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1. 发明授权

US5502018A Nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process 失效
标题翻译：含镍组合物用于催化和烯烃二聚和低聚过程
公开(公告)号：US5502018A
公开(公告)日：1996-03-26
申请号：US309703
申请日：1994-09-21
申请人： Yves Chauvin , Sandra Einloft , Helene Olivier
发明人： Yves Chauvin , Sandra Einloft , Helene Olivier
IPC分类号： B01J31/02 , B01J31/14 , B01J31/18 , B01J31/22 , B01J31/24 , C07B61/00 , C07C2/32 , C07C2/36 , C07C11/02 , C10G50/00 , B01J27/185
CPC分类号： C07C2/36 , B01J31/143 , B01J31/181 , B01J31/24 , B01J31/2404 , B01J2231/20 , B01J2531/847 , B01J2531/90 , B01J31/0234 , B01J31/2208 , C07C2527/128 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： The invention concerns a catalytic composition and a process for the dimerization, codimerization or oligomerization of olefins, said composition comprising a mixture of at least one bivalent nickel complex which contains two tertiary phosphine molecules, at least one nickel compound or complex compound which contains neither water nor phosphine, and at least one alkylaluminum halide. The mixture is particularly for use in ionic type non aqueous liquid compositions, such as those formed by quaternary ammonium halides and/or quaternary phosphonium halides with aluminum halides and/or alkylaluminum halides.
摘要翻译：本发明涉及一种催化组合物和烯烃二聚，共二聚或低聚的方法，所述组合物包含至少一种含有两个叔膦分子的二价镍络合物的混合物，至少一种不含水的镍化合物或络合物也不是膦，以及至少一种烷基铝卤化物。该混合物特别用于离子型非水性液体组合物，例如由具有卤化铝和/或烷基卤化铝的季铵卤化物和/或季卤化鏻形成的那些。

2. 发明授权

US5550304A Nickel-containing composition for catalysis and olefin dimerisation and oligomerisation process 失效
标题翻译：含镍组合物用于催化和烯烃二聚和低聚过程
公开(公告)号：US5550304A
公开(公告)日：1996-08-27
申请号：US451159
申请日：1995-05-26
申请人： Yves Chauvin , Sandra Einloft , Helene Olivier
发明人： Yves Chauvin , Sandra Einloft , Helene Olivier
IPC分类号： B01J31/02 , B01J31/14 , B01J31/18 , B01J31/22 , B01J31/24 , C07B61/00 , C07C2/32 , C07C2/36 , C07C11/02 , C10G50/00 , C07C2/02 , C07C2/24
CPC分类号： C07C2/36 , B01J31/143 , B01J31/181 , B01J31/24 , B01J31/2404 , B01J2231/20 , B01J2531/847 , B01J2531/90 , B01J31/0234 , B01J31/2208 , C07C2527/128 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： The invention concerns a catalytic composition and a process for the dimerisation, codimerisation or oligomerisation of olefins, said composition comprising a mixture of at least one bivalent nickel complex which contains two tertiary phosphine molecules, at least one nickel complex which contains neither water nor phosphine, and at least one alkylaluminium halide. The mixture is particularly for use in ionic type non aqueous liquid compositions, such as those formed by quaternary ammonium halides and/or quaternary phosphonium halides with aluminium halides and/or alkylaluminium halides.
摘要翻译：本发明涉及烯烃的二聚，共二聚或低聚的催化组合物和方法，所述组合物包含至少一种含有两个叔膦分子的二价镍络合物，至少一个既不含水也不含有膦的镍络合物的混合物，和至少一种烷基卤化铝。该混合物特别用于离子型非水性液体组合物，例如由具有卤化铝和/或烷基卤化铝的季铵卤化物和/或卤化鏻形成的那些。

3. 发明授权

US5550306A Catalytic process for the dimerization of olefins 失效
标题翻译：催化二烯化烯烃的方法
公开(公告)号：US5550306A
公开(公告)日：1996-08-27
申请号：US456820
申请日：1995-06-01
申请人： Yves Chauvin , Sandra Einloft , Helene Olivier
发明人： Yves Chauvin , Sandra Einloft , Helene Olivier
IPC分类号： B01J27/125 , B01J31/02 , B01J31/14 , B01J31/24 , C07C2/36 , C07C2/24
CPC分类号： B01J27/125 , B01J31/0284 , B01J31/0288 , B01J31/143 , B01J31/24 , C07C2/36 , B01J2231/20 , B01J2531/847 , C07C2531/22 , C07C2531/24
摘要： The invention is concerned with a process for the dimerization, co-dimerization and oligomerization of olefins with a catalytic composition resulting from mixing at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, at least one aluminum halide, at least one aromatic hydrocarbon and optionally an aluminium organometallic compound.
摘要翻译：本发明涉及一种通过将至少一种季铵卤化物和/或至少一种季鏻卤化物，至少一种卤化铝和至少一种卤化铝混合而得到的催化组合物进行烯烃二聚，共二聚和低聚的方法芳族烃和任选的铝有机金属化合物。

4. 发明授权

US5536689A Catalytic composition and a process for the dimerization of olefins 失效
标题翻译：催化组合物和烯烃二聚的方法
公开(公告)号：US5536689A
公开(公告)日：1996-07-16
申请号：US309702
申请日：1994-09-21
申请人： Yves Chauvin , Sandra Einloft , Helene Olivier
发明人： Yves Chauvin , Sandra Einloft , Helene Olivier
IPC分类号： B01J23/28 , B01J23/30 , B01J27/125 , B01J31/02 , B01J31/14 , B01J31/24 , C07B61/00 , C07C2/32 , C07C2/36 , C07C11/02 , C10G50/00 , B01J31/22
CPC分类号： B01J27/125 , B01J31/0284 , B01J31/0288 , B01J31/143 , B01J31/24 , C07C2/36 , B01J2231/20 , B01J2531/847 , C07C2527/053 , C07C2527/128 , C07C2531/02 , C07C2531/04 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C07C2531/30
摘要： The invention is concerned with a catalytic composition resulting from dissolving a nickel complex mixed or complexed with a tertiary phosphine in the medium resulting from mixing at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, at least one aluminum halide, at least one aromatic hydrocarbon and optionally an aluminum organometallic compound. The invention is also concerned with a process for the dimerization, codimerization and oligomerization of olefins with this composition.
摘要翻译：本发明涉及一种催化组合物，该催化剂组合物是将在混合至少一种季铵卤化物和/或至少一种卤化鏻卤化物（至少一种卤化铝）的混合或与叔膦络合的镍络合物至少一种芳烃和任选的铝有机金属化合物。本发明还涉及使用该组合物进行烯烃二聚，共聚和低聚的方法。

5. 发明授权

US08470940B2 Complexes and method for synthesis of group 4 organometallics grafted on anions olefin oligomerization and polymerization method 失效
标题翻译：用于合成第4族有机金属化合物的络合物和方法接枝在阴离子烯烃低聚和聚合方法上
公开(公告)号：US08470940B2
公开(公告)日：2013-06-25
申请号：US12667557
申请日：2008-07-03
申请人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
发明人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
IPC分类号： C08F4/52 , C08F4/64 , C08F4/76 , B01J31/38 , C07F7/00
CPC分类号： C07F17/00 , C07F7/00 , C08F4/65912 , C08F10/00 , C08F10/02 , C08F2410/03 , C08F4/659 , C08F4/65908 , C08F4/643 , C08F4/65925
摘要： Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminum comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.
摘要翻译：通过至少一种包含至少一个羟基的硼酸盐或铝与至少一种4族过渡金属化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新型4族有机金属化合物。这些化合物用于以烯烃低聚或聚合方法实施的催化组合物。

6. 发明申请

US20100286349A1 NOVEL COMPLEXES AND METHOD FOR SYNTHESIS OF GROUP 4 ORGANOMETALLICS GRAFTED ON ANIONS OLEFIN OLIGOMERIZATION AND POLYMERIZATION METHOD 失效
标题翻译：合成低聚物和聚合方法的组合4组分的新型复合物和方法
公开(公告)号：US20100286349A1
公开(公告)日：2010-11-11
申请号：US12667557
申请日：2008-07-03
申请人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
发明人： Christine Bibal , Catherine Santini , Yves Chauvin , Helene Olivier-Bourbigou , Christophe Vallee
IPC分类号： C08F4/52 , C07D233/58 , C07F9/54 , C07D207/06 , B01J31/14
CPC分类号： C07F17/00 , C07F7/00 , C08F4/65912 , C08F10/00 , C08F10/02 , C08F2410/03 , C08F4/659 , C08F4/65908 , C08F4/643 , C08F4/65925
摘要： Novel group 4 organometallic compounds, supported on anions by means of at least one covalent metal-oxygen bond, are obtained by reaction of at least one borate or aluminium comprising at least one hydroxy group with at least one group 4 transition metal compound. These compounds are used in a catalytic composition implemented in an olefin oligomerization or polymerization method.
摘要翻译：通过至少一种包含至少一个羟基的硼酸盐或铝与至少一种4族过渡金属化合物的反应获得通过至少一种共价金属 - 氧键负载在阴离子上的新型4族有机金属化合物。这些化合物用于以烯烃低聚或聚合方法实施的催化组合物。

7. 发明授权

US5852130A Catalytic composition based on transition metal complexes, and a process for the hydrogenation of unsaturated compounds 失效
标题翻译：基于过渡金属络合物的催化组合物，以及不饱和化合物氢化的方法
公开(公告)号：US5852130A
公开(公告)日：1998-12-22
申请号：US664539
申请日：1996-06-17
申请人： Lothar Mussmann , Yves Chauvin , Helene Olivier
发明人： Lothar Mussmann , Yves Chauvin , Helene Olivier
IPC分类号： B01J31/22 , B01J23/46 , B01J31/02 , B01J31/16 , B01J31/24 , C07B61/00 , C07C5/03 , C07C5/11 , C07C9/00 , C07C13/20 , C07C13/58 , C08F8/04
CPC分类号： B01J31/16 , B01J31/0278 , B01J31/0284 , B01J31/0288 , B01J31/20 , B01J31/2291 , B01J31/2404 , B01J31/2409 , B01J2231/645 , B01J23/462 , B01J23/464 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/845
摘要： A novel catalytic composition comprises at least one quaternary ammonium and/or phosphonium salt in which the anion is selected from the group formed by tetrafluoroborate, tetrachloroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, trifluorosulphonate, fluorosulphonate, tetrachloroaluminate, dichlorocuprate, and trichlorozincate, and at least one complex of a transition metal from groups 8, 9 and 10, i.e., iron, ruthenium, cobalt, rhodium iridium, nickel, palladium and platinum. Application to total or selective hydrogenation of unsaturated compounds such as monoolefins, diolefins, acetylenic compounds, aromatic compounds, polynuclear aromatic compounds. Hydrogenation may be accompanied by isomerisation.
摘要翻译：一种新型催化剂组合物包含至少一种季铵盐和/或鏻盐，其中阴离子选自四氟硼酸盐，四氯硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，三氟磺酸盐，氟磺酸盐，四氯铝酸盐，二氯磷酸盐和三氯酸锌形成的基团，来自组8,9和10的过渡金属的一个复合物，即铁，钌，钴，铑铱，镍，钯和铂。适用于单烯烃，二烯烃，炔属化合物，芳香族化合物，多核芳香族化合物等不饱和化合物的全部或选择性氢化。氢化可伴随异构化。

8. 发明授权

US5693585A Aliphatic alkylation catalyst comprising an active phase containing a cuprous compound on a support 失效
标题翻译：脂肪族烷基化催化剂包含在载体上含有亚铜化合物的活性相
公开(公告)号：US5693585A
公开(公告)日：1997-12-02
申请号：US664538
申请日：1996-06-17
申请人： Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
发明人： Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
IPC分类号： B01J21/08 , B01J27/125 , B01J31/02 , B01J31/26 , B01J31/28 , B01J32/00 , B01J35/02 , B01J35/10 , C07B61/00 , C07C2/58 , C07C2/60 , C07C9/16 , B01J27/122 , B01J27/25 , B01J31/00
CPC分类号： C07C2/60 , B01J31/0294 , B01J31/26 , B01J31/28 , B01J31/30 , B01J21/08 , B01J2231/323 , B01J35/023 , B01J35/1019 , B01J35/1047 , C07C2521/08 , C07C2527/053 , C07C2527/122 , C07C2527/125 , C07C2527/126 , C07C2527/24 , C07C2531/02 , C07C2531/04 , Y02P20/584
摘要： A catalyst containing a porous organic or mineral support and at least one active phase having at least one aluminum halide, at least one compound selected for quaternary ammonium halides and amine hydrohalides, and at least one cuprous compound, the support having been impregnated with the active phase, the catalyst essentially constituted by particles with an average diameter in the range 0.1 .mu.m to 150 .mu.m, and the support, before impregnation with the active phase, has a total pore volume in the range 0.1 cm.sup.3 /g and 6 cm.sup.3 /g.
摘要翻译：含有多孔有机或矿物载体和至少一种具有至少一种卤化铝，至少一种选自季铵卤化物和胺氢卤化物的化合物和至少一种亚铜化合物的活性相的催化剂，该载体已经浸渍有活性相，催化剂基本上由平均直径在0.1μm至150μm的颗粒构成，并且在用活性相浸渍之前，载体的总孔体积在0.1cm 3 / g和6cm 3 / G。

9. 发明授权

US4845201A Process for producing organolanthanides, the resultant compounds and their use 失效
标题翻译：生产有机镧系元素的方法，所得化合物及其用途
公开(公告)号：US4845201A
公开(公告)日：1989-07-04
申请号：US146752
申请日：1988-01-22
申请人： Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
发明人： Yves Chauvin , Dominique Commereuc , Francois Hugues , Helene Olivier , Lucien Saussine
IPC分类号： C07C5/03 , C07C29/143 , C07C45/61 , C07C45/62 , C07C45/65 , C07F5/00 , C08F4/42 , C22B59/00
CPC分类号： C22B59/00 , C07C29/143 , C07C45/61 , C07C45/62 , C07C45/65 , C07C5/03 , C07F5/00 , C08F4/42 , C07C2103/24 , C07C2531/12 , Y02P20/52
摘要： A process for producing organolanthanides by reaction of a rare-earth metal with an unsaturated compound in an ether medium, the resultant compounds and the use of these compounds in organic synthesis and for catalysis is disclosed. The process is conducted at -80.degree. to +100.degree. C., in the absence of oxygen and any compound having active protons. The resultant compounds are useful as catalysts, e.g., in the hydrogenation of olefins and diolefins and in the polymerization thereof, and are useful as chemical intermediates.
摘要翻译：公开了一种通过稀土金属与不饱和化合物在醚介质中反应制备有机镧系元素的方法，所得化合物以及这些化合物在有机合成和催化中的用途。该方法在-80℃至+ 100℃下进行，在不存在氧气和任何具有活性质子的化合物的情况下进行。所得化合物可用作催化剂，例如在烯烃和二烯烃的氢化中和在其聚合反应中，并且可用作化学中间体。

10. 发明授权

US5874638A Process for hydroformylation of olefinic compounds 失效
标题翻译：烯烃化合物加氢甲酰化方法
公开(公告)号：US5874638A
公开(公告)日：1999-02-23
申请号：US755853
申请日：1996-12-02
申请人： Yves Chauvin , Helene Olivier , Lothar Mussmann
发明人： Yves Chauvin , Helene Olivier , Lothar Mussmann
IPC分类号： B01J31/16 , C07B61/00 , C07C45/50 , C07C47/02 , C07C47/12
CPC分类号： C07C45/50
摘要： A hydroformylation process for unsaturated compounds such as monoolefins and diolefins is carried out in an ionic medium in which the catalytic species is dissolved, but in which the reaction products (aldehydes) formed are only slightly soluble or are insoluble. The ionic medium is liquid at a temperature below 90.degree. C. and comprises at least one quaternary ammonium and/or phosphonium cation and at least one anion which is preferably selected from the group formed by tetrafluoroborate when the cation is ammonium, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, perfluoroalkylsulphonates, fluorosulphonate, bis-perfluoroalkylsulphonyl amides or dichlorocuprate, tetrachlorocuprate, tetrachloroaluminate, or trichlorozincate. At the end of the reaction, the organic phase is separated out and the polar phase containing the catalyst is used again.
摘要翻译：用于不饱和化合物如单烯烃和二烯烃的加氢甲酰化方法在其中溶解催化物质的离子介质中进行，但其中形成的反应产物（醛）仅仅是微溶或不溶解的。离子介质在低于90℃的温度下是液体，并且包含至少一种季铵和/或鏻阳离子和至少一种阴离子，当阳离子是铵，六氟磷酸盐，六氟锑酸盐时，优选选自四氟硼酸盐形成的基团，六氟砷酸盐，全氟烷基磺酸盐，氟磺酸盐，双全氟烷基磺酰胺或二氯磷酸盐，四氯磷酸盐，四氯铝酸盐或三氯酸锌。在反应结束时，分离有机相，再次使用含有催化剂的极性相。

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