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1. 发明授权

US07594992B2 Highly homogeneous amorphous silica-alumina catalyst composition 失效
标题翻译：高均相无定形二氧化硅 - 氧化铝催化剂组合物
公开(公告)号：US07594992B2
公开(公告)日：2009-09-29
申请号：US11248877
申请日：2005-12-28
申请人： Hye Kyung C. Timken , Mohammad M. Habib
发明人： Hye Kyung C. Timken , Mohammad M. Habib
IPC分类号： C10G47/00 , C10G11/00 , B01J21/00 , B01J23/00 , B01J23/08
CPC分类号： B01J37/036 , B01J21/12 , B01J37/0009 , C10G11/04 , C10G45/60 , C10G47/10 , C10G49/02
摘要： Silica-alumina catalyst compositions and to a process for converting hydrocarbonaceous feed using the catalyst are disclosed. The present invention relates to a highly homogeneous, amorphous silica-alumina cogel material, the attributes of which make it especially useful for the Hydroprocessing of hydrocarbonaceous feeds either alone or in combination with other catalysts. This invention relates to a highly homogeneous amorphous silica-alumina catalyst having a surface to bulk silica to alumina ratio (SB ratio) of from about 0.7 to about 1.3, preferably from about 0.8 to about 1.2, more preferably from about 0.9 to about 1.1, and most preferably 1.0 and a crystalline alumina phase present in an amount no more than about 10%, preferably no more than about 5%. A catalyst of the present invention exhibits higher activity and better product selectivity in comparison with other silica-alumina catalysts.
摘要翻译：公开了二氧化硅 - 氧化铝催化剂组合物和使用该催化剂转化含烃原料的方法。本发明涉及高度均匀的无定形二氧化硅 - 氧化铝共凝胶材料，其特性使其特别适用于单独或与其它催化剂组合的烃类进料的加氢处理。本发明涉及高度均匀的无定形二氧化硅 - 氧化铝催化剂，其具有约0.7至约1.3，优选约0.8至约1.2，更优选约0.9至约1.1的表面与体积二氧化硅与氧化铝的比率（SB比）最优选为1.0，结晶氧化铝相的含量不超过约10％，优选不超过约5％。与其它二氧化硅 - 氧化铝催化剂相比，本发明的催化剂表现出更高的活性和更好的产物选择性。

2. 发明授权

US5925235A Middle distillate selective hydrocracking process 有权
标题翻译：中间馏分选择性加氢裂化过程
公开(公告)号：US5925235A
公开(公告)日：1999-07-20
申请号：US178159
申请日：1998-10-23
申请人： Mohammad M. Habib
发明人： Mohammad M. Habib
IPC分类号： C10G65/10 , C10G47/16
CPC分类号： C10G65/10
摘要： A layered hydrocracking catalyst system has high middle distillate selectivity when used for hydrocracking a high sulfur and high nitrogen containing feedstock. The layered system comprises a first layer catalyst with contains a zeolite having a unit cell size of greater than about 24.35 Angstroms, and a second layer catalyst which contains a zeolite having a unit cell size of less than about 24.30 Angstroms. The layered system is particularly beneficial in terms of catalyst life and product selectivity for reactors operated under conditions of a high temperature profile.
摘要翻译：分层加氢裂化催化剂体系在用于加氢裂化高硫和高含氮原料时具有较高的中间馏分选择性。分层体系包括含有单元尺寸大于约24.35埃的沸石的第一层催化剂，以及含有单元尺寸小于约24.30埃的沸石的第二层催化剂。对于在高温度条件下运行的反应器的催化剂寿命和产物选择性，分层系统是特别有利的。

3. 发明授权

US4361706A Process for preparing aldehydes 失效
标题翻译：醛的制备方法
公开(公告)号：US4361706A
公开(公告)日：1982-11-30
申请号：US289404
申请日：1981-08-03
申请人： Mohammad M. Habib , Wayne R. Pretzer
发明人： Mohammad M. Habib , Wayne R. Pretzer
IPC分类号： C07C47/07 , B01J31/00 , C07C45/00 , C07C45/49 , C07C67/00
CPC分类号： C07C45/49
摘要： A process for selectively producing aldehydes, particularly acetaldehyde, which comprises introducing into a reaction zone (1) methanol, (2) carbon monoxide, (3) hydrogen, (4) cobalt, (5) iodine and (6) a ligand containing atoms from Group VB of the Periodic Table separated by a sterically constrained carbon-carbon bond and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to said aldehydes.
摘要翻译：选择性地生产醛，特别是乙醛的方法，其包括将甲醇，（2）一氧化碳，（3）氢，（4）钴，（5）碘和（6）含有原子的配体由空间限制的碳 - 碳键分隔的元素周期表的第VB族化合物，然后将所述反应区的内容物升温至升高的压力达足以将甲醇转化为所述醛的时间。

4. 发明授权

US06995112B2 Highly homogeneous amorphous silica-alumina catalyst composition 失效
公开(公告)号：US06995112B2
公开(公告)日：2006-02-07
申请号：US10290787
申请日：2002-11-08
申请人： Hye Kyung C. Timken , Mohammad M. Habib
发明人： Hye Kyung C. Timken , Mohammad M. Habib
IPC分类号： B01J29/06
CPC分类号： B01J37/036 , B01J21/12 , B01J37/0009 , C10G11/04 , C10G45/60 , C10G47/10 , C10G49/02
摘要： Silica-alumina catalyst compositions and to a process for converting hydrocarbonaceous feed using the catalyst are disclosed. The present invention relates to a highly homogeneous, amorphous silica-alumina cogel material, the attributes of which make it especially useful for the Hydroprocessing of hydrocarbonaceous feeds either alone or in combination with other catalysts. This invention relates to a highly homogeneous amorphous silica-alumina catalyst having a surface to bulk silica to alumina ratio (SB ratio) of from about 0.7 to about 1.3, preferably from about 0.8 to about 1.2, more preferably from about 0.9 to about 1.1, and most preferably 1.0 and a crystalline alumina phase present in an amount no more than about 10%, preferably no more than about 5%. A catalyst of the present invention exhibits higher activity and better product selectivity in comparison with other silica-alumina catalysts.

5. 发明授权

US5593570A Catalyst system for combined hydrotreating and hydrocracking and a process for upgrading hydrocarbonaceous feedstocks 失效
标题翻译：用于组合加氢处理和加氢裂化的催化剂体系和用于改质含烃原料的方法
公开(公告)号：US5593570A
公开(公告)日：1997-01-14
申请号：US438150
申请日：1995-05-09
申请人： Mohammad M. Habib , Philip L. Winslow , Richard O. Moore, Jr.
发明人： Mohammad M. Habib , Philip L. Winslow , Richard O. Moore, Jr.
IPC分类号： B01J29/14 , B01J37/04 , C10G47/20 , C10G65/12 , C10G47/16 , C10G45/12
CPC分类号： B01J37/04 , B01J29/146 , C10G47/20 , C10G65/12
摘要： A physically intermixed catalyst system comprising two distinctly different catalytic particles, the first of which is a hydrodenitrification and/or hydrodesulfurization catalyst and the second of which is a relatively active hydrocracking catalyst, wherein the catalyst particles of both catalytic components are substantially the same size, that is the effective diameter of each catalyst component is substantially the same. The catalyst system of the present invention can be layered with unmixed catalysts. The novel systems of the present invention have been found to provide surprisingly good selectivity for liquid products and stability against catalyst fouling when used in combined hydrotreating and hydrocracking applications, and can therefore be used to provide a stable catalyst system which offers even heat distribution and reactor control in such applications.
摘要翻译：一种物理混合的催化剂体系，其包含两个明显不同的催化剂颗粒，其中第一个催化剂颗粒是氢化脱氮和/或加氢脱硫催化剂，第二个是相对活性的加氢裂化催化剂，其中两个催化组分的催化剂颗粒大体上相同，即每个催化剂组分的有效直径基本相同。本发明的催化剂体系可以用未混合的催化剂层压。已经发现本发明的新型体系在用于组合加氢处理和加氢裂化应用中时，对液体产物提供令人惊讶的良好的选择性和对催化剂结垢的稳定性，因此可用于提供稳定的催化剂体系，其提供均匀的热分布和反应器控制在这样的应用程序。

6. 发明授权

US4438020A Catalyst suitable for preparing aldehydes 失效
标题翻译：催化剂适用于制备醛类
公开(公告)号：US4438020A
公开(公告)日：1984-03-20
申请号：US417534
申请日：1982-09-13
申请人： Mohammad M. Habib , Wayne R. Pretzer
发明人： Mohammad M. Habib , Wayne R. Pretzer
IPC分类号： C07C45/49 , B01J31/02
CPC分类号： C07C45/49
摘要： A catalyst particularly suitable for selectively producing aldehydes, particularly acetaldehyde, which comprises (1) cobalt, (2) iodine and (3) a ligand containing atoms from Group VB of the Periodic Table separated by a sterically constrained carbon-carbon bonding.
摘要翻译：特别适用于选择性地生产醛（特别是乙醛）的催化剂，它包括（1）钴，（2）碘和（3）含有空间受限碳 - 碳键的元素周期表第VB族原子的配体。

7. 发明授权

US5282958A Use of modified 5-7 a pore molecular sieves for isomerization of hydrocarbons 失效
标题翻译：使用改性的5-7孔分子筛进行烃的异构化
公开(公告)号：US5282958A
公开(公告)日：1994-02-01
申请号：US556560
申请日：1990-07-20
申请人： Donald S. Santilli , Mohammad M. Habib , Thomas V. Harris , Stacey I. Zones
发明人： Donald S. Santilli , Mohammad M. Habib , Thomas V. Harris , Stacey I. Zones
IPC分类号： C07B61/00 , B01J29/00 , B01J29/83 , B01J29/85 , C10G45/64 , C10G65/04 , C10G73/44 , C10M101/02 , C10N30/02 , C10N60/00 , C10N60/02 , C10N70/00 , C07C5/13 , C10G11/02
CPC分类号： C10G45/64 , C10G2300/70 , C10G2400/10
摘要： A process is disclosed for dewaxing a hydrocarbon feed to produce a dewaxed lube oil. The feed includes straight chain and slightly branched chain paraffins having 10 or more carbon atoms. In the process the feed is contacted under isomerization conditions with an intermediate pore size molecular sieve having a crystallite size of no more than about 0.5.mu. and pores with a minimum diameter of at least 4.8.ANG. and with a maximum diameter of 7.1.ANG. or less. The catalyst has sufficient acidity so that 0.5 g thereof when positioned in a tube reactor converts at least 50% of hexadecane at 370.degree. C., a pressure of 1200 psig, a hydrogen flow of 160 ml/min, and a feed rate of 1 ml/hr. It also exhibits 40 or greater isomerization selectivity when used under conditions leading to 96% conversion of hexadecane to other chemicals. The catalyst includes at least one Group VIII metal. The contacting is carried out at a pressure from about 15 psig to about 3000 psig.
摘要翻译：公开了一种用于使烃进料脱蜡以生产脱蜡润滑油的方法。进料包括具有10个或更多个碳原子的直链和轻链支链烷烃。在该过程中，进料在异构化条件下与具有不超过约0.5（my）的微晶尺寸的中孔分子筛和最小直径至少为4.8（Aangstroem）的孔和最大直径为7.1 （Aangstroem）或更少。该催化剂具有足够的酸度，使得当其位于管式反应器中时，其0.5g在370℃下转化至少50％的十六烷，压力为1200psig，氢气流量为160ml / min，进料速率为1 ml / hr。当在导致十六烷转化为其他化学品的96％的条件下使用时，它还具有40或更高的异构化选择性。该催化剂包括至少一种第VIII族金属。接触在约15psig至约3000psig的压力下进行。

8. 发明授权

US4352947A Process for producing ethanol 失效
标题翻译：生产乙醇的方法
公开(公告)号：US4352947A
公开(公告)日：1982-10-05
申请号：US289406
申请日：1981-08-03
申请人： Mohammad M. Habib , Wayne R. Pretzer
发明人： Mohammad M. Habib , Wayne R. Pretzer
IPC分类号： B01J31/00 , B01J31/18 , B01J31/24 , C07C27/00 , C07C29/32 , C07C31/08 , C07C45/49 , C07C67/00 , C07C29/00
CPC分类号： C07C45/49 , B01J31/2409 , C07C29/32 , B01J2531/821 , B01J2531/845 , B01J31/1805 , B01J31/1895
摘要： A process for selectively producing alcohols, particularly ethanol, which comprises introducing into a reaction zone (1) methanol, (2) carbon monoxide, (3) hydrogen, (4) cobalt, (5) iodine, (6) ruthenium and (7) a ligand containing atoms from Group VA of the Periodic Table separated by a sterically constrained carbon-carbon bond, and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to said ethanol.
摘要翻译：一种选择性生产醇类，特别是乙醇的方法，包括将甲醇，（2）一氧化碳，（3）氢，（4）钴，（5）碘，（6）钌和（7））含有通过空间受限碳 - 碳键分隔的元素周期表第VA族原子的配体，然后使所述反应区的内容物升温至高压并将其升温至足以将甲醇转化为所述乙醇的时间。

9. 发明授权

US5439860A Catalyst system for combined hydrotreating and hydrocracking and a process for upgrading hydrocarbonaceous feedstocks 失效
标题翻译：用于组合加氢处理和加氢裂化的催化剂体系和用于改质含烃原料的方法
公开(公告)号：US5439860A
公开(公告)日：1995-08-08
申请号：US044359
申请日：1993-04-07
申请人： Mohammad M. Habib , Philip L. Winslow , Richard O. Moore, Jr.
发明人： Mohammad M. Habib , Philip L. Winslow , Richard O. Moore, Jr.
IPC分类号： B01J29/14 , B01J37/04 , C10G47/20 , C10G65/12 , B01J29/00 , B01J29/068 , B01J29/072
CPC分类号： B01J37/04 , B01J29/146 , C10G47/20 , C10G65/12
摘要： A physically intermixed catalyst system comprising two distinctly different catalytic particles, the first of which is a hydrodenitrification and/or hydrodesulfurization catalyst and the second of which is a relatively active hydrocracking catalyst, wherein the catalyst particles of both catalytic components are substantially the same size, that is the effective diameter of each catalyst component is substantially the same. The catalyst system of the present invention can be layered with unmixed catalysts. The novel systems of the present invention have been found to provide surprisingly good selectivity for liquid products and stability against catalyst fouling when used in combined hydrotreating and hydrocracking applications, and can therefore be used to provide a stable catalyst system which offers even heat distribution and reactor control in such applications.
摘要翻译：一种物理混合的催化剂体系，其包含两个明显不同的催化剂颗粒，其中第一个催化剂颗粒是氢化脱氮和/或加氢脱硫催化剂，第二个是相对活性的加氢裂化催化剂，其中两个催化组分的催化剂颗粒大体上相同，即每个催化剂组分的有效直径基本相同。本发明的催化剂体系可以用未混合的催化剂层压。已经发现本发明的新型体系在用于组合加氢处理和加氢裂化应用中时，对液体产物提供令人惊讶的良好的选择性和对催化剂结垢的稳定性，因此可用于提供稳定的催化剂体系，其提供均匀的热分布和反应器控制在这样的应用程序。

10. 发明授权

US5393410A Hydrocarbon conversion processes and catalysts used therein 失效
标题翻译：其中使用的烃转化方法和催化剂
公开(公告)号：US5393410A
公开(公告)日：1995-02-28
申请号：US139487
申请日：1993-10-20
申请人： Mohammad M. Habib , Arthur J. Dahlberg
发明人： Mohammad M. Habib , Arthur J. Dahlberg
IPC分类号： B01J29/10 , C10G47/20 , C10G65/12
CPC分类号： B01J29/106 , C10G47/20 , C10G65/12
摘要： This invention relates to catalyst compositions useful in converting hydrocarbonaceous oils. The catalyst comprises an ultra stable Y zeolite base, wherein said Y zeolite has a unit cell size greater than about 24.55 .ANG. and a crystal size less than about 2.8 microns, an amorphous cracking component, a binder, and a catalytic amount of hydrogenation component selected from the group consisting of a Group VI metal, a Group VIII metal, and mixtures thereof. The invention also relates to processes that are suitable for the catalyst use therein.
摘要翻译：本发明涉及可用于转化含烃油的催化剂组合物。催化剂包含超稳定的Y沸石基质，其中所述Y沸石的单元尺寸大于约24.55，晶体尺寸小于约2.8微米，非晶形裂化组分，粘合剂和催化量的氢化组分由VI族金属，VIII族金属及其混合物组成。本发明还涉及适用于其中的催化剂使用的方法。

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