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1. 发明授权

US4544791A Process for producing premium gasoline by polymerizing C.sub.4 cuts 失效
标题翻译：通过聚合C4切割生产优质汽油的方法
公开(公告)号：US4544791A
公开(公告)日：1985-10-01
申请号：US623672
申请日：1984-06-22
申请人： Bernard Juguin , Jean Miquel
发明人： Bernard Juguin , Jean Miquel
IPC分类号： C10G57/02 , B01J21/00 , B01J27/00 , C07C1/00 , C07C2/08 , C07C2/10 , C07C11/02 , C07C67/00 , C10G50/00 , C07C2/02
CPC分类号： C07C11/02 , C07C2/10 , C10G50/00 , C07C2521/02 , C07C2521/04 , C07C2521/12
摘要： The invention relates to a process for producing premium gasoline from olefinic C.sub.4 cuts containing 1- and 2-butenes and isobutene, the process consisting of converting at least 97% of the total isobutene content of the charge and at least the major portion of the 1- and 2-butenes thereof to C.sub.4 hyrocarbons dimers and trimers without producing substantial amounts of kerosene, said process being characterized in that, in a first step, the olefinic C.sub.4 cut is treated in a first polymerization catalytic zone so as to convert at least 80% of the isobutene to isobutene dimers and trimers and to convert at most 45% of the mixture of 1- and 2-butenes to dimers and trimers thereof, in that, subsequently, the effluent from said first catalytic polymerization zone is fractionated so as to recover, on the one hand, from the column bottom, essentially the C.sub.4 olefinic hydrocarbon dimers and trimers and, on the other hand, from the top of the column, a mixture containing the major part of the isobutene and 1- and 2-butenes not converted in said first catalytic polymerization zone, said mixture being, during a second step, at least partly fed to a second catalytic polymerization zone so as to convert (a) substantially the total amount of isobutene to isobutene dimers and trimers in said second zone and (b) at least 50% of the 1- and 2-butenes, supplied to said second zone to n-butenes dimers and trimers.
摘要翻译：本发明涉及从含有1-和2-丁烯和异丁烯的烯烃C4馏分产生优质汽油的方法，该方法包括将至少97％的电荷的异丁烯含量和至少大部分的1 - 和2-丁烯，其不产生大量的煤油，所述方法的特征在于，在第一步骤中，将烯烃C4馏分在第一聚合催化剂区域中处理以使其转化为至少80 ％异丁烯与异丁烯二聚体和三聚体的比例，并将至多45％的1-和2-丁烯的混合物转化为二聚体和三聚体，因为随后将来自所述第一催化聚合区的流出物分馏，以便一方面从塔底回收，基本上是C4烯烃二聚体和三聚体，另一方面从塔顶回收含有主要部分异丁烯的混合物并且在所述第一催化聚合区中未转化的1-和2-丁烯，所述混合物在第二步骤期间至少部分地进料到第二催化聚合区，从而将（a）基本上将异丁烯的总量转化为异丁烯所述第二区域中的二聚体和三聚体，和（b）至少50％的1-和2-丁烯，被供应到所述第二区域以形成正丁烯二聚体和三聚体。

2. 发明授权

US4434315A Process for isomerizing olefins 失效
标题翻译：烯烃异构化方法
公开(公告)号：US4434315A
公开(公告)日：1984-02-28
申请号：US380857
申请日：1982-05-21
申请人： Bernard Juguin , Jean Miquel
发明人： Bernard Juguin , Jean Miquel
IPC分类号： C07C5/27 , C07C11/09 , C07C5/23
CPC分类号： C07C11/09 , C07C5/2772 , C07C5/2791
摘要： Process for isomerizing linear ethylenic hydrocarbons to branched ethylenic hydrocarbons having the same number of carbon atoms in the molecule, in the presence of steam and of a catalyst containing alumina, silica and a metal or compound of a metal selected from chromium, palladium, nickel, copper and silver at critical concentrations of silica and of metal, and with a critical proportion of water with respect to the hydrocarbons.
摘要翻译：将异构化的线性烯烃异构化为分子中具有相同数目碳原子的支链烯烃在蒸汽存在下和含有氧化铝，二氧化硅和金属或选自铬，钯，镍，铜和银在临界浓度的二氧化硅和金属，以及相对于烃的临界比例的水。

3. 发明授权

US4250056A Catalysts for hydroreforming 失效
标题翻译：催化剂用于加氢成型
公开(公告)号：US4250056A
公开(公告)日：1981-02-10
申请号：US112260
申请日：1980-01-15
申请人： Jean-Francois Le Page , Germain Martino , Jean Miquel
发明人： Jean-Francois Le Page , Germain Martino , Jean Miquel
IPC分类号： C10G35/085 , B01J23/62 , B01J23/656 , B01J27/06 , B01J27/13 , C10G35/09 , B01J21/04 , B01J23/64 , B01J27/08
CPC分类号： B01J23/6567 , B01J27/06 , C10G35/09
摘要： Process for reforming hydrocarbons or producing aromatic hydrocarbons under severe operating conditions, in the presence of a catalyst comprising an alumina carrier and, expressed by weight with respect to alumina:(a) from 0.05 to 0.6% of platinum(b) from 0.01 to 2% of rhenium(c) from 0.05 to 3% of thallium or indium, and(d) from 0.1 to 10% of a halogen.
摘要翻译：在严格的操作条件下，在包含氧化铝载体的催化剂存在下，以重量计相对于氧化铝的方法：（a）0.05至0.6％的铂（b），0.01至2 铼（c）的百分比为0.05〜3％的铊或铟，（d）为0.1〜10％的卤素。

4. 发明授权

US4217205A Catalysts for hydrocarbon conversion 失效
标题翻译：用于烃转化的催化剂
公开(公告)号：US4217205A
公开(公告)日：1980-08-12
申请号：US936966
申请日：1978-08-25
申请人： Christian Marcilly , Jean-Francois Le Page , Germain Martino , Jean Miquel
发明人： Christian Marcilly , Jean-Francois Le Page , Germain Martino , Jean Miquel
IPC分类号： B01J23/652 , B01J27/13 , C10G35/09 , C10G35/08
CPC分类号： B01J23/6527 , C10G35/09
摘要： Catalyst, particularly useful in catalytic reforming and for producing highly pure aromatic hydrocarbons, comprising an alumina carrier and containing, expressed in proportion of the weight of the alumina carrier:0.005 to 1% of platinum0.01 to 4% of gallium, indium or thallium0.01 to 2% of tungsten, and0.1 to 10% of halogen.
摘要翻译：催化剂，特别适用于催化重整和生产高纯度芳族烃，包含氧化铝载体并含有以氧化铝载体重量比例表示的：0.005至1％的铂，0.01至4％的镓，铟或铊0.01 至2％的钨和0.1至10％的卤素。

5. 发明授权

US4201661A Process for producing aromatics of high purity from oil cuts 失效
标题翻译：从油切割生产高纯度芳烃的方法
公开(公告)号：US4201661A
公开(公告)日：1980-05-06
申请号：US454942
申请日：1974-03-26
申请人： Bernard Juguin , Jean-Francois Le Page , Jean Miquel
发明人： Bernard Juguin , Jean-Francois Le Page , Jean Miquel
IPC分类号： C10G35/085 , B01J23/00 , B01J23/48 , B01J23/89 , B01J37/22 , C07B61/00 , C07C1/00 , C07C5/373 , C07C5/393 , C07C5/41 , C07C15/02 , C07C67/00 , C10G35/09 , C10G45/62 , C10G35/08
CPC分类号： C10G35/09 , B01J23/48 , B01J23/8926 , B01J37/22 , C07C5/417 , C10G2400/02
摘要： Aromatic hydrocarbons of high purity are produced from saturated or unsaturated gasolines and hydrogen in the presence of a new catalyst containing alumina, platinum, at least one metal selected from the group consisting of iridium, rhodium and palladium and at least one metal selected from the group consisting of copper, silver and gold.
摘要翻译：在含有氧化铝，铂，选自铱，铑和钯的至少一种金属和选自铱，铑和钯的至少一种金属的新催化剂存在下，由饱和或不饱和的汽油和氢气生成高纯度的芳族烃，由铜，银和金组成。

6. 发明授权

US4180453A Process for the steam-cracking of heavy feedstocks 失效
标题翻译：重质原料蒸汽裂解的工艺
公开(公告)号：US4180453A
公开(公告)日：1979-12-25
申请号：US876825
申请日：1978-02-10
申请人： Jean-Pierre Franck , Edouard Freund , Jean-Francois Le Page , Jean Miquel
发明人： Jean-Pierre Franck , Edouard Freund , Jean-Francois Le Page , Jean Miquel
IPC分类号： B01J27/00 , C10G65/06 , C10G69/06 , C10G37/00
CPC分类号： C10G65/06 , C10G2400/20
摘要： A fresh charge containing aromatic hydrocarbons is hydrotreated in admixture with a recycle fraction, in the presence of a bifunctional catalyst, a portion of the effluent is subjected to steam-cracking, thereby recovering a gas oil fraction which is subjected to hydrogenation and forms said recycle fraction. The mixture of recycle fraction and charge is advantageously treated with hydrogen in the presence of a monofunctional catalyst to hydrogenate olefins, at a lower temperature than the hydrotreatment, and then passed to the hydrotreatment zone.
摘要翻译：将含有芳烃的新鲜电荷与再循环部分混合加氢处理，在双官能催化剂存在下，将一部分流出物进行蒸汽裂化，从而回收粗制油馏分进行氢化并形成所述再循环分数。有利的是，在单官能催化剂存在下，用氢气处理再循环部分和装料的混合物，以在比加氢处理的温度更低的温度下氢化烯烃，然后通入加氢处理区。

7. 发明授权

US4058450A Process for producing aromatic hydrocarbons of high purity 失效
标题翻译：生产高纯度芳烃的方法
公开(公告)号：US4058450A
公开(公告)日：1977-11-15
申请号：US669335
申请日：1976-03-22
申请人： Jean-Francois Le Page , Bernard Juguin , Jean Miquel
发明人： Jean-Francois Le Page , Bernard Juguin , Jean Miquel
IPC分类号： C07C5/393 , B01J23/00 , B01J27/00 , C07B61/00 , C07C1/00 , C07C15/02 , C07C67/00 , C10G47/00 , C10G59/02 , C10G35/04 , C07C3/58
CPC分类号： C10G59/02 , C10G2400/30
摘要： Process for producing aromatic hydrocarbons from gasolines substantially free of mono- and diolefins, comprising an aromizing step in the presence of a catalyst at a temperature from 400.degree. to 600.degree. C under a pressure from 1 to 30 kg/cm.sup.2 followed with the separation of an aromatic cut and of an alkylaromatic cut and a step of hydrodealkylating said alkylaromatic cut by means of hydrogen recovered from the aromizing step, in the presence of a catalyst, at a temperature from 400.degree. to 650.degree. C, under a pressure substantially equal or lower than that of the aromizing step.
摘要翻译：从基本上不含单烯烃和二烯烃的汽油制备芳烃的方法，包括在催化剂存在下在400至600℃的压力下在1至30kg / cm2下进行芳香化步骤，然后分离芳香族切割和烷基芳族化合物切割的步骤，以及在400℃至650℃的温度下，在基本相等的压力下，在芳香化步骤中回收的氢气在烷基芳族化合物加氢脱烷基化的步骤，低于芳香化步骤。

8. 发明授权

US4043944A Catalysts for hydrocarbon conversion 失效
标题翻译：用于烃转化的催化剂
公开(公告)号：US4043944A
公开(公告)日：1977-08-23
申请号：US620410
申请日：1975-10-07
申请人： Bernard Juguin , Jean Cosyns , Jean-Francois Le Page , Jean Miquel
发明人： Bernard Juguin , Jean Cosyns , Jean-Francois Le Page , Jean Miquel
IPC分类号： C07C5/393 , B01J23/04 , B01J23/75 , B01J23/84 , B01J23/89 , C07B61/00 , C07C1/00 , C07C15/02 , C07C67/00 , C10G35/09 , B01J23/38 , B01J21/00 , B01J23/62 , C10G35/06
CPC分类号： B01J23/04 , B01J23/75 , B01J23/84 , B01J23/8933 , B01J23/8986 , C10G35/09
摘要： New catalyst comprising a carrier such for example as alumina, platinum, at least one metal selected from iridium, tungsten and ruthenium, cobalt, at least one metal selected from the group consisting of copper, manganese, silver and gold, and at least one halogen such for example as chlorine.
摘要翻译：包含载体的新型催化剂，例如氧化铝，铂，至少一种选自铱，钨和钌的金属，钴，至少一种选自铜，锰，银和金的金属和至少一种卤素例如氯。

9. 发明授权

US4423264A Process for the joint production of highly pure 1-butene and premium gasoline from a C.sub.4 olefinic cut 失效
标题翻译：从C4烯烃切割联合生产高纯度1-丁烯和优质汽油的方法
公开(公告)号：US4423264A
公开(公告)日：1983-12-27
申请号：US392056
申请日：1982-06-25
申请人： Bernard Juguin , Jean Cosyns , Jean Miquel
发明人： Bernard Juguin , Jean Cosyns , Jean Miquel
IPC分类号： C10G69/12 , C07C11/08 , C10L1/04 , C10L1/06 , C07C2/74
CPC分类号： C07C11/08 , C10L1/04 , C10L1/06
摘要： Highly pure 1-butene and premium gasoline are obtained by(a) subjecting a C.sub.4 olefinic cut to a polymerization-disproportionation to partly convert the isobutene thereof to a gasoline which, in turn, by partial disproportionation, yields a jet fuel base and butenes,(b) fractionating the effluent from step (a) to a mixture (.alpha.) of gasoline and jet fuel base and to a fraction (.beta.) containing isobutane, n-butane, butenes, a small amount of isobutene and a minor amount of butadiene,(c) selectively polymerizing fraction (.beta.) to convert more than 90% of the isobutene thereof to gasoline,(d) fractionating the polymerized fraction (.beta.) to a gasoline cut (.gamma.) containing isobutene dimers and trimers and to a fraction (.delta.) containing isobutane, n-butane and butenes,(e) selectively hydrogenating the fraction (.delta.),(f) removing isobutane from the hydrogenated fraction (.delta.) and(g) fractionating the deisobutanized hydrogenated fraction (.delta.) to obtain a fraction containing at least 99% of 1-butene, the mixture (.alpha.) being admixed with the cut (.gamma.).
摘要翻译：通过以下方法获得高纯度的1-丁烯和优质汽油：（a）使C4烯烃切割物进行聚合歧化，将其异丁烯部分转化成汽油，然后汽油通过部分歧化产生喷气燃料基体和丁烯，（b）将来自步骤（a）的流出物分馏成汽油和喷气燃料基料的混合物（α）和含有异丁烷，正丁烷，丁烯，少量异丁烯和少量丁二烯的馏分（β），（c）选择性地聚合馏分（β）以将其超过90％的异丁烯转化成汽油，（d）将聚合馏分（β）分馏成含有异丁烯二聚体和三聚体的汽油馏分（γ）（e）选择性氢化馏分（δ），（f）从氢化馏分（delta）中除去异丁烷，和（g）分离除异丁氢化氢化馏分（delta）以获得af 反应物含有至少99％的1-丁烯，混合物（α）与切割（γ）混合。

10. 发明授权

US4324646A Process for converting C.sub.4 olefinic cracking cuts to alkylate and gasoline 失效
标题翻译：将C4烯烃裂解馏分转化为烷基化物和汽油的方法
公开(公告)号：US4324646A
公开(公告)日：1982-04-13
申请号：US180205
申请日：1980-08-21
申请人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
发明人： Jean-Francois Le Page , Jean Cosyns , Jean Miquel , Bernard Juguin
IPC分类号： C10G57/02 , C07C9/16 , C10G35/04 , C10G50/00 , C10G69/12 , C10L1/06
CPC分类号： C07C9/16 , C10L1/06
摘要： A process is provided for selectively polymerizing isobutene in an olefinic C.sub.4 cut comprising isobutene and normal butenes by contacting the cut with a catalyst consisting essentially of silica-alumina; whereby at least 90% of the isobutene and less than 10% of the normal butenes in the cut are converted.
摘要翻译：提供了一种通过使切割与基本上由二氧化硅 - 氧化铝组成的催化剂接触来选择性地聚合包含异丁烯和正丁烯的烯烃C4馏分中的异丁烯的方法; 由此转化了至少90％的异丁烯和小于正丁烯的10％。

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