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1. 发明授权

US4482588A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4482588A
公开(公告)日：1984-11-13
申请号：US496345
申请日：1983-05-19
申请人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
发明人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
IPC分类号： B32B27/04 , C08J5/12 , C08L67/00 , C08L77/12 , C09J177/12 , B65D3/00 , B32B27/10 , C08F12/30
CPC分类号： C09J177/12 , B32B27/04 , C08J5/124 , C08L67/00 , C08L77/12 , Y10T428/1379 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.8 dl/g, said poly(esteramide) containing repeating units from 70 to 90 mol percent of a dicarboxylic acid selected from adipic, pimelic, suberic, azelaic, sebacic acid or combinations thereof and 10 to 30 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 10 mol percent to 30 mol percent of a diamine selected from 1,6-hexanediamine, 1,4-cyclohexanebismethylamine or combinations thereof; and repeating units from 90 to 70 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. The repeating units from the second linear aliphatic dicarboxylic acid and repeating units from the diamine are present in equal molar amounts. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译：用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.8dl / g的聚（酯酰胺），所述聚（酯酰胺）含有70-90mol重量单元选自己二酸，庚二酸，辛二酸，壬二酸，癸二酸或其组合的二羧酸的百分比和10至30摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸酸; 从10摩尔％至30摩尔％的选自1,6-己二胺，1,4-环己烷二甲胺或其组合的二胺的重复单元; 以及90-70mol％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二醇的重复单元。来自第二直链脂族二羧酸的重复单元和来自二胺的重复单元以相等摩尔量存在。还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。

2. 发明授权

US4481238A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4481238A
公开(公告)日：1984-11-06
申请号：US496343
申请日：1983-05-19
申请人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
发明人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
IPC分类号： B32B7/12 , B32B27/30 , B32B27/36 , C08G63/68 , C08G69/00 , C08G69/44 , C08G73/16 , C08J5/12 , C08L77/00 , C09J167/00 , C09J177/12 , C09J179/00 , B32B15/08
CPC分类号： B32B27/36 , C08G73/16 , C08J5/124 , C09J177/12 , C09J179/00 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.45 dl/g, said poly(esteramide) containing repeating units from at least 80 mol percent of a dicarboxylic acid selected from pimelic, azelaic, sebacic acid or combinations thereof and optionally up to 20 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 5 mol percent to 20 mol percent of 1,2-ethanediamine; and repeating units from 95 to 80 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译：用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.45dl / g的聚（酯酰胺），所述聚（酯酰胺）含有至少80mol 百分比选自庚二酸，壬二酸，癸二酸或其组合的二羧酸和任选至多20摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸; 重复单元为5mol％至20mol％的1,2-乙二胺; 和95〜80摩尔％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二元醇的重复单元。还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。

3. 发明授权

US4604446A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4604446A
公开(公告)日：1986-08-05
申请号：US686508
申请日：1984-12-26
申请人： I. Daniel Sand , Freddie A. Shepherd , David R. Fagerburg
发明人： I. Daniel Sand , Freddie A. Shepherd , David R. Fagerburg
IPC分类号： C08G63/672 , C08G63/688 , C08G63/18
CPC分类号： C08G63/6886 , C08G63/672
摘要： Disclosed are polyesterether bonding compositions comprising repeating units from trans-1,4-cyclohexanedicarboxylic acid, a difunctional sulfomonomer, a polyetherglycol, 1,4-butanediol or 1,4-cyclohexanedimethanol and ethylene glycol.
摘要翻译：公开了包含来自反式-1,4-环己烷二羧酸的重复单元，双官能磺基单体，聚醚二醇，1,4-丁二醇或1,4-环己烷二甲醇和乙二醇的聚酯树脂粘合组合物。

4. 发明授权

US4482587A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4482587A
公开(公告)日：1984-11-13
申请号：US496344
申请日：1983-05-19
申请人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
发明人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
IPC分类号： B32B27/04 , C08G69/44 , B65D3/00 , B32B27/10 , C08F12/30
CPC分类号： C08G69/44 , B32B27/04 , Y10T428/1379 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.8 dl/g, said poly(esteramide) containing repeating units from at least 70 mol percent of a dicarboxylic acid selected from pimelic, azelaic, sebacic acid or combinations thereof and optionally up to 30 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 10 mol percent to 30 mol percent of a diamine selected from 1,6-hexanediamine, 1,4-cyclohexanebismethylamine or combinations thereof; and repeating units from 90 to 70 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译：用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.8dl / g的聚（酯酰胺），所述聚（酯酰胺）含有至少70mol 百分比选自庚二酸，壬二酸，癸二酸或其组合的二羧酸和任选至多30摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸; 从10摩尔％至30摩尔％的选自1,6-己二胺，1,4-环己烷二甲胺或其组合的二胺的重复单元; 以及90-70mol％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二醇的重复单元。还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。

5. 发明授权

US5006613A Tricomponent polymer blends of poly(ethylene tereptholate), poly(ethylene naphthalate) and a copolyester 失效
标题翻译：聚（乙烯苯乙烯酸酯），聚（萘二甲酸乙二醇酯）和共聚酯的组分聚合物共混物
公开(公告)号：US5006613A
公开(公告)日：1991-04-09
申请号：US560653
申请日：1990-07-30
申请人： Freddie A. Shepherd , Ronald R. Light
发明人： Freddie A. Shepherd , Ronald R. Light
IPC分类号： C08L67/02
CPC分类号： C08L67/02
摘要： This invention concerns blends of poly(ethylene terephthalate), poly(ethylene naphthalate) and a compatibilizing amount of a copolyester which comprises (1) an acid component comprising repeating units of from about 10 to about 20 mole % terephthalic acid and about 80 to about 90 mole % naphthalenedicarboxylic acid, and (2) a glycol component comprising repeating units of ethylene glycol. Clear containers containing less than 10% haze produced from such blends are useful for a variety of packaging applications, particularly hot-fill food and beverage containers where good barrier and clarity are needed.
摘要翻译：本发明涉及聚（对苯二甲酸乙二醇酯），聚（萘二甲酸乙二醇酯）和相容量的共聚酯的共混物，其包含（1）包含约10至约20摩尔％对苯二甲酸和约80至约20重量％的重复单元的酸组分 90摩尔％萘二羧酸，和（2）包含乙二醇重复单元的二元醇组分。含有少于10％混浊度的透明容器可用于各种包装应用，特别是需要良好屏障和透明度的热灌装食品和饮料容器。

6. 发明授权

US4835214A Polymer blends useful for hot fillable containers having improved gas barrier properties 失效
标题翻译：可用于具有改善的气体阻隔性能的可热填充容器的聚合物共混物
公开(公告)号：US4835214A
公开(公告)日：1989-05-30
申请号：US123689
申请日：1987-11-23
申请人： Freddie A. Shepherd , Henry Gonzalez, Jr. , Steven L. Hess
发明人： Freddie A. Shepherd , Henry Gonzalez, Jr. , Steven L. Hess
IPC分类号： B29C49/08 , B29K67/00 , B29L22/00 , C08L67/00 , C08L67/02
CPC分类号： C08L67/02 , Y10S525/931 , Y10S525/933
摘要： Blends of poly(ethylenenaphthalene 2,6-dicarboxylate) with olefin/vinyl alcohol copolymers having improved resistance to oxygen permeability are disclosed. Also disclosed are shaped articles such as biaxially oriented containers produced therefrom.
摘要翻译：公开了聚（亚乙基萘-2,6-二羧酸）与具有改善的耐氧渗透性的烯烃/乙烯醇共聚物的共混物。还公开了成形制品，例如由其制造的双轴取向容器。

7. 发明授权

US4011286A Polyetherester-radial teleblock copolymer blend molding composition 失效
标题翻译：聚酯 - 径向电纺共聚物共混组合物
公开(公告)号：US4011286A
公开(公告)日：1977-03-08
申请号：US705964
申请日：1976-07-16
申请人： Robert W. Seymour , Freddie A. Shepherd , Theodore F. Gray, Jr.
发明人： Robert W. Seymour , Freddie A. Shepherd , Theodore F. Gray, Jr.
IPC分类号： C08L67/02 , C08L67/06
CPC分类号： C08L67/025
摘要： A composition comprised of a polyetherester and a radial teleblock copolymer. This composition exhibits the combination of a desirable overall balance of general mechanical properties and an unobviously high elastic recovery.

8. 发明授权

US4216129A Molding composition comprising a blend of poly (tetramethylene terephthalate) and poly(tetramethylene terephthalate) modified with dimer acid 失效
标题翻译：包含由二聚酸改性的聚（对苯二甲酸丁二酯）和对苯二甲酸丁二醇酯的共混物的成型组合物
公开(公告)号：US4216129A
公开(公告)日：1980-08-05
申请号：US10190
申请日：1979-02-07
申请人： Burns Davis , Freddie A. Shepherd
发明人： Burns Davis , Freddie A. Shepherd
IPC分类号： C08L67/02 , C08G63/02 , C09J3/16
CPC分类号： C08L67/02
摘要： A composition comprised of an admixture of poly-(tetramethylene terephthalate) and poly(tetramethylene terephthalate) modified with dimer acid. This composition exhibits enhanced flexural modulus and enhanced flexural strength compared with a poly(tetramethylene terephthalate) which has been modified with dimer acid and contains an amount of dimer acid equivalent to the admixture.
摘要翻译：由对苯二甲酸双（对苯二甲酸对苯二甲酸酯）和用二聚酸修饰的聚对苯二甲酸四亚甲基酯的混合物组成的组合物。与已经用二聚酸改性且含有相当于该混合物的二聚酸的量的聚（对苯二甲酸丁二醇酯）相比，该组合物显示出增强的弯曲模量和增强的弯曲强度。

9. 发明授权

US4636442A Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers 失效
标题翻译：聚对苯二甲酸乙二醇酯和弹性共聚醚的层压结构
公开(公告)号：US4636442A
公开(公告)日：1987-01-13
申请号：US786433
申请日：1985-10-11
申请人： Randy S. Beavers , Finley E. McFarlane , Harry R. Musser , Freddie A. Shepherd
发明人： Randy S. Beavers , Finley E. McFarlane , Harry R. Musser , Freddie A. Shepherd
IPC分类号： B32B27/36 , C08G63/672 , B32B27/08
CPC分类号： B32B27/36 , C08G63/672 , Y10T428/31786
摘要： Disclosed is multi-layered sheet material comprising a layer of polyethylene terephthalate and a layer of an elastomeric copolyesterether. This sheet material is useful in packaging applications where resistance to flex cracking is important.
摘要翻译：公开了包括聚对苯二甲酸乙二醇酯层和弹性共聚酯层的多层片材。这种片材材料在包装应用中很有用，其中抗挠曲开裂是重要的。

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