillation zone, associated with a hydrogenation reaction zone, at least in part outside of the distillation zone, and an isomerization zone, so as to discharge—at the top of the distillation zone and at the bottom of the distillation zone—an effluent that is low in unsaturated compounds, whereby said process comprises the treatment of at least a second feedstock, comprising at least one unsaturated compound including benzene, at least partially directly injected into the hydrogenation zone that is outside of the distillation zone.
摘要翻译：用于处理原料的方法，例如每分子包含至少4个碳原子并且包含至少一种包括苯的不饱和化合物的烃，使得所述原料在与氢化反应区相关的蒸馏区中至少部分在蒸馏区外部和异构化区，以在蒸馏区的顶部和蒸馏区的底部排出低级不饱和化合物的流出物，由此所述方法包括处理至少一种第二原料，其包含至少一种至少部分直接注入到位于蒸馏区外部的氢化区中的包含苯的不饱和化合物。

8. 发明申请

US20100307958A1 PROCESS FOR THE PRODUCTION OF A DESULFURIZED GASOLINE FROM A GASOLINE FRACTION THAT CONTAINS CONVERSION GASOLINE 有权
标题翻译：从含有转化汽油的汽油分离器中生产脱硫汽油的方法
公开(公告)号：US20100307958A1
公开(公告)日：2010-12-09
申请号：US12791492
申请日：2010-06-01
申请人： Quentin DEBUISSCHERT , Denis UZIO , Jean-Luc NOCCA , Florent PICARD
发明人： Quentin DEBUISSCHERT , Denis UZIO , Jean-Luc NOCCA , Florent PICARD
IPC分类号： C10G45/58
CPC分类号： C10G67/08 , C10G65/06 , C10G2400/02
摘要： Production of gasolines with low sulfur contents from a starting gasoline containing sulfur-containing compounds comprising a stage a) for selective hydrogenation of non-aromatic polyunsaturated compounds present in the starting gasoline, a stage b) for increasing the molecular weight of the light sulfur-containing products that are initially present in the gasoline that enters this stage, a stage c) for alkylation of at least a portion of the sulfur-containing compounds present in the product that originates from stage b), a stage d) for fractionation of the gasoline that originates from stage c) into at least two fractions, one fraction virtually lacking in sulfur-containing compounds, whereby the other contains a larger proportion of sulfur-containing compounds (heavy gasoline), a stage e) for catalytic treatment of the heavy gasoline for transformation of sulfur-containing compounds under conditions for the at least partial decomposition of hydrogenation of these sulfur-containing compounds.
摘要翻译：从含有硫化合物的起始汽油中制备含硫低的汽油，包括a）用于选择氢化存在于起始汽油中的非芳族多不饱和化合物的步骤，b）用于提高轻质硫化物的分子量，最初存在于进入该阶段的汽油中的含有产物，c）用于烷基化存在于产物中的步骤b）中的至少一部分含硫化合物的阶段d），用于分馏起始于阶段c）的汽油至少有两个馏分，一个实际上不含硫化合物的馏分，另一个馏分含有较大比例的含硫化合物（重汽油），e）用于催化处理重质用于在含硫化合物的至少部分分解氢化的条件下转化含硫化合物的汽油化合物。

9. 发明授权

US07374667B2 Process for the production of gasoline with a low sulfur content comprising a stage for transformation of sulfur-containing compounds, an acid-catalyst treatment and a desulfurization 有权
标题翻译：用于生产低硫含量的汽油的方法，包括用于转化含硫化合物的阶段，酸催化剂处理和脱硫
公开(公告)号：US07374667B2
公开(公告)日：2008-05-20
申请号：US10095293
申请日：2002-03-12
申请人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard , David B Arnett , Mike Grayson , Donald E Zeek , Carl Snider
发明人： Quentin Debuisschert , Denis Uzio , Jean-Luc Nocca , Florent Picard , David B Arnett , Mike Grayson , Donald E Zeek , Carl Snider
IPC分类号： C10G45/04 , C07C2/54
CPC分类号： C10G67/08 , C10G2400/02
摘要： For the production of gasoline with a low sulfur content, a process comprises at least one stage for transformation of sulfur-containing compounds consisting of an alkylation or adsorption of sulfur-containing compounds and/or an increasing of the weight of light sulfur-containing compounds, at least one stage for treatment in the presence of an acid catalyst and at least one desulfurization treatment of at least a portion of the gasoline. The process can also optionally comprise at least one stage for selective hydrogenation of diolefins and optionally at least one fractionation of the gasoline that is obtained into at least two fractions: light gasoline and heavy gasoline.
摘要翻译：为了生产硫含量低的汽油，一种方法包括至少一个阶段，用于转化由含硫化合物的烷基化或吸附组成的含硫化合物和/或轻质含硫化合物的重量的增加，在酸催化剂存在下处理的至少一个阶段和至少一部分汽油的至少一个脱硫处理。该方法还可以任选地包含至少一个阶段，用于二烯烃的选择性氢化和任选的至少一种汽油的分馏，其被获得至少两个馏分：轻汽油和重汽油。

10. 发明授权

US6084141A Hydrogenation process comprising a catalytic distillation zone comprising a reaction zone with distribution of hydrogen 有权
标题翻译：包含催化蒸馏区的氢化方法，该催化蒸馏区包含氢分布的反应区
公开(公告)号：US6084141A
公开(公告)日：2000-07-04
申请号：US154756
申请日：1998-09-17
申请人： Paul Mikitenko , Christine Travers , Jean Cosyns , Charles Cameron , Jean-Luc Nocca , Francoise Montecot , Jean-Charles Viltard , Michel Dorbon , Blaise DiDillon
发明人： Paul Mikitenko , Christine Travers , Jean Cosyns , Charles Cameron , Jean-Luc Nocca , Francoise Montecot , Jean-Charles Viltard , Michel Dorbon , Blaise DiDillon
IPC分类号： B01D3/14 , B01D3/00 , B01J8/02 , B01J8/04 , C07B37/02 , C07B61/00 , C07B63/00 , C07C5/02 , C07C5/03 , C07C5/10 , C07C5/13 , C07C5/27 , C07C7/04 , C10G7/00 , C10G45/00 , C10G45/40 , C10G45/44 , C10G49/00
CPC分类号： C10G49/002 , B01D3/009 , B01J8/0257 , B01J8/0278 , C07C5/02 , C07C5/2767 , C10G45/00 , C10G45/40 , C10G45/44 , Y02P20/127 , Y10S203/06
摘要： The invention concerns a reactive distillation process comprising a distillation zone, associated with a reaction zone which is at least in part internal to said distillation zone and comprises at least one catalytic bed in which the feed is transformed in the presence of a catalyst and at least one gas stream containing hydrogen, characterized in that each catalytic bed in the internal portion of said reaction zone is traversed by said gas stream and liquid in ascending co-current mode. The invention particularly concerns selective hydrogenation processes for light unsaturated hydrocarbons, mainly any olefins and benzene, comprised in a mixture, the major portion of which is constituted by hydrocarbons containing at least five carbon atoms per molecule.
摘要翻译：本发明涉及一种反应蒸馏方法，其包括蒸馏区，该反应区至少部分地位于所述蒸馏区内部，并且包含至少一个催化床，在该催化床中，在催化剂存在下转化进料，并且至少一个含有氢的气流，其特征在于，所述反应区的内部部分的每个催化床以上升的并流模式被所述气流和液体横穿。本发明特别涉及用于轻质不饱和烃（主要是任何烯烃和苯）的选择性氢化方法，其包含在混合物中，其主要部分由每分子含有至少五个碳原子的烃构成。

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