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    • 2. 发明申请
    • PROCESS FOR PRODUCING ALKYLATE WITH AN INCREASED RON
    • 生产烷基酸的方法增加
    • US20110144399A1
    • 2011-06-16
    • US13031444
    • 2011-02-21
    • Saleh ElomariHye Kyung C. Timken
    • Saleh ElomariHye Kyung C. Timken
    • C07C2/58
    • C10G69/123C07C2/58C07C9/16C07C2531/14C10G29/205C10G2300/1081C10G2300/1088C10G2400/02C10G2400/20
    • A process for producing alkylate comprising contacting a first hydrocarbon stream comprising at least one olefin having from 2 to 6 carbon atoms which contains 1-butene with an isomerization catalyst under conditions favoring the isomerization of 1-butene to 2-butene so the isomerized stream contains a greater concentration of 2-butene than the first hydrocarbon stream and contacting the isomerized stream and a second hydrocarbon stream comprising at least one isoparaffin having from 4 to 6 carbon atoms with an acidic ionic liquid catalyst under alkylation conditions to produce an alkylate stream, wherein the alkylate stream has a RON that is increased from 5 to 32 numbers compared to a comparison alkylate stream made from the first hydrocarbon stream without the step of contacting with the isomerization catalyst.
    • 一种生产烷基化物的方法,包括在有利于1-丁烯异构化为2-丁烯的条件下使包含至少一种含有2-6个碳原子的含有1-丁烯的烯烃与异构化催化剂接触的第一烃料流,使得异构化料流含有 比第一烃流更高浓度的2-丁烯,并且在烷基化条件下使异源化物流和含有至少一个具有4-6个碳原子的异链烷烃的第二烃物流与酸性离子液体催化剂接触以产生烷基化物流,其中 与由第一烃流制备的比较烷基化物流相比,烷基化物流具有从5至32个数量增加的RON,而不与异构化催化剂接触的步骤。
    • 3. 发明授权
    • Alkylation process using chloroaluminate ionic liquid catalysts
    • 使用氯铝酸盐离子液体催化剂的烷基化方法
    • US07432409B2
    • 2008-10-07
    • US11021165
    • 2004-12-21
    • Saleh ElomariSteve TrumbullHye Kyung C. TimkenRobert Cleverdon
    • Saleh ElomariSteve TrumbullHye Kyung C. TimkenRobert Cleverdon
    • C07C2/54
    • C10G29/205C07C2/58C10G50/00C07C9/16
    • A process for the production of a high quality gasoline blending components from refinery process streams by the alkylation of light isoparaffins with olefins using an ionic liquid catalyst is disclosed. The process includes reacting a refinery stream containing isopentane and/or isobutane with a refinery stream containing ethylene and/or propylene and butylenes under alkylation conditions in the presence of a chloroaluminate ionic liquid catalyst comprising a hydrocarbyl substituted pyridinium chloroaluminate or a hydrocarbyl substituted imidazolium chloroaluminate of the general formulas A and B, respectively. Where R═H, methlyl, ethyl, propyl, butyl, pentyl or hexyl group and X is a chloroaluminate, and R1 and R2=H, methyl, ethyl, propyl, butyl, pentyl or hexyl group and where R1 and R2 may or may not be the same.
    • 公开了一种通过使用离子液体催化剂通过烯烃使轻质异链烷烃烷基化从炼厂工艺流中生产高品质汽油调和组分的方法。 该方法包括在烷基化条件下,在氯铝酸盐离子液体催化剂存在下使包含异戊烷和/或异丁烷的炼油厂物流与含有乙烯和/或丙烯和丁烯的炼油厂物流反应,所述氯铝酸盐离子液体催化剂包含烃基取代的氯铝酸吡啶鎓或氯铝酸盐的烃基取代的咪唑鎓氯铝酸盐 分别是通式A和B。 其中RH,甲基,乙基,丙基,丁基,戊基或己基,X是氯铝酸盐,R1和R2 = H,甲基,乙基,丙基,丁基,戊基或己基,其中R 1和R 2可以是或不是 一样。
    • 5. 发明授权
    • Extremely low acidity ultrastable Y zeolite catalyst composition and process
    • 极低的酸度超稳定的Y沸石催化剂组成及工艺
    • US06860986B2
    • 2005-03-01
    • US10290791
    • 2002-11-08
    • Hye Kyung C. TimkenLucy Melinda BullThomas V. Harris
    • Hye Kyung C. TimkenLucy Melinda BullThomas V. Harris
    • B01J29/08B01J29/16C10G47/16C10G47/20
    • C10G47/20B01J29/084B01J29/166B01J2229/16C10G47/16
    • A catalyst composition comprising a low acidity, highly dealuminated ultra stable Y zeolite having an Alpha value of less than about 3 and Broensted acidity measured by FT-IR from about 1 to about 20, preferably from about 1-10, micro mole/g of, an amorphous cracking component and a catalytic amount of hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal, and mixtures thereof is disclosed. The present invention provides for a process for converting hydrocarbonaceous oils comprising contacting the hydrocarbonaceous oils with the catalyst under suitable hydrocarbon conversion conditions. Such processes in include, but are not limited to, single stage hydrocracking, two-stage hydrocracking, series-flow hydrocracking, mild hydrocracking, lube hydrocracking, hydrotreating, lube hydrofinishing, hydrodesulphurization, hydrodenitrification, catalytic dewaxing and catalytic cracking.
    • 一种催化剂组合物,其包含具有低于约3的α值低于约3的低酸度,高度脱铝的超稳定Y沸石,通过FT-IR测量的Broensted酸度为约1至约20,优选约1-10微摩尔/ g 公开了无定形裂化组分和催化量的选自VI族金属,VIII族金属及其混合物的氢化组分。 本发明提供了一种用于转化含烃油的方法,包括在合适的烃转化条件下使烃类油与催化剂接触。 这些方法包括但不限于单级加氢裂化,两级加氢裂化,串联加氢裂化,轻度加氢裂化,润滑油加氢裂化,加氢处理,润滑油加氢精制,加氢脱硫,加氢脱氮,催化脱蜡和催化裂化。