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    • 4. 发明授权
    • Shoot and run printing materials
    • 拍摄和运行印刷材料
    • US5395734A
    • 1995-03-07
    • US983124
    • 1992-11-30
    • Dennis E. VogelLeonard J. Stulc
    • Dennis E. VogelLeonard J. Stulc
    • B41N1/08B41N1/14B41N3/08G03F7/00G03F7/004G03F7/029G03F7/033G03F7/039G03F7/075G03F7/26G03F7/021G03C1/77
    • G03F7/0758G03F7/039Y10S430/111Y10S430/12Y10S430/122Y10S430/126
    • Acid-sensitive polymers and imageable articles employing them are disclosed. In particular, photosensitive compositions are disclosed comprising: (a) a photoinitiator which generates an acid upon exposure to radiation; and (b) a polymer having acid labile groups pendant from the polymer backbone, said acid labile pendant groups comprising at least one each of A and B wherein A has the formula --T--(C.dbd.O)OCR.sup.1 R.sup.2 OR.sup.3, and B has the formula --T--(C.dbd.O)OR.sup.4 Si(R.sup.5).sub.3, wherein R.sup.1 and R.sup.2 each represent H or an alkyl group with the proviso that at least one of R.sup.1 and R.sup.2 must be hydrogen; R.sup.3 represents an alkyl group; or any two of R.sup.1, R.sup.2, and R.sup.3 may together form a ring group having from 3 to 36 carbon atoms; R.sup.5 represents an alkyl group, aryl group, an alkoxy group, an aryloxy group, an acyloxy group, or a trialkylsiloxy group; and R.sup.4 and T represents a divalent linking group wherein T is bonded to the polymer backbone and R.sup.4 is not bonded to the polymer backbone, the divalent linking group containing a total of from 0 (a covalent bond) or 1 to 18 carbon atoms where up to one of each three carbon atoms may be replaced by oxygen, nitrogen, or sulfur atoms or combinations thereof in the polymer backbone.
    • 公开了使用它们的酸敏感聚合物和可成像制品。 特别地,公开了光敏组合物,其包含:(a)在暴露于辐射时产生酸的光引发剂; 和(b)具有从聚合物主链悬挂的酸不稳定基团的聚合物,所述酸不稳定侧基包含A和B中的至少一个,其中A具有式-T-(C = O)OCR 1 R 2 R 3,B具有式 -T-(C = O)OR 4 Si(R 5)3,其中R 1和R 2各自表示H或烷基,条件是R 1和R 2中的至少一个必须是氢; R3表示烷基; 或者R 1,R 2和R 3中的任何两个可以一起形成具有3至36个碳原子的环基; R5表示烷基,芳基,烷氧基,芳氧基,酰氧基或三烷基甲硅烷氧基; 并且R 4和T表示二价连接基团,其中T与聚合物主链键合,并且R 4不与聚合物主链结合,二价连接基团含有总共0(共价键)或1至18个碳原子 可以在聚合物主链中被氧,氮或硫原子或其组合替代为每三个碳原子中的一个。
    • 5. 发明授权
    • Off-center deposition of organic semiconductor in an organic semiconductor device
    • 有机半导体在有机半导体器件中的偏心沉积
    • US07948016B1
    • 2011-05-24
    • US12611556
    • 2009-11-03
    • Scott M. SchnobrichRobert S. CloughDennis E. VogelMichael E. Griffin
    • Scott M. SchnobrichRobert S. CloughDennis E. VogelMichael E. Griffin
    • H01L29/76H01L23/58
    • H01L51/0005H01L51/0558
    • The present disclosure provides a method of making a thin film semiconductor device such as a transistor comprising the steps of: a) providing a substrate bearing first and second conductive zones which define a channel therebetween, where the channel does not border more than 75% of the perimeter of either conductive zone; and b) depositing a discrete aliquot of a solution comprising an organic semiconductor adjacent to or on the channel, where a majority of the solution is deposited to one side of the channel and not on the channel. In some embodiments of the present disclosure, the solution is deposited entirely to one side of the channel, not on the channel, and furthermore the solution is deposited in a band having a length that is less than the channel length. The present disclosure additionally provides thin film semiconductor devices such as a transistors.
    • 本公开内容提供了制造诸如晶体管的薄膜半导体器件的方法,包括以下步骤:a)提供承载第一和第二导电区域的衬底,其在其间限定通道,其中通道不超过75% 任一导电区的周长; 以及b)沉积包含邻近于或在通道上的有机半导体的溶液的离散等分试样,其中大部分溶液沉积在通道的一侧,而不是在通道上。 在本公开的一些实施例中,溶液完全沉积在通道的一侧,而不是在通道上,此外,溶液沉积在具有小于通道长度的长度的带中。 本公开另外提供诸如晶体管的薄膜半导体器件。
    • 9. 发明申请
    • METHODS OF PREPARING FLUORINATED CARBOXYLIC ACIDS AND THEIR SALTS
    • 制备氟化羧酸及其盐的方法
    • US20120184770A1
    • 2012-07-19
    • US13497173
    • 2010-10-21
    • Klaus HintzerDennis E. VogelMiguel A. GuerraJolanta IgnatowskaGerd-Volker RöschenthalerOleg ShyshkovKim M VogelTilman C. Zipplies
    • Klaus HintzerDennis E. VogelMiguel A. GuerraJolanta IgnatowskaGerd-Volker RöschenthalerOleg ShyshkovKim M VogelTilman C. Zipplies
    • C07C51/16C07C51/285C07C51/305C07C51/23C25B3/02C07C51/27C07C51/29
    • C07C51/27C07C53/21C07C59/135
    • A method for preparing fluorinated carboxylic acids and theirs salts is described comprising subjecting a fluorinated alcohol of the general formula (A): A-CH2—OH to at least one first and at least one second oxidizing agent to produce a highly fluorinated carboxylic acid or their salts of the general formula (B): A-COO M+, wherein M+ represents a cation and wherein A in formulas (A) and (B) is the same and A represents the residue: Rf-[0]p-CX″Y″-[0]m-CX′Y′-[0]n-CXY— wherein Rf represents a fluorinated alkyl residue which may or may not contain one or more catenary oxygen atoms, p, m and n are independently from each other either 1 or O, X, X′, X″, Y, Y′ and Y″ are independently from each other H, F, CF3, or C2F5 with the proviso that not all of X, X′, X″, Y, Y′ and Y″ are H; or A represents the residue: R—CFX— wherein X and R are independently selected from a hydrogen, a halogen, or an alkyl, alkenyl, cycloalkyl, or aryl residue, which may or may not contain one or more fluorine atoms and which may or may not contain one or more catenary oxygen atoms; wherein said at least one first oxidizing agent is a compound that can be converted, by action of the second oxidizing agent, into a reactive species capable of oxidizing the fluorinated alcohol.
    • 描述了制备氟化羧酸及其盐的方法,其包括将通式(A)的氟化醇:A-CH 2 -OH置于至少一种第一和至少一种第二氧化剂中以产生高度氟化的羧酸或 其通式(B)的盐:A-COO M +,其中M +表示阳离子,式(A)和(B)中的A相同,A表示残基:Rf- [0] p-CX“ Y“ - [0] m-CX'Y' - [0] n-CXY-其中Rf表示可以或可以不含有一个或多个链状氧原子的氟化烷基残基,p,m和n彼此独立地 1或O,X,X',X“,Y,Y'和Y”彼此独立地为H,F,CF 3或C 2 F 5,条件是不是全部X,X',X“,Y, Y'和Y“为H; 或A表示残基:R-CFX-,其中X和R独立地选自氢,卤素或烷基,烯基,环烷基或芳基残基,其可以含有或不含有一个或多个氟原子, 或者可以不包含一个或多个链状氧原子; 其中所述至少一种第一氧化剂是可以通过第二氧化剂的作用转化成能够氧化氟化醇的反应性物质的化合物。
    • 10. 发明授权
    • Acene-thiophene copolymers
    • 乙烯 - 噻吩共聚物
    • US07608679B2
    • 2009-10-27
    • US11278222
    • 2006-03-31
    • Peiwang ZhuTzu-Chen LeeDennis E. VogelChristopher P. Gerlach
    • Peiwang ZhuTzu-Chen LeeDennis E. VogelChristopher P. Gerlach
    • C08G75/00
    • H01L51/0043C08G61/126C08G2261/124C08G2261/1424C08G2261/314C08G2261/3223H01L51/0037
    • Acene-thiophene copolymers are provided that can be used as semiconductor materials in electronic devices. The acene-thiophene copolymers are of Formula I. In Formula I, Ac is a radical of an acene having 2 to 5 fused aromatic rings. The acene can be unsubstituted or substituted with a substituent selected from an alkyl, alkoxy, thioalkyl, aryl, aralkyl, halo, haloalkyl, hydroxyalkyl, heteroalkyl, alkenyl, or combinations thereof. Divalent group Q is selected from Formula III where each R1 and R2 group is independently selected from hydrogen, alkyl, alkoxy, thioalkyl, aryl, aralkyl, halo, haloalkyl, hydroxyalkyl, heteroalkyl, alkenyl, or combinations thereof. The subscript n in Formula I is an integer equal to at least 4. The asterisks in Formula I indicate the location of attachment to another group such as another repeat unit of formula —Ac-Q-.
    • 提供了可用作电子器件中的半导体材料的乙烯 - 噻吩共聚物。 乙烯 - 噻吩共聚物具有式I化合物。在式I中,Ac是具有2至5个稠合芳环的苊基团。 该烯可以是未取代的或被选自烷基,烷氧基,硫代烷基,芳基,芳烷基,卤代,卤代烷基,羟基烷基,杂烷基,烯基或其组合的取代基取代。 二价基团Q选自式III,其中每个R 1和R 2基团独立地选自氢,烷基,烷氧基,硫代烷基,芳基,芳烷基,卤素,卤代烷基,羟基烷基,杂烷基,烯基或其组合。 式I中的下标n是等于至少4的整数。式I中的星号表示连接到另一组的位置,例如式-Ac-Q-的另一个重复单元。