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    • 1. 发明授权
    • Method of producing an aromatics alkylation catalyst
    • 芳烃烷基化催化剂的制备方法
    • US06051521A
    • 2000-04-18
    • US139226
    • 1998-08-25
    • Jane C. ChengHye Kyung C. Timken
    • Jane C. ChengHye Kyung C. Timken
    • B01J29/04B01J37/00B01J37/30
    • B01J29/70B01J29/7038B01J37/0009B01J37/30
    • This invention provides a method of producing an aromatics alkylation catalyst comprising the steps of:(a) synthesizing a layered oxide material MCM-56 in the presence of alkali and/or alkaline earth metal cations;(b) prior to any calcination of the MCM-56, subjecting the MCM-56 produced in step (a) to ammonium ion exchange so as to at least partially replace the alkaline or alkaline earth metal cations associated with the MCM-56 with ammonium ions; then(c) heating the ammonium-exchanged MCM-56 to decompose the ammonium cations and convert the MCM-56 into the hydrogen form; and(d) after step (b), forming the MCM-56 into catalyst particles.The resultant catalyst exhibits enhanced activity in the alkylation of benzene with ethylene and propylene.
    • 本发明提供一种生产芳烃烷基化催化剂的方法,包括以下步骤:(a)在碱金属和/或碱土金属阳离子存在下合成层状氧化物材料MCM-56; (b)在MCM-56的任何煅烧之前,使步骤(a)中产生的MCM-56进行铵离子交换,以便至少部分地用铵与铵相关的碱金属或碱土金属阳离子 离子 然后(c)加热铵交换的MCM-56以分解铵阳离子并将MCM-56转化为氢形式; 和(d)步骤(b)之后,将MCM-56形成催化剂颗粒。 所得催化剂在用乙烯和丙烯烷基化苯中表现出增强的活性。
    • 6. 发明授权
    • Extremely low acidity ultrastable Y zeolite catalyst composition and process
    • 极低的酸度超稳定的Y沸石催化剂组成及工艺
    • US06860986B2
    • 2005-03-01
    • US10290791
    • 2002-11-08
    • Hye Kyung C. TimkenLucy Melinda BullThomas V. Harris
    • Hye Kyung C. TimkenLucy Melinda BullThomas V. Harris
    • B01J29/08B01J29/16C10G47/16C10G47/20
    • C10G47/20B01J29/084B01J29/166B01J2229/16C10G47/16
    • A catalyst composition comprising a low acidity, highly dealuminated ultra stable Y zeolite having an Alpha value of less than about 3 and Broensted acidity measured by FT-IR from about 1 to about 20, preferably from about 1-10, micro mole/g of, an amorphous cracking component and a catalytic amount of hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal, and mixtures thereof is disclosed. The present invention provides for a process for converting hydrocarbonaceous oils comprising contacting the hydrocarbonaceous oils with the catalyst under suitable hydrocarbon conversion conditions. Such processes in include, but are not limited to, single stage hydrocracking, two-stage hydrocracking, series-flow hydrocracking, mild hydrocracking, lube hydrocracking, hydrotreating, lube hydrofinishing, hydrodesulphurization, hydrodenitrification, catalytic dewaxing and catalytic cracking.
    • 一种催化剂组合物,其包含具有低于约3的α值低于约3的低酸度,高度脱铝的超稳定Y沸石,通过FT-IR测量的Broensted酸度为约1至约20,优选约1-10微摩尔/ g 公开了无定形裂化组分和催化量的选自VI族金属,VIII族金属及其混合物的氢化组分。 本发明提供了一种用于转化含烃油的方法,包括在合适的烃转化条件下使烃类油与催化剂接触。 这些方法包括但不限于单级加氢裂化,两级加氢裂化,串联加氢裂化,轻度加氢裂化,润滑油加氢裂化,加氢处理,润滑油加氢精制,加氢脱硫,加氢脱氮,催化脱蜡和催化裂化。
    • 10. 发明申请
    • PROCESS FOR PRODUCING ALKYLATE WITH AN INCREASED RON
    • 生产烷基酸的方法增加
    • US20110144399A1
    • 2011-06-16
    • US13031444
    • 2011-02-21
    • Saleh ElomariHye Kyung C. Timken
    • Saleh ElomariHye Kyung C. Timken
    • C07C2/58
    • C10G69/123C07C2/58C07C9/16C07C2531/14C10G29/205C10G2300/1081C10G2300/1088C10G2400/02C10G2400/20
    • A process for producing alkylate comprising contacting a first hydrocarbon stream comprising at least one olefin having from 2 to 6 carbon atoms which contains 1-butene with an isomerization catalyst under conditions favoring the isomerization of 1-butene to 2-butene so the isomerized stream contains a greater concentration of 2-butene than the first hydrocarbon stream and contacting the isomerized stream and a second hydrocarbon stream comprising at least one isoparaffin having from 4 to 6 carbon atoms with an acidic ionic liquid catalyst under alkylation conditions to produce an alkylate stream, wherein the alkylate stream has a RON that is increased from 5 to 32 numbers compared to a comparison alkylate stream made from the first hydrocarbon stream without the step of contacting with the isomerization catalyst.
    • 一种生产烷基化物的方法,包括在有利于1-丁烯异构化为2-丁烯的条件下使包含至少一种含有2-6个碳原子的含有1-丁烯的烯烃与异构化催化剂接触的第一烃料流,使得异构化料流含有 比第一烃流更高浓度的2-丁烯,并且在烷基化条件下使异源化物流和含有至少一个具有4-6个碳原子的异链烷烃的第二烃物流与酸性离子液体催化剂接触以产生烷基化物流,其中 与由第一烃流制备的比较烷基化物流相比,烷基化物流具有从5至32个数量增加的RON,而不与异构化催化剂接触的步骤。