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1. 发明授权

US4482588A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4482588A
公开(公告)日：1984-11-13
申请号：US496345
申请日：1983-05-19
申请人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
发明人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
IPC分类号： B32B27/04 , C08J5/12 , C08L67/00 , C08L77/12 , C09J177/12 , B65D3/00 , B32B27/10 , C08F12/30
CPC分类号： C09J177/12 , B32B27/04 , C08J5/124 , C08L67/00 , C08L77/12 , Y10T428/1379 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.8 dl/g, said poly(esteramide) containing repeating units from 70 to 90 mol percent of a dicarboxylic acid selected from adipic, pimelic, suberic, azelaic, sebacic acid or combinations thereof and 10 to 30 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 10 mol percent to 30 mol percent of a diamine selected from 1,6-hexanediamine, 1,4-cyclohexanebismethylamine or combinations thereof; and repeating units from 90 to 70 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. The repeating units from the second linear aliphatic dicarboxylic acid and repeating units from the diamine are present in equal molar amounts. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译：用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.8dl / g的聚（酯酰胺），所述聚（酯酰胺）含有70-90mol重量单元选自己二酸，庚二酸，辛二酸，壬二酸，癸二酸或其组合的二羧酸的百分比和10至30摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸酸; 从10摩尔％至30摩尔％的选自1,6-己二胺，1,4-环己烷二甲胺或其组合的二胺的重复单元; 以及90-70mol％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二醇的重复单元。来自第二直链脂族二羧酸的重复单元和来自二胺的重复单元以相等摩尔量存在。还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。

2. 发明授权

US4481238A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4481238A
公开(公告)日：1984-11-06
申请号：US496343
申请日：1983-05-19
申请人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
发明人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
IPC分类号： B32B7/12 , B32B27/30 , B32B27/36 , C08G63/68 , C08G69/00 , C08G69/44 , C08G73/16 , C08J5/12 , C08L77/00 , C09J167/00 , C09J177/12 , C09J179/00 , B32B15/08
CPC分类号： B32B27/36 , C08G73/16 , C08J5/124 , C09J177/12 , C09J179/00 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.45 dl/g, said poly(esteramide) containing repeating units from at least 80 mol percent of a dicarboxylic acid selected from pimelic, azelaic, sebacic acid or combinations thereof and optionally up to 20 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 5 mol percent to 20 mol percent of 1,2-ethanediamine; and repeating units from 95 to 80 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译：用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.45dl / g的聚（酯酰胺），所述聚（酯酰胺）含有至少80mol 百分比选自庚二酸，壬二酸，癸二酸或其组合的二羧酸和任选至多20摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸; 重复单元为5mol％至20mol％的1,2-乙二胺; 和95〜80摩尔％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二元醇的重复单元。还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。

3. 发明授权

US4482587A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4482587A
公开(公告)日：1984-11-13
申请号：US496344
申请日：1983-05-19
申请人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
发明人： David R. Fagerburg , Freddie A. Shepherd , Benny W. Wright , I. Daniel Sand
IPC分类号： B32B27/04 , C08G69/44 , B65D3/00 , B32B27/10 , C08F12/30
CPC分类号： C08G69/44 , B32B27/04 , Y10T428/1379 , Y10T428/1383 , Y10T428/31736 , Y10T428/31757 , Y10T428/31786
摘要： Bonding compositions for bonding polyesters or copolyesters to poly(vinyl alcohol) or copolymers thereof, the composition comprising a poly(esteramide) having an inherent viscosity of at least 0.8 dl/g, said poly(esteramide) containing repeating units from at least 70 mol percent of a dicarboxylic acid selected from pimelic, azelaic, sebacic acid or combinations thereof and optionally up to 30 mol percent of a second linear aliphatic dicarboxylic acid having at least four carbon atoms connected linearly between the two acid groups or an aromatic dicarboxylic acid; repeating units from 10 mol percent to 30 mol percent of a diamine selected from 1,6-hexanediamine, 1,4-cyclohexanebismethylamine or combinations thereof; and repeating units from 90 to 70 mol percent of a glycol selected from ethylene glycol, 1,4-butanediol, 1,4-cyclohexanedimethanol or combinations thereof. Also disclosed are shaped articles comprising a polyester polymer layer and a poly(vinyl alcohol) layer, the layers being bonded together with bonding compositions of this invention.
摘要翻译：用于将聚酯或共聚酯键合到聚（乙烯醇）或其共聚物的粘合组合物，该组合物包含特性粘度为至少0.8dl / g的聚（酯酰胺），所述聚（酯酰胺）含有至少70mol 百分比选自庚二酸，壬二酸，癸二酸或其组合的二羧酸和任选至多30摩尔％的具有至少四个碳原子的直链脂族二羧酸在两个酸基之间直接连接或芳族二羧酸; 从10摩尔％至30摩尔％的选自1,6-己二胺，1,4-环己烷二甲胺或其组合的二胺的重复单元; 以及90-70mol％的选自乙二醇，1,4-丁二醇，1,4-环己烷二甲醇或其组合的二醇的重复单元。还公开了包含聚酯聚合物层和聚（乙烯醇）层的成型制品，这些层通过本发明的粘合组合物结合在一起。

4. 发明授权

US4604446A Bonding compositions and shaped articles utilizing the bonding compositions 失效
标题翻译：使用粘合组合物的粘结组合物和成型制品
公开(公告)号：US4604446A
公开(公告)日：1986-08-05
申请号：US686508
申请日：1984-12-26
申请人： I. Daniel Sand , Freddie A. Shepherd , David R. Fagerburg
发明人： I. Daniel Sand , Freddie A. Shepherd , David R. Fagerburg
IPC分类号： C08G63/672 , C08G63/688 , C08G63/18
CPC分类号： C08G63/6886 , C08G63/672
摘要： Disclosed are polyesterether bonding compositions comprising repeating units from trans-1,4-cyclohexanedicarboxylic acid, a difunctional sulfomonomer, a polyetherglycol, 1,4-butanediol or 1,4-cyclohexanedimethanol and ethylene glycol.
摘要翻译：公开了包含来自反式-1,4-环己烷二羧酸的重复单元，双官能磺基单体，聚醚二醇，1,4-丁二醇或1,4-环己烷二甲醇和乙二醇的聚酯树脂粘合组合物。

5. 发明授权

US5241038A Method for the preparation of aromatic imide sulfide polymers 失效
标题翻译：制备芳族酰亚胺硫化物聚合物的方法
公开(公告)号：US5241038A
公开(公告)日：1993-08-31
申请号：US753599
申请日：1991-09-03
申请人： David M. Teegarden , Robert J. Perry , S. Richard Turner , David R. Fagerburg
发明人： David M. Teegarden , Robert J. Perry , S. Richard Turner , David R. Fagerburg
IPC分类号： C08G75/02 , C08G75/14
CPC分类号： C08G75/0236 , C08G75/14
摘要： A process for the preparation of aromatic imide sulfide polymers and polymers produced. In the process, elemental sulfur is reacted with a compound having the general formula ##STR1## wherein Z.sup.1 is a direct link and Z.sup.2 is H, or Z.sup.1 has the general structure ##STR2## or Z.sup.1 and Z.sup.2 together complete a moiety having the general structure ##STR3## n= 0-4 . R.sup.1 is substituted or unsubstituted: aryl or heteroaryl. ##STR4## which R.sup.3 is an independently selected aryl group, m is an integer from 1 to 12, and j is an integer from 0 to 300.

6. 发明授权

US5155176A Blends of copoly(arylene sulfide) and polyamide 失效
标题翻译：共聚（亚芳基硫醚）和聚酰胺的共混物
公开(公告)号：US5155176A
公开(公告)日：1992-10-13
申请号：US856273
申请日：1992-03-23
申请人： Shriram Bagrodia , David R. Fagerburg , Joseph J. Watkins , Paul B. Lawrence
发明人： Shriram Bagrodia , David R. Fagerburg , Joseph J. Watkins , Paul B. Lawrence
IPC分类号： C08L77/00 , C08L81/02
CPC分类号： C08L77/00 , C08L81/02
摘要： A composition comprising an admixture of(A) a copoly(arylene sulfide) corresponding to the structure[(--A--S--).sub.1-x (--A--S--S--).sub.x ].sub.n wherein A is a divalent substituted or unsubstituted aromatic radical, x is in the range of 0.5 to 0.001 and n is at least 25, and(B) a polyamide corresponding to the general structure ##STR1## or to the general structure ##STR2##
摘要翻译：对应于[（-AS-）1-x（-ASS-）x] n结构的（A）共聚（亚芳基硫醚）的混合物的组合物，其中A是二价取代或未取代的芳族基团，x在 0.5至0.001的范围和n至少为25，和（B）与通用结构相对应的聚酰胺或一般结构

7. 发明授权

US5021546A Copoly(phenylene sulfide) 失效
标题翻译：共聚（苯硫醚）
公开(公告)号：US5021546A
公开(公告)日：1991-06-04
申请号：US536049
申请日：1990-06-11
申请人： David R. Fagerburg , Mark Rule , Joseph J. Watkins , Paul B. Lawrence
发明人： David R. Fagerburg , Mark Rule , Joseph J. Watkins , Paul B. Lawrence
IPC分类号： C08G75/02 , C08G75/14
CPC分类号： C08G75/0227 , C08G75/0263 , C08G75/14
摘要： A process for producing elemental iodine and a copoly(arylene sulfide) corresponding to the structure ##STR1## wherein y is in the range of 0.001 to 0.15, x is in the range of 0.02 to 0.65 and n is at least 100, consisting essentially of (1) reacting at a temperature above about 175.degree. C., a mixture of diiodobenzene and diiodobiphenyl and elemental sulfur to produce the copoly(arylene sulfide), and (2) recovering the elemental iodine.
摘要翻译：对应于结构 + TR 的元素碘和共聚（亚芳基硫醚）的方法，其中y在0.001至0.15的范围内，x在0.02至0.65的范围内，n至少为 100，基本上由（1）在高于约175℃的温度下反应，二碘苯和二碘联苯和元素硫的混合物产生共聚（亚芳基硫醚），和（2）回收元素碘。

8. 发明授权

US4501877A Higher molecular weight polyesters from diacid anhydrides and cyclic alkylene carbonates 失效
标题翻译：来自二酸酐和环状碳酸亚烷基酯的较高分子量聚酯
公开(公告)号：US4501877A
公开(公告)日：1985-02-26
申请号：US558391
申请日：1983-12-05
申请人： David R. Fagerburg
发明人： David R. Fagerburg
IPC分类号： C08G63/42 , C08G63/00
CPC分类号： C08G63/42
摘要： Higher molecular weight polyesters are prepared from diacid anhydrides and cyclic alkylene carbonates by the process of first drying the reaction mixture either totally or at least substantially completely by azeotropic distillation of water using a suitable organic medium. The catalyst is then added and the polycondensation conducted as conventional. The polymers obtained are markedly higher in molecular weight than if the drying step is omitted, and the polycondensation period is dramatically shortened.
摘要翻译：通过首先通过使用合适的有机介质共沸蒸馏水来完全或至少基本完全地干燥反应混合物的方法，由二酸酐和环状亚碳酸酯制备高分子量聚酯。然后加入催化剂，并按常规进行缩聚反应。获得的聚合物的分子量显着高于省略干燥步骤，并且缩聚期显着缩短。

9. 发明授权

US4003883A Polyesterether having commercially acceptable mold release characteristics 失效
标题翻译：聚酯具有商业上可接受的脱模特性
公开(公告)号：US4003883A
公开(公告)日：1977-01-18
申请号：US626518
申请日：1975-10-28
申请人： David R. Fagerburg , Burns Davis
发明人： David R. Fagerburg , Burns Davis
IPC分类号： C08G63/199 , C08G63/672 , C08G63/12
CPC分类号： C08G63/672 , C08G63/199
摘要： Disclosed is a polyesterether having a critical range of poly(alkylene oxide) glycol. Articles molded from this polyesterether exhibit unobvious mold release characteristics.
摘要翻译：公开了具有聚（环氧烷）二醇的临界范围的聚酯醚。由该聚酯树脂成型的制品表现出不可见的脱模特性。

10. 发明授权

US06254950B1 Polyester phenylenedi (oxyacetic acid) copolyester blends having improved gas barrier properties 失效
标题翻译：具有改进的气体阻隔性能的聚酯亚苯基二（氧乙酸）共聚酯共混物
公开(公告)号：US06254950B1
公开(公告)日：2001-07-03
申请号：US09332829
申请日：1999-06-14
申请人： Martin E. Rogers , Robert B. Barbee , David R. Fagerburg , Timothy E. Long
发明人： Martin E. Rogers , Robert B. Barbee , David R. Fagerburg , Timothy E. Long
IPC分类号： C08L6702
CPC分类号： C08J5/18 , C08J2367/02 , C08L67/02 , C08L67/025 , Y10T428/1352 , Y10T428/1397
摘要： This invention relates to polyester compositions that possess improved gas barrier properties. The novel copolyester blends comprise repeat units of phenylenedi(oxyacetic acid). Such copolyesters with improved gas barrier properties are useful in packaging applications where low gas permeability are required for protection or preservation of the contents.
摘要翻译：本发明涉及具有改善的阻气性的聚酯组合物。新型共聚酯共混物包含亚苯基二（重氮乙酸）的重复单元。具有改善的气体阻隔性能的这种共聚酯可用于需要低气体渗透性以保护或保存内容物的包装应用中。

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