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    • 3. 发明授权
    • Polyester resins useful for forming containers having improved gas
barrier properties
    • 用于形成具有改善的阻气性的容器的聚酯树脂
    • US4546170A
    • 1985-10-08
    • US686504
    • 1984-12-26
    • Robert B. BarbeeBurns Davis
    • Robert B. BarbeeBurns Davis
    • C08G63/672C08G63/16
    • C08G63/672
    • The present invention provides polyester resins useful for forming containers having improved resistance to gas permeability. The polyester resin comprises the reaction product of a diol containing up to about 8 carbon atoms and a diacid component which comprises terephthalic acid and oxydiacetic acid. The oxydiacetic acid is present in a concentration of about 5 to 50 mole percent, based upon the total amount of diacid. The polyester resin has an inherent viscosity of about 0.4 to 1.5. A preferred polyester is that derived from ethylene glycol, terephthalic acid, and about 10 to 40 mole percent oxydiacetic acid. The polyesters which are provided by the present invention may be formed into containers in the form of sheet, film, molded articles, such as bottles, and other such structures.
    • 本发明提供了可用于形成具有改善的耐气体渗透性的容器的聚酯树脂。 聚酯树脂包含含有至多约8个碳原子的二醇的反应产物和包含对苯二甲酸和氧代二乙酸的二酸组分。 氧基二乙酸以基于二酸总量的约5至50摩尔%的浓度存在。 聚酯树脂的特性粘度为约0.4〜1.5。 优选的聚酯是衍生自乙二醇,对苯二甲酸和约10至40摩尔%的氧代二乙酸的聚酯。 由本发明提供的聚酯可以形成为片状,薄膜状,模塑制品,例如瓶子等形式的容器,以及其它这样的结构。
    • 5. 发明授权
    • Copolyesterethers
    • 共聚醚醚共聚酯
    • US4328333A
    • 1982-05-04
    • US257449
    • 1981-04-24
    • Robert B. BarbeeBurns Davis
    • Robert B. BarbeeBurns Davis
    • C08G63/668C08G63/66
    • C08G63/668
    • Disclosed are copolyesterethers that can be formed into bottles, tubing, film and the like having improved clarity. The copolyetheresters have an inherent viscosity of from 0.8 to about 2.0 and compriseA. a dicarboxylic acid component consisting essentially of terephthalic acid and an aliphatic or cycloaliphatic acid, andB. a diol component comprising(1) at least 70 mole percent 1,4-butanediol, and(2) from about 10 to about 60 weight percent, based on the weight of the polyetherester, of polypropyleneether glycol having a molecular weight of 1700 to 2400.
    • 公开了可以形成具有改进的透明度的瓶,管,膜等的共聚酯。 共聚醚酯具有0.8至约2.0的特性粘度,并且包含A.基本上由对苯二甲酸和脂族或脂环族酸组成的二羧酸组分,和B.一种二醇组分,其包含(1)至少70摩尔%的1,4 - 丁二醇,和(2)约10至约60重量%,基于聚醚酯的重量,分子量为1700至2400的聚丙烯醚二醇。
    • 6. 发明授权
    • Process for producing polyetherester elastomer
    • 生产聚醚酯弹性体的方法
    • US4256861A
    • 1981-03-17
    • US106964
    • 1979-12-26
    • Burns DavisRobert B. Barbee
    • Burns DavisRobert B. Barbee
    • C08G63/672C08G63/76
    • C08G63/672
    • Disclosed is a method for producing a relatively high molecular weight copolyester which comprises the steps of(a) melt-phase copolymerizing to an inherent viscosity of about 0.50 to about 1.10 a dibasic acid component and a glycol component, the dibasic acid component consisting essentially of trans-1,4-cyclohexanedicarboxylic acid and the glycol component comprising, from about 97 to about 70 mol percent 1,4-cyclohexanedimethanol, about 3 to about 30 mol percent of a glycol having 2 to 5 carbon atoms and from about 15 to about 80 weight percent of the total polymer of a polyalkyleneether glycol, and(b) solid-phase polymerizing the copolyester from step (a) at a temperature of from about 110.degree. C. to about 200.degree. C. to a higher inherent viscosity of from about 0.60 to about 2.50, the higher inherent viscosity being at least 0.10 higher than the inherent viscosity reached in step (a).Such a process using a particular acid and particular mixture of glycols allows inherent viscosity build-up without use of temperature high enough to cause thermal degradation and the resulting odor and color formation.
    • 公开了一种生产相对高分子量的共聚酯的方法,其包括以下步骤:(a)二元酸组分和二元醇组分的熔融相共聚至约0.50至约1.10的特性粘度,所述二元酸组分基本上由 反式-1,4-环己烷二羧酸和二醇组分,其包含约97至约70摩尔%的1,4-环己烷二甲醇,约3至约30摩尔%的具有2至5个碳原子的二醇和约15至约 聚亚烷基醚二醇的总聚合物的80重量%,和(b)在约110℃至约200℃的温度下将来自步骤(a)的共聚酯固相聚合至较高的 约0.60至约2.50,较高的特性粘度比步骤(a)中达到的特性粘度至少高0.10。 使用特定酸和二醇的特定混合物的这种方法允许特性粘度增加,而不使用高到足以引起热降解和产生的气味和颜色形成的温度。
    • 9. 发明授权
    • Copolyesterethers
    • 共聚醚醚共聚酯
    • US4349469A
    • 1982-09-14
    • US235385
    • 1981-02-17
    • Burns DavisTheodore F. GrayHarry R. Musser
    • Burns DavisTheodore F. GrayHarry R. Musser
    • C08G63/66C08G63/18
    • C08G63/66
    • Disclosed are copolyesterethers having an inherent viscosity of from about 0.8 to about 1.5 comprisingA. a dicarboxylic acid component consisting essentially of 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70%, andB. a glycol component consisting essentially of(1) 1,4-cyclohexanedimethanol, and(2) from about 15 to about 50 weight percent, based on the weight of the polyesterether, of polytetramethyleneether glycol having a molecular weight of about 500 to about 1100,C. from about 0.1 to about 1.5 mole %, based on the mole % of the acid or glycol component, of a branching agent having at least three COOH or OH functional groups and from 3 to 60 carbon atoms,said copolyesterethers being characterized by having a die swell of between about -90% and about +100% and a minimum crystallization time of less than 2.5 minutes.
    • 公开的具有约0.8至约1.5的特性粘度的共聚醚醚醚包括A.基本上由反式异构体含量为至少70%的1,4-环己烷二羧酸组成的二羧酸组分,以及B.一种二醇组分,主要由 (1)1,4-环己烷二甲醇,和(2)约15至约50重量%,基于聚酯醚的重量,分子量为约500至约1100的聚四亚甲基醚二醇,约0.1至 约1.5摩尔%,基于酸或二醇组分的摩尔%,具有至少三个COOH或OH官能团和3-60个碳原子的支化剂,所述共聚醚醚的特征在于具有介于约 -90%和约+ 100%,最小结晶时间小于2.5分钟。