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    • 4. 发明授权
    • Shoot and run printing materials
    • 拍摄和运行印刷材料
    • US5395734A
    • 1995-03-07
    • US983124
    • 1992-11-30
    • Dennis E. VogelLeonard J. Stulc
    • Dennis E. VogelLeonard J. Stulc
    • B41N1/08B41N1/14B41N3/08G03F7/00G03F7/004G03F7/029G03F7/033G03F7/039G03F7/075G03F7/26G03F7/021G03C1/77
    • G03F7/0758G03F7/039Y10S430/111Y10S430/12Y10S430/122Y10S430/126
    • Acid-sensitive polymers and imageable articles employing them are disclosed. In particular, photosensitive compositions are disclosed comprising: (a) a photoinitiator which generates an acid upon exposure to radiation; and (b) a polymer having acid labile groups pendant from the polymer backbone, said acid labile pendant groups comprising at least one each of A and B wherein A has the formula --T--(C.dbd.O)OCR.sup.1 R.sup.2 OR.sup.3, and B has the formula --T--(C.dbd.O)OR.sup.4 Si(R.sup.5).sub.3, wherein R.sup.1 and R.sup.2 each represent H or an alkyl group with the proviso that at least one of R.sup.1 and R.sup.2 must be hydrogen; R.sup.3 represents an alkyl group; or any two of R.sup.1, R.sup.2, and R.sup.3 may together form a ring group having from 3 to 36 carbon atoms; R.sup.5 represents an alkyl group, aryl group, an alkoxy group, an aryloxy group, an acyloxy group, or a trialkylsiloxy group; and R.sup.4 and T represents a divalent linking group wherein T is bonded to the polymer backbone and R.sup.4 is not bonded to the polymer backbone, the divalent linking group containing a total of from 0 (a covalent bond) or 1 to 18 carbon atoms where up to one of each three carbon atoms may be replaced by oxygen, nitrogen, or sulfur atoms or combinations thereof in the polymer backbone.
    • 公开了使用它们的酸敏感聚合物和可成像制品。 特别地,公开了光敏组合物,其包含:(a)在暴露于辐射时产生酸的光引发剂; 和(b)具有从聚合物主链悬挂的酸不稳定基团的聚合物,所述酸不稳定侧基包含A和B中的至少一个,其中A具有式-T-(C = O)OCR 1 R 2 R 3,B具有式 -T-(C = O)OR 4 Si(R 5)3,其中R 1和R 2各自表示H或烷基,条件是R 1和R 2中的至少一个必须是氢; R3表示烷基; 或者R 1,R 2和R 3中的任何两个可以一起形成具有3至36个碳原子的环基; R5表示烷基,芳基,烷氧基,芳氧基,酰氧基或三烷基甲硅烷氧基; 并且R 4和T表示二价连接基团,其中T与聚合物主链键合,并且R 4不与聚合物主链结合,二价连接基团含有总共0(共价键)或1至18个碳原子 可以在聚合物主链中被氧,氮或硫原子或其组合替代为每三个碳原子中的一个。
    • 6. 发明授权
    • Release layers and compositions for forming the same
    • 用于形成它们的剥离层和组合物
    • US06342324B1
    • 2002-01-29
    • US09504461
    • 2000-02-16
    • Minyu LiM. Zaki AliEric D. MorrisonCharles W. SimpsonLeonard J. StulcRamnath SubramaniamJiayi Zhu
    • Minyu LiM. Zaki AliEric D. MorrisonCharles W. SimpsonLeonard J. StulcRamnath SubramaniamJiayi Zhu
    • G03G5147
    • G03G5/14773C09D183/04C08L83/00
    • Release compositions include (a) from zero to about 30 parts by weight of a polymer selected from the group consisting of wherein R1, R2, R3, R6, R7, R10, R11, and R12 are each independently selected from an alkyl group, an alkenyl group, an aryl group, and an aralkyl group, such that at least one of R6 and R7 is an alkenyl group, l, m, and n are each independently an integer so long as the polymer contains greater than 3 mol % vinyl-containing siloxane groups; a (vinyl siloxy)(siloxy)-modified silica having a vinyl content of at least about 0.4 vinyl equivalent/kg; and a combination thereof; (b) more than about 20 parts by weight of a polymer having the formula wherein R13, R14, R15, R18, R19, R22, R23, and R24 are each independently selected from an alkyl group, an alkenyl group, an aryl group, and an aralkyl group, such that at least two of R13, R14, R15, R18, R19, R22, R23, and R24 are alkenyl groups, p, q, and r are each independently integers so long as the polymer has less than 3 mol % vinyl-containing siloxane groups; and (c) up to about 20 parts by weight of a cross-linking agent of the formula wherein R36, R37, R38, R43, R44, and R45 are each independently selected from hydrogen, an alkyl group, an aryl group, and an aralkyl group, X is O, or a divalent organic linking group, and s and t are independently integers so long as there are at least two functional groups capable of cross-linking per molecule.
    • 脱模剂组合物包括(a)从0至约30重量份的选自由以下组成的组的聚合物:R1,R2,R3,R6,R7,R10,R11和R12各自独立地选自烷基,烯基 基团,芳基和芳烷基,使得R 6和R 7中的至少一个为烯基,l,m和n各自独立地为整数,只要该聚合物含有大于3摩尔%的含乙烯基的 硅氧烷基团; 具有至少约0.4乙烯当量/ kg的乙烯基含量的(乙烯基甲硅烷氧基)(甲硅烷氧基) - 改性二氧化硅; 及其组合;(b)大于约20重量份的具有式R 13,R 14,R 15,R 18,R 19,R 22,R 23和R 24的聚合物各自独立地选自烷基,烯基, 芳基和芳烷基,使得R 13,R 14,R 15,R 18,R 19,R 22,R 23和R 24中的至少两个是烯基,p,q和r各自独立地为整数,只要聚合物 具有少于3摩尔%的含乙烯基的硅氧烷基团; 和(c)最多约20重量份的式R 36,R 37,R 38,R 43,R 44和R 45的交联剂各自独立地选自氢,烷基,芳基和芳烷基 基团,X为O或二价有机连接基团,且t和t独立地为整数,只要每分子具有至少两个能够交联的官能团即可。
    • 7. 发明授权
    • Liquid toners comprising organic pigments and methods
    • 包含有机颜料和方法的液体调色剂
    • US07018769B2
    • 2006-03-28
    • US10676142
    • 2003-09-30
    • Leonard J. Stulc
    • Leonard J. Stulc
    • G03G9/12
    • G03G9/122
    • Liquid electrographic toner compositions are provided comprising a liquid carrier having a Kauri-Butanol number less than about 30 mL and a plurality of toner particles dispersed in the liquid carrier. The toner particles comprise polymeric binder and a pigment comprising a first ionic dye component ionically complexed with a second ionic dye component in a predetermined ratio to form an ionically complexed colorant compound exhibiting a predetermined color. The colorant compound has a molecular weight of less than about 5000 Daltons and is substantially free of metals that are not covalently bonded to the colorant compound. Toners comprising pigments comprising a ionic dye component and a second ionic dye component complexed to form ionically complexed compounds that together in a colorant composition exhibit a predetermined color are also provided. Methods of making and using these toners are disclosed.
    • 提供液体电摄影调色剂组合物,其包含具有小于约30mL的贝壳杉脂丁醇值的液体载体和分散在液体载体中的多个调色剂颗粒。 调色剂颗粒包括聚合物粘合剂和颜料,其包含与预定比例的第二离子染料组分离子地络合的第一离子染料组分,以形成呈现预定颜色的离子络合着色剂化合物。 着色剂化合物具有小于约5000道尔顿的分子量,并且基本上不含不与着色剂化合物共价键合的金属。 还提供了包含颜料的调色剂,其包含络合以形成离子络合化合物的离子染料组分和第二离子染料组分,所述化合物一起在着色剂组合物中呈现预定的颜色。 公开了制造和使用这些调色剂的方法。